Coexistence of twisted and untwisted crystals: An impurity/structural order model with implications for agate patterns

J. Comer; P. Ortoleva

doi:10.2138/am.2007.2547

Home/Archive/USGS

USGS · 70031454

Coexistence of twisted and untwisted crystals: An impurity/structural order model with implications for agate patterns

J. Comer·P. Ortoleva

View original source ↗Export metadata ↓

Abstract

Coexistence of twisted and untwisted crystals is explained via a model that accounts for the coupling of the entropic and energetic effects of impurities and a supra-lattice-scale structural order parameter. It is shown that twisted impure crystals can be in equilibrium with untwisted purer ones. The model explains how coexistence can occur in agates and other systems under hydrostatic stress. The model implies that untwisted crystals grown under one set of conditions could undergo a phase separation that, when accompanied by an imposed compositional gradient, leads to commonly observed, alternating bands of twisted and untwisted crystals and, when occurring in the absence of an external gradient, mossy patterns of crystal texture can emerge. This phenomenon is not related to anisotropic applied stress. Rather coexistence is a consequence of a compositional segregation/twist phase transition. Since twist coexistence is a compositional equilibrium, it arises from the exchange between bulk phases; hence, the detailed nature of the atomic structure within an interface between twisted and untwisted zones is not relevant. The approach places crystal-twist phenomena within the theory of order/disorder phase transitions.

Explore related subjects

American Mineralogist Article

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

J. Comer, P. Ortoleva. 2007. Coexistence of twisted and untwisted crystals: An impurity/structural order model with implications for agate patterns. https://doi.org/10.2138/am.2007.2547

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

An assessment of the quality of microanalysis of natural silicate glass using scanning electron microscope-based energy dispersive spectrometry (SEM-EDS)

The composition of volcanic glass records important clues into the origin and evolution of magmatic systems. However, the analysis of volcanic glass presents challenges when performed using electron-beam techniques, particularly due to Na mobility. While microanalysis of geological materials is usually performed using electron probe microanalyzer-based wavelength-dispersive spectrometry (EPMA-WDS), we present here results of glass analysis using energy-dispersive spectrometry with a scanning electron microscope (SEM-EDS). We use three U.S. Geological Survey (USGS) whole-rock reference materials (i.e., RGM-1, STM-1, QLO-1) that were fused into glass using a double-fusion technique. Results for 12 sessions over two months using the SEM-EDS reveal excellent reproducibility, agreement with the expected values for RGM-1 and STM-1, and excellent counting statistics when using live acquisition times of 15 s; results for QLO-1 suggest that the fused material is somewhat inhomogeneous. For longer acquisition times (30, 60, 90 s), significant Na migration is observed; we conclude that minimal Na migration takes place with acquisition times of 15 s using our analytical instrumentation. We also compile data for RGM-1 obtained using the same instrument over the last decade, and we further demonstrate the reliability of SEM-EDS for microanalysis of silicate glasses. Comparison of our results with EPMA-WDS results for a range of reference materials published by researchers at the USGS Alaska Volcano Observatory suggest that both EPMA-WDS and SEM-EDS can yield adequate analysis of volcanic glass, but SEM-EDS can potentially lead to higher precision for major elements (>1 wt.% concentration), while EPMA-WDS typically leads to higher precision for minor elements. The higher precision of SEM-EDS results for major elements, combined with the more widespread distribution, lower usage cost, and higher ease of use of such systems, makes analysis via SEM-EDS an attractive option for measuring major-element compositions of volcanic glass. However, it is critical to test the quality of each instrument given differences in hardware and software between SEM and EDS systems.

American Mineralogist↗

USGS2026

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California↗

USGS2025

Pre-eruptive characteristics of “suspect” silicic magmas in Carlin-type Au-forming systems

World-class Carlin-type Au deposits hosted in sedimentary rock were formed when profuse Eocene silicic magmatism swept across northern Nevada in response to arc migration. Carlin-type Au deposits formed along with porphyry/skarn Cu-Mo-W-Au deposits, epithermal Ag-Au deposits, and distal disseminated Ag-Au deposits. But unlike these other Au-bearing deposits that have clear associations with igneous intrusions, Carlin-type ore deposits appear to have formed distant from concealed plutons, and their origin remains controversial. Despite decades of abundant geophysical, geochronological, and geochemical studies suggesting the involvement of magmas, concrete evidence for magmatic involvement is still lacking. Consequently, the involvement of contemporaneous igneous systems remains inferred based on age, proximity, and variable isotopic, geochemical, and geophysical clues. A recent synthesis of deposit models postulates that Carlin-type Au deposits are intrusion-related, but that the causative magmas reside deeper (∼6–12 km) than in typical porphyry and peripheral systems (∼3–5 km), meaning that Carlin-type deposits are perhaps more distal expressions of igneous intrusions. We investigate a collection of “suspect” magmatic systems over a ∼7 m.y. timespan (∼41–34 Ma) that are contemporaneous with and near known Carlin-type ore deposits. We report results of a multifaceted array of in situ geochemical analyses (FTIR, EMP, SHRIMP-RG, LA-ICP-MS) of quartz-hosted melt inclusions, biotite, and quartz to better characterize the pre-eruptive characteristics of these magmas. We also report results of thermobarometry and thermodynamic phase equilibria modeling to help place constraints on magmatic reservoir depths and processes. Rather than a single “flavor” of silicic magma, we observe a surprisingly broad compositional spectrum of rhyolites, with one end of the spectrum exhibiting more arc-like (I-type) characteristics and the other end displaying more post-subduction, thick-crust extensional (A-type) characteristics. This broad compositional spectrum suggests a more complex picture of silicic crustal magmatism operating over a narrow span of time during slab rollback. Despite this spectrum, magmatic systems in this study are consistently ferroan and generally peraluminous, which we interpret as an expression of the relatively elevated geotherm at the time and incorporation of variable amounts of highly peraluminous metasedimentary crustal components. The silicic magma spectrum encompasses a range of mineralization associations, including subduction-related Cu-Mo-W-Au-Ag and post-subduction, thick-crust extensional rare-metal Mo-Sn-W-F-Be-Ag-Au, consistent with the prolific and diverse array of ore deposits that formed during this time. Carlin-type Au deposition appears to be associated with nearly the entire magmatic spectrum. This apparent indifference to silicic magma “flavor” would seem to imply that if magmas are involved in Carlin-type Au deposit genesis, they perhaps do not need to be compositionally specialized and/or possibly are only relevant as heat sources driving circulation to remobilize and redistribute metals.

Nevada↗