Search USGS⌕ Search

Geology topics

Research about Poland

Source-linked reports with geographic coverage including Poland.

6 recordsLinked to original sources
USGS2016

Significance of groundwater discharge along the coast of Poland as a source of dissolved metals to the southern Baltic Sea

Fluxes of dissolved trace metals (Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn) via groundwater discharge along the southern Baltic Sea have been assessed for the first time. Dissolved metal concentrations in groundwater samples were less variable than in seawater and were generally one or two orders of magnitude higher: Cd (2.1–2.8 nmol L − 1 ), Co (8.70–8.76 nmol L − 1 ), Cr (18.1–18.5 nmol L − 1 ), Mn (2.4–2.8 μmol L − 1 ), Pb (1.2–1.5 nmol L − 1 ), Zn (33.1–34.0 nmol L − 1 ). Concentrations of Cu (0.5–0.8 nmol L − 1 ) and Ni (4.9–5.8 nmol L − 1 ) were, respectively, 32 and 4 times lower, than in seawater. Groundwater-derived trace metal fluxes constitute 93% for Cd, 80% for Co, 91% for Cr, 6% for Cu, 66% for Mn, 4% for Ni, 70% for Pb and 93% for Zn of the total freshwater trace metal flux to the Bay of Puck. Groundwater-seawater mixing, redox conditions and Mn-cycling are the main processes responsible for trace metal distribution in groundwater discharge sites.

Baltic Sea↗
USGS2008

The effect of acid rain and altitude on concentration, δ34S, and δ18O of sulfate in the water from Sudety Mountains, Poland

The analyses of sulfate content, δ 34 S and δ 18 O of dissolved sulfate, and δ 18 O of water were carried out in a 14 km 2 crystalline massif located in the Sudety Mountains (SW Poland) to 1) assess the amount of the sulfate delivered to the surface and groundwater systems by modern atmospheric precipitation, 2) determine the effect of altitude on these parameters, and 3) investigate their seasonal variations. In April and November of 2002, August 2003, and March and September of 2005, samples of water were collected from springs and streams of the massif. During these seasons, sulfate contents and δ 18 O(SO 4 2− ) values varied from 5.80 to 18.00 mg/l and from 3.96 to 8.23‰, respectively, showing distinctively higher values of δ 18 O(SO 4 2− ) in wet seasons. The δ 34 S(SO 4 2− ) values had a relatively narrow range from 4.09 to 5.28‰ and were similar to those reported for organic matter in soil and the canopy throughfall in the Sudety Mountains. Sulfate content, δ 34 S(SO 4 2− ), δ 18 O(SO 4 2− ), and δ 18 O(H 2 O) values revealed a remarkable dependence on the altitude. The calculated altitude effects for five season averages of these parameters were − 1.00 mg/l/100 m, − 0.18‰/100 m, − 0.27‰/100 m, and − 0.17‰/100 m, respectively. This dependence on the altitude resulted mainly from the mixing of sulfates of different origins such as anthropogenic sulfate, sulfate produced in the soil within the weathered zone of the massif, and that one from the tree canopy. The oxygen isotope mass balance indicates that, in the study area, about one third of the sulfate delivered to the surface and groundwater by modern precipitation comes from anthropogenic pollution. Further interaction of meteoric water within the weathered rocks causes a continuous decrease of δ 18 O(SO 4 2− ) values resulting from biological transformation of the sulfate due to plant vegetation and decomposition of organic matter.

Sudety Mountains↗
USGS2008

Evaluating transition-metal catalysis in gas generation from the Permian Kupferschiefer by hydrous pyrolysis

Transition metals in source rocks have been advocated as catalysts in determining extent, composition, and timing of natural gas generation (Mango, F. D. (1996) Transition metal catalysis in the generation of natural gas. Org. Geochem.24, 977–984). This controversial hypothesis may have important implications concerning gas generation in unconventional shale-gas accumulations. Although experiments have been conducted to test the metal-catalysis hypothesis, their approach and results remain equivocal in evaluating natural assemblages of transition metals and organic matter in shale. The Permian Kupferschiefer of Poland offers an excellent opportunity to test the hypothesis with immature to marginally mature shale rich in both transition metals and organic matter. Twelve subsurface samples containing similar Type-II kerogen with different amounts and types of transition metals were subjected to hydrous pyrolysis at 330° and 355 °C for 72 h. The gases generated in these experiments were quantitatively collected and analyzed for molecular composition and stable isotopes. Expelled immiscible oils, reacted waters, and spent rock were also quantitatively collected. The results show that transition metals have no effect on methane yields or enrichment. δ 13 C values of generated methane, ethane, propane and butanes show no systematic changes with increasing transition metals. The potential for transition metals to enhance gas generation and oil cracking was examined by looking at the ratio of the generated hydrocarbon gases to generated expelled immiscible oil (i.e., GOR), which showed no systematic change with increasing transition metals. Assuming maximum yields at 355 °C for 72 h and first-order reaction rates, pseudo-rate constants for methane generation at 330 °C were calculated. These rate constants showed no increase with increasing transition metals. The lack of a significant catalytic effect of transition metals on the extent, composition, and timing of natural gas generation in these experiments is attributed to the metals not occurring in the proper form or the poisoning of potential catalytic microcosms by polar-rich bitumen, which impregnates the rock matrix during the early stages of petroleum formation.

Permian Kupferschiefer↗
USGS1993

Exhumation of eclogitized continental basement during Variscan lithospheric delamination and gravitational collapse, Sudety Mountains, Poland

A Variscan,deep-crustal-level (eclogite-facies),continental basement massif in western Poland, the Snieznik complex, was tectonically exhumed. Crustal-penetrating mylonite zones record three main kinematic events: early top-to-the-north-directed thrusting, right-slip transpression-tension, and late top-to-the-south and -east normal faulting. Thrusting resulted in extreme crustal thickening and associated eclogite-facies metamorphism. Right-slip movements produced retrogressive crystal-plastic simple-shear zones. Normal faults flank Carboniferous to Early Permian terrigenous sedimentary basins, documenting tectonic and erosional denudation of the Snieznik complex during lithospheric extension. Sm/Nd isotopic dates previously reported for the in situ eclogite-facies metamorphic mineral assemblages are 341, 337, and 329 Ma (Brueckner et al., 1991). 40 Ar/ 39 Ar isotopic dates for metamorphic hornblende (338, 333, and 332 Ma), muscovite (329 and 329 Ma), and biotite (328 Ma) reflect times of cooling through the ∼500, 350, and 300 °C isotherms, respectively. These nearly concordant mineral dates document rapid cooling from ∼850 °C (eclogue-facies temperatures) to ∼300 °C. Rapid denudation of these deep-crustal rocks (∼19-22 kbar pressures, >70 km depth) is attributed to processes, similar to those of metamorphic-core complexes, that operated during lithospheric delamination and gravitational collapse. The sequence of late Paleozoic (Alleghanian) crustal thickening followed by right-slip transpression-tension followed by normal faulting recognized in the U.S. Appalachians implies that this tectonic pattern may exist throughout the Afleghanian-Variscan belt.

Sudety Mountains↗
USGS1981

The terminal Eocene event and the Polish connection

The Eocene/Oligocene boundary in Europe is marked by major discontinuities in all environments: the “Grande Coupure” in continental mammals; the elimination of semitropical elements from high-latitude floras; the virtually complete replacement of the shallow-marine malacofauna; and an extraordinary downslope excursion of carbonate deposition in deep-ocean basins (drop in the CCD). These phenomena collectively represent the “Terminal Eocene Event” (TEE). In the Carpathian Mountains, the TEE is manifested in the thin but regionally persistent Globigerina Marl, a calcareous unit containing abundant cool-water microplankton that occurs within very thick, siliceous, bathyal flysch sequences. In southern Poland, the marl is of very latest Eocene age, within planktonic foraminifera zone P17, calcareous nannoplankton zone NP19/20, and the zone of the dinoflagellate Rhomdodinium perforatum . Zircons from bentonites bracketing the marl are dated by fission-track analysis; at Polany, two underlying bentonites are 41.7 and 39.8 Ma, and at Znamirowice two overlying bentonites are 34.6 and 28.9 Ma, in sequence. This accords with glauconite K/Ar ages in Western Europe by which the Eo/Oligocene boundary age is estimated at 37–38 Ma. Global correlations indicate that the TEE corresponds to a major glacio-eustatic regression with a duration of about 0.5 Ma, in which a large Antarctic ice cap was formed, the ocean circulation was permanently changed to the psychrospheric condition, and world climate shifted irreversibly towards the modern state.

Palaeogeography, Palaeoclimatology, Palaeoecology↗