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Research about Illinois

Source-linked reports with geographic coverage including Illinois.

At least 217 records · Page 12Linked to original sources

Delineation of the Troy Bedrock Valley and particle-tracking analysis of ground-water flow underlying Belvidere, Illinois

The U.S. Geological Survey, U.S. Environmental Protection Agency, and Illinois Environmental Protection Agency began a study of the hydrogeology, flow system, and distribution of contaminants in the aquifers underlying Belvidere, Ill., and vicinity in 1992. As part of the study, the ancestral Troy Bedrock Valley, located about 1.5 miles west of Belvidere, was identified as an important part of the ground-water-flow system. In the deepest parts of the valley, the basal Glenwood confining unit may be absent; thick deposits of sand and gravel that infill part of the valley may directly overlie the sandstone St. Peter aquifer, a regionally important source of water for public supply. With few deep wells open to the St. Peter aquifer present in the valley to provide necessary geologic information, tritium and other water-chemistry data were collected from eight wells to possibly delineate areas where the confining unit may be absent; the data also provide baseline water-quality information for an area expecting changes in land use and increases in water withdrawal. Also as part of the study, particle-tracking analysis was done using an available flow model to (1) identify possible discharge locations of ground water and contaminants and (2) delineate areas contributing recharge to the Belvidere municipal wells. This report presents and interprets water-chemistry data collected during December 2000 and presents results of particle-tracking analysis. Ground water in samples from two of four wells open to the St. Peter aquifer appears to have recharged after 1954, suggesting that the Glenwood confining unit may be absent near the wells. Other hydrogeologic and water-chemistry data, however, were inconclusive or contradictory. Concentrations of iron, manganese, and lead exceeded maximum contaminant levels in five or less samples, but materials associated with the water-distribution systems appear to contribute to the elevated concentrations above natural levels. Particle-tracking analysis indicates that most ground-water flow beneath possible contaminant-source areas discharges from the glacial drift aquifer to the Kishwaukee River. Most of the source areas are in or near Belvidere and are within 1,500 feet of the river. The analysis also indicates the possibility that in parts of the study area, some ground water does not discharge to the river, but flows beneath the Kishwaukee River in the underlying carbonate Galena-Platteville aquifer. Ground water that discharges to the one municipal well open to the glacial drift aquifer is estimated to travel over 1 mile in less than 25 years. Simulated residence (travel) times of ground water from the base of the glacial drift aquifer to the six municipal wells open, in part, to the Galena-Platteville aquifer, are estimated at less than about 40 years. Because fractures in this aquifer are unaccounted for in the flow model, actual areas contributing recharge are likely larger and travel times faster than those simulated for most of the municipal wells. Tritium data indicate that, in general, travel times from the land surface to the deepest parts of the Galena-Platteville aquifer are less than 46 years. Methyl tertiary-butyl ether data indicate that travel times to the upper part of the aquifer may be less than 16 years. The water-quality-based estimates of travel time generally are consistent with the estimates from particle-tracking analysis.

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Life in the fast lane: Fish and foodweb structure in the main channel of large rivers

We studied the main channel of the lower Illinois River and of the Mississippi River just upstream and downstream of its confluence with the Illinois River to describe the abundance, composition, and/or seasonal appearance of components of the main-channel community. Abundance of fishes in the main channel was high, especially adults. Most adult fishes were present in the main channel for either 3 or 4 seasons/y, indicating that fishes regularly reside in the main channel. We documented abundant zooplankton and benthic invertebrates in the main channel, and the presence of these food types in the diets of channel catfish and freshwater drum. All trophic levels were well represented in the main channel, indicating that the main channel supports a unique food web. The main channel also serves as an important energetic link with other riverine habitats (e.g., floodplains, secondary channels, backwater lakes) because of the mobility of resident fishes and because of the varied energy sources supplying this food web. It may be more realistic to view energy flow in large-river systems as a combination of 3 existing concepts, the river continuum concept (downstream transport), the flood pulse concept (lateral transport to the floodplain), and the riverine productivity model (autochthonous production). We urge additional research to quantify the links between the main channel and other habitat types in large rivers because of the apparent importance of main-channel processes in the overall structure and function of large-river ecosystems.

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Geology, hydrology, and water quality in the vicinity of a Brownfield redevelopment site in East Moline, Illinois

An investigation of the geology, hydrology, and water quality in the vicinity of a Brownfield redevelopment site in East Moline, Illinois, was designed to determine if metals and organic compounds detected in the fill deposits in this area posed a threat to the water resources. The hydrologic features of concern at the site are surface water at a pond and surrounding wetland, the Mississippi River, and an unnamed stream and ground water in the shallow aquifer. The shallow aquifer is composed of saturated fill, sand and gravel, and weathered bedrock. The overall direction of surface- and ground-water flow in the study area is toward the Mississippi River. In the eastern part of the pond and wetland, ground water discharges to surface water. In the western part of the pond and wetland, surface water recharges to ground water. Everyday during the period for which water-level data were available, between 4.7 ' 10-4 and 1.4 ' 10-1 cubic feet of water flowed across a 1 square foot area of aquifer. Variations in values for oxidation-reduction potential and specific conductance may be affected by heterogeneity in the chemical composition of the fill and unconsolidated deposits and the bedrock units. Chemical and biological processes are altering the chemistry of the water in the pond relative to its ground-water source. Concentrations of iron and manganese in water samples appear to be affected by the local geochemical environment in the aquifer. The data do not indicate that contaminants in the fill material are having a substantial adverse affect on surface- or ground-water quality in the study area.

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Storms Consolidated field, Illinois basin: Identifying new reserves in a mature area

Discovered in 1939, Storms Consolidated field in the central Illinois basin has produced approximately 24.5 million bbl oil, mainly from Mississippian sandstone reservoirs, yet may contain significant remaining reserves. The field produces from a combination structural-stratigraphic trap along the upthrown side of a major normal fault trend. Although the principal reservoir zone, the Waltersburg Sandstone, is mostly depleted, another important interval, the Aux Vases Sandstone, appears underexploited in many parts of the field. Description and analysis of the only continuous core through the Aux Vases has led to the identification of major lithofacies and their characterization in terms of reservoir quality. The Aux Vases appears to represent a series of shallow marine bars separated by nonreservoir areas of siltstone, shale, and shaly sandstone. Log-based mapping of reservoir distribution, plus production and pressure data, indicates significant lateral and vertical compartmentalization of the reservoir. Although insufficient data exist for full-scale integrated reservoir characterization studies, a trend surface analysis was performed on structural information across the field. The results of this analysis were compared with reservoir distribution maps to identify areas for future drilling or recompletion.Discovered in 1939, Storms Consolidated field in the central Illinois basin has produced approximately 24.5 million bbl oil, mainly from Mississippian sandstone reservoirs, yet may contain significant remaining reserves. The field produces from a combination structural-stratigraphic trap along the upthrown side of a major normal fault trend. Although the principal reservoir zone, the Waltersburg Sandstone, is mostly depleted, another important interval, the Aux Vases Sandstone, appears underexploited in many parts of the field. Description and analysis of the only continuous core through the Aux Vases has led to the identification of major lithofacies and their characterization in terms of reservoir quality. The Aux Vases appears to represent a series of shallow marine bars separated by nonreservoir areas of siltstone, shale, and shaly sandstone. Log-based mapping of reservoir distribution, plus production and pressure data, indicates significant lateral and vertical compartmentalization of the reservoir. Although insufficient data exist for full-scale integrated reservoir characterization studies, a trend surface analysis was performed on structural information across the field. The results of this analysis were compared with reservoir distribution maps to identify areas for future drilling or recompletion.

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Sequence stratigraphy of the Aux Vases Sandstone: A major oil producer in the Illinois basin

The Aux Vases Sandstone (Mississippian) has contributed between 10 and 25% of all the oil produced in Illinois. The Aux Vases is not only an important oil reservoir but is also an important source of groundwater, quarrying stone, and fluorspar. Using sequence stratigraphy, a more accurate stratigraphic interpretation of this economically important formation can be discerned and thereby enable more effective exploration for the resources contained therein. Previous studies have assumed that the underlying Spar Mountain, Karnak, and Joppa formations interfingered with the Aux Vases, as did the overlying Renault Limestone. This study demonstrates that these formations instead are separated by sequence boundaries; therefore, they are not genetically related to each other. A result of this sequence stratigraphic approach is the identification of incised valleys, paleotopography, and potential new hydrocarbon reservoirs in the Spar Mountain and Aux Vases. In eastern Illinois, the Aux Vases is bounded by sequence boundaries with 20 ft (6 m) of relief. The Aux Vases oil reservoir facies was deposited as a tidally influenced siliciclastic wedge that prograded over underlying carbonate-rich sediments. The Aux Vases sedimentary succession consists of offshore sediment overlain by intertidal and supratidal sediments. Low-permeability shales and carbonates typically surround the Aux Vases reservoir sandstone and thereby form numerous bypassed compartments from which additional oil can be recovered. The potential for new significant oil fields within the Aux Vases is great, as is the potential for undrained reservoir compartments within existing Aux Vases fields.

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Water quality in the lower Illinois River Basin, Illinois, 1995-98

Major influences and findings for water quality and biology in central Illinois, including the Illinois River from Ottawa, Illinois to Valley City, Illinois, are described and illustrated. Samples were collected to determine nitrate, phosphorus, pesticides, volatile organic carbon compounds, and radon-222 in streams and ground water. Agricultural and other land-use practices are discussed in relation to their effects on water quality and aquatic life and habitat. Implications of arsenic in ground water are examined. The interactions between nutrients and stream algal populations are discussed. Results are compared with other studies across the country.

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Diagenesis and reservoir quality of the Upper Mississippian Aux Vases Sandstone, Illinois Basin

Conventional reservoir quality data for more than 300 wells provided by the Illinois and Indiana state geological surveys were analyzed to determine the factors governing porosity and permeability in the Upper Mississippian Aux Vases Sandstone, an important hydrocarbon-producing unit in the Illinois Basin. In addition, approximately 150 samples of the Aux Vases Sandstone were collected for mineralogical and geochemical analysis to reconstruct the burial and diagenetic history and to establish the timing of diagenesis relative to the entrapment of hydrocarbons. One aspect of the study involved linking inorganic and organic diagenesis to late Paleozoic tectonism and hydrothermal fluid-flow events in the region.

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Geology, hydrology, and ground-water quality of the Galena-Platteville aquifer in the vicinity of the Parson's Casket Hardware Superfund Site, Belvidere, Illinois

The geology, hydrology, and distribution of contaminants in the Galena-Platteville aquifer in the vicinity of the Parson's Casket Hardware Superfund site in northeastern Belvidere, Ill., were characterized on the basis of data collected from boreholes using geophysical logging and packer assemblies. Horizontal flow in the Galena-Platteville aquifer is affected by a network of subhorizontal fractures that are concentrated in the weathered part of the bedrock, vugs and fractures present from the bottom of the weathered bedrock to the top of a shaley layer at about 662 ft (feet) above sea level, and through a widespread subhorizontal fracture at about 524 ft. Inclined fractures provide pathways for vertical flow within the Galena-Platteville aquifer. Some fractures and flow pathways appear to be affected by the stratigraphy of the Galena-Platteville deposits. Water-level data indicate the potential for downward flow within the Galena-Platteville aquifer. During periods when pumping in nearby municipal-supply wells is minimal or absent, the direction of flow through the fracture at about 524 ft above sea level is south toward two industrial-supply wells. Flow through the fracture is toward the municipal-supply wells when they are being pumped. Flow in the upper part of the Galena-Platteville aquifer does not appear to be affected by pumping in nearby water-supply wells. Chlorinated ethenes were the volatile organic compounds detected most often and at the highest concentration in the Galena-Platteville aquifer beneath northeastern Belvidere. Volatile organic compounds are migrating primarily to the southeast toward the Kishwaukee River, with components of movement to the north, east, and west. Volatile organic compound and monitored natural attenuation parameter data indicate reductive dechlorination of some chlorinated ethene compounds is occurring under either nitrate or iron-reducing conditions in the unconsolidated deposits and possibly the upper part of the Galena-Platteville aquifer near the center of the plume. Oxidizing conditions appear to be present at least in the upper part of the aquifer beneath most of the study area, and the occurrence of reductive dechlorination in the Galena-Platteville aquifer beneath most of the area of investigation is not clearly indicated.

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Equations for estimating Clark unit-hydrograph parameters for small rural watersheds in Illinois

Equations for estimating the time of concentration ( T C ) and storage coefficient ( R ) of the Clark unit-hydrograph method were developed for small rural watersheds [0.02–2.3 square miles (mi 2 )] in Illinois. The equations will provide State and local engineers and planners with more accurate methods to estimate the T C and R for use in simulating discharge hydrographs on small rural watersheds when designing stormwater-management facilities and other hydraulic structures, determining flood-plain boundaries, and assessing the safety of structures in rivers. The rainfall and runoff data from gaged small rural watersheds (0.02–2.3 mi 2 ) with insignificant amounts of impervious land cover in Illinois were used to develop the equations. Equations were developed on the basis of data for 121 storms that occurred in 39 watersheds. Data for 29 storms in 18 watersheds were used to verify the equations. T C and R were determined by calibrating available rainfall and runoff data, using the U.S. Army Corps of Engineers Flood Hydrograph Package HEC-1. The mathematical relations between watershed and storm characteristics, and T C and R were determined by multiple-linear regression of the logarithms of the values. Main-channel length and slope were identified as important watershed characteristics for estimating T C and R . The estimation equations had coefficients of determination of 0.73 and 0.64 for the logarithms of T C and R , respectively. When storm characteristics were added in the regression of hydrograph parameters utilizing length and slope, only minimal increases to the coefficient of determination resulted. Thus, storm characteristics were not considered further in development of the equations. Simulation of the measured discharge hydrographs for the verification storms utilizing T C and R obtained from the estimation equations yielded good results. The error in peak discharge for 21 of the 29 verification storms was less than 25 percent, and the error in time-to-peak discharge for 18 of the 29 verification storms also was less than 25 percent. Therefore, applying the estimation equations to determine T C and R for design-storm simulation may result in reliable design hydrographs, as long as the physical characteristics of the watersheds under consideration are within the range of those characteristics for the watersheds in this study [area: 0.02–2.3 mi 2 , main-channel length: 0.17–3.4 miles, main-channel slope: 10.5–229 feet per mile, and insignificant percentage of impervious cover].

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Geology, hydrology, and ground-water quality of the upper part of the Galena-Platteville aquifer at the Parson's Casket Hardware Superfund site in Belvidere, Illinois

The geology, hydrology, hydraulic properties, and distribution of contaminants in the upper part of the Galena-Platteville aquifer at the Parson's Casket Hardware Superfund site in Belvidere, Illinois, were characterized on the basis of data collected from boreholes by use of packer assemblies, flowmeter logging, and borehole ground-penetrating radar. Four permeable intervals were identified in the upper part of the Galena-Platteville aquifer: (1) a shallow, subhorizontal fracture from 37 to 40 feet below land surface; (2) an inclined fracture from 75 to 85 feet; (3) a shallow, vuggy interval from 90 to 100 feet; and (4) a deep, vuggy interval from about 140 to 180 feet. The calculated horizontal hydraulic conductivity of the two fractured intervals exceeds 50 feet per day and is more than an order of magnitude greater than that of the vuggy intervals. Water levels in the Galena-Platteville aquifer respond to pumping cycles in the Belvidere municipal-supply wells below a depth of at least 180 feet. Results of flowmeter logging and constant discharge aquifer testing indicate that the shallow, subhorizontal fracture is hydraulically connected to the overlying unconsolidated aquifer. Discrete inclined fractures are the primary conduits for vertical ground-water flow between the permeable units within the upper part of the Galena-Platteville aquifer, and perhaps for flow to the deeper parts of the aquifer. The inclined fractures may become less permeable with depth. A maximum effective porosity in the deep, vuggy interval of 8.8 percent was calculated from hydrologic and borehole radar-tomography data collected during tracer testing. The average maximum horizontal ground-water velocity through this interval was calculated at 21.4 feet per day using cross-hole radar tomography under a hydraulic gradient of 1.25 feet per foot. Trichloroethene, trichloroethane, and tetrachloroethene are the primary volatile organic compounds detected in the aquifer. There is no distinct pattern of the concentration of volatile organic compounds with depth; however, the highest concentrations tend to be present in the shallow part of the aquifer at the site. Movement of organic compounds through vertical fractures may account for their presence in the deeper parts of the aquifer.

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Analysis of nutrients, selected inorganic constituents, and trace elements in water from Illinois community-supply wells, 1984–91

The lower Illinois River Basin (LIRB) study unit is part of the National Water-Quality Assessment program that includes studies of most major aquifer systems in the United States. Retrospective water-quality data from community-supply wells in the LIRB and in the rest of Illinois are grouped by aquifer and depth interval. Concentrations of selected chemical constituents in water samples from community-supply wells within the LIRB vary with aquifer and depth of well. Ranked data for 16 selected trace elements and nutrients are compared by aquifer, depth interval, and between the LIRB and the rest of Illinois using nonparametric statistical analyses. For all wells, median concentrations of nitrate and nitrite (as Nitrogen) are highest in water samples from the Quaternary aquifer at well depths less than 100 ft; ammonia concentrations (as Nitrogen), however, are highest in samples from well depths greater than 200 ft. Chloride and sulfate concentrations are higher in samples from the older bedrock aquifers. Arsenic, lead, sulfate, and zinc concentrations are appreciably different between samples from the LIRB and samples from the rest of Illinois for ground water from the Quaternary aquifer. Arsenic concentration is highest in the deep Quaternary aquifer. Chromium, cyanide, lead, and mercury are not frequently detected in water samples from community-supply wells in Illinois.

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Impact of urban development on the chemical composition of ground water in a fen-wetland complex

A 15-month-long hydrogeologic investigation of a fen-wetland complex in northeastern Illinois, USA indicated the encroachment of ground-water-borne anthropogenic contaminants into two of three high quality fens. Ground-water flow directions and chemical evidence indicated that plumes of ground water with anomalously large concentrations of Na − and Cl − originated from a private septic system and from rock salt spread on an adjacent road. The contamination, in turn, had an adverse effect on fen vegetation; within the plumes, diverse vegetation was replaced by the more salt-tolerant narrow-leaf cattail ( Typha angustifolia ). Ground water of the third fen contained large concentrations of SO 4 2− as high as 516 mg/L. The SO 4 2− anomaly was observed on a transient and/or seasonal basis in the fen ground water and in an adjacent marsh and pond. Isotopically light δ 34 S values in these waters indicated that the addition of SO 4 2− resulted from the oxidation of pyrite within underlying peat and/or pyritic gravel. However, the large SO 4 2− concentrations had no discernible effect on fen vegetation. The results of this investigation indicate how easily construction of houses with private septic systems and deicing agents from roadway maintenance can contaminate fen ground water with relatively large concentrations of Na + and Cl − , resulting in a significant loss of biodiversity in fens.

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Upper crust beneath the central Illinois basin, United States

Newly available industry seismic reflection data provide critical information for understanding the structure and origin of the upper crust (0–12 km depth) beneath the central Illinois basin and the seismic-tectonic framework north of the New Madrid seismic zone in the central Mississippi Valley. Mapping of reflector sequences furnishes the first broad three-dimensional perspective of the structure of Precambrian basement beneath the central United States Midcontinent. The highly coherent basement reflectivity is expressed as a synformal wedge of dipping and subhorizontal reflections situated beneath the center of the Illinois basin that thickens and deepens to the northeast (e.g., 0 to ∼3 km thickness along a 123 km south to north line). The thickening trend of the wedge qualitatively mimics the northward thickening of the Late Cambrian Mt. Simon Sandstone; however, other Paleozoic units in the Illinois basin generally thicken southward into the basin center. The seismic data also reveal an anomalous subsequence defined by a spoon-shaped distribution of disrupted reflections located along the southern margin of the wedge. The boundaries of this subsequence are marked by distinct steeply dipping reflections (possible thrust faults?) that continue or project up to antiformal disruptions of lower Paleozoic marker reflectors, suggesting Paleozoic or possibly later tectonic reactivation of Precambrian structure. The areal extent of the subsequence appears to roughly correspond to an anomalous concentration of larger magnitude upper to middle crustal earthquakes. There are multiple hypotheses for the origin of the Precambrian reflectivity, including basaltic flows or sills interlayered with clastic sediments and/or emplaced within felsic igneous rocks. Such explanations are analogous to nearby Keweenawan rift-related volcanism and sedimentation, which initiated during Proterozoic rifting, and were followed eventually by reverse faulting along the rift margins caused by Grenville compression.

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Liquefaction evidence for at least two strong Holocene paleo-earthquakes in central and southwestern Illinois, USA

Two strong mid-Holocene earthquakes in Illinois have been documented by paleoliquefaction features such as clastic dikes, sills, and detachments of fine-grained sediment that sunk into liquefied sand. At least one paleo-earthquake occurred in central Illinois about 35 km NE of Springfield, probably sometime between 5,900 and 7,400 yr BP. Dike widths are as much as 0.4 m near the energy center of the earthquake. Outward from this center, dike widths attenuate and ultimately disappear at about 35 km. More than one paleo-earthquake is probably represented by liquefaction features near Springfield. Another paleo-earthquake that appears to have been centered about 65 km ESE of St. Louis, Missouri, occurred near 5,700 yr BP. The energy center is inferred as being in Illinois, and most likely near lowermost Shoal Creek where the meizoseismal region is defined by dikes as wide as 0.5 m and by a regional abundance of dikes. Dikes from this earthquake probably extend at least as far as 35 km from its inferred energy center. The earthquake near Shoal Creek and one earthquake near Springfield almost certainly exceeded M 6. The paleomagnitudes can be more closely bracketed by geotechnical testing and analysis, when used in conjunction with existing data.

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Geology, hydrology, and results of tracer testing in the Galena-Platteville aquifer at a waste-disposal site near Byron, Illinois

A study was conducted by the U.S. Geological Survey and the U.S. Environmental Protection Agency of the geohydrology of the dolomite bedrock at a waste-disposal site near Byron, Illinois. The study was designed to identify and characterize the flow pathways through the bedrock aquifer beneath the site. The geologic units of concern at the site are the Glenwood Formation of the Ancell Group, and the Platteville and Galena Groups. These deposits compose the Galena-Platteville aquifer and the underlying Harmony Hill Shale semiconfining unit. The Galena-Platteville aquifer is an unconfined aquifer. Geophysical logging, water levels, and aquifer-test data indicate the presence of interconnected, hydraulically active fractures in the middle of the Galena-Platteville aquifer (the upper flow pathway), and a second set of hydraulically active fractures (the lower flow pathway). The lower flow pathway may be present through much of the site. Few hydraulically active fractures are present in the upper part of the aquifer near the center of the site, but appear to be more numerous in the upper part of the aquifer in the western and northeastern parts of the site. Water-level data obtained during the tracer test indicate that pumping effects were present near the pumped wells. Pumping effects may have been present at several wells located along directions of identified fracture orientation from the pumped well. The upper part of the aquifer did not appear to be hydraulically well connected to the flow pathways supplying water to the pumped well. Large background changes in water levels obscured the effects of pumping and prevented calculation of aquifer properties. The velocity of the bromide tracer through the lower flow pathway under the hydraulic gradient resulting from the pumping was about 152 feet per day. Solution of the Darcy velocity equation results in a calculated effective porosity for this interval of 3.5 percent, indicating hydraulic interconnection between the fractures and the aquifer matrix. Ground-water velocity through the lower flow pathway was calculated to be 15.4 feet per day under hydrostatic conditions.

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Potentiometric levels and water quality in the aquifers underlying Belvidere, Illinois, 1993–96

In 1992, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency (USEPA), began a study of the hydrogeology and water quality of the aquifers underlying the vicinity of Belvidere, Boone County, Ill. Previously, volatile organic compounds (VOC's) and other constituents of industrial origin were detected in one or more ground-water samples from about 100 of the approximately 700 monitoring and water-supply wells in the area, including the 8 municipal wells in Belvidere. A glacial drift aquifer underlies at least 50 percent of the 80-square-mile study area; bedrock aquifers that underlie virtually all of the study area include the Galena-Platteville, St. Peter Sandstone, Ordovician, and Cambrian-Ordovician aquifers. During 1993, water levels were measured in 152 wells and water-quality samples were collected from 97 wells distributed throughout the study area. During 1994–96, similar data were collected from 31 wells. Potentiometric levels in the glacial drift and Galena-Platteville aquifers are similar and range from about 750 to 900 feet above sea level. The potentiometric surfaces of the aquifers are subdued representations of the land surface. Horizontal ground-water flow in the aquifers primarily is towards the Kishwaukee River, which flows through the central part of the study area, and its principal tributaries. Vertical ground-water flow appears to be downward at most locations in the study area, particularly in the urbanized areas affected by pumping of the Belvidere municipal wells and upland areas remote from the principal surface-water drainages. Flow appears to be upward between the Galena-Platteville and glacial drift aquifers where ground water discharges to the Kishwaukee River and its principal tributaries. All water samples were analyzed for VOC's. Selected samples also were analyzed for trace metals, cyanide, semivolatile organic compounds, or other constituents. VOC's were detected in samples from 50 wells (52 percent of total wells sampled). Twenty-seven specific VOC's were identified in the samples. Samples were collected from six municipal wells in use during the study; two wells were not in use because one or more VOC's exceeded maximum contaminant levels (MCL's). Two VOC's were detected in one of the samples at concentrations below MCL's established by the USEPA for protection of public-water supplies. Samples from 21 wells had at least one VOC detected at a concentration above MCL's. The VOC's detected above MCL's and their maximum concentrations were 1,2-dichloroethene (total), 470 micrograms per liter; trichloroethene (TCE), 360 micrograms per liter; tetrachloroethene (PCE), 82 micrograms per liter; benzene, 53 micrograms per liter; and vinyl chloride, 11 micrograms per liter. TCE and PCE were the most frequently detected VOC's and generally had the highest concentrations. VOC's with concentrations above MCL's were detected in samples from 15 wells open to the glacial drift aquifer and 6 wells open to the Galena-Platteville aquifer. Generally, the concentrations of VOC's were higher, and number and type of VOC's detected were greater in the glacial drift aquifer than in the Galena-Platteville aquifer and the deeper bedrock aquifers. The high concentrations and spatial distribution of VOC's in the glacial drift aquifer usually were related to nearby sources of contamination. Except in the immediate vicinity of a known hazardous-waste site, possible sources of VOC's in the bedrock aquifers were difficult to identify in the study area; VOC concentrations at most locations in the bedrock aquifers were below 5 micrograms per liter. Most locations where VOC's were detected in the glacial and bedrock aquifers were within about 1,000 feet of the Kishwaukee River. Hydrogeologic factors that affect the distribution of VOC's in the aquifers include ground-water flow through (1) the glacial drift aquifer with discharge to the nearby Kishwaukee River; and (2) the weathered-surface deposits, bedding-plane partings, and fractures in the Galena-Platteville aquifer. One bedding-plane parting intersecting wells that represent an area of about 1.5 square miles has a horizontal hydraulic conductivity as high as 220 feet per day. Pumping of high-capacity wells may contribute to the widespread distribution of VOC’s at low concentrations in the bedrock aquifers.

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Environmentally critical elements in channel and cleaned samples of Illinois coals

Sixteen trace and minor elements that occur in coal are listed among 189 substances identified as ‘hazardous air pollutants’ (HAPs) in the US Clean Air Act Amendments of 1990. We investigated the occurrence and cleanability of the 16 HAPs in Illinois coals, as a contribution to the discussion about the potential effect of pending environmental regulations on the future use of these coals in power generation. The average ash content of the samples of conventionally cleaned as-shipped coals is about 20% lower than that of standard channel samples. Conventional cleaning reduces the average concentrations of As, Cd, Co, Hg, Mn, Ni, Pb, Sb and Th in the as-shipped coals by more than 20% relative to channel samples. Thus, basing assessments of health risks from emissions of HAPs during coal combustion on channel samples without appropriate adjustment would overestimate the risk. Additional cleaning by froth-flotation reduces the ash content of finely-ground as-shipped coals by as much as 76% at an 80% combustibles recovery. Although the average froth-flotation cleanability for the majority of HAPs is less than that for ash, the cleanabilities in some individual cases approaches, or even exceeds, the cleanability for ash, depending on the modes of occurrences of the elements.

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