Helium detection as a guide for uranium exploration

Abstract

Helium, a byproduct of radioactive decay, may prove to be a valuable indicator of the presence and distribution of uranium deposits. Recent technological advances permit the development of instrumentation not previously adapted for this purpose. Commercially available equipment can provide high sensitivity at low cost and allow reasonable mobility for field use. A truck-mounted mass-spectrometer, tuned for helium-4, permits immediate adjustment or modification of sampling patterns in response to accumulating data. The inlet system of the spectrometer has been designed to allow flexibility in gas analyses from various sample types--soil gas, atmosphere, or gases in water. Sensitivity of the instrument is better than 50 parts of helium per 10 9 parts of gas. Replicate samples and standards can be analyzed in only 3 minutes. Helium in soil gas is being used for the initial evaluation of the technique. A hollow probe, as much as 2 m long, is driven into the ground; and a 10-cc syringe is used to purge the probe and extract the gas. This sample is then injected into the inlet system and introduced into the spectrometer at constant pressure. The output signal is displayed on a chart recorder. Investigations can be performed on a qualitative, relative basis, or on a quantitative basis by comparison to calibrated helium standards. Preliminary field testing includes studies of the responses to variations in wind speed, temperature, barometric pressure, moisture, and sampling depth over extended time periods, as well as studies of geologic controls on the helium content in soil gas. Surveys over known uranium occurrences reveal some anomalous helium distributions. This report describes an updated technological approach to an old idea: that of using helium, a byproduct of uranium radioactive decay, as an exploration tool for uranium. Helium is the sixth most abundant gas found in the earth's atmosphere (Table 1). It is an inert gas and very mobile, mixing rapidly. When the alpha particles from the radioactive decay of uranium and thorium pick up two electrons, atoms of the isotope helium-4 are formed. Several helium-4 atoms are produced from each decay series of U-238, U-235, and Th-232 (fig. 1). The half-lives of the parent isotopes are5also shown in figure 1. One gram of uranium will produce ~10 5 atoms of helium-4 per second, and one gram of thorium produces ~2.5 x 10 4 atoms of helium-4 per second (fig. 2). Calculations of the helium produced from the crust and mantle reveal that 1,125 x 10 30 atoms per year are produced, but only 7 x 10 30 atoms per year escape from the earth (Damon and Kulp, 1958). More is being produced than is being lost; in fact, the total atmospheric content of helium could be produced in only 2 million years (MacDonald, 1963)! However, all the crustal and mantle helium-4 does not degas into the atmosphere as it is formed. It is trapped in crystal lattices and in pore spaces within the earth. What this means is that there is excess helium-4 in the earth--excess, that is, compared to the atmospheric concentration in equilibrium with the helium-4 escape rate into space and the helium-4 flux from the crust and mantle (Nicolet, 1957). Near-surface pockets of high helium-4 concentrations are known, and some natural gas fields are so enriched that they are the source for commercial production of helium. Work by Roberts and others (1975) has shown high helium concentration in the soil gas associated with geothermal areas; and work by Clark and Kugler (1973), Dyck (1975), and Goldak (1974), for example, has noted high helium concentrations in soils and waters in the vicinity of uranium deposits. These latter studies certainly indicate the potential of helium detection for use as an exploration tool for uranium.