Geology topics

Research about Sleepers River Research Watershed

Source-linked reports with geographic coverage including Sleepers River Research Watershed.

5 recordsLinked to original sources

USGS2022

Optical properties of dissolved organic matter in throughfall and stemflow vary across tree species and season in a temperate headwater forest

Tree-derived dissolved organic matter (DOM) comprises a significant carbon flux within forested watersheds. Few studies have assessed the optical properties of tree-derived DOM. To increase understanding of the factors controlling tree-derived DOM quality, we measured DOM optical properties, dissolved organic carbon (DOC) and calcium concentrations in throughfall and stemflow for 17 individual rain events during summer and fall in a temperate deciduous forest in Vermont, United States. DOC and calcium fluxes in throughfall and stemflow were enriched on average 4 to 70 times incident fluxes in rain. A multiway model was developed using absorbance and fluorescence spectroscopy to further characterize DOM optical properties. Throughfall contained a higher percentage of protein-like DOM fluorescence than stemflow while stemflow was characterized by a higher percentage of humic-like DOM fluorescence. DOM absorbance spectral slopes in yellow birch ( Betula alleghaniensis ) stemflow were significantly higher than in sugar maple ( Acer saccharum ) stemflow. DOM optical metrics were not influenced by rainfall volume, but percent protein-like fluorescence increased in throughfall during autumn when leaves senesced. Given the potential influence of tree-derived DOM fluxes on receiving soils and downstream ecosystems, future modeling of DOM transport and soil biogeochemistry should represent the influence of differing DOM quality in throughfall and stemflow across tree species and seasons.

Vermont↗

USGS2022

Using dissolved organic matter fluorescence to predict total mercury and methylmercury in forested headwater streams, Sleepers River, Vermont USA

Aqueous transport of mercury (Hg) across the landscape is closely linked to dissolved organic matter (DOM). Both quantity and quality of DOM affect Hg mobility, as well as the formation and transport of toxic methylmercury (MeHg), but only a limited number of field studies have investigated Hg and MeHg with respect to specific DOM components. We investigated these interactions at the 41-ha forested W-9 catchment at Sleepers River, Vermont, which has a long history of mercury and other biogeochemical research. We examined spatial and temporal patterns of filtered Hg fractions and dissolved organic carbon (DOC) concentration, DOM quality, and major solutes at 12 stream sites within W-9 and the downstream W-3 gage (837 ha) over five sampling campaigns including a large (79 mm) fall storm, spring snowmelt, and three seasonally contrasting base flow periods. Filtered total Hg (THg), MeHg, and DOC concentrations increased in order base flow < snowmelt < fall storm, except that MeHg remained at baseflow levels during snowmelt. Ranges of median concentrations across sites for the five campaigns were THg, <0.2–4.1 ng L −1 ; MeHg, <0.03–0.45 ng L −1 ; and DOC, 0.8–14.0 mg L −1 . Humic-like DOM fluorescence components, as determined by parallel factor analysis (PARAFAC), dominated the fluorescence across sites and sampling campaigns. THg correlated strongly ( r > 0.94) with these humic components, but even more strongly with bulk DOC and absorbance at 254 nm (UV 254 ; r > 0.96), and less strongly with protein-like DOM (0.7 < r < 0.9). MeHg correlated in the same order but less strongly with humic- (0.8 < r < 0.9) and protein-like (0.6 < r < 0.8) DOM. MeHg increased in summer, potentially in response to enhanced microbial production in warmer periods. MeHg formation may have been linked to protein-like DOM, but its transport was linked to humic-like DOM.

Vermont↗

USGS2021

Event scale relationships of DOC and TDN fluxes in throughfall and stemflow diverge from stream exports in a forested catchment

Aquatic fluxes of carbon and nutrients link terrestrial and aquatic ecosystems. Within forests, storm events drive both the delivery of carbon and nitrogen to the forest floor and the export of these solutes from the land via streams. To increase understanding of the relationships between hydrologic event character and the relative fluxes of carbon and nitrogen in throughfall, stemflow and streams, we measured dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) concentrations in each flow path for 23 events in a forested watershed in Vermont, USA. DOC and TDN concentrations increased with streamflow, indicating their export was limited by water transport of catchment stores. DOC and TDN concentrations in throughfall and stemflow decreased exponentially with increasing precipitation, suggesting that precipitation removed a portion of available sources from tree surfaces during the events. DOC and TDN fluxes were estimated for 76 events across a 2-year period. For most events, throughfall and stemflow fluxes greatly exceeded stream fluxes, but the imbalance narrowed for larger storms (>30 mm). The largest 10 stream events exported 40% of all stream event DOC whereas those same 10 events contributed 14% of all throughfall export. Approximately 2–5 times more DOC and TDN was exported from trees during rain events than left the catchment via streams annually. The diverging influence of event size on tree versus stream fluxes has important implications for forested ecosystems as hydrological events increase in intensity and frequency due to climate change.

Vermont↗

USGS2019

Soil aggregates as a source of dissolved organic carbon to streams: An experimental study on the effect of solution chemistry on water extractable carbon

Over the past two decades, headwater streams of the northern hemisphere have shown increased amounts of dissolved organic carbon (DOC), coinciding with decreased acid deposition. The exact nature of the mechanistic link between precipitation composition and stream water DOC is still widely debated in the literature. We hypothesize that soil aggregates are the main source of stream water DOC and that DOC release is greater in organic rich, riparian soils vs. hillslope soils. To test these hypotheses, we collected soils from two main landscape positions (hillslope and riparian zones) from the acid-impacted Sleepers River Research Watershed in northeastern Vermont. We performed aqueous soil extracts with solutions of different ionic strength (IS) and composition to simulate changes in soil solution. We monitored dynamic changes in soil particle size, aggregate architecture and composition, leachate DOC concentrations, dissolved organic matter (DOM) characteristics by fluorescence spectroscopy and trends in bioavailability. In low IS solutions, extractable DOC concentrations were significantly higher, particle size (by laser diffraction) was significantly smaller and organic material was separated from mineral particles in scanning electron microscope observations. Furthermore, higher DOC concentrations were found in Na + compared to Ca 2+ solutions of the same IS. These effects are attributed to aggregate dispersion due to expanding diffuse double layers in decreased IS solutions and to decreased bridging by divalent cations. Landscape position impacted quality but not quantity of released DOC. Overall, these results indicate that soil aggregates might be one important link between Critical Zone inputs (i.e., precipitation) and exports in streams.

Vermont↗

USGS2003

Shallow water table fluctuations in relation to soil penetration resistance

Hydrologic modeling of catchments is frequently hampered by lack of information on subsurface stratigraphy and zones of preferred flow. We evaluated the usefulness of soil penetration resistance, easily measured by a dynamic cone penetrometer, together with measurements of ground water level fluctuations, as a cost-effective means to infer subsurface flow patterns. At our field site at Sleepers River, Vermont, penetration resistance was lowest in the surficial 10 to 30 cm, then typically increased to a local maximum at 60 to 80 cm, which we interpreted as the soil/till interface. Below this depth usually lies a zone of decreased resistance in the till, giving way to either a gradual or abrupt increase in resistance toward the bedrock surface at 1 to 4.5 m depth. Penetration resistance had a weak but significant negative correlation with saturated hydraulic conductivity determined by bail tests (r 2 = 0.25, p < 0.05). At many wells, monthly ground water levels tended to cluster at or just above the resistant zone near the soil/till interface. Chemical and isotopic dynamics in nested wells finished above and below the resistant zone suggest that the zone may temporarily isolate the deeper ground water reservoir from meltwater inputs, which were clearly identified by low δ 18 O values. In ground water discharge zones, δ 18 O values tended to converge throughout the profile. In contrast, dissolved organic carbon (DOC) maintained a gradient of increasing concentration toward land surface, even in otherwise well-mixed waters, reflecting its rapid release from organic horizons. Understanding the effect of soil penetration resistance on ground water behavior may be useful in future catchment modeling efforts.

Vermont↗