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Research about Pennsylvania

Source-linked reports with geographic coverage including Pennsylvania.

At least 181 records · Page 10Linked to original sources

Reproductive health indicators of fishes from Pennsylvania watersheds: association with chemicals of emerging concern

Fishes were collected at 16 sites within the three major river drainages (Delaware, Susquehanna, and Ohio) of Pennsylvania. Three species were evaluated for biomarkers of estrogenic/antiandrogenic exposure, including plasma vitellogenin and testicular oocytes in male fishes. Smallmouth bass Micropterus dolomieu , white sucker Catostomus commersonii , and redhorse sucker Moxostoma species were collected in the summer, a period of low flow and low reproductive activity. Smallmouth bass were the only species in which testicular oocytes were observed; however, measurable concentrations of plasma vitellogenin were found in male bass and white sucker. The percentage of male bass with testicular oocytes ranged from 10 to 100 %, with the highest prevalence and severity in bass collected in the Susquehanna drainage. The percentage of males with plasma vitellogenin ranged from 0 to 100 % in both bass and sucker. Biological findings were compared with chemical analyses of discrete water samples collected at the time of fish collections. Estrone concentrations correlated with testicular oocytes prevalence and severity and with the percentage of male bass with vitellogenin. No correlations were noted with the percentage of male sucker with vitellogenin and water chemical concentrations. The prevalence and severity of testicular oocytes in bass also correlated with the percent of agricultural land use in the watershed above a site. Two sites within the Susquehanna drainage and one in the Delaware were immediately downstream of wastewater treatment plants to compare results with upstream fish. The percentage of male bass with testicular oocytes was not consistently higher downstream; however, severity did tend to increase downstream.

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Spatial and temporal Brook Trout density dynamics: Implications for conservation, management, and monitoring

Many potential stressors to aquatic environments operate over large spatial scales, prompting the need to assess and monitor both site-specific and regional dynamics of fish populations. We used hierarchical Bayesian models to evaluate the spatial and temporal variability in density and capture probability of age-1 and older Brook Trout Salvelinus fontinalis from three-pass removal data collected at 291 sites over a 37-year time period (1975–2011) in Pennsylvania streams. There was high between-year variability in density, with annual posterior means ranging from 2.1 to 10.2 fish/100 m 2 ; however, there was no significant long-term linear trend. Brook Trout density was positively correlated with elevation and negatively correlated with percent developed land use in the network catchment. Probability of capture did not vary substantially across sites or years but was negatively correlated with mean stream width. Because of the low spatiotemporal variation in capture probability and a strong correlation between first-pass CPUE (catch/min) and three-pass removal density estimates, the use of an abundance index based on first-pass CPUE could represent a cost-effective alternative to conducting multiple-pass removal sampling for some Brook Trout monitoring and assessment objectives. Single-pass indices may be particularly relevant for monitoring objectives that do not require precise site-specific estimates, such as regional monitoring programs that are designed to detect long-term linear trends in density.

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Evaluation of catch-and-release regulations on Brook Trout in Pennsylvania streams

In 2004, the Pennsylvania Fish and Boat Commission implemented catch-and-release (CR) regulations on headwater stream systems to determine if eliminating angler harvest would result in an increase in the number of adult (≥100 mm) or large (≥175 mm) Brook Trout Salvelinus fontinalis . Under the CR regulations, angling was permitted on a year-round basis, no Brook Trout could be harvested at any time, and there were no tackle restrictions. A before-after–control-impact design was used to evaluate the experimental regulations. Brook Trout populations were monitored in 16 treatment (CR regulations) and 7 control streams (statewide regulations) using backpack electrofishing gear periodically for up to 15 years (from 1990 to 2003 or 2004) before the implementation of the CR regulations and over a 7–8-year period (from 2004 or 2005 to 2011) after implementation. We used Poisson mixed models to evaluate whether electrofishing catch per effort (CPE; catch/100 m 2 ) of adult (≥100 mm) or large (≥175 mm) Brook Trout increased in treatment streams as a result of implementing CR regulations. Brook Trout CPE varied among sites and among years, and there was no significant effect (increase or decrease) of CR regulations on the CPE of adult or large Brook Trout. Results of our evaluation suggest that CR regulations were not effective at improving the CPE of adult or large Brook Trout in Pennsylvania streams. Low angler use, high voluntary catch and release, and slow growth rates in infertile headwater streams are likely the primary reasons for the lack of response.

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Surface disposal of produced waters in western and southwestern Pennsylvania: potential for accumulation of alkali-earth elements in sediments

Waters co-produced with hydrocarbons in the Appalachian Basin are of notably poor quality (concentrations of total dissolved solids (TDS) and total radium up to and exceeding 300,000 mg/L and 10,000 pCi/L, respectively). Since 2008, a rapid increase in Marcellus Shale gas production has led to a commensurate rise in associated wastewater while generation of produced water from conventional oil and gas activities has continued. In this study, we assess whether disposal practices from treatment of produced waters from both shale gas and conventional operations in Pennsylvania could result in the accumulation of associated alkali earth elements. The results from our 5 study sites indicate that there was no increase in concentrations of total Ra (Ra-226) and extractable Ba, Ca, Na, or Sr in fluvial sediments downstream of the discharge outfalls (p > 0.05) of publicly owned treatment works (POTWs) and centralized waste treatment facilities (CWTs). However, the use of road spreading of brines from conventional oil and gas wells for deicing resulted in accumulation of Ra-226 (1.2 ×), and extractable Sr (3.0 ×), Ca (5.3 ×), and Na (6.2 ×) in soil and sediment proximal to roads (p < 0.05). Although this study is an important initial assessment of the impacts of these disposal practices, more work is needed to consider the environmental consequences of produced waters management.

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Spectral masking of goethite in abandoned mine drainage systems: implications for Mars

Remote sensing studies of the surface of Mars use visible- to near-infrared (VNIR) spectroscopy to identify hydrated and hydroxylated minerals, which can be used to constrain past environmental conditions on the surface of Mars. However, due to differences in optical properties, some hydrated phases can mask others in VNIR spectra, complicating environmental interpretations. Here, we examine the role of masking in VNIR spectra of natural precipitates of ferrihydrite, schwertmannite, and goethite from abandoned mine drainage (AMD) systems in southeastern Pennsylvania. Mixtures of ferrihydrite, schwertmannite, and goethite were identified in four AMD sites by using X-ray diffractometry (XRD), and their XRD patterns compared to their VNIR spectra. We find that both ferrihydrite and schwertmannite can mask goethite in VNIR spectra of natural AMD precipitates. These findings suggest that care should be taken in interpreting environments on Mars where ferrihydrite, schwertmannite, or goethite are found, as the former two may be masking the latter. Additionally, our findings suggest that outcrops on Mars with both goethite and ferrihydrite/schwertmannite VNIR signatures may have high relative abundances of goethite, or the goethite may exist in a coarsely crystalline phase.

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An evaluation of remote sensing technologies for the detection of fugitive contamination at selected Superfund hazardous waste sites in Pennsylvania

This evaluation was conducted to assess the potential for using both traditional remote sensing, such as aerial imagery, and emerging remote sensing technology, such as hyperspectral imaging, as tools for postclosure monitoring of selected hazardous waste sites. Sixteen deleted Superfund (SF) National Priorities List (NPL) sites in Pennsylvania were imaged with a Civil Air Patrol (CAP) Airborne Real-Time Cueing Hyperspectral Enhanced Reconnaissance (ARCHER) sensor between 2009 and 2012. Deleted sites are those sites that have been remediated and removed from the NPL. The imagery was processed to radiance and atmospherically corrected to relative reflectance with standard software routines using the Environment for Visualizing Imagery (ENVI, ITT–VIS, Boulder, Colorado) software. Standard routines for anomaly detection, endmember collection, vegetation stress, and spectral analysis were applied.

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Landscape consequences of natural gas extraction in Bedford, Blair, Cambria, Centre, Clearfield, Clinton, Columbia, Huntingdon, and Luzerne counties, Pennsylvania, 2004-2010

Increased demands for cleaner burning energy, coupled with the relatively recent technological advances in accessing unconventional hydrocarbon-rich geologic formations, have led to an intense effort to find and extract natural gas from various underground sources around the country. One of these sources, the Marcellus Shale, located in the Allegheny Plateau, is currently undergoing extensive drilling and production. The technology used to extract gas in the Marcellus Shale is known as hydraulic fracturing and has garnered much attention because of its use of large amounts of fresh water, its use of proprietary fluids for the hydraulic-fracturing process, its potential to release contaminants into the environment, and its potential effect on water resources. Nonetheless, development of natural gas extraction wells in the Marcellus Shale is only part of the overall natural gas story in this area of Pennsylvania. Conventional natural gas wells, which sometimes use the same technique, are commonly located in the same general area as the Marcellus Shale and are frequently developed in clusters across the landscape. The combined effects of these two natural gas extraction methods create potentially serious patterns of disturbance on the landscape. This document quantifies the landscape changes and consequences of natural gas extraction for Bedford, Blair, Cambria, Centre, Clearfield, Clinton, Columbia, Huntingdon, and Luzerne Counties in Pennsylvania between 2004 and 2010. Patterns of landscape disturbance related to natural gas extraction activities were collected and digitized using National Agriculture Imagery Program (NAIP) imagery for 2004, 2005/2006, 2008, and 2010. The disturbance patterns were then used to measure changes in land cover and land use using the National Land Cover Database (NLCD) of 2001. A series of landscape metrics is also used to quantify these changes and is included in this publication. In this region, natural gas development disturbed approximately 943 hectares of land in which forest sustained three times the amount of disturbance as agricultural land. One-quarter of that total disturbance was from Marcellus natural gas development.

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Baseline groundwater quality from 34 wells in Wayne County, Pennsylvania, 2011 and 2013

Wayne County, Pennsylvania, is underlain by the Marcellus Shale, which currently (2014) is being developed elsewhere in Pennsylvania for natural gas. All residents of largely rural Wayne County rely on groundwater for water supply, primarily from bedrock aquifers (shales and sandstones). This study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for Wayne County prior to development of the natural gas resource in the Marcellus Shale. Selected wells completed in the Devonian-age Catskill Formation, undifferentiated; the Poplar Gap and Packerton Members of the Catskill Formation, undivided; and the Long Run and Walcksville Members of the Catskill Formation, undivided, were sampled. Water samples were collected once from 34 domestic wells during August 2011 and August and September 2013 and analyzed to characterize their physical and chemical quality. Samples were analyzed for 45 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. The quality of the sampled groundwater was generally within U.S. Environmental Protection Agency (USEPA) drinking-water standards, although in some samples, the concentrations of a few constituents exceeded USEPA drinking-water standards and health advisories. The pH of water samples ranged from 5.5 to 9.3 with a median of 7.0. The pH was outside the USEPA secondary maximum contaminant level (SMCL) range of 6.5 to 8.5 in water samples from 14 of the 34 wells (41 percent). Eleven samples had a pH less than 6.5, and three samples had a pH greater than 8.5. Dissolved oxygen concentrations ranged from 0.2 to 11.5 milligrams per liter (mg/L) with a median of 4.7 mg/L. The dissolved oxygen concentration was less than 1 mg/L in water samples from 6 wells; 5 of these 6 water samples had a pH greater than 7.7. Concentrations of dissolved methane ranged from less than 0.00006 to 3.3 mg/L. Methane was detectable in 22 of the 34 wells sampled (65 percent). Methane concentrations were greatest in the 5 samples with pH of 7.8 or higher, ranging from 0.040 to 3.3 mg/L. These samples also had among the lowest concentrations of dissolved oxygen. Three water samples, which had sufficient dissolved methane concentrations (greater than 0.9 mg/L), were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell within (two samples) or close to (one sample) the range for a thermogenic natural gas source. The total dissolved solids concentration ranged from 33 to 346 mg/L; the median concentration was 126 mg/L. Sodium concentrations ranged from 1.07 to 116 mg/L; the median concentration was 9.42 mg/L. The sodium concentration exceeded the USEPA health advisory for sodium of 20 mg/L in water samples from 7 of the 34 wells (21 percent). Concentrations of dissolved arsenic ranged from less than 0.06 to 21.8 micrograms per liter (&micro;g/L); the median concentration was 0.59 &micro;g/L. Water samples from 2 of the 34 wells (6 percent) exceeded the USEPA maximum contaminant level (MCL) of 10 &micro;g/L for arsenic. Concentrations of dissolved manganese ranged from less than 0.15 to 61.5 &micro;g/L; the median concentration was 0.42 &micro;g/L. A water sample from 1 of the 34 wells (3 percent) exceeded the USEPA SMCL of 50 &micro;g/L for manganese; the concentration was less than the USEPA lifetime health advisory of 300 &micro;g/L for manganese. Activities of radon-222 in water from the 34 sampled wells ranged from 110 to 7,180 picocuries per liter (pCi/L); the median activity was 2,105 pCi/L. Water samples from 33 of the 34 wells (97 percent) exceeded the proposed USEPA MCL of 300 pCi/L, and 4 water samples (12 percent) exceeded the USEPA proposed alternative MCL of 4,000 pCi/L for radon-222. Differences in groundwater chemistry were related to pH. Water with a pH greater than 7.6 generally had low dissolved oxygen concentrations, indicating reducing conditions in the aquifer. These high pH waters also had relatively elevated concentrations of methane, arsenic, boron, bromide, fluoride, lithium, and sodium but low concentrations of copper, nickel, and zinc. Water samples with a pH greater than 7.8 had methane concentrations equal to or greater than 0.04 mg/L.

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Estimation of methane concentrations and loads in groundwater discharge to Sugar Run, Lycoming County, Pennsylvania

A stream-sampling study was conducted to estimate methane concentrations and loads in groundwater discharge to a small stream in an active shale-gas development area of northeastern Pennsylvania. Grab samples collected from 15 streams in Bradford, Lycoming, Susquehanna, and Tioga Counties, Pa., during a reconnaissance survey in May and June 2013 contained dissolved methane concentrations ranging from less than the minimum reporting limit (1.0) to 68.5 micrograms per liter (µg/L). The stream-reach mass-balance method of estimating concentrations and loads of methane in groundwater discharge was applied to a 4-kilometer (km) reach of Sugar Run in Lycoming County, one of the four streams with methane concentrations greater than or equal to 5 µg/L. Three synoptic surveys of stream discharge and methane concentrations were conducted during base-flow periods in May, June, and November 2013. Stream discharge at the lower end of the reach was about 0.10, 0.04, and 0.02 cubic meters per second, respectively, and peak stream methane concentrations were about 20, 67, and 29 µg/L. In order to refine estimated amounts of groundwater discharge and locations where groundwater with methane discharges to the stream, the lower part of the study reach was targeted more precisely during the successive studies, with approximate spacing between stream sampling sites of 800 meters (m), 400 m, and 200 m, in May, June, and November, respectively. Samples collected from shallow piezometers and a seep near the location of the peak methane concentration measured in streamwater had groundwater methane concentrations of 2,300 to 4,600 µg/L. These field data, combined with one-dimensional stream-methane transport modeling, indicate groundwater methane loads of 1.8 ±0.8, 0.7 ±0.3, and 0.7 ±0.2 kilograms per day, respectively, discharging to Sugar Run. Estimated groundwater methane concentrations, based on the transport modeling, ranged from 100 to 3,200 µg/L. Although total methane load and the uncertainty in calculated loads both decreased with lower streamflow conditions and finer-resolution sampling in June and November, the higher loads during May could indicate seasonal variability in base flow. This is consistent with flowmeter measurements indicating that there was less inflow occurring at lower streamflow conditions during June and November.

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Landscape consequences of natural gas extraction in Cameron, Clarion, Elk, Forest, Jefferson, McKean, Potter, and Warren Counties, Pennsylvania, 2004-2010

Increased demands for cleaner burning energy, coupled with the relatively recent technological advances in accessing hydrocarbon-rich geologic formations, have led to an intense effort to find and extract unconventional natural gas from various underground sources around the country. One of these sources, the Marcellus Shale, located in the Allegheny Plateau, is currently undergoing extensive drilling and production. The technology used to extract gas in the Marcellus Shale is known as hydraulic fracturing and has garnered much attention because of its use of large amounts of fresh water, its use of proprietary fluids for the hydraulic-fracturing process, its potential to release contaminants into the environment, and its potential effect on water resources. Nonetheless, development of natural gas extraction wells in the Marcellus Shale is only part of the overall natural gas story in this area of Pennsylvania. Conventional natural gas wells, which sometimes use the same technique for extraction, are commonly located in the same general area as the Marcellus Shale and are frequently developed in clusters across the landscape. The combined effects of these two natural gas extraction methods create potentially serious patterns of disturbance on the landscape. This document quantifies the landscape changes and consequences of natural gas extraction for Cameron, Clarion, Elk, Forest, Jefferson, McKean, Potter, and Warren Counties in Pennsylvania between 2004 and 2010. Patterns of landscape disturbance related to natural gas extraction activities were collected and digitized using National Agriculture Imagery Program (NAIP) imagery for 2004, 2005/2006, 2008, and 2010. The disturbance patterns were then used to measure changes in land cover and land use using the National Land Cover Database (NLCD) of 2001. A series of landscape metrics is also used to quantify these changes and is included in this publication. In this region, natural gas and oil development disturbed approximately 5,255 hectares (ha) (conventional, 2,400 ha; Marcellus, 357 ha; and oil, 1,883 ha) of land of which 3,507 ha were forested land and 610 ha were agricultural land. Eighty percent of that total disturbance was from conventional natural gas and oil development.

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Urban ecosystem services and decision making for a green Philadelphia

Traditional approaches to urban development often do not account for, or recognize, the role of ecosystem services and the benefits these services provide to the health and well-being of city residents. Without such accounting, urban ecosystem services are likely to be degraded over time, with negative consequences for the sustainability of cities and the well-being of their residents (Millennium Ecosystem Assessment, 2005; Hirsch, 2008). On May 23, 2013, the Spatial Integration Laboratory for Urban Systems (SILUS), a collaboration between the U.S. Geological Survey (USGS) Science and Decisions Center and the Wharton GIS Lab, convened a one-day symposium—Urban Ecosystem Services and Decision Making: A Green Philadelphia—at the University of Pennsylvania in Philadelphia, Pennsylvania, to examine the role of green infrastructure in the environmental, economic, and social well-being of cities. Cosponsored by the USGS and the Penn Institute for Urban Research (Penn IUR), the symposium brought together policymakers, practitioners, and researchers from a range of disciplines to advance a research agenda on the use of science in public decision making to inform investment in green infrastructure and ecosystem services in urban areas. The city of Philadelphia has recently implemented a program designed to sustain urban ecosystem services and advance the use of green infrastructure. In 2009, the Philadelphia Mayor’s Office of Sustainability launched its Greenworks plan, establishing a citywide sustainability strategy. Major contributions towards its goals are being implemented in coordination with the Philadelphia Water Department (PWD). The Green City, Clean Waters initiative, the city’s nationally recognized stormwater management plan, was signed into action with the U.S. Environmental Protection Agency (EPA) in April 2012. The plan outlines a 25-year strategy to use green infrastructure to protect and improve the city’s watershed. Widespread support for the plan marks a citywide effort to factor environmental quality concerns into the city’s strategic planning, choosing to replace expensive and aging grey infrastructure, with innovative and resilient green infrastructure. The symposium focused on these city of Philadelphia initiatives and also on two new Federal- local partnership programs: America’s Great Outdoors, initiated to promote conservation and recreation, and the Urban Waters Federal Partnership, a multiagency effort to reconnect urban communities to their waterways. A second goal of the symposium was to advance a research agenda on urban ecosystem services. While there has been considerable work on ecosystem services, the discussion of the benefits provided by urban ecosystems is not as developed. Benefits range from improved water and air quality to quality of life gains, including aesthetic and recreational considerations. There is also need for additional focused research toward furthering the understanding of the multiple indirect benefits provided by urban ecosystem services (Bolund and Hunhammar, 1999). Moreover, there is a need for a greater understanding of how best to inform local decision making in this area, as local decision makers in cities across the country are increasingly recognizing the importance of developing sustainability measures for their immediate and long-term planning (United States Conference of Mayors, 2005). Approaching these local and regional plans from a holistic perspective has become a guiding principle of sustainability and resiliency. Therefore, there is a need to better understand the gains that have been achieved and to advance a research agenda on ecosystem services going forward. The day’s program included presentations on greening initiatives from the Philadelphia’s Mayor’s Office of Sustainability, as well as discussion about using an urban ecosystem services framework to evaluate these initiatives. Panel sessions included discussion of the Green City, Clean Waters initiative; a dialogue about the management of urban trees and green space; and a conversation addressing the needs for future research.

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Drilling and geophysical logs of the tophole at an oil-and-gas well site, Central Venango County, Pennsylvania

In a study conducted by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey, drilling and geophysical logs were used to characterize the geohydrologic framework and the freshwater and saline-water zones penetrated by the tophole at an oil-and-gas well site in central Venango County, Pennsylvania. The geohydrologic setting of the well site is typical of the dissected Appalachian Plateau underlain by Pennsylvanian and Mississippian sandstone and shale. The drilling, gamma, and acoustic-televiewer logs collected from the 575-foot deep tophole define the penetrated Pennsylvanian and Mississippian stratigraphic units and their lithology. The caliper, video, and acoustic-televiewer logs delineate multiple bedding-related and high-angle fractures in the lower Pottsville Group and Shenango Formation from 22 to 249 feet below land surface. The caliper and acoustic-televiewer logs indicate a sparsity of fractures below 249 feet below land surface in the lowermost Shenango Formation, Cuyahoga Group, Corry Sandstone, &ldquo;Drake Well&rdquo; formation, and upper Riceville Formation. About half of the blown yield during drilling of the tophole was from fractures in the upper Shenango Formation between 80 and 167 feet below land surface and the other half from fractures in the lower Shenango between 190 and 249 feet below land surface. Following drilling, fractures above the water level at about 145 feet below land surface produced freshwater with a specific conductance of less than 150 microsiemens per centimeter at 25 degrees Celsius that cascaded down the hole. As indicated by the fluid resistivity and temperature logs, most of the downflow exited the hole at the water-bearing fractures at 249 feet below land surface. The downward flow in the tophole reflects the downward hydraulic gradient between the water-bearing fractures above the water level and those at 249 feet below land surface. Low conductivity and high resistivity values on the dual induction logs indicate freshwater above 285 feet below land surface in the Shenango sandstones, which is consistent with a specific conductance of blown yield of 400 microsiemens per centimeter at 25 degrees Celsius at 200 feet below land surface. High conductivity and low resistivity values on the induction logs indicate the presence of saline water below 450 feet in the Corry Sandstone. The highest specific conductance of the blown yield, 1,200 microsiemens per centimeter at 25 degrees Celsius, was measured at 480 feet below land surface following penetration of the Corry Sandstone. Collection and integrated analysis of drilling and geophysical logs provided an efficient and effective means for characterizing the geohydrologic framework and conditions penetrated by the tophole at the selected oil-and-gas well site. The logging methods and lessons learned at this well site could be applied at other oil-and-gas drilling sites to better characterize the shallow subsurface with the overall goal of protecting freshwater aquifers during hydrocarbon development.

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Calibration of a two-dimensional hydrodynamic model for parts of the Allegheny, Monongahela, and Ohio Rivers, Allegheny County, Pennsylvania

The U.S. Geological Survey (USGS), in cooperation with the Allegheny County Sanitary Authority, developed a validated two-dimensional Resource Management Associates2 (RMA2) hydrodynamic model of parts of the Allegheny, Monongahela, and Ohio Rivers (Three Rivers) to help assess the effects of combined sewer overflows (CSOs) and sanitary sewer overflows (SSOs) on the rivers. The hydrodynamic model was used to drive a water-quality model of the study area that was capable of simulating the transport and fate of fecal-indicator bacteria and chemical constituents under open-water conditions. The study area includes 14 tributary streams and parts of the Three Rivers where they enter and exit Allegheny County, an area of approximately 730 square miles (mi 2 ). The city of Pittsburgh is near the center of the county, where the Allegheny and Monongahela Rivers join to form the headwaters of the Ohio River. The Three Rivers are regulated by a series of fixed-crest dams, gated dams, and radial (tainter) gates and serve as the receiving waters for tributary streams, CSOs, and SSOs. The RMA2 model was separated into four individual segments on the basis of the U.S. Army Corps of Engineers navigational pools in the study area (Dashields; Emsworth; Allegheny River, Pool 2; and Braddock), which were calibrated individually using measured water-surface slope, velocity, and discharge during high- and low-flow conditions. The model calibration process included the comparison of water-surface elevations at five locations and velocity profiles at more than 80 cross sections in the study area. On the basis of the calibration and validation results that included water-surface elevations and velocities, the model is a representative simulation of the Three Rivers flow patterns for discharges ranging from 4,050 to 47,400 cubic feet per second (ft 3 /s) on the Allegheny River, 2,550 to 40,000 ft 3 /s on the Monongahela River, and 10,900 to 99,000 ft 3 /s on the Ohio River. The Monongahela River was characterized by unsteady conditions during low and high flows, which affected the calibration range. The simulated low-flow water-surface elevations typically were within 0.2 feet (ft) of measured values, whereas the simulated high-flow water-surface elevations were typically within 0.3 ft of the measured values. The mean error between simulated and measured velocities was less than 0.07 ft/s for low-flow conditions and less than 0.17 ft/s for high-flow conditions.

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Flood-inundation maps for the Susquehanna River near Harrisburg, Pennsylvania, 2013

A series of 28 digital flood-inundation maps was developed for an approximate 25-mile reach of the Susquehanna River in the vicinity of Harrisburg, Pennsylvania. The study was selected by the U.S. Army Corps of Engineers (USACE) national Silver Jackets program, which supports interagency teams at the state level to coordinate and collaborate on flood-risk management. This study to produce flood-inundation maps was the result of a collaborative effort between the USACE, National Weather Service (NWS), Susquehanna River Basin Commission (SRBC), The Harrisburg Authority, and the U.S. Geological Survey (USGS). These maps are accessible through Web-mapping applications associated with the NWS, SRBC, and USGS. The maps can be used in conjunction with the real-time stage data from the USGS streamgage 01570500, Susquehanna River at Harrisburg, Pa., and NWS flood-stage forecasts to help guide the general public in taking individual safety precautions and will provide local municipal officials with a tool to efficiently manage emergency flood operations and flood mitigation efforts. The maps were developed using the USACE HEC–RAS and HEC–GeoRAS programs to compute water-surface profiles and to delineate estimated flood-inundation areas for selected stream stages. The maps show estimated flood-inundation areas overlaid on high-resolution, georeferenced, aerial photographs of the study area for stream stages at 1-foot intervals between 11 feet and 37 feet (which include NWS flood categories Action, Flood, Moderate, and Major) and the June 24, 1972, peak-of-record flood event at a stage of 33.27 feet at the Susquehanna River at Harrisburg, Pa., streamgage.

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Flood-inundation maps for the West Branch Susquehanna River near the Boroughs of Lewisburg and Milton, Pennsylvania

Digital flood-inundation maps for an approximate 8-mile reach of the West Branch Susquehanna River from approximately 2 miles downstream from the Borough of Lewisburg, extending upstream to approximately 1 mile upstream from the Borough of Milton, Pennsylvania, were created by the U.S. Geological Survey (USGS) in cooperation with the Susquehanna River Basin Commission (SRBC). The inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation/ , depict the estimated areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage 01553500, West Branch Susquehanna River at Lewisburg, Pa. In addition, the information has been provided to the Susquehanna River Basin Commission (SRBC) for incorporation into their Susquehanna Inundation Map Viewer (SIMV) flood warning system ( http://maps.srbc.net/simv/ ). The National Weather Service (NWS) forecasted peak-stage information ( http://water.weather.gov/ahps ) for USGS streamgage 01553500, West Branch Susquehanna River at Lewisburg, Pa., may be used in conjunction with the maps developed in this study to show predicted areas of flood inundation. In this study, flood profiles were computed for the stream reach by means of a one-dimensional step-backwater model. Calibration of the model was achieved using the most current stage-discharge relations (rating number 11.1) at USGS streamgage 01553500, West Branch Susquehanna River at Lewisburg, Pa., a documented water-surface profile from the December 2, 2010, flood, and recorded peak stage data. The hydraulic model was then used to determine 26 water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datum ranging from 14 feet (ft) to 39 ft. Modeled flood stages, as defined by NWS, include Action Stage, 14 ft; Flood Stage, 18 ft; Moderate Flood Stage, 23 ft; and Major Flood Stage, 28 ft. Geographic information system (GIS) technology was then used to combine the simulated water-surface profiles with a digital elevation model (DEM) derived from light detection and ranging (lidar) data to delineate the area flooded at each water level. The availability of these maps, along with World Wide Web information regarding current stage from USGS streamgages and forecasted stream stages from the NWS, provide emergency management personnel and residents with information that is critical for flood response activities, such as evacuations and road closures, as well as for post-flood recovery efforts.

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A reconnaissance spatial and temporal assessment of methane and inorganic constituents in groundwater in bedrock aquifers, Pike County, Pennsylvania, 2012-13

Pike County in northeastern Pennsylvania is underlain by the Devonian-age Marcellus Shale and other shales, formations that have potential for natural gas development. During 2012&ndash;13, the U.S. Geological Survey in cooperation with the Pike County Conservation District conducted a reconnaissance study to assess baseline shallow groundwater quality in bedrock aquifers prior to possible shale-gas development in the county. For the spatial component of the assessment, 20 wells were sampled in summer 2012 to provide data on the occurrence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines. For the temporal component of the assessment, 4 of the 20 wells sampled in summer 2012 were sampled monthly from July 2012 through June 2013 to provide data on seasonal variability in groundwater quality. All water samples were analyzed for major ions, nutrients, selected inorganic trace constituents (including metals and other elements), stable isotopes of water, radon-222, gross alpha- and gross beta-particle activity, dissolved gases (methane, ethane, and ethene), and, if possible, isotopic composition of methane. Additional analyses for boron and strontium isotopes, age-dating of water, and radium-226 were done on water samples collected from six wells in June 2013. Results of the summer 2012 sampling show that water from 16 (80 percent) of 20 wells had detectable concentrations of methane, but concentrations were less than 0.1 milligram per liter (mg/L) in most well-water samples; only two well-water samples had concentrations greater than 1 mg/L. The groundwater with elevated methane also had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with low methane concentrations. The two well-water samples with the highest methane concentrations (about 3.7 and 5.8 mg/L) also had the highest pH values (8.7 and 8.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, and bromide. Elevated concentrations of some other constituents, such as barium, strontium, and chloride, were not limited to well-water samples with elevated methane, although the two samples with elevated methane also had among the highest concentrations of these constituents. One sample with elevated methane concentrations also had elevated arsenic concentrations, with the arsenic concentration of 30 micrograms per liter (&mu;g/L) exceeding the drinking-water standard of 10 &micro;g/L for arsenic. No other sample from the 20 wells sampled in summer 2012 had concentrations of constituents that exceeded any established primary drinking-water standards. However, radon-222 activities ranging up to 4,500 picocuries per liter (pCi/L) exceeded the proposed drinking-water standard of 300 pCi/L in 85 percent of the 20 well-water samples. The isotopic composition methane in the two high-methane samples (&delta;C CH4 values of -64.55 and -64.41 per mil and &delta;D CH4 values of -216.9 and -201.8 per mil, respectively) indicates a predominantly microbial source for the methane formed by a carbon dioxide reduction process. The stable isotopic composition of water (&delta;D H20 and &delta; 18 O H20 ) in samples from all 20 wells falls on the local meteoric line, indicating water in the wells was of relatively recent meteoric origin (modern precipitation), including samples with elevated methane concentrations. Analytical results for 4 of the 20 wells sampled monthly for 1 year ending June 2013 in order to assess temporal variability in groundwater quality show that concentrations of major ions generally varied by less than 20 percent, with most differences less than 4 mg/L. Concentrations of methane varied by less than 1 &mu;g/L (0.001 mg/L) in samples from three wells with low methane and by as much as 1 mg/L (1,000 &mu;g/L) in samples from one well with relatively high methane. The isotopic composition of methane in the one well with relatively high methane varied slightly in the monthly samples, ranging from about -64.5 to -64.8 per mil for &delta; 13 C CH4 and from about -217 to -228 per mil for &delta;D CH4 . The &delta; 13 C values for dissolved inorganic carbon (DIC) in water from this well were consistent with microbial methane formation by carbon dioxide reduction (drift-type methane) and varied little in the temporal samples, ranging from -10.5 to -10.1 per mil. Additional analyses of samples collected in late June 2013 from six wells with a range of methane and trace constituent concentrations provided baseline data on strontium and boron isotopic compositions ( 87 Sr/ 86 Sr ratios and &delta; 11 B, respectively) that potentially may be used to differentiate among sources of these constituents. The strontium and boron isotopic composition determined in the six shallow Pike County groundwater samples had 87 Sr/ 86 Sr ratios of 0.71426 to 0.71531 and &delta; 11 B values of 11.7 to 27.0 per mil, which differ from those reported for brines in Devonian-age formations in Pennsylvania. The June 2013 samples were also analyzed for radium-226 and age-dating dissolved gases. Activities of radium-226 ranged from 0.041 to 0.29 pCi/L in water samples from the six wells and were less than the drinking-water standard of 5 pCi/L for combined radium-226 and radium-228. Age-dating of groundwater using a method based on the presence of anthropogenic gases (chlorofluorocarbons and sulfur hexafluoride) released into the atmosphere yielded estimated recharge dates for water from these six wells that ranged from the 1940s to early 2000s. The oldest water was in samples from wells that had the highest methane concentrations and the youngest water was in samples from a continuously pumped 300-foot deep production well.

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Understanding water column and streambed thermal refugia for endangered mussels in the Delaware River

Groundwater discharge locations along the upper Delaware River, both discrete bank seeps and diffuse streambed upwelling, may create thermal niche environments that benefit the endangered dwarf wedgemussel (Alasmidonta heterodon). We seek to identify whether discrete or diffuse groundwater inflow is the dominant control on refugia. Numerous springs and seeps were identified at all locations where dwarf wedgemussels still can be found. Infrared imagery and custom high spatial resolution fiber-optic distributed temperature sensors reveal complex thermal dynamics at one of the seeps with a relatively stable, cold groundwater plume extending along the streambed/water-column interface during mid-summer. This plume, primarily fed by a discrete bank seep, was shown through analytical and numerical heat-transport modeling to dominate temperature dynamics in the region of potential habitation by the adult dwarf wedgemussel.

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Surface-water and groundwater interactions in an extensively mined watershed, upper Schuylkill River, Pennsylvania, USA

Streams crossing underground coal mines may lose flow, while abandoned mine drainage (AMD) restores flow downstream. During 2005-12, discharge from the Pine Knot Mine Tunnel, the largest AMD source in the upper Schuylkill River Basin, had near-neutral pH and elevated concentrations of iron, manganese, and sulfate. Discharge from the tunnel responded rapidly to recharge but exhibited a prolonged recession compared to nearby streams, consistent with rapid infiltration and slow release of groundwater from the mine. Downstream of the AMD, dissolved iron was attenuated by oxidation and precipitation while dissolved CO 2 degassed and pH increased. During high-flow conditions, the AMD and downstream waters exhibited decreased pH, iron, and sulfate with increased acidity that were modeled by mixing net-alkaline AMD with recharge or runoff having low ionic strength and low pH. Attenuation of dissolved iron within the river was least effective during high-flow conditions because of decreased transport time coupled with inhibitory effects of low pH on oxidation kinetics. A numerical model of groundwater flow was calibrated using groundwater levels in the Pine Knot Mine and discharge data for the Pine Knot Mine Tunnel and the West Branch Schuylkill River during a snowmelt event in January 2012. Although the calibrated model indicated substantial recharge to the mine complex took place away from streams, simulation of rapid changes in mine pool level and tunnel discharge during a high flow event in May 2012 required a source of direct recharge to the Pine Knot Mine. Such recharge produced small changes in mine pool level and rapid changes in tunnel flow rate because of extensive unsaturated storage capacity and high transmissivity within the mine complex. Thus, elimination of stream leakage could have a small effect on the annual discharge from the tunnel, but a large effect on peak discharge and associated water quality in streams.

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