Search USGS⌕ Search
Home/Archive/USGS

USGS · 70268377

Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida

Philip T. Harte·Michael A. Singletary·James E. Landmeyer
View original source ↗Export metadata ↓

Abstract

In-situ chemical oxidation (ISCO) is a common method to remediate chlorinated ethene contaminants in groundwater. Monitoring the effectiveness of ISCO can be hindered because of insufficient observations to assess oxidant delivery. Advantageously, potassium permanganate, one type of oxidant, provides the opportunity to use its strong electrical signal as a surrogate to track oxidant delivery using time-series borehole geophysical methods, like electromagnetic (EM) induction logging. Here we report a passive ISCO (P-ISCO) experiment, using potassium permanganate cylinders emplaced in boreholes, at a chlorinated ethene contamination site, Naval Air Station Pensacola, Florida. The contaminants are found primarily at the base of a shallow sandy aquifer in contact with an underlying silty-clay confining bed. We used results of the time-series borehole logging collected between 2017 and 2022 in 4 monitoring wells to track oxidant delivery. The EM-induction logs from the monitoring wells showed an increase in EM response primarily along the contact, likely from pooling of the oxidant, during P-ISCO treatment in 2021. Interestingly, concurrent natural gamma-ray (NGR) logging showed a decrease in NGR response at 3 of the 4 wells possibly from the formation of manganese precipitates coating sediments. The coupling of time-series logging and well-chemistry data allowed for an improved assessment of passive ISCO treatment effectiveness.

Explore related subjects

Hydrology JournalArticle

Keep this discovery

BibTeXRIS

Philip T. Harte, Michael A. Singletary, James E. Landmeyer. 2025-06-18. Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida. https://doi.org/10.3390/hydrology12060155

Cite the original work for its findings. Save a collection to share your selection of sources.

Discover connections

Florida placeArticle subjectHydrology Journal subjectNAS Pensacola placePensacola placeUnited STates place

Connections use source metadata and explicit phrase matches, not verified experimental comparisons.

KEEP EXPLORING

Related USGS reports

USGS2025

Simulation of the impacts of projected climate change on groundwater resources in the urban, semiarid Yucaipa Valley watershed, southern California using an integrated hydrologic model

Managing water resources in semiarid watersheds is challenging due to limited supply and uncertain future climate conditions. This paper examines the impact of future climate changes on an urban watershed in southern California using an integrated hydrologic model. GSFLOW modeling software is used to simulate the nonlinear relationships between climate trends and precipitation partitioning into ET, runoff, and subsurface storage. Four global circulation models (GCMs), each with two greenhouse-gas scenarios, RCP45 and RCP85 are used to project future climate conditions. GCMs include the CanESM2, CNRM-CM5, HadGEM2-ES, and MIROC5 models. The model's simulated hydrologic conditions are compared with historical data to assess changes in water budgets and groundwater supply. Results indicate decreased groundwater storage in most scenarios due to increased natural evapotranspiration, vegetation consumptive use, and streamflow out of the watershed. Only scenarios with substantially increased future precipitation show increased groundwater storage. The study also highlights increased future aridity despite the rise in precipitation and large precipitation events forecast by GCMs, which increase the risk of urban floods and decrease stream leakage and water available to vegetation.

California↗
USGS2026

Assessing future hydrologic extremes using an integrated hydrology and river operations model in the Russian River watershed

Study region The Russian River watershed, situated in coastal, northern California, experiences hydrologic extremes, including periodic droughts and flooding. Water managers are working to maintain sustainable water supplies and environmental flows, while mitigating flood risks. Study focus This paper introduces an integrated hydrology and river operations model for the Russian River watershed. This model is distinct from models in previous studies because it represents surface-groundwater interactions and uses climate forcings to estimate dynamic water use demands that are superimposed onto both reservoir operations and water supply constraints. The model was used to examine three historical (1990–2015) and eight future (2016–2099) water use and climate change scenarios. New hydrological insights for the region The direct connection between streams and aquifers facilitated both annual aquifer replenishment by high winter streamflows and streamflow depletion by groundwater wells (19 % of pumped groundwater in alluvial aquifers from stream leakage) during critical low flow periods. Simulated streamflow changes included 59 % longer and 54 % more severe streamflow droughts, 26 % lower seasonal low streamflows, and up to 125 % higher peak streamflows, averaged over future climate and water use scenarios, suggesting increased future flood and water availability risks. Results showed the importance of reservoir operations for mitigating the impacts of increased hydroclimatic volatility, despite a decrease in reservoir reliability at Lake Mendocino, suggesting that reservoir management may be used to decrease future risks.

California↗
USGS2025

Hydrologic variability and groundwater age of springs in eastern Oregon and northern Nevada, USA

The ecological importance of springs in semiarid regions is far greater than their small size and sparse distribution, yet little is known about the hydrologic functioning of these systems. During 2016–22, 261 springs were visited in the volcanic terrane of eastern Oregon and northern Nevada. When conditions were suitable, measurements of discharge, water temperature, and specific conductance were made, and samples for the analysis of carbon-14, tritium, and water stable isotopes (WSI) were collected. A subset of 60 springs was revisited during different seasons in the same year and during the dry season in multiple years to evaluate variability in discharge, chemistry, and groundwater age. Specific conductance and WSI varied considerably among springs across the study area but were unexpectedly stable across seasons and years at individual springs. Seasonal and interannual variability in spring discharge was related to the residence time of the discharging groundwater. Springs discharging older groundwater (10 3 –10 4 years) had significantly less variability in their discharge compared to springs discharging younger groundwater (10 0 –10 1 years). Variability among springs discharging younger groundwater included cessation of late-summer discharge at 18 % of the repeat-visit springs. A logistic regression model predicted the age of discharging spring water with 89 % accuracy using only the spring latitude, longitude, elevation, and δ 2 H value. This study framework provides a simple, inexpensive, and robust method to provisionally assess the hydrologic behavior of springs having little or no prior information in understudied, semiarid regions across the globe.

Nevada, Oregon↗