Geology topics

Research about Madison, Wisconsin

Source-linked reports with geographic coverage including Madison, Wisconsin.

At least 19 recordsLinked to original sources

USGS2025

Quantifying leachable phosphorus from the leaves of common midwest urban street trees and implications for stormwater management

Urban runoff containing high amounts of nutrients like phosphorus (P) is a well-established driver of surface water eutrophication. In residential areas, a primary source of nutrients is derived from leaf litter. P contained in leaves is leached and transported by stormwater from source to stream. The majority of P leached from leaf litter is in the dissolved phase, which can be difficult to remove using conventional treatment practices, leaving source control as the most viable option. Additional tools are needed to help forecast how different tree species may improve or hinder contributions of nutrients to runoff. For this reason, ten street tree species that are common throughout the contiguous U.S. were chosen to evaluate the effect of species on leachable P from tree leaves using laboratory experiments. After 48 h of exposure to water, the amount of P released ranged from 2.16 mg P g −1 leaf for Silver Maple to 0.03 mg P g −1 leaf for Hackberry. More than half of the P was lost in the first 12 h for eight of the ten tree species, making guided source control important to reduce inputs to surface water from key locations. Results were used to identify ‘hotspots’ of P leaching in Madison, WI and can be used to assess current street tree inventories that can then guide management to areas with the highest nutrient reduction potential and inform urban foresters who may wish to tailor future planting scenarios that minimize nutrients in runoff.

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USGS2025

The role of street cleaning on the water-quality performance of a stormwater treatment pond in Madison, Wisconsin

The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources and the City of Madison, evaluated how street cleaning frequency influences the pollutant removal efficiency of a stormwater treatment pond in Madison, Wisconsin (2020–24). Paired influent and effluent samples were analyzed for nutrients, sediment, and chloride under a weekly and monthly street cleaning scenario. Results showed that less frequent cleaning (monthly frequency) led to higher pollutant accumulation on streets, increasing influent concentrations of nitrogen and sediment. This, in turn, allowed the pond to achieve higher overall load-reduction percentage compared to weekly cleaning, particularly for total suspended sediment, total nitrogen, and total phosphorus. Dissolved phosphorus was an exception where removal was significantly greater under weekly cleaning. One explanation could be related to internal phosphorus release from pond sediments under anoxic conditions. Nearly all events showed net export of chloride from the pond, with effluent loads exceeding influent loads for both street cleaning frequencies.

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USGS2023

Fall contributions of phosphorus and nitrogen in stormwater runoff through weekly street cleaning

This report describes a study that characterized reductions in total and dissolved forms of phosphorus and nitrogen in stormwater runoff through implementation of a municipal leaf collection and street cleaning program in two medium-density residential catchments in Madison, Wisconsin. One catchment was established as a control in which no effort was made to remove leaf litter and other organic detritus from streets. The second catchment served as the test catchment in which leaf litter was removed through a combination of biweekly leaf collection and weekly mechanical-broom street cleaning. Loads of total and dissolved phosphorus in the test catchment were reduced by 46 and 51 percent (probability less than 0.20), respectively, and total and dissolved nitrogen by 42 and 52 percent (probability less than 0.20), respectively, with an active leaf collection and street cleaning program compared to no program in the control catchment. Results from this study support an ongoing effort to characterize how various combinations of municipal leaf collection and street cleaning can affect nutrient loads in urban runoff.

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USGS2020

Assessment of restorative maintenance practices on the infiltration capacity of permeable pavement

Permeable pavement has the potential to be an effective tool in managing stormwater runoff through retention of sediment and other contaminants associated with urban development. The infiltration capacity of permeable pavement declines as more sediment is captured, thereby reducing its ability to treat runoff. Regular restorative maintenance practices can alleviate this issue and prolong the useful life and benefits of the system. Maintenance practices used to restore the infiltration capacity of permeable pavement were evaluated on three surfaces: Permeable interlocking concrete pavers (PICP), pervious concrete (PC), and porous asphalt (PA). Each of the three test plots received a similar volume of runoff and sediment load from an adjacent, impervious asphalt parking lot. Six different maintenance practices were evaluated over a four-year period: Hand-held pressure washer and vacuum, leaf blower and push broom, vacuum-assisted street cleaner, manual disturbance of PICP aggregate, pressure washing and vacuuming, and compressed air and vacuuming. Of the six practices tested, five were completed on PICP, four on PC, and two on PA. Nearly all forms of maintenance resulted in increased average surface infiltration rates. Increases ranged from 94% to 1703% for PICP, 5% to 169% for PC, and 16% to 40% for PA. Disruption of the aggregate between the joints of PICP, whether by simple hand tools or sophisticated machinery, resulted in significant (p ≤ 0.05) gains in infiltration capacity. Sediment penetrated into the solid matrix of the PC and PA, making maintenance practices using a high-pressure wash followed by high-suction vacuum the most effective for these permeable pavement types. In all instances, when the same maintenance practice was done on multiple surfaces, PICP showed the greatest recovery in infiltration capacity.

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USGS2019

Stormwater-quality performance of line permeable pavement systems

Three permeable pavements were evaluated for their ability to improve the quality of stormwater runoff over a 22-month period in Madison, Wisconsin. Using a lined system with no internal water storage, permeable interlocking concrete pavers (PICP), pervious concrete (PC), and porous asphalt (PA) were able to significantly remove sediment and sediment-bound pollutant loads from runoff originating from an asphalt parking lot five times larger than the receiving permeable pavement area. Reductions in total suspended solids were similar for all three surfaces at approximately 60 percent. Clogging occurred after approximately one year, primarily due to winter sand application that led to high sediment load in spring runoff. Winter road salt application resulted in high chloride load that was initially attenuated in all three permeable pavements but later released during subsequent spring runoff events. Total phosphorus load was reduced by nearly 20 percent for PICP and PA, and 43 percent for PC. These values were likely tempered by the export of dissolved phosphorus observed in PICP and PA, but not PC. Average removal efficiencies for metals were 40, 42, and 49 percent in PA, PICP, and PC, respectively. A median pH of 10.2 in PC effluent could explain elevated removal efficiency of phosphorus and select metals in PC over PICP and PA (median = 7.5 and 7.8, respectfully) through enhanced precipitation. Elevated pH values in PC may also have led to higher removal efficiencies for select metals than PICP or PA. The environmental benefits as well as potential unintended consequences of stormwater practices like permeable pavement that utilize infiltration as a form of treatment warrant consideration in management of urban runoff.

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USGS2019

An integrated statistical and deterministic hydrologic model for analyzing trace organic contaminants in commercial and high-density residential stormwater runoff

Urbanization can dramatically alter stormwater, both the quantity and quality, by engendering larger peak flows and through the introduction of contaminants into runoff. The current study builds on previous research that developed relationships between a suite of nonpoint source contaminants, known as trace organic contaminants (TOrCs), and hydrologic measurements for a series of storms (one site had 15 storms and the other had 19 storms) in Madison, WI, by creating statistical and deterministic models. Correlations and regressions were calculated between TOrC loads and hydrologic measurements for a series of storms for both a commercial site and a high-density residential site. From the regressions, it became evident that loading responses to precipitation were not the same between the two land covers for some TOrCs, indicating varying load responses for TOrCs depending on land cover. The regressions were utilized in the Source Loading and Management Model for Windows (WinSLAMM), an event-based hydrologic and water-quality model, to demonstrate that it can be used to model novel contaminants. The regressions were also used to estimate mean annual loads of TOrCs from all commercial and high-density residential areas in Madison, WI, for the watersheds to which Madison discharges its stormwater. The mean annual loads varied between grams per year to tens of thousands of grams per year depending on the TOrC and watershed. This work will ultimately allow managers to simulate the presence of, establish total maximum daily loads for, and mitigate the loads of TOrCs through stormwater best management practices.

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USGS2019

Evaluation of stormwater treatment vault with Coanda-effect screen for removal of solids and phosphorus in urban runoff

Catch basins commonly are used by cities as part of a stormwater management plan to remove sediment and associated contaminants from stormwater, keeping them in compliance with regulations. Recently, the city of Madison, Wisconsin modified traditional catch basins by incorporating a fine-mesh (1-mm) Coanda-effect screen into the design with the goal of increasing removal of sediment and organic matter from stormwater. The US Geological Survey (USGS), in cooperation with the City of Madison, installed a water-quality monitoring station at such a catch basin to quantify reductions in total suspended solids (TSS), volatile suspended solids (VSS), suspended sediment concentration (SSC), total phosphorus (TP), and dissolved phosphorus (DP) from urban stormwater before entering Lake Monona. A comparison of the cumulative load from 33 samples collected during the summers of 2016 and 2017 showed 23% and 45% reductions in TSS and SSC, respectively. A smaller reduction was observed for TP, 16%, whereas DP remained unchanged. Reported traditional catch basin sediment removal varies greatly, although typical removal rates are similar. Results from this study will help regulated municipalities determine whether the use of screened catch basins can help meet water-quality goals.

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USGS2018

Hydraulic, water-quality, and temperature performance of three types of permeable pavement under high sediment loading conditions

Three permeable pavement surfaces - asphalt (PA), concrete (PC), and interlocking pavers (PIP) - were evaluated side-by-side to measure changes to the infiltrative capacity and water quality of stormwater runoff originating from a conventional asphalt parking lot in Madison, Wisconsin. During the 24-month monitoring period (2014-16), all three permeable pavements resulted in statistically significant reductions in the cumulative load of solids (total suspended solids and suspended sediment), total phosphorus, Escherichia coli ( E. coli ), and Enterococci . Most of the removal occurred through capture and retention in the void spaces of each permeable surface and aggregate base. The largest reduction in total suspended solids was for PC at 80 percent, followed by PIP and PA at 69 and 65 percent, respectively. Reductions (generally less than 50 percent) in total phosphorus also were observed, which might have been tempered by increases in the dissolved fraction observed in PIP and PA. Conversely, PC results indicated a slight reduction in dissolved phosphorus but failed to meet statistical significance. E. coli and Enterococci were reduced by about 80 percent for PC, almost twice the amount observed for PIP and PA. Results for the PIP and PC surfaces initially indicated higher pollutant load reduction than results for the PA surface. The efficiency of PIP and PC surfaces capturing sediment, however, led to a decline in infiltration rates that resulted in more runoff flowing over, not through, the permeable surface. This result led to a decline in treatment until the permeable surface was partially restored through maintenance practices, to which PIP responded more dramatically than PC or PA. Conversely, the PA surface was capable of infiltrating most of the influent runoff volume during the monitoring period and, thus, continued to provide some level of treatment. The combined effect of underdrain and overflow drainage resulted in similar pollutant treatment for all three permeable surfaces. Temperatures below each permeable surface generally followed changes in air temperature with a more gradual response observed in deeper layers. Therefore, permeable pavement may do little to mitigate heated runoff during summer. During winter, deeper layers remained above freezing even when air temperature was below freezing. Although temperatures were not high enough to melt snow or ice accumulated on the surface, temperatures below each permeable pavement did allow void spaces to remain open, which promoted infiltration of melted ice and snow as air temperatures rose above freezing. These open void spaces could potentially reduce the need for application of deicing agents in winter because melted snow and ice would infiltrate, thereby preventing refreezing of pooled water in what is known as the “black ice” effect.

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USGS2016

Evaluation of leaf removal as a means to reduce nutrient concentrations and loads in urban stormwater

While the sources of nutrients to urban stormwater are many, the primary contributor is often organic detritus, especially in areas with dense overhead tree canopy. One way to remove organic detritus before it becomes entrained in runoff is to implement a city-wide leaf collection and street cleaning program. Improving our knowledge of the potential reduction of nutrients to stormwater through removal of leaves and other organic detritus on streets could help tailor more targeted municipal leaf collection programs. This study characterized an upper ideal limit in reductions of total and dissolved forms of phosphorus and nitrogen in stormwater through implementation of a municipal leaf collection and street cleaning program in Madison, WI, USA. Additional measures were taken to remove leaf litter from street surfaces prior to precipitation events. Loads of total and dissolved phosphorus were reduced by 84 and 83% (p < 0.05), and total and dissolved nitrogen by 74 and 71% (p < 0.05) with an active leaf removal program. Without leaf removal, 56% of the annual total phosphorus yield (winter excluded) was due to leaf litter in the fall compared to 16% with leaf removal. Despite significant reductions in load, total nitrogen showed only minor changes in fall yields without and with leaf removal at 19 and 16%, respectively. The majority of nutrient concentrations were in the dissolved fraction making source control through leaf removal one of the few treatment options available to environmental managers when reducing the amount of dissolved nutrients in stormwater runoff. Subsequently, the efficiency, frequency, and timing of leaf removal and street cleaning are the primary factors to consider when developing a leaf management program.

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USGS2013

Source and transport of human enteric viruses in deep municipal water supply wells

Until recently, few water utilities or researchers were aware of possible virus presence in deep aquifers and wells. During 2008 and 2009 we collected a time series of virus samples from six deep municipal water-supply wells. The wells range in depth from approximately 220 to 300 m and draw water from a sandstone aquifer. Three of these wells draw water from beneath a regional aquitard, and three draw water from both above and below the aquitard. We also sampled a local lake and untreated sewage as potential virus sources. Viruses were detected up to 61% of the time in each well sampled, and many groundwater samples were positive for virus infectivity. Lake samples contained viruses over 75% of the time. Virus concentrations and serotypes observed varied markedly with time in all samples. Sewage samples were all extremely high in virus concentration. Virus serotypes detected in sewage and groundwater were temporally correlated, suggesting very rapid virus transport, on the order of weeks, from the source(s) to wells. Adenovirus and enterovirus levels in the wells were associated with precipitation events. The most likely source of the viruses in the wells was leakage of untreated sewage from sanitary sewer pipes.

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USGS2012

Regression modeling of particle size distributions in urban stormwater: Advancements through improved sample collection methods

A new sample collection system was developed to improve the representation of sediment entrained in urban storm water by integrating water quality samples from the entire water column. The depth-integrated sampler arm (DISA) was able to mitigate sediment stratification bias in storm water, thereby improving the characterization of suspended-sediment concentration and particle size distribution at three independent study locations. Use of the DISA decreased variability, which improved statistical regression to predict particle size distribution using surrogate environmental parameters, such as precipitation depth and intensity. The performance of this statistical modeling technique was compared to results using traditional fixed-point sampling methods and was found to perform better. When environmental parameters can be used to predict particle size distributions, environmental managers have more options when characterizing concentrations, loads, and particle size distributions in urban runoff.

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USGS2012

Parking lot runoff quality and treatment efficiencies of a hydrodynamic-settling device in Madison, Wisconsin, 2005-6

A hydrodynamic-settling device was installed in 2004 to treat stormwater runoff from a roof and parking lot located at the Water Utility Administration Building in Madison, Wis. The U.S. Geological Survey, in cooperation with the Wisconsin Department of Natural Resources, the City of Madison, cities in the Waukesha Permit Group, Hydro International, Earth Tech, Inc., National Sanitation Foundation International, and the U.S. Environmental Protection Agency, monitored the device from November 2005 through September 2006 to evaluate it as part of the U.S. Environmental Protection Agency's Environmental Technology Verification Program. Twenty-three runoff events monitored for flow volume and water quality at the device's inlet and outlet were used to calculate the percentage of pollutant reduction for the device. The geometric mean concentrations of suspended sediment (SS), "adjusted" total suspended solids (TSS), total phosphorus (TP), dissolved phosphorus (DP), total recoverable zinc (TZn), and total recoverable copper (TCu) measured at the inlet were 107 mg/L (milligrams per liter), 92 mg/L, 0.17 mg/L, 0.05 mg/L, 38 μg/L (micrograms per liter), and 12 μg/L, respectively, and these concentrations are in the range of values observed in stormwater runoff from other parking lots in Wisconsin and Michigan. Efficiency of the settling device was calculated using the efficiency ratio and summation of loads (SOL) methods. Using the efficiency ratio method, the device reduced concentrations of SS, and DP, by 19, and 15, percent, respectively. Using the efficiency ratio method, the device increased "adjusted" TSS and TZn concentrations by 5 and 19, respectively. Bypass occurred for 3 of the 23 runoff events used in this assessment, and the bypass flow and water-quality concentrations were used to determine the efficiency of the bypass system. Concentrations of SS, "adjusted" TSS, and DP were reduced for the system by 18, 5, and 18, respectively; however, TZn increased by 5 percent. Some of the TSS concentrations were "adjusted" to add the particles that remained on the sieves during sample processing. The loads of SS, "adjusted" TSS, and DP were reduced using the SOL method for the settling device by 38, 9, and 19 percent, respectively, and TZn increased by 13 percent. For the bypass system, the loads of SS, "adjusted" TSS, and DP had percentage reductions of 39, 12, 22, respectively, however TZn increased by 4 percent. The SOL method produced percentage reductions for SS and 'adjusted" TSS that were twice those for the efficiency ratio method. Removing the two large runoff events on August 23 and 24, 2006, from the SOL calculation brought the reduction for SS down to 16 and increased "adjusted" TSS by 4 percent. The two large runoff events were anomalies in that the runoff volumes and dissolved solids concentrations were greatly increased by overflow from an adjacent recycling facility. The SOL method was used to determine the percentage of SS load reduction for six different particle sizes for both the settling device and bypass system. Essentially no load reduction was observed for particles less than 125 micrometers (μm) in diameter, and about a 90-percent reduction occurred for particle sizes greater than 250 μm in diameter. The large removal efficiencies for particle sizes greater than 250 μm in diameter were further supported by the fact that more than 80 percent of the particle sizes trapped in the sump were greater than 250 μm in diameter. These results support the claim by the manufacturer of achieving a large percentage load reduction for particle sizes greater than 250 μm in diameter.

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USGS2010

Parking lot runoff quality and treatment efficiency of a stormwater-filtration device, Madison, Wisconsin, 2005-07

To evaluate the treatment efficiency of a stormwater-filtration device (SFD) for potential use at Wisconsin Department of Transportation (WisDOT) park-and-ride facilities, a SFD was installed at an employee parking lot in downtown Madison, Wisconsin. This type of parking lot was chosen for the test site because the constituent concentrations and particle-size distributions (PSDs) were expected to be similar to those of a typical park-and-ride lot operated by WisDOT. The objective of this particular installation was to reduce loads of total suspended solids (TSS) in stormwater runoff to Lake Monona. This study also was designed to provide a range of treatment efficiencies expected for a SFD. Samples from the inlet and outlet were analyzed for 33 organic and inorganic constituents, including 18 polycyclic aromatic hydrocarbons (PAHs). Samples were also analyzed for physical properties, including PSD. Water-quality samples were collected for 51 runoff events from November 2005 to August 2007. Samples from all runoff events were analyzed for concentrations of suspended sediment (SS). Samples from 31 runoff events were analyzed for 15 constituents, samples from 15 runoff events were analyzed for PAHs, and samples from 36 events were analyzed for PSD. The treatment efficiency of the SFD was calculated using the summation of loads (SOL) and the efficiency ratio methods. Constituents for which the concentrations and (or) loads were decreased by the SFD include TSS, SS, volatile suspended solids, total phosphorous (TP), total copper, total zinc, and PAHs. The efficiency ratios for these constituents are 45, 37, 38, 55, 22, 5, and 46 percent, respectively. The SOLs for these constituents are 32, 37, 28, 36, 23, 8, and 48 percent, respectively. The SOL for chloride was -21 and the efficiency ratio was -18. Six chemical constituents or properties-dissolved phosphorus, chemical oxygen demand, dissolved zinc, total dissolved solids, dissolved chemical oxygen demand, and dissolved copper-were not included in the efficiency or SOL, because the difference between concentrations in samples from the inlet and outlet were not significant. Concentrations of TP and TSS were inexplicably high in samples at the inlet for one event.

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USGS2009

Concentrations of polycyclic aromatic hydrocarbons (PAHs) in urban stormwater, Madison, Wisconsin, 2005–08

Concentrations of 18 PAH compounds were characterized from six urban source areas (parking lots, feeder street, collector street, arterial street, rooftop, and strip mall) around Madison, Wisconsin. Parking lots were categorized into those that were or were not sealed. On average, chrysene, fluoranthene, and pyrene were the dominant PAH compounds in all urban stormwater samples. Geometric mean concentrations for most individual PAH compounds were significantly greater for a parking lot that was sealed than for lots that were not sealed. Results from this study are consistent with similar studies that measured PAH concentrations in urban stormwater samples in Marquette, Mich., and Madison, Wis.

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USGS2007

Human enteric viruses in groundwater from a confined bedrock aquifer

Confined aquifers are overlain by low-permeability aquitards that are commonly assumed to protect underlying aquifers from microbial contaminants. However, empirical data on microbial contamination beneath aquitards is limited. This study determined the occurrence of human pathogenic viruses in well water from a deep sandstone aquifer confined by a regionally extensive shale aquitard. Three public water-supply wells were each sampled 10 times over 15 months. Samples were analyzed by reverse transcription−polymerase chain reaction (RT-PCR) for several virus groups and by cell culture for infectious enteroviruses. Seven of 30 samples were positive by RT-PCR for enteroviruses; one of these was positive for infectious echovirus 18. The virus-positive samples were collected from two wells cased through the aquitard, indicating the viruses were present in the confined aquifer. Samples from the same wells showed atmospheric tritium, indicating water recharged within the past few decades. Hydrogeologic conditions support rapid porous media transport of viruses through the upper sandstone aquifer to the top of the aquitard 61 m below ground surface. Natural fractures in the shale aquitard are one possible virus transport pathway through the aquitard; however, windows, cross-connecting well bores, or imperfect grout seals along well casings also may be involved. Deep confined aquifers can be more vulnerable to contamination by human viruses than commonly believed.

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USGS1999

Sources of phosphorus in stormwater and street dirt from two urban residential basins in Madison, Wisconsin, 1994-95

Eutrophication is a common problem for lakes in agricultural and urban areas, such as Lakes Wingra and Mendota in Madison, Wisconsin. This report describes a study to estimate the sources of phosphorus, a major contributor to eutrophication, to Lakes Wingra and Mendota from two small urban residential drainage basins. The Monroe Basin empties into Lake Wingra, and the Harper Basin into Lake Mendota. Phosphorus data were collected from streets, lawns, roofs, driveways, and parking lots (source areas) within these two basins and were used to estimate loads from each area. In addition to the samples collected from these source areas, flow-composite samples were collected at monitoring stations located at the watershed outfalls (storm sewers); discharge and rainfall also were measured. Resulting data were then used to calibrate the Source Loading and Management Model (SLAMM, version 6.3, copyright 1993, Pitt & Vorhees) for conditions in the city of Madison and determine within these basins which of the source areas are contributing the most phosphorus. Water volumes in the calibrated model were calculated to within 23 percent and 24 percent of those measured at the outfalls of each of the basins. These water volumes were applied to the suspended- solids and phosphorus concentrations that were used to calibrate SLAMM for suspended-solids and phosphorus loads. Suspended-solids loads were calculated to be within 4 percent and 17 percent, total-phosphorus loads within 24 percent and 28 percent, and dissolved-phosphorus loads within 9 percent and 10 percent of those measured at the storm-sewer outfall at the Monroe and Harper basins, respectively. Lawns and streets are the largest sources of total and dissolved phosphorus in the basins. Their combined contribution was approximately 80 percent, with lawns contributing more than the streets. Streets were the largest source of suspended solids. Street-dirt samples were collected using industrial vacuum equipment. Leaves in these samples were separated out and the remaining sediment was sieved into >250 mm, 250-63 mm, 63-25 mm, <25 mm size fractions and were analyzed for total phosphorus. Approximately 75 percent of the sediment mass resides in the >250 mm size fractions. Less than 5 percent of the mass can be found in the particle sizes less than 63 mm. The >250 mm size fraction also contributed nearly 50 percent of the total-phosphorus mass and the leaf fraction contributed an additional 30 percent. In each particle size, approximately 25 percent of the total-phosphorus mass is derived from leaves or other vegetation.

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USGS1999

Evaluation of the effectiveness of an urban stormwater treatment unit in Madison, Wisconsin, 1996-97

An urban stormwater treatment unit was tested as part of an ongoing program of urban nonpoint- pollution research in Madison, Wis. Flow measurements were made and water samples were collected at the inlet to, outlet from, and bypass around the treatment chamber of the device that was installed to collect the runoff from a city maintenance yard. About 90 percent of the runoff water from the 4.3-acre basin was treated by the unit. The remaining 10 percent bypassed the treatment chamber when the flow rate reached approximately 500 gallons per minute. A 24-percent difference between the estimated amount (405 kilograms) and the actual amount (536 kilograms) of retained material in the treatment chamber may be attributed to bedload material that the automatic samplers could not effectively collect. Assuming this, 8 percent of the total mass in the untreated runoff water was estimated as the unsampled bedload. On the basis of water-sample data collected over the course of the study, the suspended solids removal efficiency of treatment chamber was about 25 percent, and the efficiency of the unit as a whole was 21 percent. If the unsampled bedload material was accounted for, the treatment-chamber efficiency was 33 percent. About 19 percent of the total phosphorus was removed from the water that passed through the treatment chamber and 17 percent was removed by the unit as a whole. Total polycyclic aromatic hydrocarbon (PAH) loads were reduced about 39 percent by the treatment chamber and 34 percent by the unit as a whole; these were some of the most effectively removed constituents. Total metals were reduced about 20 to 30 percent by both the treatment chamber and the unit as a whole. In general, dissolved constituents were unaffected by the unit. The material retained in the treatment chamber had high concentrations of lead and PAH and may be subject to special disposal restrictions based on those concentrations and the presence of benzo(a)anthracene. The chemical makeup of the retained material in other similar stormwater treatment units will probably vary depending on the land use and activities in the drainage basin.

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USGS1996

Stormwater-runoff data, Madison, Wisconsin, 1993-94

Section 402(P) of the Water Quality Control Act of 1987 requires that municipalities with a population of 100,000 or more obtain permits to discharge stormwater runoff and to control its quality. Monitoring and sampling of stormwater runoff from seven drainage basins in Madison, Wis., was performed from April 1993 through November 1994 by the U.S. Geological Survey and the city of Madison to (1) characterize the quantity and quality of wet-weather discharge, (2) determine storm and annual loadings of selected constituents, and (3) characterize rainfall and runoff conditions. The seven basins were selected for monitoring rainfall and runoff on the basis of land-use characteristics, dry-weather flow conditions, and monitorability. As required by Section 402(P) of the Water Quality Control Act of 1987, stormwater-runoff samples collected during storms that met three criteria (rainfall depths 50 to 150 percent of average depth range, rainfall durations 50 to 150 percent of average duration, and antecedent dry-weather period of at least 72 hours) were analyzed for semivolatile organic chemicals, total metals, pesticides, polychlorinated biphenyls, inorganic constituents, bacteria, oil and grease, pH, and water temperature. Two of the seven sites also had samples analyzed for volatile organic chemicals. In addition to the required sampling, additional runoff samples that did not necessarily meet the three rainfall criteria, were analyzed for total metals and inorganic constituents. Storm loads of selected constituents were computed.

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