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Research about Illinois, Indiana, Kentucky

Source-linked reports with geographic coverage including Illinois, Indiana, Kentucky.

18 recordsLinked to original sources
USGS2025

The impact of burial diagenesis on soil-formed minerals in paleosols using stable isotopes of phyllosilicates and carbonate clumped isotopes

To understand the effects of burial diagenesis on the stable isotope geochemistry of soil-formed clay and carbonate minerals in paleosols, samples were collected from seven cores, spanning middle- to upper-Pennsylvanian strata of the Illinois Basin, with varied maximum burial depths of 1–3 km. Mixed-layer illite-smectite and kaolinite mixtures give δ 2 H and δ 18 O values of −83 ‰ to −36 ‰ and 11.9 ‰ to 21.1 ‰ (VSMOW), respectively. After carbonates were screened petrographically for diagenetic textures using transmitted light and cathodoluminescence, measured clumped isotope Δ 47 values range from 0.504 to 0.563 ‰ (I-CDES). Resulting mineral formation temperatures for phyllosilicate mineral mixtures are 28 to 66 °C (mean = 47 °C), whereas T(Δ 47 ) estimates for calcites are 36 to 61 °C (mean = 45 °C). Calculated δ 18 O water values from which phyllosilicate minerals and calcites precipitated under isotopic equilibrium ranges from −7.1 to −1.2 ‰ and − 1.4 to +4.9 ‰, respectively. Closed and open-system phyllosilicate-fluid exchange modeling indicates that phyllosilicate alteration occurred in the presence of a low temperature brine or meteoric water and is interpreted to occur in a layer-by-layer illitization transformation. Due to the lack of diagenetic textures and positively correlated T(Δ 47 ) and δ 18 O water , calcites are interpreted to have undergone solid-state bond reordering. Despite low to moderate temperatures (<125 °C) and varying depths of shallow burial (1–3 km), solid-state transformation of phyllosilicates and calcites indicates paleosols had prolonged exposure to burial conditions which has implications for the use of paleosol minerals for paleoenvironmental reconstructions.

Illinois, Indiana, Kentucky↗
USGS2019

Estimating the pressure-limited dynamic capacity and costs of basin-scale CO2 storage in a Saline Formation

Deployment of carbon capture and storage (CCS) could be necessary to be able to satisfy baseload electricity demand, maintain diversity in the energy mix, and achieve mitigation of carbon dioxide (CO 2 ) emissions at lowest cost ( IPCC, 2015 ; U.S. DOE, 2016 ). If basin-, regional- or national-scale deployment of CCS is needed, it may be possible to store only a small fraction of the captured CO 2 in oil and natural gas reservoirs. The vast majority would likely have to be stored in saline formations. Pressure buildup as a result of injecting CO 2 into such reservoirs is expected to be an important source of risk associated with CO 2 storage, and could constrain dynamic storage capacities (maximum injection rates) to be far below estimates based on access to theoretical storage resources. Estimates of CO 2 storage costs based on an assumption of practical availability of the theoretical storage resource could lead to underestimation of the costs of CO 2 storage. In this study, simulation results suggest that the pressure-limited dynamic CO 2 storage capacity of the Mount Simon Sandstone could be less than 4% of the theoretical storage resource in this saline formation, and storage costs could be an order of magnitude higher than recent estimates. However, consideration of the geologic heterogeneity in this deep saline formation allowed definition of a high injectivity zone, and estimated costs of CO 2 storage in this “sweet spot” of the reservoir approached recent estimates that did not include costs for pressure management.

Illinois, Indiana, Kentucky↗
USGS2005

Ground-motion parameters of the southwestern Indiana earthquake of 18 June 2002 and the disparity between the observed and predicted values

The M 4.5 southwestern Indiana earthquake of 18 June 2002 triggered 46 blast monitors in Indiana, Illinois, and Kentucky. The resulting flee-field particle velocity records, along with similar data from previous earthquakes in the study area, provide a clear standard for judging the reliability of current maps for predicting ground motions greater than 2 Hz in southwestern Indiana and southeastern Illinois. Peak horizontal accelerations and velocities, and 5% damped pseudo-accelerations for the earthquake, generally exceeded ground motions predicted for the top of the bedrock by factors of 2 or more, even after soil amplifications were taken into consideration. It is suggested, but not proven, that the low shear-wave velocity and weathered bedrock in the area are also amplifying the higher-frequency ground motions that have been repeatedly recorded by the blast monitors in the study area. It is also shown that there is a good correlation between the peak ground motions and 5% pseudo-accelerations recorded for the event, and the Modified Mercalli intensities interpreted for the event by the U.S. Geological Survey.

Illinois, Indiana, Kentucky↗
USGS2002

Regional fluid flow as a factor in the thermal history of the Illinois basin: Constraints from fluid inclusions and the maturity of Pennsylvanian coals

Vitrinite reflectance measurements on Pennsylvanian coals in the Illinois basin indicate significantly higher thermal maturity than can be explained by present-day burial depths. An interval of additional sedimentary section, now removed by erosion, has been suggested to account for the discrepancy. Although burial could indeed account for the observed maturity levels of organic matter, fluid-inclusion temperatures provide a stringent additional constraint. In this article, we combine measurements of coal maturity with fluid-inclusion temperatures from three sites to constrain the basin's thermal and burial history: the Fluorspar district at the Illinois basin's southern margin, the Upper Mississippi Valley zinc district at the basin's northern margin, and a north-central location. Two-dimensional numerical modeling of a north-south cross section through the basin tests scenarios both with and without regional fluid flow. Vitrinite reflectance values can be matched assuming burial by 1.8-2.8 km of southward-thickening additional, post-Pennsylvanian sedimentary section. In the central and northern Illinois basin, however, these burial depths and temperatures are not sufficient to account for the fluid-inclusion data. To account for both parameters with burial alone does not appear feasible. In contrast, our best hypothesis assumes a wedge of post-Pennsylvanian sediment-thickening southward to about 1.2 km and a brief period of magmatism in the Fluorspar district. Significant advective heat redistribution by northward regional fluid flow accounts for fluid-inclusion temperatures and coal maturities throughout the basin. The modeling results demonstrate the potential contribution of advective heat transport to the thermal history of the Illinois basin.

Illinois, Indiana, Kentucky↗
USGS2002

Material-balance assessment of the New Albany-Chesterian petroleum system of the Illinois basin

The New Albany-Chesterian petroleum system of the Illinois basin is a well-constrained system from which petroleum charges and losses were quantified through a material-balance assessment. This petroleum system has nearly 90,000 wells penetrating the Chesterian section, a single New Albany Shale source rock accounting for more than 99% of the produced oil, well-established stratigraphic and structural frameworks, and accessible source rock samples at various maturity levels. A hydrogen index (HI) map based on Rock-Eval analyses of source rock samples of New Albany Shale defines the pod of active source rock and extent of oil generation. Based on a buoyancy-drive model, the system was divided into seven secondary-migration catchments. Each catchment contains a part of the active pod of source rock from which it derives a petroleum charge, and this charge is confined to carrier beds and reservoirs within these catchments as accountable petroleum, petroleum losses, or undiscovered petroleum. A well-constrained catchment with no apparent erosional or leakage losses is used to determine an actual petroleum charge from accountable petroleum and residual migration losses. This actual petroleum charge is used to calibrate the other catchments in which erosional petroleum losses have occurred. Petroleum charges determined by laboratory pyrolysis are exaggerated relative to the actual petroleum charge. Rock-Eval charges are exaggerated by a factor of 4-14, and hydrouspyrolysis charges are exaggerated by a factor of 1.7. The actual petroleum charge provides a more meaningful material balance and more realistic estimates of petroleum losses and remaining undiscovered petroleum. The total petroleum charge determined for the New Albany-Chesterian system is 78 billion bbl, of which 11.4 billion bbl occur as a accountable in place petroleum, 9 billion bbl occur as residual migration losses, and 57.6 billion bbl occur as erosional losses. Of the erosional losses, 40 billion bbl were lost from two catchments that have highly faulted and extensively eroded sections. Anomalies in the relationship between erosional losses and degree of erosion suggest there is potential for undiscovered petroleum in one of the catchments. These results demonstrate that a material-balance assessment of migration catchments provides a useful means to evaluate and rank areas within a petroleum system. The article provides methodologies for obtaining more realistic petroleum charges and losses that can be applied to less data-rich petroleum systems.

Illinois, Indiana, Kentucky↗
USGS2002

The Commerce geophysical lineament and its possible relation to Mesoproterozoic igneous complexes and large earthquakes in the central Illinois Basin

New inversions of existing magnetic and gravity data lead to insights on upper crustal structures in the central Illinois basin. The results of 2D and 3D inversion techniques suggest that the source of the Commerce geophysical lineament follows the southeast boundary of a dense and magnetic, northeast-trending igneous center, named the Vincennes igneous center. Thus the Commerce geophysical lineament, defining the 5- to 10-km-wide Commerce deformation zone, appears to have influenced the structural development of the Vincennes igneous center. Overlying this igneous center is the Centralia seismic-reflection sequence, expressed as highly coherent reflectors ( McBride and Kolata, 1999 ). We suggest that the buried Vincennes igneous center is the source of inferred volcanic units of the Centralia sequence and is related to a rifted margin or a Proterozoic plate boundary. A comparison of gravity and magnetic fields over the Vincennes igneous center and the St. Francois Mountains igneous center in southeastern Missouri suggests that the associated sources in these regions are similar in composition and perhaps origin. Such a conclusion, although speculative, suggests that ∼1.47 Ga-year-old volcanic fields of high-silica rocks, with more abundant mafic components at depth, characterize basement in the regions of the Vincennes igneous center and the St. Francois Mountains. Further, we conclude that the Commerce deformation zone evolved in the Mesoproterozoic (1.1 to 1.5 Ga) as a major cratonic rheological boundary and was the focus of episodic reactivation related to varying stress regimes throughout its history. Spatial relations of the Commerce deformation zone with large Pleistocene and Holocene earthquakes suggest that the zone represents a major rheological boundary intimately related to both surface and deep structures and to the seismic hazard of the Illinois basin region. Assuming recent right-lateral slip along the Commerce deformation zone, we propose that a jog or left step in the Vincennes area leads to thrusting or a restraining bend, where associated stress accumulations may have resulted in nearby large prehistoric earthquakes and may also be the nucleation sites of future large earthquakes.

Illinois, Indiana, Kentucky↗
USGS2002

Interpreting the earthquake source of the Wabash Valley seismic zone (Illinois, Indiana, and Kentucky) from seismic-reflection, gravity, and magnetic-intensity data

Reprocessing of seismic-reflection data reveals new images of upper- to middle-crustal structures beneath the Wabash Valley seismic zone, located north of the New Madrid seismic zone within the seismically active southern Illinois basin. Four intersecting deep seismic profiles (243 km total) indicate an anomalous, 5–10-km-wide zone of dipping reflections and diffractions below the western flank of the Wabash Valley fault system (WVFS). The zone corresponds in places to gently arched regions of Paleozoic strata. The reflector zone can be interpreted as a result of either (or a combination of) magmatic intrusion or structural deformation. The area encompassing the reflection profiles has experienced several moderate magnitude (3.0 ≤ m bLg ≤ 5.5) earthquakes during the past 50 years, defining the central part of the Wabash Valley seismic zone. The hypocenter of the largest 20th-century earthquake in the central USA midcontinent (9 November 1968, m bLg 5.5) corresponds to the most prominent zone of dipping middle-crustal reflections, just west of the WVFS. Both the focal mechanism (moderately dipping reverse fault) and the expected rupture zone size (∼2.9 km fault length) of this earthquake are consistent with the orientation and size of observed reflectors. Dipping reflector patterns in the Precambrian crust are not collinear with fault surfaces updip in the Paleozoic sedimentary section. This indicates that shallow Paleozoic structures are effectively “decoupled” from deeper, possibly seismogenic structure, which suggests that understanding Paleozoic structure is not the key to understanding the earthquake source. The complex dipping crustal reflectivity beneath the WVFS is typical of Paleozoic continental convergent zones observed elsewhere ( e.g. , Appalachian orogen) and thus may suggest a preserved Proterozoic suture, possibly associated with the distal Grenville orogeny or an older event. Although magnetic intensity, Bouguer gravity, and seismic-reflection data present different means of understanding the deep geology of the area, their integration aids in limiting the number of admissible interpretations. The reflection profiles indicate a variable zone of anomalous crustal structure, including the dipping reflector zone, along a trend of northeast-trending gravity and magnetic highs locally defining the Commerce geophysical lineament (CGL), which is a suspected source of seismic hazard in the central USA midcontinent. Three-dimensional inverse modeling of the residual isostatic gravity anomaly values indicates that the upper part of the dipping reflector zone beneath the CGL lies near an important density boundary in the upper Precambrian crust. The results of our study suggest that the seismogenic source just north of the New Madrid seismic zone consists, in part, of a pre-existing fabric of blind thrusts localized along pre-existing igneous intrusions, locally coincident with the CGL. This suggests that the CGL may be seismogenic in places and thus a potential seismic hazard. The variation in the expression of the CGL using reflection and potential-field data sets is probably partly related to the differing geologic features by which it is expressed, but would be also consistent with its reactivation numerous times under varying stress regimes.

Illinois, Indiana, Kentucky↗
USGS2001

Regional fluid migration in the Illinois basin: Evidence from in situ oxygen isotope analysis of authigenic K-feldspar and quartz from the Mount Simon Sandstone

Oxygen isotope compositions of widespread, authigenic K-feldspar and quartz overgrowths and cements in the Upper Cambrian Mount Simon Sandstone were measured by ion microprobe in 11 samples distributed across the Illinois basin and its periphery. Average K-feldspar δ 18 O values increase systematically from +14‰ ± 1‰ in the southernmost and deepest samples in Illinois to +24‰ ± 2‰ in the northernmost outcrop sample in Wisconsin. A similar trend was observed for quartz overgrowths (22‰ ± 2‰ to 28‰ ± 2‰). Constant homogenization temperatures (100–130 °C) of fluid inclusions associated with quartz overgrowths throughout the basin suggest that the geographic trend in oxygen isotope compositions is a result of diagenetic modification of a south to north migrating basinal fluid.

Illinois, Indiana, Kentucky↗
USGS1997

Seismic interpretation of the deep structure of the Wabash Valley Fault System

Interpretations of newly available seismic reflection profiles near the center of the Illinois Basin indicate that the Wabash Valley Fault System is rooted in a series of basement-penetrating faults. The fault system is composed predominantly of north-northeast-trending high-angle normal faults. The largest faults in the system bound the 22-km wide 40-km long Grayville Graben. Structure contour maps drawn on the base of the Mount Simon Sandstone (Cambrian System) and a deeper pre-Mount Simon horizon show dip-slip displacements totaling at least 600 meters across the New Harmony fault. In contrast to previous interpretations, the N-S extent of significant fault offsets is restricted to a region north of 38° latitude and south of 38.35° latitude. This suggests that the graben is not a NE extension of the structural complex composed of the Rough Creek Fault System and the Reelfoot Rift as previously interpreted. Structural complexity on the graben floor also decreases to the south. Structural trends north of 38° latitude are offset laterally across several large faults, indicating strike-slip motions of 2 to 4 km. Some of the major faults are interpreted to penetrate to depths of 7 km or more. Correlation of these faults with steep potential field gradients suggests that the fault positions are controlled by major lithologic contacts within the basement and that the faults may extend into the depth range where earthquakes are generated, revealing a potential link between specific faults and recently observed low-level seismicity in the area.

Illinois, Indiana, Kentucky↗
USGS1987

Use of stable sulphur isotopes to monitor directly the behaviour of sulphur in coal during thermal desulphurization

A method has been developed using stable sulphur isotope analyses to monitor the behaviour of sulphur forms in a coal during thermal desulphurization. In this method, the natural stable isotopic composition of the pyritic and organic sulphur in coal is used as a tracer to follow their mobility during the desulphurization process. This tracer method is based on the fact that the isotopic compositions of pyritic and organic sulphur are significantly different in some coals. Isotopic results of pyrolysis experiments at temperatures ranging from 350 to 750 °C indicate that the sulphur released with the volatiles is predominantly organic sulphur. The pyritic sulphur is evolved in significant quantities only when pyrolysis temperatures exceed 500 °C. The presence of pyrite seems to have no effect on the amount of organic sulphur evolved during pyrolysis. The chemical and isotopic mass balances achieved from three different samples of the Herrin (No. 6) coal of the Illinois Basin demonstrate that this stable isotope tracer method is quantitative. The main disadvantage of this tracing technique is that not all coals contain isotopically distinct organic and pyritic sulphur.

Illinois, Indiana, Kentucky↗
USGS1985

Organic geochemical characterization of the New Albany Shale group in the Illinois Basin

Benzene extractable aliphatic hydrocarbons from the New Albany Shale in the Illinois Basin were characterized by gas chromatography and mass spectrometry, and the total organic matter of the shale was characterized by solid state carbon-13 cross polarization magic angle spinning nuclear magnetic resonance. Core samples from a northwest-trending cross-section of the Illinois Basin were studied. Gas chromatography (GC) and gas chromatography-mass spectrometric analysis (GC/MS) data indicate a regional variation of the aliphatic composition of the shale extracts. A positive, linear relationship between the two ratios, pristane/ n -C 17 and phytane/ n -C 18 , is indicated. The NMR results indicated that organic matter deposited in northwestern Illinois shale is relatively high in aliphatic hydrocarbon content while, in contrast, organic matter found in southeastern Illinois shale is relatively low in aliphatic hydrocarbon content. Our findings suggest that the organic variation of the shale is mainly due to the differences in thermal maturity of the shale organic matter and the use of pristane/ n -C 17 ratio as a thermal parameter in the study of oil may be extended to the study of the ancient sediments.

Illinois, Indiana, Kentucky↗
USGS1984

Coalification of organic matter in coal balls of the Pennsylvanian (upper Carboniferous) of the Illinois Basin, United States

An evaluation was made of the degree of coalification of two coal balls from the Illinois Basin of the Pennsylvanian (upper Carboniferous) of the United States. Previous interpretations are mainly misleading and contradictory, primarily because of the assumption that the brown color and exceptional cellular and subcellular preservation typical of American coal balls imply chemical preservation of cellulose and lignin, the primary components of peat. Xylem tissue from a medullosan seed fern contained in a coal ball and the coal attached to the coal ball from the Calhoun coal bed, Mattoon Formation, Illinois, was analyzed by elemental, petrographic, and nuclear magnetic resonance (NMR) techniques to determine the degree of coalification. The NMR and elemental data indicate the lack of cellulose and lignin and a probable rank of high-volatile C bituminous coal. These data corroborate data for a coal ball from the Herrin (No. 6) coal bed (Carbondale Formation, Middle Pennsylvanian) and support our hypothesis that the organic matter in coal balls of the Pennsylvanian strata of the United States is coalified to about the same degree as the surrounding coal. Data presented show a range of lower reflectances for xylem tissue and vitrinite in the analyzed coal balls compared with vitrinite in the attached coal. The data reported indicate that physical preservation of organic matter in coal balls does not imply chemical preservation. Also our study supports the hypothesis that compactional (static load) pressure is not a prerequisite for coalification up to a rank of high-volatile C bituminous coal. A whole-rock analysis of the Calhoun coal ball indicates a similarity to other carbonate coal balls from the United States. It consists primarily of calcium carbonate and 1–2% organic matter; silica and alumina together make up less than 0.5%, indicating the lack of minerals such as quartz and clays.

Illinois, Indiana, Kentucky↗
USGS1960

Minor element content of coal from Illinois beds 5 and 6 and their correlatives in Indiana and western Kentucky

Spectrographic analyses for 15 elements of 249 block samples of coal are reported here. These samples represent 28 localities of beds 5 and 6 of Illinois and their correlatives in Indiana and western Kentucky. Comparison with the coals of the Northern Great Plains province shows a similarity in the total amount of these elements in the coal, however, individual elements differ considerably. The degree of association with the organic or inorganic matter of coal is determined by the separation of thirteen samples into float and sink fractions. Be, B, Ti, V, Ga, and Ge are essentially associated with the organic matter of coal. Zn, Sn and La are invariably found to be associated with the inorganic matter. Cr, Co, Ni, Cu, Mo and Y have intermediate degrees of association.

Illinois, Indiana, Kentucky↗