Geology topics

Research about Schuylkill River

Source-linked reports with geographic coverage including Schuylkill River.

3 recordsLinked to original sources

USGS2015

Monitoring, field experiments, and geochemical modeling of Fe(II) oxidation kinetics in a stream dominated by net-alkaline coal-mine drainage, Pennsylvania, USA

Watershed-scale monitoring, field aeration experiments, and geochemical equilibrium and kinetic modeling were conducted to evaluate interdependent changes in pH, dissolved CO 2 , O 2 , and Fe(II) concentrations that typically take place downstream of net-alkaline, circumneutral coal-mine drainage (CMD) outfalls and during aerobic treatment of such CMD. The kinetic modeling approach, using PHREEQC, accurately simulates observed variations in pH, Fe(II) oxidation, alkalinity consumption, and associated dissolved gas concentrations during transport downstream of the CMD outfalls (natural attenuation) and during 6-h batch aeration tests on the CMD using bubble diffusers (enhanced attenuation). The batch aeration experiments demonstrated that aeration promoted CO 2 outgassing, thereby increasing pH and the rate of Fe(II) oxidation. The rate of Fe(II) oxidation was accurately estimated by the abiotic homogeneous oxidation rate law −d[Fe(II)]/d t = k 1 ·[O 2 ]·[H + ] − 2 ·[Fe(II)] that indicates an increase in pH by 1 unit at pH 5–8 and at constant dissolved O 2 (DO) concentration results in a 100-fold increase in the rate of Fe(II) oxidation. Adjusting for sample temperature, a narrow range of values for the apparent homogeneous Fe(II) oxidation rate constant ( k 1 ′) of 0.5–1.7 times the reference value of k 1 = 3 × 10 −12 mol/L/min (for pH 5–8 and 20 °C), reported by Stumm and Morgan (1996), was indicated by the calibrated models for the 5-km stream reach below the CMD outfalls and the aerated CMD. The rates of CO 2 outgassing and O 2 ingassing in the model were estimated with first-order asymptotic functions, whereby the driving force is the gradient of the dissolved gas concentration relative to equilibrium with the ambient atmosphere. Although the progressive increase in DO concentration to saturation could be accurately modeled as a kinetic function for the conditions evaluated, the simulation of DO as an instantaneous equilibrium process did not affect the model results for Fe(II) or pH. In contrast, the model results for pH and Fe(II) were sensitive to the CO 2 mass transfer rate constant ( k L , CO2 a). The value of k L , CO2 a estimated for the stream (0.010 min −1 ) was within the range for the batch aeration experiments (0–0.033 min −1 ). These results indicate that the abiotic homogeneous Fe(II) oxidation rate law, with adjustments for variations in temperature and CO 2 outgassing rate, may be applied to predict changes in aqueous iron and pH for net-alkaline, ferruginous waters within a stream (natural conditions) or a CMD treatment system (engineered conditions).

Pennsylvania↗

USGS2013

Surface-water and groundwater interactions in an extensively mined watershed, upper Schuylkill River, Pennsylvania, USA

Streams crossing underground coal mines may lose flow, while abandoned mine drainage (AMD) restores flow downstream. During 2005-12, discharge from the Pine Knot Mine Tunnel, the largest AMD source in the upper Schuylkill River Basin, had near-neutral pH and elevated concentrations of iron, manganese, and sulfate. Discharge from the tunnel responded rapidly to recharge but exhibited a prolonged recession compared to nearby streams, consistent with rapid infiltration and slow release of groundwater from the mine. Downstream of the AMD, dissolved iron was attenuated by oxidation and precipitation while dissolved CO 2 degassed and pH increased. During high-flow conditions, the AMD and downstream waters exhibited decreased pH, iron, and sulfate with increased acidity that were modeled by mixing net-alkaline AMD with recharge or runoff having low ionic strength and low pH. Attenuation of dissolved iron within the river was least effective during high-flow conditions because of decreased transport time coupled with inhibitory effects of low pH on oxidation kinetics. A numerical model of groundwater flow was calibrated using groundwater levels in the Pine Knot Mine and discharge data for the Pine Knot Mine Tunnel and the West Branch Schuylkill River during a snowmelt event in January 2012. Although the calibrated model indicated substantial recharge to the mine complex took place away from streams, simulation of rapid changes in mine pool level and tunnel discharge during a high flow event in May 2012 required a source of direct recharge to the Pine Knot Mine. Such recharge produced small changes in mine pool level and rapid changes in tunnel flow rate because of extensive unsaturated storage capacity and high transmissivity within the mine complex. Thus, elimination of stream leakage could have a small effect on the annual discharge from the tunnel, but a large effect on peak discharge and associated water quality in streams.

Pennsylvania↗

USGS1966

Extent and frequency of inundation of Schuylkill River flood plain from Conshohocken to Philadelphia, Pennsylvania

Information on flood conditions plays an important part in the development and use of river valleys. This report presents maps, profiles, and flood-frequency relations developed from past flood experience on the Schuylkill River from Conshohocken to Philadelphia, Pa. The maps and profiles are used to define the areal extent and depth of flooding of the August 24, 1933, and August 19, 1955, floods. The flood of October 4, 1869, which is the greatest flood known on the lower Schuylkill River, is presented on the flood profile and on the ten cross sections. The area inundated by the 1869 flood is not defined because insufficient data are available and because hydrologic and hydraulic conditions have undoubtedly changed to such an extent that such a definition would have little present significance. The basic flood data were prepared to aid individuals, organizations, and governmental agencies in making sound decisions for the safe and economical development of the lower Schuylkill River valley. Recommendations for land use, or suggestions for limitations of land use, are not made in this report. The responsibility for planning for the optimum land use in the flood plain and the implementation of flood-plain regulations to achieve such optimum use rests with the State and local interests. The preparation of this report was undertaken after consultation with representatives of the Philadelphia City Planning Commission and the Montgomery County Planning Commission who expressed the need for flood-plain information and their willingness to consider floodplain regulations. The area covered by this report extends downstream along the Schuylkill River from Plymouth Dam in Conshohocken to the mouth of Wissahickon Creek in Philadelphia. Flooding along Wissahickon Creek is not included in the report. The reach studied extends from 13.0 miles to 21.0 miles upstream from the river mouth. All river distances used in the report are river miles upstream from the mouth of the Schuylkill River as used by the Corps of Engineer, U.S. Army and by the U.S. Geological Survey (Bogart, 1960, p. 194). For the convenience of users a tabulation of river miles of selected points upstream from the mouth of the Schuylkill River is included at the end of this report (table 1).

Pennsylvania↗