Geobarometry of ultramafic xenoliths from Loihi Seamount, Hawaii, on the basis of CO2 inclusions in olivine

Abstract

Abundant fluid inclusions in olivine of dunite xenoliths (∼1–3 cm) in basalt dredged from the young Loihi Seamount, 30 km southeast of Hawaii, are evidence for three coexisting immiscible fluid phases—silicate melt (now glass), sulfide melt (now solid), and dense supercritical CO 2 (now liquid + gas)—during growth and later fracturing of some of these olivine crystals. Some olivine xenocrysts, probably from disaggregation of xenoliths, contain similar inclusions. Most of the inclusions (2–10 μm) are on secondary planes, trapped during healing of fractures after the original crystal growth. Some such planes end abruptly within single crystals and are termed pseudosecondary, because they formed during the growth of the host olivine crystals. The “vapor” bubble in a few large (20–60 μm), isolated, and hence primary, silicate melt inclusions is too large to be the result of simple differential shrinkage. Under correct viewing conditions, these bubbles are seen to consist of CO 2 liquid and gas, with an aggregate ϱ = ∼ 0.5–0.75 g cm −3 , and represent trapped globules of dense supercritical CO 2 (i.e., incipient “vesiculation” at depth). Some spinel crystals enclosed within olivine have attached CO 2 blebs. Spherical sulfide blebs having widely variable volume ratios to CO 2 and silicate glass are found in both primary and pseudosecondary inclusions, demonstrating that an immiscible sulfide melt was also present. Assuming olivine growth at ∼ 1200°C and hydrostatic pressure from a liquid lava column, extrapolation of CO 2 P-V-T data indicates that the primary inclusions were trapped at ∼ 220–470 MPa (2200–4700 bars), or ∼ 8–17 km depth in basalt magma of ϱ = 2.7 g cm −3 . Because the temperature cannot change much during the rise to eruption, the range of CO 2 densities reveals the change in pressure from that during original olivine growth to later deformation and rise to eruption on the sea floor. The presence of numerous decrepitated inclusions indicates that the inclusion sample studied is biased by the loss of higher-density inclusions and suggests that some part of these olivine xenoliths formed at greater depths.