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Research about Kentucky

Source-linked reports with geographic coverage including Kentucky.

At least 73 records · Page 4Linked to original sources
USGS2010

CO 2 , CO, and Hg emissions from the Truman Shepherd and Ruth Mullins coal fires, eastern Kentucky, USA

Carbon dioxide (CO 2 ), carbon monoxide (CO), and mercury (Hg) emissions were quantified for two eastern Kentucky coal-seam fires, the Truman Shepherd fire in Floyd County and the Ruth Mullins fire in Perry County. This study is one of the first to estimate gas emissions from coal fires using field measurements at gas vents. The Truman Shepherd fire emissions are nearly 1400 t CO 2 /yr and 16 kg Hg/yr resulting from a coal combustion rate of 450–550 t/yr. The sum of CO 2 emissions from seven vents at the Ruth Mullins fire is 726 ± 72 t/yr, suggesting that the fire is consuming about 250–280 t coal/yr. Total Ruth Mullins fire CO and Hg emissions are estimated at 21 ± 1.8 t/yr and > 840 ± 170 g/yr, respectively. The CO 2 emissions are environmentally significant, but low compared to coal-fired power plants; for example, 3.9 × 10 6 t CO 2 /yr for a 514-MW boiler in Kentucky. Using simple calculations, CO 2 and Hg emissions from coal-fires in the U.S. are estimated at 1.4 × 10 7 – 2.9 × 10 8 t/yr and 0.58–11.5 t/yr, respectively. This initial work indicates that coal fires may be an important source of CO 2 , CO, Hg and other atmospheric constituents.

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USGS2010

Breakpoint analysis and relations of nutrient and turbidity stressor variables to macroinvertebrate integrity in streams in the Crawford-Mammoth Cave Uplands Ecoregion, Kentucky, for the development of nutrient criteria

To assist Kentucky in refining numeric nutrient criteria in the Pennyroyal Bioregion, the U.S. Geological Survey and the Kentucky Division of Water collected and analyzed water chemistry, turbidity, and biological-community data from 22 streams throughout the Crawford-Mammoth Cave Upland ecoregion (U.S. Environmental Protection Agency Level IV Ecoregion, 71a) within the Pennyroyal Bioregion from September 2007 to May 2008. Statistically significant and ecologically relevant relations among the stressor (total phosphorus, total nitrogen, and turbidity) variables and response (macroinvertebrate-community attributes) variables and the breakpoint values of biological-community attributes and metrics in response to changes in stressor variables were determined. Thirteen of 18 macroinvertebrate attributes were significantly and ecologically correlated (p-value < 0.10) with at least one nutrient measure. Total number of individuals, Ephemeroptera-Plecoptera-Trichoptera richness, and average tolerance value were macroinvertebrate measures that most strongly correlated with the concentrations of nutrients. Comparison of the average macroinvertebrate-breakpoint value for the median concentration of total phosphorus (TP, 0.033 mg/L) and for median concentration of total nitrogen (TN, 1.1 mg/L) to Dodds' trophic classification for TP and TN indicates streams in the Crawford-Mammoth Cave Uplands ecoregion within the Pennyroyal Bioregion would be classified as mesotrophic-eutrophic. The biological breakpoint relations with median concentrations of TP in this study were similar to the U.S. Environmental Protection Agency proposed numeric TP criteria (0.037 mg/L), but were 1.5 times higher than the proposed numeric criteria for concentrations of TN (0.69 mg/L). No sites were impacted adversely using median turbidity values based on a 25 Formazin nephelometric turbidity unit biological threshold. The breakpoints determined in this study, in addition to Dodds' trophic classifications, were used as multiple lines of evidence to show changes in macroinvertebrate community and attributes based on exposure to nutrients.

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USGS2009

The Tiptop coal-mine fire, Kentucky: Preliminary investigation of the measurement of mercury and other hazardous gases from coal-fire gas vents

The Tiptop underground coal-mine fire in the Skyline coalbed of the Middle Pennsylvanian Breathitt Formation was investigated in rural northern Breathitt County, Kentucky, in May 2008 and January 2009, for the purpose of determining the concentrations of carbon dioxide (CO2), carbon monoxide (CO), and mercury (Hg) in the vent and for measuring gas-vent temperatures. At the time of our visits, concentrations of CO2 peaked at 2.0% and > 6.0% (v/v) and CO at 600 ppm and > 700 ppm during field analysis in May 2008 and January 2009, respectively. For comparison, these concentrations exceed the U.S. Occupational Safety & Health Administration (OSHA) eight-hour safe exposure limits (0.5% CO2 and 50 ppm CO), although the site is not currently mined. Mercury, as Hg0, in excess of 500 and 2100 μg/m3, in May and January, respectively, in the field, also exceeded the OSHA eight-hour exposure limit (50 μg/m3). Carbonyl sulfide, dimethyl sulfide, carbon disulfide, and a suite of organic compounds were determined at two vents for the first sampling event. All gases are diluted by air as they exit and migrate away from a gas vent, but temperature inversions and other meteorological conditions could lead to unhealthy concentrations in the nearby towns. Variation in gas temperatures, nearly 300 °C during the January visit to the fire versus < 50 °C in May, demonstrates the large temporal variability in fire intensity at the Tiptop mine. These preliminary results suggest that emissions from coal fires may be important, but additional data are required that address the reasons for significant variations in the composition, flow, and temperature of vent gases.

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USGS2009

Concentrations, and estimated loads and yields of total nitrogen and total phosphorus at selected water-quality monitoring network stations in Kentucky, 1979-2004

To evaluate the State’s water quality, the Kentucky Division of Water collects data from a statewide network of primary ambient stream water-quality monitoring stations and flexible, rotating watershed-monitoring stations. This ambient stream water-quality monitoring network program is directed to assess the conditions of surface waters throughout Kentucky. Water samples were collected monthly for the majority of the stations from 1979 to 1998, which represented agricultural, undeveloped (mainly forested), and areas of mixed land use/land cover. In 1998, the number of water samples collected was reduced to a collection frequency of six times per year (every 2 months) every 4 of 5 years, because a new monitoring network was implemented involving a 5-year rotating Basin Management Unit scheme of monitoring. This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the Kentucky Energy and Environment Cabinet–Kentucky Division of Water, to summarize concentrations of total nitrogen and total phosphorus and provide estimates of total nitrogen and total phosphorus loads and yields in 55 selected streams in Kentucky’s ambient stream water-quality monitoring network, which was operated from 1979 through 2004. Streams in predominately agricultural basins had higher concentrations of total nitrogen (TN) and concentrations of total phosphorus (TP) than streams in predominately undeveloped (forested) basins. Streams in basins in intensely developed karst areas characterized by caves, springs, sinkholes, and sinking streams had a higher median concentration of TN (1.5 milligrams per liter [mg/L]) than streams in basins with limited or no karst areas (0.63 mg/L). As with TN, median concentrations of TP also were higher in areas of intense karst (0.05 mg/L) than in areas with limited or no karst (0.02 mg/L). The U.S. Environmental Protection Agency (USEPA) has recommended ecoregional nutrient water-quality criteria as a starting point for States to establish more precise numeric water-quality criteria for nutrients to protect aquatic life and recreational and other uses of rivers and streams. On the basis of the 25 th percentile of concentration data from reference stations aggregated by ecoregion, the USEPA established recommended water-quality criteria for TN and TP in the two Aggregated Ecoregions (IX and XI) in Kentucky waters. The 25 th percentile median values for TN and TP from this study exceeded the USEPA’s recommendations in both aggregated ecoregions in the agricultural and mixed land-use/land-cover basins, and for TN in the undeveloped land-use/land-cover basins in Aggregated Ecoregion XI. However, the 25 th percentile median values for TN (Aggregated Ecoregion IX) and TP in both aggregated ecoregions did not exceed the USEPA’s recommendations in the undeveloped land-use/land-cover basins. Estimated loads and yields of TN and TP varied substantially among the individual stations. Estimated mean annual yields of TN ranged from 0.10 [tons per year per square mile (ton/yr)/mi 2 ] to 7.2 (ton/yr)/mi 2 , and estimated mean annual yields of TP ranged from 0.02 (ton/yr)/mi 2 to 1.4 (ton/yr)/mi 2 . Estimated mean annual yields of TN and TP were generally highest at stations in predominately agricultural basins, and lowest at stations in undeveloped land-use/land-cover basins.

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USGS2009

The Water Availability Tool for Environmental Resources (WATER): A water-budget modeling approach for managing water-supply resources in non-karst areas of Kentucky (phase I) — Data processing and model structure documentstion

The Water Availability Tool for Environmental Resources (WATER) was developed in cooperation with the Kentucky Division of Water to provide a consistent and defensible method of estimating streamflow and water availability in ungaged basins. WATER is process oriented; it is based on the TOPMODEL code and incorporates historical water-use data together with physiographic data that quantitatively describe topography and soil-water storage. The result is a user-friendly decision tool that can estimate water availability in non-karst areas of Kentucky without additional data or processing. The model runs on a daily time step, and critical source data include a historical record of daily temperature and precipitation, digital elevation models (DEMs), the Soil Survey Geographic Database (SSURGO), and historical records of water discharges and withdrawals. The model was calibrated and statistically evaluated for 12 basins by comparing the estimated discharge to that observed at U.S. Geological Survey streamflow-gaging stations. When statistically evaluated over a 2,119-day time period, the discharge estimates showed a bias of -0.29 to 0.42, a root mean square error of 1.66 to 5.06, a correlation of 0.54 to 0.85, and a Nash-Sutcliffe Efficiency of 0.26 to 0.72. The parameter and input modifications that most significantly improved the accuracy and precision of streamflow-discharge estimates were the addition of Next Generation radar (NEXRAD) precipitation data, a rooting depth of 30 centimeters, and a TOPMODEL scaling parameter (m) derived directly from SSURGO data that was multiplied by an adjustment factor of 0.10. No site-specific optimization was used.

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USGS2005

Analysis of multi-temporal geospatial data sets to assess the landscape effects of surface mining

Geospatial data sets, especially digital elevation data, have proven useful for characterizing and analyzing land surface conditions. Digital elevation models are routinely used for describing the morphology of the land surface in terms of slope gradient and aspect. Additionally, the elevation data are useful for deriving parameters that describe the local drainage conditions such as watersheds and stream channels. When the element of time is added to the analysis through the use of multi-temporal topographic data, the effects of changes to the physical shape of the land surface may be studied. Such is the case with analysis of historical (pre-mining) and recent (post-mining) topographic and other geospatial data sets, including land cover maps derived from remote sensing. Nationwide geospatial data sets now exist with the required spatial and temporal resolution that allow for assessment of the effects of surface mining operations. Changes to the local landscape morphology are readily identified, and the effects to the surface drainage features are quantifiable, such as changes to local relief and drainage pattern and the total length of affected streams. Additionally, the visual impact of the movement of rock and soil materials may be assessed through viewshed analysis. Examples in both Appalachian and Western coalfields show the usefulness of analyzing detailed historical and recent geospatial data sets to better map and describe the effects of surface mining.

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USGS2003

Estimating the magnitude of peak flows for streams in Kentucky for selected recurrence intervals

This report gives estimates of, and presents techniques for estimating, the magnitude of peak flows for streams in Kentucky for recurrence intervals of 2, 5, 10, 25, 50, 100, 200, and 500 years. A flowchart in this report guides the user to the appropriate estimates and (or) estimating techniques for a site on a specific stream. Estimates of peak flows are given for 222 U.S. Geological Survey streamflow-gaging stations in Kentucky. In the development of the peak-flow estimates at gaging stations, a new generalized skew coefficient was calculated for the State. This single statewide value of 0.011 (with a standard error of prediction of 0.520) is more appropriate for Kentucky than the national skew isoline map in Bulletin 17B of the Interagency Advisory Committee on Water Data. Regression equations are presented for estimating the peak flows on ungaged, unregulated streams in rural drainage basins. The equations were developed by use of generalized-least-squares regression procedures at 187 U.S. Geological Survey gaging stations in Kentucky and 51 stations in surrounding States. Kentucky was divided into seven flood regions. Total drainage area is used in the final regression equations as the sole explanatory variable, except in Regions 1 and 4 where main-channel slope also was used. The smallest average standard errors of prediction were in Region 3 (from -13.1 to +15.0 percent) and the largest average standard errors of prediction were in Region 5 (from -37.6 to +60.3 percent). One section of this report describes techniques for estimating peak flows for ungaged sites on gaged, unregulated streams in rural drainage basins. Another section references two previous U.S. Geological Survey reports for peak-flow estimates on ungaged, unregulated, urban streams. Estimating peak flows at ungaged sites on regulated streams is beyond the scope of this report, because peak flows on regulated streams are dependent upon variable human activities.

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USGS2002

Arsenic in rocks and stream sediments of the central Appalachian Basin, Kentucky

Arsenic (As) enrichment in coal and stream sediments has been documented in the southern Appalachian basin (see Goldhaber and others, submitted) and is attributed to interaction of rocks and coal with metamorphic fluids generated during the Allegheny Orogeny (late Paleozoic). Similarly derived fluids are expected to affect the coal and in the Kentucky Appalachian Basin to the north as well. In addition, similar processes may have influenced the Devonian oil shale on the western margin of the basin. The major goals of this study are to determine the effect such fluids had on rocks in the Kentucky Appalachian basin (fig. 1), and to understand the geochemical processes that control trace-metal source, residence, and mobility within the basin. This report includes data presented in a poster at the USGS workshop on arsenic (February 21 and 22, 2001), new NURE stream sediment data3 , and field data from a trip in April 2001. Although data for major and minor elements and all detectable trace metals are reported in the Appendices, the narrative of this report primarily focuses on arsenic.

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USGS2001

Estimated loads and yields of suspended solids and water-quality constituents in Kentucky streams

Loads and yields of suspended solids, nutrients, major ions, trace elements, organic carbon, fecal coliform, dissolved oxygen, and alkalinity were estimated for 22 streams in 11 major river basins in Kentucky. Mean daily discharge was estimated at ungaged stations or stations with incomplete discharge records using drainage-area ratio, regression analysis, or a combination of the two techniques. Streamflow was partitioned into total and base flow and used to estimate loads and yields for suspended solids and water-quality constituents by use of the ESTIMATOR and FLUX computer programs. The relative magnitude of constituent transport to streams from groundand surface-water sources was determined for the 22 stations. Nutrient and suspended solids yields for drainage basins with relatively homogenous land use were used to estimate the total-flow and base-flow yields of nutrient and suspended solids for forested, agricultural, and urban land. Yields of nutrients?nitrite plus nitrate, ammonia plus organic nitrogen, and total phosphorus?in forested drainage basins were generally less than 1 ton per square mile per year ((ton/mi2)/yr) and were generally less than 2 (ton/mi2)/yr in agricultural drainage basins. The smallest total-flow yields for nitrogen (nitrite plus nitrate) was estimated at Levisa Fork at Paintsville in which 95 percent of the land is forested. This site also had one of the smallest total-flow yields for ammonia plus organic nitrogen. In general, nutrient yields from forested lands were lower than those from urban and agricultural land. Some of the largest estimated total-flow yields of nutrients among agricultural basins were for streams in the Licking River Basin, the North Fork Licking River near Milford, and the South Fork Licking River at Cynthiana. Agricultural land constitutes greater than 75 percent of the drainage area in these two basins. Possible sources of nutrients discharging into the Licking River are farm and residential fertilizers. Estimated base-flow yields of suspended solids and nutrients at several basins in the larger Green River and Lower Cumberland River Basins were about half of their estimated total-flow yields. The karst terrain in these basins makes the ground water highly susceptible to contamination, especially if a confining unit is thin or absent.

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USGS2001

Calibration and validation of a two-dimensional hydrodynamic model of the Ohio River, Jefferson County, Kentucky

The quantification of current patterns is an essential component of a Water Quality Analysis Simulation Program (WASP) application in a riverine environment. The U.S. Geological Survey (USGS) provided a field validated two-dimensional Resource Management Associates-2 (RMA-2) hydrodynamic model capable of quantifying the steady-flowpatterns in the Ohio River extending from river mile 590 to 630 for the Ohio River Valley Water Sanitation Commission (ORSANCO) water-quality modeling efforts on that reach. Because of the hydrodynamic complexities induced by McAlpine Locks and Dam (Ohio River mile 607), the model was split into two segments: an upstream reach, which extended from the dam upstream to the upper terminus of the study reach at Ohio River mile 590; and a downstream reach, which extended from the dam downstream to a lower terminus at Ohio River mile 636. The model was calibrated to a low-flow hydraulic survey (approximately 35,000 cubic feet per second (ft 3 /s)) and verified with data collected during a high-flow survey (approximately 390,000 ft 3 /s). The model calibration and validation process included matching water-surface elevations at 10 locations and velocity profiles at 30 cross sections throughout the study reach. Based on the calibration and validation results, the model is a representative simulation of the Ohio River steady-flow patterns below discharges of approximately 400,000 ft 3 /s.

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USGS2001

Evaluation of passive diffusion bag samplers in selected wells at the Naval Surface Warfare Center, Louisville, Kentucky, July 1999 to January 2000

Passive diffusion bag samplers were tested in 11 wells at the Naval Surface Warfare Center, Louisville, Kentucky, by comparing the volatile organic compound concentrations obtained from passive diffusion bag samplers to volatile organic compound concentrations obtained by pumping the wells. The wells were screened in poorly permeable formations, including overburden, shale, and limestone. In five of the tested wells containing detectable volatile organic compound contamination, the data suggest that the diffusion samplers accurately reflected ambient contaminant concentrations (wells 1-NEC-15-P, 1-NEC-MW17-S, 1-NEMW23-S, 1-NW-MW24-S, and 1-NW-MW24-P). Comparison of a third well (1-NEC-MW34-S), in which the passive diffusion bag samplers produced higher concentrations than the pumped sample, is less certain because the passive diffusion bag sampler had passed through a layer of light non-aqueous phase liquid during deployment, suggesting the possibility of carryover contamination. In two wells (1-NE-MW23-P and 1-NEC-MW15-S), it was unclear whether concentrations obtained by using the passive diffusion bag samplers adequately represented in situ concentrations because the comparison of concentrations obtained by using the samplers and the pump was inconsistent between sampling events and/or between volatile organic compounds. In one well (1-NEC-MW34-P), the methodologies matched poorly, with volatile organic compound concentrations obtained by using the passive diffusion bag sampler substantially lower than those obtained by using the pump. Two of the tested wells (1-NW-MW6-I and 1-SE-MW13-I) contained no detectable contaminants in water obtained from either method. Data from wells where multiple passive diffusion bag samplers were deployed showed the lowest volatile organic compound concentrations adjacent to the vuggy limestone and higher volatile organic compound concentrations deeper in the limestone, supporting colloidal-borescope data that indicate the vuggy limestone is not a zone that supplies water to the wells.

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USGS2001

Biodegradation potential of chlorinated solvents in ground water at the Naval Surface Warfare Center, Louisville, Kentucky, July 1999 to February 2000

The U.S. Geological Survey, in cooperation with the U.S. Department of the Navy, Southern Division Naval Facilities Engineering Command, investigated the potential for biodegradation of chlorinated solvents in ground water at the Naval Surface Warfare Center (also known as the Naval Ordnance Station, or the station), Louisville, Kentucky. The subsurface down to at least 100 feet at the station is characterized, from shallowest to deepest, by overburden deposits, a shale layer, and limestone. In general, all of the strata are poorly permeable. The permeable zones of the overburden and the limestone make up the overburden aquifer and the bedrock aquifer, respectively. Observed concentrations of redox-sensitive solutes suggest that the predominant anaerobic terminal electron accepting process in the overburden aquifer can shift between iron reduction and sulfate reduction, possibly as a result of rainfall-induced oxidation events. Daughter-product concentrations and laboratory experiments indicate that a variety of mechanisms, including reductive dechlorination and cometabolic oxidation, appear to be actively

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USGS1999

An in situ occurrence of coal balls in the Amburgy coal bed, Pikeville Formation (Duckmantian), central Appalachian Basin, USA

Carbonate concretions containing permineralized peat, commonly called coal balls, were encountered in the Amburgy coal, a generally low-ash (9.4%), but commonly high-sulfur (3.6%), Middle Pennsylvanian coal of the Eastern Kentucky Coal Field. These are the first coal balls from the Amburgy coal, and one of only a few reported occurrences from the central Appalachian Basin. The coal balls occur in the upper part of the coal, between two paleochannel cut-outs at the top of the Pikeville Formation, and immediately beneath a scour with a marine fossil lag at the base of the Kendrick Shale Member, Hyden Formation. The coal is thickest (1.3 m) in a narrow (<300 m), elongate depression between the bounding paleochannels, and thins toward the occurrence of coal balls. Total biovolume as measured from acetate peels of coal balls indicates cordaites or lycopsid (36.1% each) dominance. Vertical sampling through one coal-ball aggregate shows zoning from a lower cordaites-dominant (88.7%) assemblage, to a middle, degraded, sphenopsid-rich assemblage, to an upper lycopsid-dominant (88.6%) assemblage. Beneath the coal balls, palynologic and petrographic analyses indicate the basal and middle portions of the bed are dominated by arborescent lycopsid spores and cordaites pollen, and by vitrinite macerals. The top part of the bed, above the coal balls, contains increased intertinite macerals, increased percentages of small fern spores, and variable ash yield (5-21%). Thickening of the Amburgy coal along a structural low, in combination with basal high-ash yields, vitrinite-dominance, and heterogenous palynoflora, indicate paleotopographic control on initial peat accumulation. Abundant lycopsid spores in the basal and middle part of the coal reflect rheotrophic conditions consistent with accumulation in a paleotopographic depression. Apparent zonation preserved in one of the coal-ball masses may document plant successions in response to flooding. Similar percentages of cordaites and lycopods, respectively, in the zones above and below the degraded incursion interval reflect development of a mixed, successional pattern in response to the flooding. Coal-ball formation may have been facilitated by channeling along the Kendrick ravinement, within a paleotopographic depression, at the split margin of the Amburgy peat, either through direct transmittal of carbonates and marine waters into the peat, or through degassing of the peat beneath the scour.

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