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Research about Pennsylvania

Source-linked reports with geographic coverage including Pennsylvania.

At least 253 records · Page 14Linked to original sources
USGS2010

Hydraulic modeling of mussel habitat at a bridge-replacement site, Allegheny River, Pennsylvania, USA

The Allegheny River in Pennsylvania supports a large and diverse freshwater-mussel community, including two federally listed endangered species, Pleurobema clava (Clubshell) and Epioblasma torulosa rangiana (Northern Riffleshell). It is recognized that river hydraulics and morphology play important roles in mussel distribution. To assess the hydraulic influences of bridge replacement on mussel habitat, metrics such as depth, velocity, and their derivatives (shear stress, Froude number) were collected or computed. The objectives of the project were to evaluate mussel and hydraulic data at a reference site and to compare those findings to a bridge-replacement site. The findings were used to support a statistical analysis, which establishes correlations between mussel count and hydraulics, and a numerical model to forecast habitat based on the statistics. ArcGIS was selected to manage the data and generate a grid to compute area statistics for 3319, 4.9-m × 4.9-m cells (cell) for total mussel count, depth, velocity, shear stress, and Froude number. The Wilcoxon Rank Sum test indicated no statistical significance between the total mussel count and the hydraulic variables; however, trellis graphs were used to account for the spatial variability in the data set. For the flow conditions measured, the total mussel count per cell is greatest at sections where (1) velocities range from 0.061 to 0.21 m/s, (2) shear stresses range from 0.48 to 3.8 dyne/cm 2 , and (3) Froude numbers range from 0.006 to 0.04. Based on the statistical targets established, the hydraulic model results suggest that an additional 2428 m 2 or a 30-percent increase in suitable mussel habitat could be generated at the replacement-bridge site when compared to the baseline condition associated with the existing bridge at that same location. The study did not address the influences of substrate, acid mine drainage, sediment loads from tributaries, and surface-water/ground-water exchange on mussel habitat. Future studies could include methods for quantifying (1) channel–substrate composition and distribution using tools such as hydroacoustic echosounders specifically designed and calibrated to identify bed composition and mussel populations, (2) surface-water and ground-water interactions, and (3) a high-streamflow event.

Pennsylvania↗
USGS2010

Pennsylvania StreamStats: A web-based application for obtaining water-resource-related information

StreamStats is a national web-based Geographic Information System (GIS) application, developed by the U.S. Geological Survey (USGS), in cooperation with Environmental Systems Research Institute, Inc., to provide a variety of water-resource-related information. Users can easily obtain descriptive information, basin characteristics, and streamflow statistics for USGS streamgages and ungaged stream locations throughout Pennsylvania. StreamStats also allows users to search upstream and (or) downstream from user-selected points to identify locations of and obtain information for water-resource-related activities, such as dams and streamgages.

Pennsylvania↗
USGS2010

Changes in groundwater flow and volatile organic compound concentrations at the Fischer and Porter Superfund Site, Warminster Township, Bucks County, Pennsylvania, 1993-2009

The 38-acre Fischer and Porter Company Superfund Site is in Warminster Township, Bucks County, Pa. Historically, as part of the manufacturing process, trichloroethylene (TCE) degreasers were used for parts cleaning. In 1979, the Bucks County Health Department detected TCE and other volatile organic compounds (VOCs) in water from the Fischer and Porter on-site supply wells and nearby public-supply wells. The Fischer and Porter Site was designated as a Superfund Site and placed on the National Priorities List in September 1983. A 1984 Record of Decision for the site required the Fischer and Porter Company to pump and treat groundwater contaminated by VOCs from three on-site wells at a combined rate of 75 gallons per minute to contain groundwater contamination on the property. Additionally, the Record of Decision recognized the need for treatment of the water from two nearby privately owned supply wells operated by the Warminster Heights Home Ownership Association. In 2004, the Warminster Heights Home Ownership Association sold its water distribution system, and both wells were taken out of service. The report describes changes in groundwater levels and contaminant concentrations and migration caused by the shutdown of the Warminster Heights supply wells and presents a delineation of the off-site groundwater-contamination plume. The U.S. Geological Survey (USGS) conducted this study (2006-09) in cooperation with the U.S. Environmental Protection Agency (USEPA). The Fischer and Porter Site and surrounding area are underlain by sedimentary rocks of the Stockton Formation of Late Triassic age. The rocks are chiefly interbedded arkosic sandstone and siltstone. The Stockton aquifer system is comprised of a series of gently dipping lithologic units with different hydraulic properties. A three-dimensional lithostratigraphic model was developed for the site on the basis of rock cores and borehole geophysical logs. The model was simplified by combining individual lithologic units into generalized units representing upward fining sedimentary cycles capped by a siltstone bed. These cycles were labeled units 1 through 8 and are called stratigraphic units in this report. Groundwater in the unweathered zone mainly moves through a network of interconnecting secondary openings--bedding-plane fractures and joints. Groundwater generally is unconfined in the shallower part of the aquifer and confined or semiconfined in the deeper part of the aquifer. The migration of VOCs from the Fischer and Porter Site source area is influenced by geologic and hydrologic controls. The hydrologic controls have changed with time. Stratigraphic units 2 and 3 crop out beneath the former Fischer and Porter plant. VOCs originating at the plant source area entered these stratigraphic units and moved downdip to the northwest. When the wells at and in the vicinity of the site were initially sampled in 1979-80, three public-supply wells (BK-366, BK-367, MG-946) and three industrial-supply wells (BK-368, BK-370, and BK-371) were pumping. Groundwater contaminated with VOCs flowed downdip and then northeast along strike toward well BK-366, downdip toward well BK-368, and downdip and then west along strike toward well MG-946. The long axis of the TCE plume is oriented about N. 18° W. in the direction of dip. In 1979-80, the leading edge of the plume was about 3,500 feet wide. With the cessation of pumping of the supply wells in 2004, the size of the plume has decreased. In 2007-09, the plume was approximately 2,000 feet long and 2,000 feet wide at the leading edge. On the western side of the site, TCE and tetrachloroethylene (PCE) appear to be moving downdip though stratigraphic unit 3. The downdip extent of TCE and PCE migration extended approximately 550 feet off-site to the northwest and 750 feet off-site to the north. TCE concentrations in water samples from wells at the western site boundary increased from 1996 to 2007. On the northern side of the site, TCE and PCE appeared to be moving downward and laterally though stratigraphic units 2, 3, and 4. Groundwater-flow directions shifted to the northwest in the intermediate and deep zones after cessation of pumping of well BK-366 in 2004. The shutdown of the Warminster Heights wells had little effect on the direction of groundwater flow in the shallow zone. In 2007, TCE concentrations measured in water samples from the three remediation wells by the USGS ranged from less than 340 to 3,000 µg/L, and PCE concentrations ranged from less than 8.4 to 51 µg/L. TCE concentrations in water samples from the source-area remediation wells have decreased with time but remain highly variable. From 2001 to 2008, the TCE and PCE concentrations in water samples from wells BK-370 and BK-371 showed a linear decreasing trend. TCE and PCE concentrations in water samples from well BK-1324 showed an exponentially decreasing trend. In 2007, TCE concentrations measured in water samples from shallow wells ranged from less than 0.1 to 14,000 µg/L, and PCE concentrations ranged from less than 0.1 to 340 µg/L. The TCE and PCE plumes followed the hydraulic gradient in the shallow zone. In 2007, TCE concentrations measured in water samples from on-site intermediate-depth monitor wells ranged from less than 0.1 to 500 µg/L, and PCE concentrations ranged from 1.3 to 28 µg/L. The TCE and PCE plumes followed the hydraulic gradient in the intermediate zone and extended off-site to the north and northwest of the source area. Concentrations of TCE in water samples north and west of the source area increased from 1996 to 2007. In 2007, the TCE concentrations measured in water samples from on-site monitor wells in the deep zone ranged from 1.1 to 86 µg/L, and PCE concentrations ranged from less than 0.1 to 8.4 µg/L. The TCE and PCE plumes generally followed the hydraulic gradient in the deep zone and extended off-site to the northwest of the source area. In general, concentrations of TCE in water samples from monitor wells outside the source area increased between 1996 and 2005 and decreased between 2005 and 2007; concentrations were less in 2007 than in 1996.

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USGS2010

Determination of time-of-travel, dispersion characteristics, and oxygen reaeration coefficients during low streamflows--Lower Tacony/Frankford Creek, Philadelphia, Pennsylvania

Time-of-travel, dispersion characteristics, and oxygen reaeration coefficients were determined by use of dye and gas tracing for a 2-mile reach of Tacony/Frankford Creek in Philadelphia, southeastern Pennsylvania. The reach frequently has concentrations of dissolved oxygen (DO) below the water-quality standard of 4 milligrams per liter during warm months. Several large combined sewer overflows (CSOs), including one of the largest in Philadelphia (former Wingohocking Creek), discharge to the study reach in this urbanized watershed, affecting water quality and the timing and magnitude of storm peaks. In addition, a dam that commonly results in backwater conditions and reduced natural reaeration is present a few hundred feet from the end of the study reach. Time-of-travel and reaeration data were collected under base-flow conditions in August and September 2009 for three sub-reaches from Roosevelt Boulevard (U.S. Route 1) to Castor Avenue. Determination of traveltimes to the centroid of the dye cloud were needed for calculation of the reaeration coefficients. Results of the dye study in Tacony/Frankford Creek indicate that traveltimes were affected by the presence of man-made structures, such as the large scour hole and pool developed at the outfall of the T14 CSO and the dam, both of which reduce stream velocities. Mean stream velocities during the dye-tracer tests ranged from a maximum of 0.44 to 0.04 foot per second through a large pool. The dispersion efficiency of the stream was determined from relations between normalized unit concentrations to time to peak for use in water-quality modeling. Oxygen reaeration coefficients determined by a constant rate-injection method using propane as the tracer gas were as low as 0.04 unit per hour in a long pool affected by backwater conditions behind a dam. The highest reaeration coefficient was 2.29 units per hour for a steep-gradient reach with multiple winding channels through gravel deposits, just downstream of a large scour pool developed at the outlet of the T14 CSO. Reaeration coefficients determined from the field tracer-gas method were compared to values calculated by two other methods, one that is based on theoretical equations using physical properties of the stream as variables and the other that is based on equations using the timing of measured daily maximum DO concentrations in the stream. Reaeration coefficients from the two alternate methods were most similar to values determined from the field tracer-gas method for the upstream portion of the study reach, characterized by free-flowing riffle and pools. Values of reaeration coefficients determined by the tracer-gas method were 2 to 10 times higher than values determined by 2 alternate methods for most subreaches hydraulically affected by man-made structures. In addition to the tracer gas, propane, the gas analysis also included methane, ethane, and ethene, of which only methane was measured in concentrations above a few micrograms per liter. Methane, thought to occur naturally or because of ongoing processes in the stream, was measured in concentrations ranging from 6.6 to 78 micrograms per liter; the concentrations were greatest in sub-reaches dominated by pools.

Pennsylvania↗
USGS2010

Factors Affecting Specific-Capacity Tests and their Application--A Study of Six Low-Yielding Wells in Fractured-Bedrock Aquifers in Pennsylvania

This report by the U.S. Geological Survey, prepared in cooperation with the Pennsylvania Department of Environmental Protection, Bureau of Mining and Reclamation, evaluates factors affecting the application of specific-capacity tests in six low-yielding water wells in areas of coal mining or quarrying in Pennsylvania. Factors such as pumping rate, duration of pumping, aquifer properties, wellbore storage, and turbulent flow were assessed by theoretical analysis and by completing multiple well tests, selected to be representative of low-yielding household-supply wells in areas of active coal mining or quarrying. All six wells were completed in fractured-bedrock aquifers--five in coal-bearing shale, siltstone, sandstone, limestone, and coal of Pennsylvanian and Permian age and one in limestone of Cambrian age. The wells were pumped 24 times during 2007-09 at rates from 0.57 to 14 gallons per minute during tests lasting from 22 to 240 minutes. Geophysical logging and video surveys also were completed to determine the depth, casing length, and location of water-yielding zones in each of the test wells, and seasonal water-level changes were measured during 2007-09 by continuous monitoring at each well. The tests indicated that specific-capacity values were reproducible within about ? 20 percent if the tests were completed at the same pumping rate and duration. A change in pumping duration, pumping rate, or saturated aquifer thickness can have a substantial effect on the comparability of repeated tests. The largest effect was caused by a change in aquifer thickness in well YO 1222 causing specific capacity from repeated tests to vary by a factor of about 50. An increase in the duration of pumping from 60 to 180 minutes caused as much as a 62 percent decrease in specific capacity. The effect of differing pumping rates on specific capacity depends on whether or not the larger rate causes the water level in the well to fall below a major water-yielding zone; when this decline happened at well CA 462, specific capacity was reduced by about 63 percent. Estimates of the maximum yield for low-yielding wells that are computed by multiplying the available drawdown by the specific-capacity value may contain large errors if the wells were pumped at low rates that do not cause much water-level drawdown. The estimates of yield are likely to be too large because the effects of lowering the water level in the well below water-yielding zones have not been incorporated. Better yield estimates can be made by the use of step-drawdown tests or by over-pumping at a rate large enough to dewater most of the wellbore. The maximum well yield, after overpumping, can be estimated from the rate of water-level recovery or by subtracting the incremental rate of change of borehole storage at the end of the test from the pumping rate.

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USGS2010

Summary of groundwater-recharge estimates for Pennsylvania

Groundwater recharge is water that infiltrates through the subsurface to the zone of saturation beneath the water table. Because recharge is a difficult parameter to quantify, it is typically estimated from measurements of other parameters like streamflow and precipitation. This report provides a general overview of processes affecting recharge in Pennsylvania and presents estimates of recharge rates from studies at various scales. The most common method for estimating recharge in Pennsylvania has been to estimate base flow from measurements of streamflow and assume that base flow (expressed in inches over the basin) approximates recharge. Statewide estimates of mean annual groundwater recharge were developed by relating base flow to basin characteristics of HUC10 watersheds (a fifth-level classification that uses 10 digits to define unique hydrologic units) using a regression equation. The regression analysis indicated that mean annual precipitation, average daily maximum temperature, percent of sand in soil, percent of carbonate rock in the watershed, and average stream-channel slope were significant factors in the explaining the variability of groundwater recharge across the Commonwealth. Several maps are included in this report to illustrate the principal factors affecting recharge and provide additional information about the spatial distribution of recharge in Pennsylvania. The maps portray the patterns of precipitation, temperature, prevailing winds across Pennsylvania’s varied physiography; illustrate the error associated with recharge estimates; and show the spatial variability of recharge as a percent of precipitation. National, statewide, regional, and local values of recharge, based on numerous studies, are compiled to allow comparison of estimates from various sources. Together these plates provide a synopsis of groundwater-recharge estimations and factors in Pennsylvania. Areas that receive the most recharge are typically those that get the most rainfall, have favorable surface conditions for infiltration, and are less susceptible to the influences of high temperatures, and thus, evapotranspiration. Areas that have less recharge in Pennsylvania are typically those with less precipitation, less permeable soils, and higher temperatures that are conducive to greater rates of evapotranspiration.

Pennsylvania↗
USGS2009

Selected ground-water-quality data in Pennsylvania - 1979-2006

This study, by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP), provides a compilation of ground-water-quality data for a 28-year period (January 1, 1979, through December 31, 2006) based on water samples from wells and springs. The data are from 14 source agencies or programs—Borough of Carroll Valley, Chester County Health Department, Montgomery County Health Department, Pennsylvania Department of Agriculture, Pennsylvania Department of Environmental Protection 2002 Pennsylvania Water-Quality Assessment, Pennsylvania Department of Environmental Protection Agency Act 537 Sewage Facilities Program, Pennsylvania Department of Environmental Protection-Ambient and Fixed Station Network, Pennsylvania Department of Environmental Protection–North-Central Region, Pennsylvania Department of Environmental Protection–South-Central Region, Pennsylvania Drinking Water Information System, Pennsylvania Topographic and Geologic Survey, Susquehanna River Basin Commission, U.S. Environmental Protection Agency, and the U.S. Geological Survey. The ground-water-quality data from the different source agencies or programs varied in type and number of analyses; however, the analyses are represented by 11 major analyte groups: antibiotics, major ions, microorganisms (bacteria, viruses, and other microorganisms), minor ions (including trace elements), nutrients (predominantly nitrate and nitrite as nitrogen), pesticides, pharmaceuticals, radiochemicals (predominantly radon or radium), volatiles (volatile organic compounds), wastewater compounds, and water characteristics (field measurements, predominantly field pH, field specific conductance, and hardness). For the USGS and the PADEP–North-Central Region, the pesticide analyte group was broken down into fungicides, herbicides, and insecticides. Summary maps show the areal distribution of wells and springs with ground-water-quality data statewide by source agency or program. Summary data tables by source agency or program provide information on the number of wells and springs and samples collected for each of the 35 watersheds and analyte groups. The number of wells and springs sampled for ground-water-quality data varies considerably across Pennsylvania. Of the 24,772 wells and springs sampled, the greatest concentration of wells and springs is in the southeast (Berks, Bucks, Chester, Delaware, Lancaster, Montgomery, and Philadelphia Counties) and in the northwest (Erie County). The number of wells and springs sampled is relatively sparse in north-central (Cameron, Elk, Forest, McKean, Potter, and Warren Counties) Pennsylvania. Little to no data are available for approximately one-fourth of the state. Nutrients and water characteristics were the most frequently sampled major analyte groups—43,025 and 30,583 samples, respectively. Minor ions and major ions were the next most frequently sampled major analyte groups–26,972 and 13,115 samples, respectively. For the remaining 10 major analyte groups, the number of samples collected ranged from a low of 24 samples (antibiotic compounds) to a high of approximately 4,674 samples (microorganisms). The number of samples that exceeded a maximum contaminant level (MCL) or secondary maximum contaminant level (SMCL) by major analyte group also varied. Of the 4,674 samples in the microorganism analyte group, 50.2 percent had water that exceeded an MCL. Of the 4,528 samples collected and analyzed for volatile organic compounds, 23.5 percent exceeded an MCL. Other major analyte groups that frequently exceeded MCLs or SMCLs included major ions (18,343 samples and a 27.7 percent exceedence), minor ions (26,972 samples, 44.7 percent exceedence), pesticides (4,868 samples, 0.7 percent exceedence), water characteristics (30,583 samples, 19.3 percent exceedence), and radiochemicals (1,866 samples, 9.6 percent exceedence). Samples collected and analyzed for antibiotics (24 samples), fungicides (1,273 samples), herbicides (1,470 samples), insecticides (1,424 samples), nutrients (43,025 samples), pharmaceuticals (28 samples), and wastewater compounds (328 samples) had the lowest exceedences of 0.0, 2.4, 1.2, <1.0, 8.3, 0.0, and <1.0 percent, respectively.

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USGS2009

National assessment of historical shoreline change: a pilot study of historical coastal bluff retreat in the Great Lakes, Erie, Pennsylvania

Coastal bluff retreat is a chronic problem along many high-relief coastlines in the United States. As coastal populations continue to grow and community infrastructures are threatened by erosion, there is increased demand for accurate information regard-ing trends and rates of bluff retreat. There is also a need for a comprehensive analysis that is consistent from one coastal region to another. To address these national needs, the U.S. Geological Survey (USGS), as part of the National Assessment of Coastal Change Hazards Project, conducted a pilot study of bluff retreat along the Lake Erie, Pa., coastline to assess the feasibility of undertaking a larger, multi-state analysis in the Great Lakes region. This report provides an overview of the pilot-study location and bluff geomorphology, the data sources and methodology, results of the analysis, and a discussion of the feasibility of undertaking a similar analysis along eroding bluffs in other Great Lakes states. This pilot study is part of an ongoing effort by the USGS to provide a comprehensive analysis of historical shoreline change and cliff and bluff retreat along open-ocean coastlines of the conterminous United States and parts of Hawaii, Alaska, and the Great Lakes. One purpose of the work is to develop standard, repeatable methods for mapping and analyzing coastal change so that systematic and consistent periodic updates of coastal erosion can be made nationally. Bluff-retreat evaluations are conducted by comparing the location of a historical bluff edge digitized from aerial photographs with those of recent bluff edges interpreted from both aerial photographs and lidar topographic surveys. The historical bluff edge is from 1938, whereas the more recent bluff edges are from 1998 and 2006 lidar data. Long-term (68-year) rates of retreat are calculated using the available bluff-edge data. The rates of retreat presented in this report represent conditions from the 1930s to 1998/2006, and are not intended for predicting future bluff-edge positions or rates of retreat. The report presents bluff-retreat rates for 32 km of a 60-km stretch along the Lake Erie, Pa., coastline. Data are discontinuous due to gaps in source data and lack of continuous bluffs. The average rate of coastal bluff retreat for the Lake Erie, Pa., bluffs was -0.3 +- 0.1 m/yr (retreat rates are presented as negative numbers in this report), based on rates averaged from 1,595 individual transects. Retreat rates generally were lowest where bedrock outcrops are exposed as the basal unit in the bluff. The highest rates are associated with anthropogenic activities, including jetties that trap littoral sediment, depleting a source of material for the natural replenishment of protective beaches downcoast, and extensive irrigation of farmlands on the tops of the bluffs, which can destabilize bluffs by enhancing ground-water outflow.

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USGS2009

Water-quality monitoring in response to young-of-the-year smallmouth bass (Micropterus dolomieu) mortality in the Susquehanna River and major tributaries, Pennsylvania: 2008

Mortalities of young-of-the-year (YOY) smallmouth bass ( Micropterus dolomieu ) recently have occurred in the Susquehanna River due to Flavobacterium columnare , a bacterium that typically infects stressed fish. Stress factors include but are not limited to elevated water temperature and low dissolved oxygen during times critical for survival and development of smallmouth bass (May 1 through July 31). The infections were first discovered in the Susquehanna River and major tributaries in the summer months of 2005 but also were prevalent in 2007. The U.S. Geological Survey, Pennsylvania Fish and Boat Commission, Pennsylvania Department of Environmental Protection, and PPL Corporation worked together to monitor dissolved oxygen, water temperature, pH, and specific conductance on a continuous basis at seven locations from May through mid October 2008. In addition, nutrient concentrations, which may affect dissolved-oxygen concentrations, were measured once in water and streambed sediment at 25 locations. Data from water-quality meters (sondes) deployed as pairs showed daily minimum dissolved-oxygen concentration at YOY smallmouth-bass microhabitats in the Susquehanna River at Clemson Island and the Juniata River at Howe Township Park were significantly lower (p-value < 0.0001) than nearby main-channel habitats. The average daily minimum dissolved-oxygen concentration during the critical period (May 1–July 31) was 1.1 mg/L lower in the Susquehanna River microhabitat and 0.3 mg/L lower in the Juniata River. Daily minimum dissolved-oxygen concentrations were lower than the applicable national criterion (5.0 mg/L) in microhabitat in the Susquehanna River at Clemson Island on 31 days (of 92 days in the critical period) compared to no days in the corresponding main-channel habitat. In the Juniata River, daily minimum dissolved-oxygen concentration in the microhabitat was lower than 5.0 mg/L on 20 days compared to only 5 days in the main-channel habitat. The maximum time periods that dissolved oxygen was less than 5.0 mg/L in microhabitats of the Susquehanna and Juniata Rivers were 8.5 and 5.5 hours, respectively. Dissolved-oxygen concentrations lower than the national criterion generally occurred during nighttime and early-morning hours between midnight and 0800. The lowest instantaneous dissolved-oxygen concentrations measured in microhabitats during the critical period were 3.3 mg/L for the Susquehanna River at Clemson Island (June 11, 2008) and 4.1 mg/L for the Juniata River at Howe Township Park (July 22, 2008). Comparison of 2008 data to available continuous-monitoring data from 1974 to 1979 in the Susquehanna River at Harrisburg, Pa., indicates the critical period of 2008 had an average daily mean dissolved-oxygen concentration that was 1.1 mg/L lower (p-value < 0.0001) than in the 1970s and an average daily mean water temperature that was 0.8 °C warmer (p-value = 0.0056). Streamflow was not significantly different (p-value = 0.0952) between the two time periods indicating that it is not a likely explanation for the differences in water quality. During the critical period in 2008, dissolved-oxygen concentrations were lower in the Susquehanna River at Harrisburg, Pa., than in the Delaware River at Trenton, N.J., or Allegheny River at Acmetonia near Pittsburgh, Pa. Daily minimum dissolved-oxygen concentrations were below the national criterion of 5.0 mg/L on 6 days during the critical period in the Susquehanna River at Harrisburg compared to no days in the Delaware River at Trenton and the Allegheny River at Acmetonia. Average daily mean water temperature in the Susquehanna River at Harrisburg was 1.8 °C warmer than in the Delaware River at Trenton and 3.4 °C warmer than in the Allegheny River at Acmetonia. These results indicate that any stress induced by dissolved oxygen or other environmental conditions is likely to be magnified by elevated temperature in the Susquehanna River at Harrisburg compared to the Delaware River at Trenton or the Allegheny River at Acmetonia.

Pennsylvania↗
USGS2009

Pesticides in ground water in selected agricultural land-use areas and hydrogeologic settings in Pennsylvania, 2003-07

This report was prepared by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Agriculture (PDA) as part of the Pennsylvania Pesticides and Ground Water Strategy (PPGWS). Monitoring data and extensive quality-assurance data on the occurrence of pesticides in ground water during 2003–07 are presented and evaluated; decreases in the land area used for agriculture and corresponding changes in the use of pesticides also are documented. In the Pennsylvania ground waters assessed since 2003, concentrations of pesticides did not exceed any maximum contaminant or health advisory levels established by the U.S. Environmental Protection Agency; PPGWS actions are invoked by the PDA at fractions of these levels and were needed only in areas designated by the PDA for special ground-water protection. Previous investigations through 1998 of pesticides in Pennsylvania ground water identified land use, as a surrogate for pesticide use, and rock type of the aquifer combined with physiography as key hydrogeologic setting variables for understanding aquifer vulnerability to contamination and the common occurrence of atrazine and metolachlor in ground water. Of 20 major hydrogeologic settings in a framework established in 1999 for pesticide monitoring in Pennsylvania, 9 were identified as priorities for data collection in order to change the monitoring status from "inadequate" to "adequate" for the PPGWS. Agricultural and forested land-use areas are decreasing because of urban and suburban growth. In the nine hydrogeologic settings evaluated using 1992 and 2001 data, decreases of up to 12 percent for agricultural land and 10 percent for forested land corresponded to increases of up to 11 percent for urban land. Changes in agricultural pesticide use were computed from crop data. For example, from 1996 to 2004–05, atrazine use declined by about 15 percent to 1,314,000 lb/yr (pounds per year) and metolachlor use increased by about 20 percent to 895,000 lb/yr; these compounds are the two most-used agricultural pesticides statewide. In 2003–07, a baseline assessment of pesticides was conducted in five of nine hydrogeologic settings with inadequate monitoring data—the Blue Ridge crystalline and Triassic Lowland siliciclastic, Eastern Lake surficial, Devonian-Silurian carbonate, Great Valley siliciclastic, and Northeastern Glaciated surficial settings. Between 20 and 30 wells in each setting were monitored. Of the 126 wells sampled, 96 well-water samples were analyzed for at least 52 pesticide compounds at the USGS National Water Quality Laboratory (NWQL) using a method with a minimum reporting level (MRL) at or above 0.002 µg/L (micrograms per liter). Of the 96 well waters analyzed by NWQL, 43 had measureable concentrations of one or more pesticides. Atrazine and (or) deethylatrazine (CIAT), a degradation product of atrazine, were reported at or above the MRL in 39 of the 43 well waters. Neither atrazine nor CIAT were reported at concentrations exceeding 0.10 µg/L; all measured concentrations in these five settings were below PPGWS action levels. Metolachlor was present in 7 of the 43 well waters with measureable concentrations of 1 or more pesticides; however, concentrations were below the MRL. The other 30 samples (10 of 20 wells in the Blue Ridge crystalline and Triassic Lowland siliciclastic setting and all 20 wells in the Eastern Lake surficial setting) were analyzed for at least 19 pesticide compounds at the Pennsylvania Department of Environmental Protection Laboratory (PADEPL); the PADEPL reported no concentrations of pesticides at or above an MRL of 0.10 µg/L. Statistical tests using the NWQL analytical results showed correlations between pesticide occurrence and two indicators of water-quality degradation—the occurrence of total coliform bacteria and nitrate concentration. A 2 × 2 contingency-table test indicated a relation between presence or absence of atrazine or metolachlor and presence or absence of bacteria only for the 10 wells representing the Blue Ridge crystalline and Triassic Lowland siliciclastic setting. Results of Spearman’s rank test showed strong positive correlations in the Devonian-Silurian carbonate setting between 1) the number of pesticides above the MRLs and nitrate concentration, and 2) concentrations of atrazine and nitrate. Atrazine concentration and nitrate concentration also showed a statistically significant positive correlation in the Great Valley siliciclastic setting. An additional component of baseline monitoring was to evaluate changes in pesticide concentration in water from wells representing hydrogeologic settings most vulnerable to contamination from pesticides. In 2003, 16 wells originally sampled in the 1990s were resampled—4 each in the Appalachian Mountain carbonate, Triassic Lowland siliciclastic, Great Valley carbonate, and Piedmont carbonate settings. Nine of these wells, where pesticide concentrations from 1993 and 2003 were analyzed at the NWQL, were chosen for a paired-sample analysis using concentrations of atrazine and metolachlor. A statistically significant decrease in atrazine concentration was identified using the Wilcoxon signed-rank test (p = 0.004); significant temporal changes in metolachlor concentrations were not observed (p = 0.625). Monitoring in three areas of special ground-water protection, where selected pesticide concentrations in well water were at or above the PPGWS action levels, was done at wells BE 1370 (Berks County, Oley Township), BA 437 (Blair County, North Woodbury Township), and LN 1842 (Lancaster County, Earl Township). Co-occurrence of pesticide-degradation products with parent compounds was documented for the first time in ground-water samples collected from these three wells. Degradation products of atrazine, cyanazine, acetochlor, alachlor, and metolachlor were commonly at larger concentrations than the parent compound in the same water sample. Pesticide occurrence in water from wells neighboring the hot-spot wells was highly variable; however, the same sets of pesticide compounds that were present in wells BA 437, BE 1370, and LN 1842 were present to some degree in water from neighboring wells. To evaluate temporal changes in concentration, nonparametric statistical tests were used to determine overall and seasonal monotonic trends. Concentrations of alachlor, atrazine, metolachlor, and nitrate were examined using the 5-year (2003–07) and the long-term data from wells BA 437 and LN 1842 (1996–2007 and 1995–2007, respectively), and the long-term data for well BE 1370 (1998–2007); results showed either downward trends or no trends. Trends in acetochlor concentrations were tested only at well LN 1842 using the 5-year data; no trends were observed. Homogeneity of trend tests indicated statistically significant downward concentration trends in the long-term data were due to seasonal trends as follows: BA 437—alachlor and atrazine (summer); BE 1370—atrazine and metolachlor (winter) and alachlor (winter and spring); LN 1842—alachlor (summer and fall) and atrazine (spring and fall).

Pennsylvania↗
USGS2007

An application of surface geophysical techniques to the study of watershed hydrology

The applicability of geophysical methods to experimental watershed research is demonstrated by a study of a 106-acre forested watershed in central Pennsylvania. Data from a shallow seismic refraction study and an electrical resistivity study of the watershed were used to determine the depth of soils, their volumes, depth to bedrock, configuration of the bedrock surface and delineation of the bedrock surface and delineation of the water table. With this information on the subsurface conditions, the hydrologic properties of the watershed were described in greater detail. This information will be of value in explaining the watershed's response to various watershed treatment practices that eventually will be used.

Pennsylvania↗
USGS2007

Watershed scaling effect on base flow nitrate, valley and ridge physiographic province

A study of stream base flow and NO 3 -N concentration was conducted simultaneously in 51 subwatersheds within the 116-square-kilometer watershed of East Mahantango Creek near Klingerstown, Pennsylvania. The study was designed to test whether measurable results of processes and observations within the smaller watersheds were similar to or transferable to a larger scale. Ancillary data on land use were available for the small and large watersheds. Although the source of land-use data was different for the small and large watersheds, comparisons showed that the differences in the two land-use data sources were minimal. A land use-based water-quality model developed for the small-scale 7.3-square-kilometer watershed for a previous study accurately predicted NO 3 -N concentrations from sampling in the same watershed. The water-quality model was modified and, using the imagery-based land use, was found to accurately predict NO 3 -N concentrations in the subwatersheds of the large-scale 116-square-kilometer watershed as well. Because the model accurately predicts NO 3 -N concentrations at small and large scales, it is likely that in second-order streams and higher, discharge of water and NO 3 -N is dominated by flow from smaller first-order streams, and the contribution of ground-water discharge to higher order streams is minimal at the large scale.

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USGS2007

Connecting ground water influxes with fish species diversity in an urbanized watershed

Valley Creek watershed is a small stream system that feeds the Schuylkill River near Philadelphia, Pennsylvania. The watershed is highly urbanized, including over 17 percent impervious surface cover (ISC) by area. Imperviousness in a watershed has been linked to fish community structure and integrity. Generally, above 10 to 12 percent ISC there is marked decline in fish assemblages with fish being absent above 25 percent ISC. This study quantifies the importance of ground water in maintaining fish species diversity in subbasins with over 30 percent ISC. Valley Creek contains an atypical fish assemblage in that the majority of the fish are warm-water species, and the stream supports naturally reproducing brown trout, which were introduced and stocked from the early 1900s to 1985. Fish communities were quantified at 13 stations throughout the watershed, and Simpson's species diversity index was calculated. One hundred and nine springs were located, and their flow rates measured. A cross covariance analysis between Simpson's species diversity index and spring flow rates upstream of fish stations was performed to quantify the spatial correlation between these two variables. The correlation was found to be highest at lag distances up to about 400 m and drop off significantly beyond lag distances of about 800 m.

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USGS2007

Multiple-methods investigation of recharge at a humid-region fractured rock site, Pennsylvania, USA

Lysimeter-percolate and well-hydrograph analyses were combined to evaluate recharge for the Masser Recharge Site (central Pennsylvania, USA). In humid regions, aquifer recharge through an unconfined low-porosity fractured-rock aquifer can cause large magnitude water-table fluctuations over short time scales. The unsaturated hydraulic characteristics of the subsurface porous media control the magnitude and timing of these fluctuations. Data from multiple sets of lysimeters at the site show a highly seasonal pattern of percolate and exhibit variability due to both installation factors and hydraulic property heterogeneity. Individual event analysis of well hydrograph data reveals the primary influences on water-table response, namely rainfall depth, rainfall intensity, and initial water-table depth. Spatial and seasonal variability in well response is also evident. A new approach for calculating recharge from continuous water-table elevation records using a master recession curve (MRC) is demonstrated. The recharge estimated by the MRC approach when assuming a constant specific yield is seasonal to a lesser degree than the recharge estimate resulting from the lysimeter analysis. Partial reconciliation of the two recharge estimates is achieved by considering a conceptual model of flow processes in the highly-heterogeneous underlying fractured porous medium.

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USGS2007

Drought-trigger ground-water levels in Chester County, Pennsylvania, for the period of record ending May 2006

This report presents the results of a study by the U.S. Geological Survey (USGS), in cooperation with the Chester County Water Resources Authority (CCWRA), to update the drought-trigger water levels for the Chester County observation-well network. The Chester County observation-well network was established in 1973 through a cooperative agreement between the CCWRA and the USGS to monitor local ground-water levels and trends and to determine drought conditions. In 1990 and again in 1997, drought-warning and drought-emergency water-level triggers were determined for the majority of wells in the existing Chester County observation-well network of 23 wells. Since 1997, the Chester County observation-well network expanded to 29 wells, some of the original wells were destroyed, and additional monthly water-level observations were made to allow for better statistical relations. Because of these changes, new statistics for water-level triggers were required. For this study, 19 of the 29 wells in the observation-well network were used to compute drought-trigger water levels. An additional 'drought-watch water-level trigger' category was developed to make the Chester County drought-trigger water-level categories consistent with those implemented by the Pennsylvania Department of Environmental Protection (PaDEP). The three drought-trigger water-level categories, as defined by PaDEP are 1) 'drought watch' when at the 75th-percentile level; 2) 'drought warning' when at the 90th-percentile level; and 3) 'drought emergency' when at the 95th-percentile level. A revised methodology, resulting from longer periods of record representing ground-water and climatic conditions and changes in local water use, has resulted in some observed differences in drought-trigger water levels. A comparison of current drought-trigger water levels to those calculated in 1997 shows the largest mean annual change in percentile values was in northeastern Chester County. In this northeastern region, the average 90th-percentile water levels changed by as much as 1.84 feet (17.5 percent) from those determined in 1997. Other observation wells in the county generally exhibited a smaller mean annual change in percentile values; a typical change was less than 0.5 foot. While most revisions in the drought-trigger water levels generally can be attributed to different methodology and (or) the additional years of data collected under existing climatic conditions, anthropogenic influences, such as the cessation of local pumping stresses, also were shown to cause changes in the drought-trigger water levels determined in this study.

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USGS2007

Concentrations of selected pharmaceuticals and antibiotics in south-central Pennsylvania waters, March through September 2006

This report presents environmental and quality-control data from analyses of 15 pharmaceutical and 31 antibiotic compounds in water samples from streams and wells in south-central Pennsylvania. The analyses are part of a study by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP) to define concentrations of selected emerging contaminants in streams and well water in Pennsylvania. Sampling was conducted at 11 stream sites and at 6 wells in 9 counties of south-central Pennsylvania. Five of the streams received municipal wastewater and 6 of the streams received runoff from agricultural areas dominated by animal-feeding operations. For all 11 streams, samples were collected at locations upstream and downstream of the municipal effluents or animal-feeding operations. All six wells were in agricultural settings. A total of 120 environmental samples and 21 quality-control samples were analyzed for the study. Samples were collected at each site in March/April, May, July, and September 2006 to obtain information on changes in concentration that could be related to seasonal use of compounds. For streams, 13 pharmaceuticals and 11 antibiotics were detected at least 1 time. Detections included analytical results that were estimated or above the minimum reporting limits. Seventy-eight percent of all detections were analyzed in samples collected downstream from municipal-wastewater effluents. For streams receiving wastewater effluents, the pharmaceuticals caffeine and para-xanthine (a degradation product of caffeine) had the greatest concentrations, 4.75 μg/L (micrograms per liter) and 0.853 μg/L, respectively. Other pharmaceuticals and their respective maximum concentrations were carbamazepine (0.516 μg/L) and ibuprofen (0.277 μg/L). For streams receiving wastewater effluents, the antibiotic azithromycin had the greatest concentration (1.65 μg/L), followed by sulfamethoxazole (1.34 μg/L), ofloxacin (0.329 μg/L), and trimethoprim (0.256 μg/L). For streams receiving runoff from animal-feeding operations, the only pharmaceuticals detected were acetaminophen, caffeine, cotinine, diphenhydramine, and carbamazepine. The maximum concentration for pharmaceuticals was 0.053 μg/L. Three streams receiving runoff from animal-feeding operations had detections of one or more antibiotic compound--oxytetracycline, sulfadimethoxine, sulfamethoxazole, and tylosin. The maximum concentration for antibiotics was 0.157 μg/L. The average number of compounds (pharmaceuticals and antibiotics) detected in sites downstream from animal-feeding operations was three. The average number of compounds detected downstream from municipal-wastewater effluents was 13. For wells used to supply livestock, four compounds were detected--two pharmaceuticals (cotinine and diphenhydramine) and two antibiotics (tylosin and sulfamethoxazole). There were five detections in all the well samples. The maximum concentration detected in well water was for cotinine, estimated to be 0.024 μg/L. Seasonal occurrence of pharmaceutical and antibiotic compounds in stream water varied by compound and site type. At four stream sites, the same compounds were detected in all four seasonal samples. At other sites, pharmaceutical or antibiotic compounds were detected only one time in seasonal samples. Winter samples collected in streams receiving municipalwastewater effluent had the greatest number of compounds detected (21). Research analytical methods were used to determine concentrations for pharmaceuticals and antibiotics. To assist in evaluating the quality of the analyses, detailed information is presented on laboratory methodology and results from qualitycontrol samples. Quality-control data include results for nine blanks, nine duplicate environmental sample pairs, and three laboratory-spiked environmental samples as well as the recoveries of compounds in laboratory surrogates and laboratory reagent spikes.

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USGS2007

Reconnaissance of arsenic concentrations in ground water from bedrock and unconsolidated aquifers in eight northern-tier counties of Pennsylvania

Samples of ground water for analysis of total-arsenic concentrations were collected in eight counties--Potter, Tioga, Bradford, Susquehanna, Wayne, Pike, Sullivan, and Wyoming--and from eight bedrock formations (bedrock aquifers) and overlying glacial aquifers in the north-central and northeastern parts of Pennsylvania in July 2005 and from March through June 2006. The samples were collected from a total of 143 domestic wells, 2 stock wells, 4 non-community wells, 2 community water-system wells, and 3 domestic springs by well or spring owners using sampling kits provided by the U.S. Geological Survey (USGS). An additional 15 domestic wells were sampled by the USGS for analysis of total arsenic. These 15 samples were collected using the same methods and sampling kits provided to the homeowners. Samples were analyzed for total arsenic by the Pennsylvania Department of Environmental Protection Laboratory using a minimum reporting level of 4.0 µg/L (micrograms per liter). Arsenic was detected in water from 18 domestic wells in four counties--Bradford (3 wells), Sullivan (1 well), Tioga (13 wells), and Wayne (1 well). The median concentration of total arsenic was less than 4.0 µg/L, and the maximum concentration was 188 µg/L. Water from 10 wells had concentrations of total arsenic greater than the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 µg/L. Detectable concentrations of total arsenic were measured in water from wells that ranged in depth from 29 to 400 feet, and that were completed in three aquifers--Lock Haven Formation, Catskill Formation, and unconsolidated glacial sediments; no springs had detectable concentrations of total arsenic. Water samples representing the Lock Haven Formation were collected from 60 wells; water from 12 of these wells had detectable concentrations of total arsenic. Water samples representing the Catskill Formation were collected from 57 wells; water from 4 wells had detectable concentrations of total arsenic. Water samples representing the unconsolidated glacial sediments were collected from 17 wells; 2 wells had water with detectable concentrations of total arsenic. Contingency tables tested for significant differences in total arsenic between aquifers, topographic settings, and well depths. Concentrations of total arsenic were significantly greater (95-percent confidence level) in the Lock Haven Formation than in the other bedrock units. Concentrations of total arsenic also varied significantly by topographic setting. Wells completed in the Lock Haven Formation and located in valleys had significantly greater concentrations of total arsenic than similar wells located on hilltops or slopes. Concentrations of total arsenic did not vary significantly by topographic setting in the Catskill Formation. Concentrations of total arsenic did not vary significantly by well depth for any aquifer. Iron staining, hydrogen-sulfide odor, or both were common complaints of well owners. Iron staining was a complaint of 44 well owners. Hydrogen-sulfide odor was a complaint of 35 well owners. Fourteen well owners complained of both iron staining and hydrogen sulfide. No correlation to the presence of arsenic in the wells sampled was found with iron staining, hydrogen-sulfide odor, or both. Water from 8 of the 10 wells that contained concentrations of total arsenic greater than 10 µg/L were sampled by USGS personnel for the determination of concentrations of dissolved arsenic (minimum reporting level 0.3 µg/L) and arsenic species {arsenite [As (III)], arsenate [As (V)], monomethylarsonate (MMA), and dimethylarsinate (DMA)} at the USGS National Water Quality Laboratory. Analytical results from these samples showed a median concentration of 38.7 µg/L dissolved arsenic in water and a maximum of 178 µg/L. As (III) was the most common arsenic species present in the water for seven of the eight wells and was found in water characteristic of reducing environments [pH 8.2 to 9.1, dissolved oxygen 0.06 to 0.29 milligrams per liter (mg/L), and oxidation reduction potential -63 to -203 millivolts (mv)]. As (V) was the dominant arsenic species in water characteristic of an oxidizing environment (pH 4.8, dissolved oxygen 2.15 mg/L, oxidation reduction potential 265 mv). The arsenic species MMA and DMA were detected in the water from two wells. The arsenic species MMA was detected at an estimated concentration of 0.9 µg/L in water from one well; the concentration was less than 1.2 µg/L in water from seven wells. The arsenic species DMA was detected at concentrations of 1.0 and 1.5 µg/L in water from two wells; the concentration was less than 0.6 µg/L in water from six wells. Both wells that contained detectable concentrations of MMA and DMA produced water that was characteristic of reducing environments.

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USGS2007

Analysis of flood-magnitude and flood-frequency data for streamflow-gaging stations in the Delaware and North Branch Susquehanna River Basins in Pennsylvania

The Delaware and North Branch Susquehanna River Basins in Pennsylvania experienced severe flooding as a result of intense rainfall during June 2006. The height of the flood waters on the rivers and tributaries approached or exceeded the peak of record at many locations. Updated flood-magnitude and flood-frequency data for streamflow-gaging stations on tributaries in the Delaware and North Branch Susquehanna River Basins were analyzed using data through the 2006 water year to determine if there were any major differences in the flood-discharge data. Flood frequencies for return intervals of 2, 5, 10, 50, 100, and 500 years (Q2, Q5, Q10, Q50, Q100, and Q500) were determined from annual maximum series (AMS) data from continuous-record gaging stations (stations) and were compared to flood discharges obtained from previously published Flood Insurance Studies (FIS) and to flood frequencies using partial-duration series (PDS) data. A Wilcoxon signed-rank test was performed to determine any statistically significant differences between flood frequencies computed from updated AMS station data and those obtained from FIS. Percentage differences between flood frequencies computed from updated AMS station data and those obtained from FIS also were determined for the 10, 50, 100, and 500 return intervals. A Mann-Kendall trend test was performed to determine statistically significant trends in the updated AMS peak-flow data for the period of record at the 41 stations. In addition to AMS station data, PDS data were used to determine flood-frequency discharges. The AMS and PDS flood-frequency data were compared to determine any differences between the two data sets. An analysis also was performed on AMS-derived flood frequencies for four stations to evaluate the possible effects of flood-control reservoirs on peak flows. Additionally, flood frequencies for three stations were evaluated to determine possible effects of urbanization on peak flows. The results of the Wilcoxon signed-rank test showed a significant difference at the 95-percent confidence level between the Q100 computed from AMS station data and the Q100 determined from previously published FIS for 97 sites. The flood-frequency discharges computed from AMS station data were consistently larger than the flood discharges from the FIS; mean percentage difference between the two data sets ranged from 14 percent for the Q100 to 20 percent for the Q50. The results of the Mann-Kendall test showed that 8 stations exhibited a positive trend (i.e., increasing annual maximum peaks over time) over their respective periods of record at the 95-percent confidence level, and an additional 7 stations indicated a positive trend, for a total of 15 stations, at a confidence level of greater than or equal to 90 percent. The Q2, Q5, Q10, Q50, and Q100 determined from AMS and PDS data for each station were compared by percentage. The flood magnitudes for the 2-year return period were 16 percent higher when partial-duration peaks were incorporated into the analyses, as opposed to using only the annual maximum peaks. The discharges then tended to converge around the 5-year return period, with a mean collective difference of only 1 percent. At the 10-, 50-, and 100-year return periods, the flood magnitudes based on annual maximum peaks were, on average, 6 percent higher compared to corresponding flood magnitudes based on partial-duration peaks. Possible effects on flood peaks from flood-control reservoirs and urban development within the basin also were examined. Annual maximum peak-flow data from four stations were divided into pre- and post-regulation periods. Comparisons were made between the Q100 determined from AMS station data for the periods of record pre- and post-regulation. Two stations showed a nearly 60- and 20-percent reduction in the 100-year discharges; the other two stations showed negligible differences in discharges. Three stations within urban basins were compared to 38 stations

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