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Research about Pacific Ocean

Source-linked reports with geographic coverage including Pacific Ocean.

At least 37 records · Page 2Linked to original sources

Climatic forcing of Quaternary deep-sea benthic communities in the North Pacific Ocean

There is growing evidence that changes in deep-sea benthic ecosystems are modulated by climate changes, but most evidence to date comes from the North Atlantic Ocean. Here we analyze new ostracod and published foraminiferal records for the last 250,000 years on Shatsky Rise in the North Pacific Ocean. Using linear models, we evaluate statistically the ability of environmental drivers (temperature, productivity, and seasonality of productivity) to predict changes in faunal diversity, abundance, and composition. These microfossil data show glacial-interglacial shifts in overall abundances and species diversities that are low during glacial intervals and high during interglacials. These patterns replicate those previously documented in the North Atlantic Ocean, suggesting that the climatic forcing of the deep-sea ecosystem is widespread, and possibly global in nature. However, these results also reveal differences with prior studies that probably reflect the isolated nature of Shatsky Rise as a remote oceanic plateau. Ostracod assemblages on Shatsky Rise are highly endemic but of low diversity, consistent with the limited dispersal potential of these animals. Benthic foraminifera, by contrast, have much greater dispersal ability and their assemblages at Shatsky Rise show diversities typical for deep-sea faunas in other regions. Statistical analyses also reveal ostracod-foraminferal differences in relationships between environmental drivers and biotic change. Rarefied diversity is best explained as a hump-shaped function of surface productivity in ostracods, but as having a weak and positive relationship with temperature in foraminifera. Abundance shows a positive relationship with both productivity and seasonality of productivity in foraminifera, and a hump-shaped relationship with productivity in ostracods. Finally, species composition in ostracods is influenced by both temperature and productivity, but only a temperature effect is evident in foraminifera. Though complex in detail, the global-scale link between deep-sea ecosystems and Quaternary climate changes underscores the importance of the interaction between the physical and biological components of paleoceanographical research for better understanding the history of the biosphere.

Paleobiology↗

Stratospheric microbiology at 20 km over the Pacific Ocean

An aerobiology sampling flight at 20 km was conducted on 28 April 2008 over the Pacific Ocean (36.5° N, 118–149° W), a period of time that coincided with the movement of Asian dust across the ocean. The aim of this study was to confirm the presence of viable bacteria and fungi within a transoceanic, atmospheric bridge and to improve the resolution of flight hardware processing techniques. Isolates of the microbial strains recovered were analyzed with ribosomal ribonucleic acid (rRNA) sequencing to identify bacterial species Bacillus sp., Bacillus subtilis, Bacillus endophyticus, and the fungal genus Penicillium. Satellite imagery and ground-based radiosonde observations were used to measure dust movement and characterize the high-altitude environment at the time of collection. Considering the atmospheric residency time (7–10 days), the extreme temperature regime of the environment (-75°C), and the absence of a mechanism that could sustain particulates at high altitude, it is unlikely that our samples indicate a permanent, stratospheric ecosystem. However, the presence of viable fungi and bacteria in transoceanic stratosphere remains relevant to understanding the distribution and extent of microbial life on Earth.

Aerobiologia↗

Retrospective characterization of ontogenetic shifts in killer whale diets via δ13C and δ15N analysis of teeth

Metabolically inert, accretionary structures such as the dentin growth layers in teeth provide a life history record of individual diet with near-annual resolution. We constructed ontogenetic δ 13 C and δ 15 N profiles by analyzing tooth dentin growth layers from 13 individual killer whales Orcinus orca collected in the eastern northeast Pacific Ocean between 1961 and 2003. The individuals sampled were 6 to 52 yr old, representing 2 ecotypes—resident and transient—collected across ~25° of latitude. The average isotopic values of transient individuals (n = 10) are consistent with a reliance on mammalian prey, while the average isotopic values of residents (n = 3) are consistent with piscivory. Regardless of ecotype, most individuals show a decrease in δ 15 N values of ~2.5‰ through the first 3 yr of life, roughly equivalent to a decrease of one trophic level. We interpret this as evidence of gradual weaning, after which, ontogenetic shifts in isotopic values are highly variable. A few individuals (n = 2) maintained relatively stable δ 15 N and δ 13 C values throughout the remainder of their lives, whereas δ 15 N values of most (n = 11) increased by ~1.5‰, suggestive of an ontogenetic increase in trophic level. Significant differences in mean δ 13 C and δ 15 N values among transients collected off California suggest that individuality in prey preferences may be prevalent within this ecotype. Our approach provides retrospective individual life history and dietary information that cannot be obtained through traditional field observations of free-ranging and elusive species such as killer whales, including unique historic ecological information that pre-dates modern studies. By providing insights into individual diet composition, stable isotope analysis of teeth and/or bones may be the only means of evaluating a number of hypothesized historical dietary shifts in killer whales of the northeast Pacific Ocean

California↗

Pacific Ocean and Cenozoic evolution of climate

The Pacific Ocean has played a major role in climate evolution throughout the Cenozoic (65–0 Ma). It is a fundamental component of global heat transport and circulation, the dominant locus of primary productivity, and, consequently, the largest reservoir for carbon exchange between the oceans and the atmosphere. A satisfactory understanding of the Cenozoic evolutionary history of the Pacific and its impact on global climate is currently data-limited. Nevertheless, the large dynamic range of Cenozoic conditions sets the stage to greatly expand our understanding of global climate and biogeochemical cycles. Past Earth “experiments” are particularly useful to understand interactions between climate and geosystems under different greenhouse gas loads. We highlight in this review four important problems in which the Pacific played a major role: the effect of changing geographic boundary conditions on ocean circulation; interactions between the carbon cycle and climate; the Pacific Ocean's influence on North American climate and its water cycle; and the gradual evolution of climate systems.

Reviews of Geophysics↗

Helium isotopes in ferromanganese crusts from the central Pacific Ocean

Helium isotopes have been measured in samples of two ferromanganese crusts (VA13/2 and CD29-2) from the central Pacific Ocean. With the exception of the deepest part of crust CD29-2 the data can be explained by a mixture of implanted solar- and galactic cosmic ray-produced (GCR) He, in extraterrestrial grains, and radiogenic He in wind-borne continental dust grains. 4 He concentrations are invariant and require retention of less than 12% of the in situ He produced since crust formation. Loss has occurred by recoil and diffusion. High 4 He in CD29-2 samples older than 42 Ma are correlated with phosphatization and can be explained by retention of up to 12% of the in situ-produced 4 He. 3 He/ 4 He of VA13/2 samples varies from 18.5 to 1852 Ra due almost entirely to variation in the extraterrestrial He contribution. The highest 3 He/ 4 He is comparable to the highest values measured in interplanetary dust particles (IDPs) and micrometeorites (MMs). Helium concentrations are orders of magnitude lower than in oceanic sediments reflecting the low trapping efficiency for in-falling terrestrial and extraterrestrial grains of Fe-Mn crusts. The extraterrestrial 3 He concentration of the crusts rules out whole, undegassed 4–40 μm diameter IDPs as the host. Instead it requires that the extraterrestrial He inventory is carried by numerous particles with significantly lower He concentrations, and occasional high concentration GCR-He-bearing particles.

Geochimica et Cosmochimica Acta↗

Overview: DVD-video disc set of seafloor transects during USGS research cruises in the Pacific Ocean

Many USGS research programs involve the gathering of underwater seafloor video footage. This footage was captured on a variety of media, including Beta III and VHS tapes. Much of this media is now deteriorating, prompting the migration of this video footage onto DVD-Video discs. Advantages of using DVD-Video discs are: less storage space, ease of transport, wider distribution, and non-degradational viewing of the media. The videos in this particular collection (328 of them) were made on the ocean floor under President Reagan's Exclusive Economic Zone proclamation of 1983. There are now five copies of these 328 discs in existence: at the USGS libraries in Menlo Park, Calif., Denver, Colo., and Reston, Va.; at the USGS Publications Warehouse (masters from which to make copies for customers); and Hank Chezar's USGS Western Coastal and Marine Geology team archives. The purpose of Open-File Report 2004-1101 is to provide users with a listing of the available DVD-Video discs (with their Open-File Report numbers) along with a brief description of their associated USGS research activities. Each disc was created by first encoding the source video and audio into MPEG-2 streams using the MediaPress Pro hardware encoder. A menu for the disc was then made using Adobe Photoshop 6.0. The disc was then authored using DVD Studio Pro and subsequently written onto a DVD-R recordable disc.

Open-File Report↗

Catastrophe, recovery and range limitation in NE Pacific kelp forests: a large-scale perspective

The 1997–98 El Niño was one of the strongest on record and resulted in widespread losses of the giant kelp Macrocystis pyrifera (Agardh) along the west coast of North America. Drawing on a rich history of studies that have shown abnormally large waves and warm nutrient-poor water associated with El Niños to negatively impact giant kelp populations at some locations in southern and Baja California, we examined (1) how these impacts scale up when considered across the species’ geographic range in the NE Pacific Ocean and (2) if these impacts are generalizable over broad spatial scales. Working at 56 sites in 14 study locations over a 3 yr period (1997 to 2000), we examined how giant kelp populations were impacted by and recovered following the 1997–98 El Niño over a ~1500 km span along the west coast of North America. Our results indicate that while nearly all giant kelp disappeared from the southern one-third of the species’ range along the coast of Baja California, Mexico, and heavy losses occurred throughout the central one-third of the species’ range in southern California, USA, only minor impacts were observed throughout the northern one-third of the species’ range in central California. Further, although highly variable among regions, these impacts were similar and generalizable among locations within each region. Our results also suggest that, as has been observed in local-scale studies, this large-scale variability in giant kelp mortality was driven by large-scale patterns in ocean temperature (nutrient concentration) and wave intensity. Recovery following El Niño, in contrast, was variable at multiple spatial scales and although not directly tested here, presumably influenced by numerous factors such as proximity to upwelling areas, competition with other algae, grazing, and propagule availability. Further, variability in the rates of recovery among locations resulted in a generally slow recovery of giant kelp throughout most of Baja California, and residual large-scale impacts of the El Niño were still evident 2 yr after the El Niño ended. As global climate change may lead to increases in the frequency and intensity of El Niños, our findings have broad implications for the ways in which ecosystems might be expected to respond to them and provide a measure by which their impacts to giant kelp ecosystems may be compared among events.

Pacific Ocean↗

The ecology of extinctions in kelp forest communities

We recognize three levels of extinction–global, local, and ecological – and provide examples of each. The protection and recovery of sea otters (Enhydra lutris) has provided abundant evidence of the consequences of their local extinction from kelp forest communities in the North Pacifc Ocean. These consequences include release of benthic invertebrate populations from limitation by predation; deforestation of kelp beds due to increased grazing by herbivorous sea urchins, one of the otter's main prey; and various cascading effects resulting from the biological and physical importance of kelp in coastal ecosystems. These interactions probably were important agents of selection for certain species. Two other examples are discussed: Steller's sea cow (Hydrodamalis gigas), a case of global extinction, and spiny lobsters, a possible case of ecological extinction. We speculate that grazing by sea cows was an important disturbance to surface-canopy-forming kelps and other algae in the littoral zones, but also point out that any such interactions probably acted in concert with physical disturbances by ocean waves. The ecological and evolutionary importance of sea cow grazing probably will remain a matter of speculation and conjecture because the species is globally extinct. Predation by spiny lobsters limits a variety of littoral and sublittoral invertebrate populations, particularly mollusks In one remarkable example, the reduction or local extinction of spiny lobsters enabled predutory whelks to increase in size and abundance, ultimately resulting in a predutor-prey role reversal. From these and other case studies we can clued that (1) the extinction of consumers may have brad and sometimes unexpected influences on kelp forest ecosystems; (2) direct or indirect interactions with now-extinct species probably exerted important selective influences on many extant forms; (3) such ecological and evolutionary influences are best understood where local or ecological extinctions, followed by recoveries, have provided comparisons in space or time; and (4) because of various ecological and behavioral barriers, local extinctions and their ecological consequences may not be simply reversed by protecting or reintroducing depleted or locally extinct species.

Conservation Biology↗

A Cenozoic diffuse alkaline magmatic province (DAMP) in the southwest Pacific without rift or plume origin

Common geological, geochemical, and geophysical characteristics of continental fragments of East Gondwana and adjacent oceanic lithosphere define a long-lived, low-volume, diffuse alkaline magmatic province (DAMP) encompassing the easternmost part of the Indo-Australian Plate, West Antarctica, and the southwest portion of the Pacific Plate. A key to generating the Cenozoic magmatism is the combination of metasomatized lithosphere underlain by mantle at only slightly elevated temperatures, in contrast to large igneous provinces where mantle temperatures are presumed to be high. The SW Pacific DAMP magmatism has been conjecturally linked to rifting, strike-slip faulting, mantle plumes, or hundreds of hot spots, but all of these associations have flaws. We suggest instead that sudden detachment and sinking of subducted slabs in the late Cretaceous induced Rayleigh-Taylor instabilities along the former Gondwana margin that in turn triggered lateral and vertical flow of warm Pacific mantle. The interaction of the warm mantle with metasomatized subcontinental lithosphere that characterizes much of the SW Pacific DAMP concentrates magmatism along zones of weakness. The model may also provide a mechanism for warming south Pacific mantle and resulting Cenozoic alkaline magmatism, where the oceanic areas are characterized primarily, but not exclusively, by short-lived hot spot tracks not readily explained by conventional mantle plume theory. This proposed south Pacific DAMP is much larger and longer-lived than previously considered.

Geochemistry, Geophysics, Geosystems↗

High-resolution climatic evolution of coastal northern California during the past 16,000 years

Holocene and latest Pleistocene oceanographic conditions and the coastal climate of northern California have varied greatly, based upon high-resolution studies (ca. every 100 years) of diatoms, alkenones, pollen, CaCO 3 %, and total organic carbon at Ocean Drilling Program (ODP) Site 1019 (41.682°N, 124.930°W, 980 m water depth). Marine climate proxies (alkenone sea surface temperatures [SSTs] and CaCO 3 %) behaved remarkably like the Greenland Ice Sheet Project (GISP)-2 oxygen isotope record during the Bølling-Allerod, Younger Dryas (YD), and early part of the Holocene. During the YD, alkenone SSTs decreased by >3°C below mean Bølling-Allerod and Holocene SSTs. The early Holocene (ca. 11.6 to 8.2 ka) was a time of generally warm conditions and moderate CaCO 3 content (generally >4%). The middle part of the Holocene (ca. 8.2 to 3.2 ka) was marked by alkenone SSTs that were consistently 1–2°C cooler than either the earlier or later parts of the Holocene, by greatly reduced numbers of the gyre-diatom Pseudoeunotia doliolus (<10%), and by a permanent drop in CaCO 3 % to <3%. Starting at ca. 5.2 ka, coastal redwood and alder began a steady rise, arguing for increasing effective moisture and the development of the north coast temperate rain forest. At ca. 3.2 ka, a permanent ca. 1°C increase in alkenone SST and a threefold increase in P. doliolus signaled a warming of fall and winter SSTs. Intensified (higher amplitude and more frequent) cycles of pine pollen alternating with increased alder and redwood pollen are evidence that rapid changes in effective moisture and seasonal temperature (enhanced El Niño–Southern Oscillation [ENSO] cycles) have characterized the Site 1019 record since about 3.5 ka.

California↗

Budgeting postglacial sedimentation history on the Santa Cruz, California mid-continental shelf

High-resolution seismic reflection profiling and surface texture mapping of the central California continental shelf, reveal a prominent subsurface reflector interpreted as a low stand erosion surface and an overlying mudbelt that covers 421 km 2 of the mid-shelf in depths of 40-90 m. Radiometric and sedimentologic analyses of samples from vibracores taken along the seaward edge of the mudbelt show that initial deposition above the pre-Holocene erosion surface began ca. 14.5 ka. These data and model results of sea-level history, tectonics, and the Monterey Bay littoral sediment budget support the notion that the entire midshelf deposit was formed during the postglacial transgression. An alternative explanation, that <30% of the deposit is Holocene, requires that (1) sediment input is overestimated and/or loss is greatly underestimated, and (2) preservation on the shelf was significant despite deep and active wave scour observed in the form of rapid cliff and bedrock cutting early and late in the transgression. The difference between a basal age of ~14.5 ka and residence time of midshelf sediment (3,273 years), derived from dividing mudbelt volume by modern accumulation rate, implies: (1) significant sediment loss occurred since the mudbelt formed and/or (2) sediment accumulation has varied greatly over time. Although modern sediment budgets are relatively well constrained, it remains uncertain how well we can apply them to the past. An evolving model of sedimentation history explores the likelihood of changes in sediment supply, accumulation patterns, and depositional patterns owing to postglacial sea-level history and human land-use activities while providing important boundary conditions for modeling shoreface evolution.

California↗

Deformation across the Pacific-North America plate boundary near San Francisco, California

We have detected a narrow zone of compression between the Coast Ranges and the Great Valley, and we have estimated slip rates for the San Andreas, Rodgers Creek, and Green Valley faults just north of San Francisco. These results are based on an analysis of campaign and continuous Global Positioning System (GPS) data collected between 1992 and 2000 in central California. The zone of compression between the Coast Ranges and the Great Valley is 25 km wide. The observations clearly show 3.8±1.5 mm yr −1 of shortening over this narrow zone. The strike slip components are best fit by a model with 20.8±1.9 mm yr −1 slip on the San Andreas fault, 10.3±2.6 mm yr −1 on the Rodgers Creek fault, and 8.1±2.1 mm yr −1 on the Green Valley fault. The Pacific-Sierra Nevada-Great Valley motion totals 39.2±3.8 mm yr −1 across a zone that is 120 km wide (at the latitude of San Francisco). Standard deviations are one σ. The geodetic results suggest a higher than geologic rate for the Green Valley fault. The geodetic results also suggest an inconsistency between geologic estimates of the San Andreas rate and seismologic estimates of the depth of locking on the San Andreas fault. The only convergence observed is in the narrow zone along the border between the Great Valley and the Coast Ranges.

California↗

Interglacial theme and variations: 500 k.y. of orbital forcing and associated responses from the terrestrial and marine biosphere, U.S. Pacific Northwest

Sediments collected off northern California by Ocean Drilling Program Leg 167 contain time series that show strong, orbitally driven insolation forcing of surface oceanographic conditions. Orbital forcing caused a strong response in the distribution of major terrestrial vegetation but a less predictable response for primary productivity offshore. Terrestrial vegetation responded primarily to regional sea surface temperature (SST). Coastal ocean productivity appears highest when SST is moderately high, not during peak interglacial conditions nor during insolation maxima. When individual interglacial intervals are examined closely, each has a different signature. Two of six interglacials (MIS [marine isotope stage] 5 and MIS 11) have higher SST than modern conditions, but each elicits a different response from the terrestrial and marine communities. The type of vegetation and the strength of upwelling vary between interglacials, depending on the relative strength of factors that drive the warming, including insolation, ice-cap size, and level of greenhouse gases.

California↗

Evolution of continental slope gullies on the northern California margin

A series of subparallel, downslope-trending gullies on the northern California continental slope is revealed on high-resolution seismic reflection profiles imaging the uppermost 50 m of sediment. The gullies are typically 100 m wide and have 1 to 3 m of relief. They extend for 10 to 15 km down the slope and merge into larger channels that feed the Trinity Canyon. In the lower half of the 50 m stratigraphic section, the gullies increase in both relief and number up section, to maxima at a surface 5 to 10 m below the last glacial maximum lowstand surface. Gully relief increased as interfluves aggraded more rapidly than thalwegs. Erosion is not evident in the gully bottoms, therefore gully growth was probably due to reduced sediment deposition within the gullies relative to that on interfluves. As the gullies increased in relief, their heads extended upslope toward the shelfbreak. At all times, a minimum of 10 km of non-gullied upper slope and shelf stretched between the heads of the gullies and the paleo-shoreline; the gullies did not connect with a subaerial drainage network at any time. Gully growth occurred when the gully heads were in relatively shallow water (∼ 200 m paleo-water depth) and were closest to potential sediment sources. We suggest that prior to the last glacial maximum, the Mad River, then within 10 km of the gully heads, supplied sediment to the upper slope, which fed downslope-eroding sediment flows. These flows removed sediment from nearly parallel gullies at a rate slightly slower than sediment accumulation from the Eel River, 40 km to the south. The process or processes responsible for gully growth and maintenance prior to the last glacial maximum effectively ceased following the lowstand, when sea level rose and gully heads lay in deeper water (∼ 300 m water depth), farther from potential sediment sources. During sea-level highstand, the Mad River is separated from the gully heads by a shelf 30 km wide and no longer feeds sediment flows down the gullies, which fill with sediment from the distal Eel River. Approximately one-half of the subsurface gullies have no expression on the seafloor, because they have completely filled with sediment following the last glacial maximum lowstand of sea level.

California↗

Sedimentary record of the California Current system, middle Miocene to Holocene: A synthesis of Leg 167 results

During Ocean Drilling Program Leg 167, the California continental margin was drilled from about 30°N to 42°N to sample high-resolution paleoceanographic and paleoclimatic records in the California Current system. Because of typically high sedimentation rates along the margin (80 to >200 m/m.y.), drilling has proved necessary to collect late Pleistocene sedimentary records that usually are sampled by standard piston cores in other oceanic regions. Triple piston coring on Leg 167 enabled us to construct continuous submillennial paleoceanographic records to about 2 Ma. In the offshore drill sites, continuous records were constructed into the Miocene. The oldest sediments recovered on Leg 167 have an age of ~14 Ma. The California margin has an active diagenetic system driven by the degradation of organic matter. Leg 167 drilling provided a means to quantify the diagenetic processes within the deep sediment column and to study the links between sediment diagenesis and primary productivity. This synthesis chapter also documents the oceanographic variability along the California margin at all time scales, from 10 3 to 10 6 yr. Millennial-scale variability is found in Santa Barbara Basin (drilled during Leg 146) and in nearby basins drilled during Leg 167. Leg 167 cores also captured millennial-scale variability in the northern and central California margin. Orbitally forced insolation changes invoke a strong response throughout the California margin. Sea-surface temperature (SST) measured by the alkenone U k' 37 paleothermometer is highly coherent with the oxygen isotope record, being cold in glacials and much warmer in interglacials. Faunal and floral plankton assemblages vary strongly on the glacial-interglacial scale. Coastal plant communities show a glacial-interglacial variability that is most pronounced in the north, near the Cordilleran Ice Sheet. Major changes in the sediments prior to the Pleistocene mark major late Neogene oceanographic events. Opaline silica burial in the middle and upper Miocene sections have step-like drops from high opal deposition in the middle Miocene. One major drop occurs at ~11 Ma and is roughly correlative with the eastern equatorial Pacific Miocene carbonate crash. A second major drop occurs at about 8 Ma, equivalent in age to the end of the Monterey Formation. A third drop occurs slightly younger than the end of the Miocene. A lower Pliocene interval, roughly from 5 to 4.2 Ma, is low in all biogenic components. It separates the Miocene high-opal sediments from upper Pliocene high-carbonate sediments. High CaCO 3 deposition occurred all along the entire California margin in the late Pliocene, but CaCO 3 burial dropped abruptly with the beginning of Northern Hemisphere glaciation (2.6 Ma).

Baja California, California↗

Cobalt-rich ferromanganese crusts in the Pacific

Co-rich Fe-Mn crusts occur throughout the Pacific on seamounts, ridges, and plateaus where currents have kept the rocks swept clean of sediments at least intermittently for millions of years. Crusts precipitate out of cold ambient sea water onto hard-rock substrates forming pavements up to 250 mm thick. Crusts are important as a potential resource for Co, Ni, Pt, Mn, Tl, Te, and other metals, as well as for the paleoclimate signals stored in their stratigraphic layers. Crusts form at water depths of about 400 to 4000 m, with the thickest and most Co-rich crusts occurring at depths of about 800 to 2500 m, which may vary on a regional scale. Gravity processes, sediment cover, submerged and emergent reefs, and currents control the distribution and thickness of crusts on seamounts. Crusts occur on a variety of substrate rocks that generally decrease in the order, breccia, basalt, phosphorite, limestone, hyaloclastite, and mudstone. Because of this wide variety of substrate types, crusts are difficult to distinguish from the substrate using remotely sensed data, such as geophysical measurements, but are generally weaker and lighter-weight than the substrate. Crusts can be distinguished from the substrates, however, by their much higher gamma radiation levels. The mean dry bulk density of crusts is 1.3 g/cm3, the mean porosity is 60%, and the mean surface area is extremely high, 300 m2/g. Crusts generally grow at rates of 1 to 10 mm/Ma. Crust surfaces are botryoidal, which may be modified to a variety of forms by current erosion. In cross-section, crusts are generally layered, with individual layers displaying massive, botryoidal, laminated, columnar, or mottled textures. Characteristic layering is persistent regionally in the Pacific. Crusts are composed of ferruginous vernadite (δ-MnO2) and X-ray amorphous Fe oxyhydroxide, with moderate amounts of carbonate fluorapatite (CFA) in thick crusts and minor amounts of quartz and feldspar in most crusts. Elements most commonly associated with the vernadite phase include Mn, Co, Ni, Cd, and Mo, whereas those most commonly associated with Fe oxyhydroxide are Fe and As. Detrital phases are represented by Si, Al, K, Ti, Cr, Mg, Fe, and Na; the CFA phase by Ca, P, Sr, Y, and CO2; and a residual biogenic phase by Ba, Sr, Ce, Cu, V, Ca, and Mg. Crusts contain Co contents up to about 2.3%, Ni to 1%, and Pt to 3 ppm, with mean Fe/Mn ratios of 0.6 to 1.3. Fe/Mn decreases, whereas Co, Ni, Ti, and Pt increase in central Pacific crusts and Fe/Mn, Si, and Al increase in continental margin crusts and in crusts with proximity to west Pacific volcanic arcs. Vernadite and CFA-related elements decrease, whereas Fe, Cu, and detrital-related elements increase with increasing water depth of crust occurrence. Cobalt, Ce, Tl, and maybe also Ti, Pb, and Pt are strongly concentrated in crusts over other metals because of oxidation reactions. Total rare earth elements (REEs) commonly vary between 0.1% and 0.3% and are derived from sea water along with other hydrogenetic elements, Co, Mn, Ni, etc. Platinum, Rh, Ir, and some Ru in crusts are also derived from sea water, whereas Pd and the remainder of the Ru derive from detrital minerals. The older parts of thick crusts were phosphatized during at least two global phosphogenic events during the Tertiary, which mobilized and redistributed elements in those parts of the crusts. 240Silicon, Fe, Al, Th, Ti, Co, Mn, Pb, and U are commonly depleted, whereas Ni, Cu, Zn, Y, REEs, Sr, and Pt are commonly enriched in phosphatized layers compared to younger nonphosphatized layers. The dominant controls on the concentration of elements in crusts include the concentration of metals in sea water and their ratios, colloid surface charge, types of complexing agents, surface area, and growth rates. Crusts act as closed systems with regard to the isotopic ratios of Be, Nd, Pb, Hf, Os, and U-series, which in part have been used to date crusts and in part used as isotopic tracers of paleoceanographic and paleoclimatic conditions. Those tracers are especially useful in delineating temporal changes in deep-ocean circulation. Research and development on the technology of mining crusts are only in their infancy. Detailed maps of crust deposits and a better understanding of small-scale seamount topography are required to design the most appropriate mining equipment.

Book chapter↗

Inorganic geochemical indicators of glacial-interglacial changes in productivity and anoxia on the California continental margin

Evidence from sediments in cores collected from within the present oxygen-minimum zone (OMZ; 600–1200 m) on the central and northern California margins record several episodes during the last interstadial (OIS-3, ca. 60-24 ka) of deposition of laminated sediments containing elevated concentrations of several trace elements indicative of anoxic conditions (e.g., Mo, Ni, Zn, and Cu). The presence of abundant well-preserved organic matter, as well as lack of bioturbation and the presence of elevated concentrations of Mo and other trace elements, all support the theory that the OMZ in the northeastern Pacific Ocean was more intense, possibly anoxic, at several times during the late Pleistocene. Sediments of all ages in cores from the southern California margin contain elevated concentrations of Mo, suggesting that this area has always had higher rates of sulfate reduction than either the central or northern California areas. Most of the Ba in sediments in all cores collected on the upper continental slope (200–2700 m) off California and southern Oregon is derived from detrital clastic material, and this source did not change much in time. However, the amount of biogenic Ba did vary with time, and these variations closely follow the temporal variations in organic C (Corg) mass accumulation rate. Using Ba and Corg mass accumulation rates as proxy variables for productivity, all cores show that organic productivity under the California Current upwelling system was highest during OIS-3 and the Holocene, and lowest during the last glacial interval (LGI, ca. 24-10 ka). All paleoproductivity proxy variables indicate that the southern California area has always experienced higher productivity than other areas under the California Current, at least over the last 50 ky.

California↗

Application of the Modern Analog Technique (MAT) of sea surface temperature estimation to middle Pliocene North Pacific planktonic foraminifer assemblages

Seventy-two samples from Deep Sea Drilling Project Sites 445 and 463 and Ocean Drilling Program Site 769 from the northwest Pacific Ocean were compared to 499 modern core top Pacific Ocean samples using the squared chord distance dissimilarity measure. Many samples show high levels of dissimilarity that can be explained by pervasive dissolution and/or evolution changing the composition of the fossil assemblages. Weighted averages of winter and summer sea surface temperatures (SST) from the nearest five modern analogs of each fossil-bearing sample were used to estimate Pliocene SST. Results show little to no middle Pliocene warming at low latitudes (Site 769) and warming of 2°C to 4°C in winter and possibly 1°C in summer just north of the Philippine Sea (Site 445). These data, when combined with other estimates of Pliocene SST in the northwest Pacific, suggest an enhanced meridional oceanic heat flow, similar to that found in the North Atlantic during the same part of the Pliocene.

Palaeontologia Electronica↗