Geology, geochemistry, and fluid-inclusion petrography of the Sapo Alegre porphyry copper prospect and its metavolcanic wallrocks, west-central Puerto Rico

Abstract

The Sapo Alegre prospect, a small porphyry copper-molybdenum occurrence in west-central Puerto Rico, is characterized by distinct zones of alteration and mineralization of quartz diorite porphyry. A biotite-chlorite zone in the porphyry near its contact with surrounding metavolcanic rocks contains copper, molybdenum, gold, silver, selenium, and tellurium. A quartz-sericite-pyrite zone within the porphyry contains abundant sulfur and traces of selenium, but metals of the biotite-chlorite zone are nearly absent and zinc, manganese, nickel, sodium, calcium, and magnesium contents are very low. Quartz grains in the biotite-chlorite zone contain abundant fluid inclusions in which halite crystals are common, whereas in the quartz-sericite-pyrite zone inclusions are less abundant and rarely contain halite inclusions. Metavolcanic rocks northwest of the mineralized porphyry are altered to amphibolitic hornfels near the contact. Biotitic alteration is strong outward from the hornfels and grades into chlorite alteration. The hornfels has very low sulfide content, and the biotite zone has moderate amounts of copper and sulfur, decreasing outward. The chlorite zone is characterized by an abrupt increase in zinc and manganese content. Fluid-inclusion data suggest temperatures between 300° and 400°C for hydrothermal fluids in the biotite-chlorite zone of the porphyry and 250° to 300°C for fluids in the quartz-sericite-pyrite zone. Pressures equivalent to about 1.5 km of burial are indicated.