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Research about Red River

Source-linked reports with geographic coverage including Red River.

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Water-quality trends for selected sites and constituents in the international Red River of the North Basin, Minnesota and North Dakota, United States, and Manitoba, Canada, 1970–2017

A comprehensive study to evaluate water-quality trends, while considering natural hydroclimatic variability, in the Red River of the North Basin and assess water-quality conditions for the Red River of the North crossing the international boundary near Emerson, Manitoba, Canada (the binational site), was completed by the U.S. Geological Survey in cooperation with the International Joint Commission, North Dakota Department of Environmental Quality, and Minnesota Pollution Control Agency and in collaboration with Manitoba Sustainable Development and Environment and Climate Change Canada. The international Red River of the North Basin encompasses 3 U.S. States (South Dakota, North Dakota, and Minnesota) and 1 Canadian Province (Manitoba). Water quality in the Red River of the North Basin is of concern for both Federal governments and State and Provincial governments. Water-quality objectives have been previously established for selected dissolved ions and recently (2019) proposed for selected nutrients for the binational site. In the current (2020) study, water-quality data from State, Provincial, and Federal agencies in the United States and Canada for sites in the Red River of the North Basin from 1970 to 2017 were compiled and used for trend analysis. Trend analysis using a water-quality dataset from multiple agencies that collect water-quality data for various objectives presented multiple challenges. The trend-analysis approach was able to accommodate differences in water-quality data caused by field-collection and laboratory-analytical method differences, disparities in sampling frequencies, and spatial and temporal gaps in data. Most of these challenges were overcome by the statistical tool, R–QWTREND, which identifies trends in concentration unrelated to variability in streamflow. The integrated basin approach used in the current study, combined with comparing current data trends with historical trends, provided valuable insights into understanding how water quality is changing spatially (34 sites analyzed for a recent period, 2000–15) and temporally (5 sites analyzed for a 45-year historical period, 1970–2015) within the Red River of the North Basin. One of the most consistent spatial and temporal changes observed in the current study was increasing concentrations of sulfate among tributary and main-stem sites since 2000. For some sites, increases were detected starting as early as 1985. Total dissolved solids and chloride concentrations had spatial and temporal patterns like sulfate. Although R–QWTREND removes the variability in constituent concentration caused by natural streamflow variability, all variability in sulfate caused by hydroclimatic variability may not be captured because of changes in hydrologic pathways and changes in the contributions of sulfate from various natural sources. Nutrient concentrations demonstrated less consistent spatial and temporal changes than sulfate, and changes in nutrient concentrations were assumed to be more closely tied to human-induced rather than natural changes. Nitrate-plus-nitrite concentrations were mostly increasing in the upper Red River of the North subbasin, and for nitrate plus nitrite and total nitrogen, the Sheyenne River subbasin had consistent decreasing concentrations. Since 2000, total phosphorus has decreased in the upper Red River of the North subbasin, but total phosphorus concentration has increased for sites in the lower Red River of the North subbasin, and for some main-stem sites, concentrations have been increasing since 1985. Unlike sulfate, the pattern in historical trends for total phosphorus for the main-stem sites differed from tributary sites, indicating that human-induced changes affected tributaries and main-stem sites differently. The more detailed evaluation of flow-averaged water-quality conditions for the binational site provided an understanding of how loads have changed over time and what proportion of the year and season concentrations are expected to exceed water-quality objectives. In a basin with highly variable streamflow like the Red River of the North, the trend in flow-averaged load (assuming streamflow conditions are the same year after year) provided a robust measure of change over time. Increasing concentrations of sulfate, chloride, total dissolved solids, and total phosphorus since 1985 for the binational site resulted in longer periods of exceedance of water-quality objectives per year occurring over time. For total nitrogen, decreasing concentrations resulted in shorter periods of exceedance per year during 1980 to 2015, but concentrations were still expected to exceed the water-quality objective about half the year. Periods of when exceedances were likely to occur during the year were affected by the source and transport mechanisms of the constituent. Trend results from this effort identified how water quality has changed across the basin, and further investigation would help to identify causes for the trends observed here. Information from the current study provides a basis for future trend attribution studies, evaluation of water-quality objectives, and development of comprehensive strategies for reducing nutrients to desired targets and establishes a baseline for tracking future progress in the Red River of the North Basin.

Minnesota, North Dakota, South Dakota, Manitoba

Bromide, Chloride, and Sulfate Concentrations and Loads at U.S. Geological Survey Streamflow-Gaging Stations 07331600 Red River at Denison Dam, 07335500 Red River at Arthur City, and 07336820 Red River near DeKalb, Texas, 2007-09

The U.S. Geological Survey, in cooperation with the City of Dallas Water Utilities Division, did a study to characterize bromide, chloride, and sulfate concentrations and loads at three U.S. Geological Survey streamflow-gaging stations on the reach of the Red River from Denison Dam, which impounds Lake Texoma, to the U.S. Highway 259 bridge near DeKalb, Texas. Bromide, chloride, and sulfate concentrations and loads were computed for streamflow-gaging stations on the study reach of the Red River. Continuous streamflow and specific conductance data and discrete samples for bromide, chloride, sulfate, and specific conductance were collected at three main-stem streamflow-gaging stations on the Red River: 07331600 Red River at Denison Dam near Denison, Texas (Denison Dam gage), 07335500 Red River at Arthur City, Texas (Arthur City gage), and 07336820 Red River near DeKalb, Texas (DeKalb gage). At each of these streamflow-gaging stations, discrete water-quality data were collected during January 2007-February 2009; continuous water-quality data were collected during March 2007-February 2009. Two periods of high flow resulted from floods during the study; floods during June-July 2007 resulted in elevated flow during June-September 2007 and smaller floods during March-April 2008 resulted in elevated flow during March-April 2008. Bromide, chloride, and sulfate concentrations in samples collected at the three gages decreased downstream. Median bromide concentrations ranged from 0.32 milligram per liter at the Denison Dam gage to 0.19 milligram per liter at the DeKalb gage. Median chloride concentrations ranged from 176 milligrams per liter at the Denison Dam gage to 108 milligrams per liter at the DeKalb gage, less than the 300-milligrams per liter secondary maximum contaminant level established by the Texas Commission on Environmental Quality. Median sulfate concentrations ranged from 213 milligrams per liter at the Denison Dam gage to 117 milligrams per liter at the DeKalb gage, also less than the 300-milligrams per liter secondary maximum contaminant level. Kruskal-Wallis analyses indicated statistically significant differences among bromide, chloride, and sulfate concentrations at the three gages. Regression equations to estimate bromide, chloride, and sulfate loads were developed for each of the three gages. The largest loads were estimated for a period of relatively large streamflow, June-September 2007, when about 50 percent of the load for the study period occurred at each gage. Adjusted R-squared values were largest for regression equations for the DeKalb gage, ranging from .957 for sulfate to .976 for chloride. Adjusted R-squared values for all regression equations developed to estimate loads of bromide, chloride, and sulfate at the three gages were .899 or larger.

Oklahoma, Texas

Questa baseline and pre-mining ground-water quality investigation. 23. Quantification of mass loading from mined and unmined areas along the Red River, New Mexico

Along the course of the Red River, between the town of Red River, New Mexico, and the U.S. Geological Survey streamflow-gaging station near Questa, New Mexico, there are several catchments that contain hydrothermally altered bedrock. Some of these alteration zones have been mined and others have not, presenting an opportunity to evaluate differences that may exist in the mass loading of metals from mined and unmined sections. Such differences may help to define pre-mining conditions. Spatially detailed chemical sampling at stream and inflow sites occurred during low-flow conditions in 2001 and 2002, and during the synoptic sampling, stream discharge was calculated by tracer dilution. Discharge from most catchments, particularly those with alteration scars, occurred as ground water in large debris fans, which generally traveled downstream in an alluvial aquifer until geomorphic constraints caused it to discharge at several locations along the study reach. Locations of discharge zones were indicated by the occurrence of numerous inflows as seeps and springs. Inflows were classified into four groups, based on differences in chemical character, which ranged from near-neutral water showing no influence of mining or alteration weathering to acidic water with high concentrations of metals and sulfate. Acidic, metal-rich inflows occurred from mined and unmined areas, but the most-acidic inflow water that had the highest concentrations of metals and sulfate only occurred downstream from the mine. Locations of ground-water inflow also corresponded to substantial changes in stream chemistry and mass loading of metals and sulfate. The greatest loading occurred in the Cabin Springs, Thunder Bridge, and Capulin Canyon sections, which all occur downstream from the mine. A distinct chemical character and substantially greater loading in water downstream from the mine suggest that there could be impacts from mining that can be distinguished from the water draining from unmined areas.

New Mexico

Questa baseline and pre-mining ground-water quality investigation. 12. Geochemical and reactive-transport modeling based on tracer injection-synoptic sampling studies for the Red River, New Mexico, 2001-2002

Reactive-transport processes in the Red River, downstream from the town of Red River in north-central New Mexico, were simulated using the OTEQ reactive-transport model. The simulations were calibrated using physical and chemical data from synoptic studies conducted during low-flow conditions in August 2001 and during March/April 2002. Discharge over the 20-km reach from the town of Red River to the USGS streamflow-gaging station near the town of Questa ranged from 395 to 1,180 L/s during the 2001 tracer and from 234 to 421 L/s during the 2002 tracer. The pH of the Red River ranged from 7.4 to 8.5 during the 2001 tracer and from 7.1 to 8.7 during the 2002 tracer, and seep and tributary samples had pH values of 2.8 to 9.0 during the 2001 tracer and 3.8 to 7.2 during the 2002 tracer. Mass-loading calculations allowed identification of several specific locations where elevated concentrations of potential contaminants entered the Red River . These locations, characterized by features on the north side of the Red River that are known to be sources of low-pH water containing elevated metal and sulfate concentrations, are: the initial 2.4 km of the study reach, including Bitter Creek, the stream section from 6.2 to 7.8 km, encompassing La Bobita well and the Hansen debris fan, Sulphur Gulch, at about 10.5 km, the area near Portal Springs, from 12.2 to 12.6 km, and the largest contributors of mass loading, the 13.7 to 13.9 km stream section near Cabin Springs and the 14.7 to 17.5 km stream section from Shaft Spring to Thunder Bridge, Goathill Gulch, and Capulin Canyon. Speciation and saturation index calculations indicated that although solubility limits the concentration of aluminum above pH 5.0, at pH values above 7 and aluminum concentrations below 0.3 mg/L inorganic speciation and mineral solubility controls no longer dominate and aluminum-organic complexing may occur. The August 2001 reactive-transport simulations included dissolved iron(II) oxidation, constrained using measured concentrations of dissolved iron(II) and dissolved iron(total). Both simulations included precipitation of amorphous Al(OH) 3 and hydrous ferric oxide as Fe(OH) 3 , and sorption of copper and zinc to the precipitated hydrous ferric oxide. Simulations revealed that hydrogen, iron, aluminum, copper, and zinc were non-conservative and that mineral precipitation can account for iron and aluminum concentrations. Copper and zinc concentrations can be accounted for by simulating their sorption to hydrous ferric oxide forming in the water column of the Red River , although hydrous manganese oxides also may be important sorption substrates.

New Mexico

Questa baseline and pre-mining ground-water quality investigation. 1. Depth to bedrock determinations using shallow seismic data acquired in the Straight Creek drainage near Red River, New Mexico

In late May and early June of 2002, the U.S. Geological Survey (USGS) acquired four P-wave seismic profiles across the Straight Creek drainage near Red River, New Mexico. The data were acquired to support a larger effort to investigate baseline and pre-mining ground-water quality in the Red River basin (Nordstrom and others, 2002). For ground-water flow modeling, knowledge of the thickness of the valley fill material above the bedrock is required. When curved-ray refraction tomography was used with the seismic first arrival times, the resulting images of interval velocity versus depth clearly show a sharp velocity contrast where the bedrock interface is expected. The images show that the interpreted buried bedrock surface is neither smooth nor sharp, but it is clearly defined across the valley along the seismic line profiles. The bedrock models defined by the seismic refraction images are consistent with the well data.

New Mexico

Questa baseline and pre-mining ground-water quality investigation. 2. Low-flow (2001) and snowmelt (2002) synoptic/tracer water chemistry for the Red River, New Mexico

Water analyses are reported for 259 samples collected from the Red River, New Mexico, and its tributaries during low-flow(2001) and spring snowmelt (2002) tracer studies. Water samples were collected along a 20-kilometer reach of the Red River beginning just east of the town of Red River and ending at the U.S. Geological Survey streamflow-gaging station located east of Questa, New Mexico. The study area was divided into three sections where separate injections and synoptic sampling events were performed during the low-flow tracer study. During the spring snowmelt tracer study, three tracer injections and synoptic sampling events were performed bracketing the areas with the greatest metal loading into the Red River as determined from the low-flow tracer study. The lowflow tracer synoptic sampling events were August 17, 20, and 24, 2001. The synoptic sampling events for the spring snowmelt tracer were March 30, 31, and April 1, 2002. Stream and large inflow water samples were sampled using equal-width and depth-integrated sampling methods and composited into half-gallon bottles. Grab water samples were collected from smaller inflows. Stream temperatures were measured at the time of sample collection. Samples were transported to a nearby central processing location where pH and specific conductance were measured and the samples processed for chemical analyses. Cations, trace metals, iron redox species, and fluoride were analyzed at the U.S. Geological Survey laboratory in Boulder, Colorado. Cations and trace metal concentrations were determined using inductively coupled plasma-optical emission spectrometry and graphite furnace atomic absorption spectrometry. Arsenic concentrations were determined using hydride generation atomic absorption spectrometry, iron redox species were measured using ultraviolet-visible spectrometry, and fluoride concentrations were determined using an ion-selective electrode. Alkalinity was measured by automated titration, and sulfate, chloride, and bromide were analyzed by ion chromatography at the U.S. Geological Survey laboratory in Salt Lake City, Utah.

New Mexico

Gaged and estimated monthly streamflow during 1931-84 for selected sites in the Red River of the North basin in North Dakota and Minnesota

Operation of the Garrison Diversion Unit in North Dakota may have various effects on the quantity and quality of streamflow in the Sheyenne River and the Red River of the North. To model the effects that the Garrison Diverson Unit could have on water quantity, monthly gaged and estimated streamflow data and estimated unregulated streamflow data were compiled to develop a complete monthly streamflow record for January 1931 through December 1984 (data-development period) for 29 sites in the Red River of the North basin. Gaged streamflow records were available for January 1931 through December 1984 for only 4 sites; no records or records of various length were available for the remaining 25 sites. Drainage-area ratio and Maintenance of Variance Extension Type 1 methods were used to estimate the streamflow for those sites that had no streamflow record or had a streamflow record available for only part of the data-development period. Unregulated streamflow for the 29 sites was estimated by removing the hydrologic effects of Lake Ashtabula, which is formed behind Baldhill Dam on the Sheyenne River, and surface-water withdrawals. VIater-balance procedures were used to remove the hydrologic effects of Lake Ashtabula from the streamflow record for sites downstream of Baldhill Dam. Mean annual gaged streamflow for the Sheyenne River below Baldhill Dam was 9,175 acre-feet less than mean annual estimated unregulated streamflow for 1950-84, when Baldhill Dam was in operation. Net evaporation losses from Lake Ashtabula account for most of the difference between gaged streamflow and estimated unregulated streamflow.

Minnesota, North Dakota