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Research about Denmark

Source-linked reports with geographic coverage including Denmark.

8 recordsLinked to original sources
USGS2025

Characterization of DOC in riparian wetland pore water and its interference in stable water isotope analysis of δ2H and δ18O

Wetlands play an important role in carbon retention, which is greatly dependent on hydrological conditions. Therefore, the interest in wetland hydrology has increased over recent decades. In wetland hydrology, stable water isotopes ( δ 2 H, δ 18 O) have found increasing use, as laser-based instruments have become readily available and allow for faster analysis and lower costs. However, the use of laser-based determinations of stable hydrogen and oxygen isotopes in wetland pore waters might be challenging because of dissolved organic carbon (DOC), especially as wetland pore waters often contain elevated DOC concentrations. To study the potential interference of DOC on laser-based stable water isotopes determination, we determined concentration, fluorescence and absorbance characteristics of DOC in pore waters collected from six restored and six near-natural riparian wetlands. The water samples’ δ 2 H and δ 18 O values were determined by two laser absorption spectrometers (LAS) and, for reference, in parallel by dual-inlet isotope-ratio mass spectrometry (DI-IRMS). The two LAS methods showed significant deviations from the DI-IRMS-determinations. Variations in the specific UV absorbance index (SUVA 254 , the quotient of the absorbance at 254 nm and the DOC concentration), which indicates the aromaticity of the DOC, partially accounted for interference for δ 2 H measurements. Elevated SUVA 254 index values were especially linked to restored wetlands. Studies that investigate pore waters with high DOC aromaticity but where the DOC is not characterized, and which require a high accuracy of the δ 2 H-values for interpretation of the hydrological system, may be severely affected by DOC interference.

Journal of Hydrology↗
USGS2023

Aeromagnetic expression of the central Nagssugtoqidian Orogen, South-East Greenland

The Paleoproterozoic Nagssugtoqidian Orogen is one of the principal tectonic features related to the assembly of Nuna, extending across Greenland from east to west and forming an orogenic belt separating the North Atlantic Craton on the south from the Rae Craton on the north. In South-East Greenland, the Ammassalik Intrusive Complex (AIC) (∼1910 to 1870 Ma) occupies the central part of the orogenic belt, was formed by subduction- and magmatic arc-related processes, and has significant potential for undiscovered deposits of critical minerals. Previous interpretations of aeromagnetic data have been hindered by terrain effects, and we use a novel mix of geophysical analysis tools to develop new tectonomagmatic interpretations of the central Nagssugtoqidian Orogen in South-East Greenland. These interpretations extend into areas covered by ocean and ice. Results show that Archean rocks of the juxtaposed North Atlantic (Isertoq Terrane) and Rae (Kuummiut Terrane) Cratons are relatively weakly magnetized (with the exception of rocks of the Schweizerland Terrane) and have a NW-striking structural fabric that likely formed or was enhanced during the Nagssugtoqidian Orogeny. The AIC is structurally complex, with weakly magnetized metasedimentary rocks, and both weakly and strongly magnetized intrusions, arrayed in a NW-striking tectonic fabric. The strongly magnetized intrusions are largely concealed and distributed in a broader and more spatially complex fashion than previously known, suggesting that additional areas may be considered for mineral exploration. Strongly magnetized NW-striking dikes are imaged within the AIC, where they are spatially closely related to the strongly magnetized intrusions, and extend southward into the North Atlantic Craton (Isertoq Terrane). This spatial pattern of arc magmatism is consistent with previously developed models of SW-directed subduction that preceded collision during the Nagssugtoqidian Orogeny. The strongly magnetized Ammassalik Batholith (∼1670 Ma) and related intrusions form a cluster of plutons within ∼ 50 km of the Nagssugtoqidian suture. Their tectonomagmatic setting is unknown, although are speculatively related to delamination of a lithospheric keel formed during the Nagssugtoqidian Orogeny ∼ 200 m.y. prior. Numerous strongly magnetized NNE-striking Paleogene dikes, related to the opening of the Atlantic Ocean, are imaged cutting most other geologic units.

Greenland↗
USGS2022

Assessing spatial transferability of a random forest metamodel for predicting drainage fraction

Fully distributed hydrological models are widely used in groundwater management, but model speed and data requirements impede their use for decision support purposes. Metamodels provide a simpler and faster model which emulates the underlying complex model using machine learning techniques. However, metamodel predictions beyond the ranges, in space and/or time, of training data are highly uncertain, and thus it is important to assess the predictive model performance to ranges outside the training data, i.e., model transferability . We present a novel methodology for evaluating model transferability to areas not contained in the training data set, based on various metrics that quantify the differences in covariate distributions between training and testing data. The transferability method can be employed as a screening tool to assess the suitability of a metamodel for spatial prediction beyond its training domain. We evaluated this transferability approach on a Random Forest metamodel of a 1000 km 2 fully distributed coupled groundwater model for predicting drainage fraction, the partitioning of infiltrating water between drains and groundwater. We conducted spatial cross-validation on 9 holdout sub-basins to assess metamodel transferability beyond sampling locations and compared this estimate with a random split-sample validation test. Using mappable covariates only, the metamodel showed high performance (R 2 = 0.79) tested on a 20% randomly sampled holdout. Conversely, metamodel performance significantly decreased for the 9 spatial holdouts (R 2 ranging from 0.13 to 0.61). We document that the proposed transferability metric correlates with metamodel predictive performance, and demonstrate its use to assess model transferability to datasets outside the training data spatial domain.

Journal of Hydrology↗
USGS2015

Testing an attachment method for solar-powered tracking devices on a long-distance migrating shorebird

Small solar-powered satellite transmitters and GPS data loggers enable continuous, multi-year, and global tracking of birds. What is lacking, however, are reliable methods to attach these tracking devices to small migratory birds so that (1) flight performance is not impacted and (2) tags are retained during periods of substantial mass change associated with long-distance migration. We developed a full-body harness to attach tags to Red Knots (Calidris canutus), a medium-sized shorebird (average mass 124 g) that undertakes long-distance migrations. First, we deployed dummy tags on captive birds and monitored them over a complete migratory fattening cycle (February–July 2013) during which time they gained and lost 31–110 g and underwent a pre-alternate moult of body feathers. Using each individual’s previous year fattening and moult data in captivity as controls, we compared individual mass and moult differences between years between the tagged and reference groups, and concluded that the attachment did not impact mass and moult cycles. However, some birds shed feathers under the tags and under the polyester harness line commonly used in avian harnesses. Feather shedding was alleviated by switching to smoothed-bottom tags and monofilament harness lines. To field-trial this design, we deployed 5-g satellite transmitters on ten Red Knots released on 3 October 2013 in the Dutch Wadden Sea. Bird movements and tag performance appeared normal. However, nine tags stopped transmitting 11–170 days post-release which was earlier than expected. We attribute this to bird mortality rather than failure of the attachments or transmitters and suggest that the extra weight and drag caused by the tag and its feather-blocking shield increased the chance of depredation by the locally common Peregrine Falcons (Falco peregrinus). Our results demonstrate that species- and place-specific contexts can strongly determine tagging success. While captive trials are an important first step in developing an attachment method, field trials are essential to fully assess attachment designs.

Wadden Sea↗
USGS2004

Transport and time lag of chlorofluorocarbon gases in the unsaturated zone, Rabis Creek, Denmark

Transport of chlorofluorocarbon (CFC) gases through the unsaturated zone to the water table is affected by gas diffusion, air–water exchange (solubility), sorption to the soil matrix, advective–dispersive transport in the water phase, and, in some cases, anaerobic degradation. In deep unsaturated zones, this may lead to a time lag between entry of gases at the land surface and recharge to groundwater. Data from a Danish field site were used to investigate how time lag is affected by variations in water content and to explore the use of simple analytical solutions to calculate time lag. Numerical simulations demonstrate that either degradation or sorption of CFC-11 takes place, whereas CFC-12 and CFC-113 are nonreactive. Water flow did not appreciably affect transport. An analytical solution for the period with a linear increase in atmospheric CFC concentrations (approximately early 1970s to early 1990s) was used to calculate CFC profiles and time lags. We compared the analytical results with numerical simulations. The time lags in the 15-m-deep unsaturated zone increase from 4.2 to between 5.2 and 6.1 yr and from 3.4 to 3.9 yr for CFC-11 and CFC-12, respectively, when simulations change from use of an exponential to a linear increase in atmospheric concentrations. The CFC concentrations at the water table before the early 1990s can be estimated by displacing the atmospheric input function by these fixed time lags. A sensitivity study demonstrates conditions under which a time lag in the unsaturated zone becomes important. The most critical parameter is the tortuosity coefficient. The analytical approach is valid for the low range of tortuosity coefficients (τ = 0.1–0.4) and unsaturated zones greater than approximately 20 m in thickness. In these cases the CFC distribution may still be from either the exponential or linear phase. In other cases, the use of numerical models, as described in our work and elsewhere, is an option.

Rabis Creek↗
USGS1998

Concentration data and dimensionality in groundwater models: Evaluation using inverse modelling

A three-dimensional inverse groundwater flow and transport model that fits hydraulic-head and concentration data simultaneously using nonlinear regression is presented and applied to a layered sand and silt groundwater system beneath the Grindsted Landfill in Denmark. The aquifer is composed of rather homogeneous hydrogeologic layers. Two issues common to groundwater flow and transport modelling are investigated: 1) The accuracy of simulated concentrations in the case of calibration with head data alone; and 2) The advantages and disadvantages of using a two-dimensional cross-sectional model instead of a three-dimensional model to simulate contaminant transport when the source is at the land surface. Results show that using only hydraulic heads in the nonlinear regression produces a simulated plume that is profoundly different from what is obtained in a calibration using both hydraulic-head and concentration data. The present study provides a well-documented example of the differences that can occur. Representing the system as a two-dimensional cross-section obviously omits some of the system dynamics. It was, however, possible to obtain a simulated plume cross-section that matched the actual plume cross-section well. The two-dimensional model execution times were about a seventh of those for the three-dimensional model, but some difficulties were encountered in representing the spatially variable source concentrations and less precise simulated concentrations were calculated by the two-dimensional model compared to the three-dimensional model. Summed up, the present study indicates that three dimensional modelling using both hydraulic heads and concentrations in the calibration should be preferred in the considered type of transport studies.

Grindsted Landfill↗
USGS1995

Three-dimensional inverse modelling using heads and concentrations at a Danish landfill

A three-dimensional inverse model using hydraulic heads and concentrations of non-reactive solutes is presented. Application to the Danish Grindsted Old Landfill is used to investigate how the concentration data affects estimates of horizontal and vertical hydraulic conductivity and longitudinal dispersivity as well as prediction uncertainty

Grindsted↗