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Research about Delaware

Source-linked reports with geographic coverage including Delaware.

At least 55 records · Page 3Linked to original sources

Hydrogeologic setting and ground water flow beneath a section of Indian River Bay, Delaware

The small bays along the Atlantic coast of the Delmarva Peninsula (Delaware, Maryland, and Virginia) are a valuable natural resource, and an asset for commerce and recreation. These coastal bays also are vulnerable to eutrophication from the input of excess nutrients derived from agriculture and other human activities in the watersheds. Ground water discharge may be an appreciable source of fresh water and a transport pathway for nutrients entering the bays. This paper presents results from an investigation of the physical properties of the surficial aquifer and the processes associated with ground water flow beneath Indian River Bay, Delaware. A key aspect of the project was the deployment of a new technology, streaming horizontal resistivity, to map the subsurface distribution of fresh and saline ground water beneath the bay. The resistivity profiles showed complex patterns of ground water flow, modes of mixing, and submarine ground water discharge. Cores, gamma and electromagnetic-induction logs, and in situ ground water samples collected during a coring operation in Indian River Bay verified the interpretation of the resistivity profiles. The shore-parallel resistivity lines show subsurface zones of fresh ground water alternating with zones dominated by the flow of salt water from the estuary down into the aquifer. Advective flow produces plumes of fresh ground water 400 to 600 m wide and 20 m thick that may extend more than 1 km beneath the estuary. Zones of dispersive mixing between fresh and saline ground water develop on the upper, lower, and lateral boundaries of the the plume. the plumes generally underlie small incised valleys that can be traced landward to stream draining the upland. The incised valleys are filled with 1 to 2 m of silt and peat that act as a semiconfining layer to restrict the downward flow of salt water from the estuary. Active circulation of both the fresh and saline ground water masses beneath the bay is inferred from the geophysical results and supported by geochemical data.

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Occurrence and distribution of mercury in the surficial aquifer, Long Neck Peninsula, Sussex County, Delaware, 2003–04

In January 2001, mercury (Hg) was detected (500 nanograms per liter, ng/L, or greater) in the distribution system of the Long Neck Water Company (LNWC), Pot Nets, Delaware. By April 2001, two LNWC production wells had been taken off-line because discharge concentrations of total mercury (HgT) either had exceeded or approached the Federal limit of 2,000 ng/L. From October 2003 through January 2005, the U.S. Geological Survey, Delaware Geological Survey, and Delaware Department of Natural Resources and Environmental Control conducted a cooperative study to (a) determine if the Hg contamination was widespread, (b) identify possible forms of Hg in ground water, and (c) examine Hg occurrence in relation to (geo)chemical conditions and characteristics of ground water and sediment in the surficial aquifer on the Long Neck Peninsula, Sussex County, Delaware. An initial water-quality survey conducted with samples from 22 production wells revealed that concentrations of HgT in ground water in the surficial aquifer ranged from 0.11 to 1,820 ng/L. Shallow ground water (less than 120 feet below land surface) throughout most of the peninsula, including that which contained elevated concentrations of HgT (exceeding 100 ng/L), appeared to be affected by human activities. All samples contained volatile organic compounds (VOCs) and elevated nitrate-nitrogen (NO3-N, exceeding 0.4 milligrams per liter, mg/L). Most (16 of 22) samples had elevated specific conductance (SC, in excess of 100 microsiemens per centimeter at 25 degrees Celsius). Elevated concentrations of HgT, however, only occurred in five production wells in the Pot Nets Bayside and Lakeside communities. The vertical distribution of HgT in shallow ground water (less than 80 feet below land surface) was determined with samples collected at 5 to 6 vertical-nest short-screened (2 - 5-foot length) monitoring wells installed near Bayside and Lakeside production wells with the highest HgT concentrations (exceeding 1,000 ng/L). Elevated concentrations ofHgT (100-6,380 ng/L) occurred in the shallow aquifer near each well at different depths. Chemical analyses of selected soil, fill, and aquifer sediment samples, obtained during the installation of nested wells, indicated that little HgT occurred in soil or fill at either site (40 micrograms per kilogram, ?g/kg, or less). No HgT was detected (less than 20 ?g/kg) in aquifer sediment samples. These low HgT concentrations imply that neither the soil, fill, nor aquifer sediment was a likely source of the elevated Hg in ground water. Given Hg occurrence appeared to be a ground-water transport phenomenon, the forms of Hg in transport were investigated. Differences in HgT concentrations between raw and filtered (0.1- and (or) 0.4-absolute micrometer pore size) samples from nested wells were random in sign and similar in magnitude to the variability in measuring HgT attributed to field and laboratory methods (? 5-10 percent, for HgT concentrations exceeding 100 ng/L). Thus, Hg transport likely occurred in a dissolved or fine-colloidal nonparticulate phase. Methyl mercury (HgMe) only was detected at low concentrations (0.06 ng/L or less) in nested-well samples with low to moderate concentrations of HgT (less than 366 ng/L). Whether HgMe occurred at similar concentrations in samples with high HgT concentrations was unresolved due to a sample-matrix interference problem. Potential complex forms of Hg were investigated in relation to the occurrence of selected ligands (organic carbon, sulfide, and chloride concentrations) and geochemical conditions (for example, pH and dissolved oxygen concentrations). Only dissolved organic carbon (DOC) appeared directly related to Hg occurrence. Elevated concentrations of HgT and DOC co-occurred in ground water at both Pot Nets sites. The average concentration of DOC was about four times greater in samples from the Pot Nets wells with the highest HgT concentrations (exceeding 1,000 ng/L) than in most Pot Nets o

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Simulation of nutrient and sediment concentrations and loads in the Delaware inland bays watershed: Extension of the hydrologic and water-quality model to ungaged segments

Rapid population increases, agriculture, and industrial practices have been identified as important sources of excessive nutrients and sediments in the Delaware Inland Bays watershed. The amount and effect of excessive nutrients and sediments in the Inland Bays watershed have been well documented by the Delaware Geological Survey, the Delaware Department of Natural Resources and Environmental Control, the U.S. Environmental Protection Agency’s National Estuary Program, the Delaware Center for Inland Bays, the University of Delaware, and other agencies. This documentation and data previously were used to develop a hydrologic and water-quality model of the Delaware Inland Bays watershed to simulate nutrients and sediment concentrations and loads, and to calibrate the model by comparing concentrations and streamflow data at six stations in the watershed over a limited period of time (October 1998 through April 2000). Although the model predictions of nutrient and sediment concentrations for the calibrated segments were fairly accurate, the predictions for the 28 ungaged segments located near tidal areas, where stream data were not available, were above the range of values measured in the area. The cooperative study established in 2000 by the Delaware Department of Natural Resources and Environmental Control, the Delaware Geological Survey, and the U.S. Geological Survey was extended to evaluate the model predictions in ungaged segments and to ensure that the model, developed as a planning and management tool, could accurately predict nutrient and sediment concentrations within the measured range of values in the area. The evaluation of the predictions was limited to the period of calibration (1999) of the 2003 model. To develop estimates on ungaged watersheds, parameter values from calibrated segments are transferred to the ungaged segments; however, accurate predictions are unlikely where parameter transference is subject to error. The unexpected nutrient and sediment concentrations simulated with the 2003 model were likely the result of inappropriate criteria for the transference of parameter values. From a model-simulation perspective, it is a common practice to transfer parameter values based on the similarity of soils or the similarity of land-use proportions between segments. For the Inland Bays model, the similarity of soils between segments was used as the basis to transfer parameter values. An alternative approach, which is documented in this report, is based on the similarity of the spatial distribution of the land use between segments and the similarity of land-use proportions, as these can be important factors for the transference of parameter values in lumped models. Previous work determined that the difference in the variation of runoff due to various spatial distributions of land use within a watershed can cause substantialloss of accuracy in the model predictions. The incorporation of the spatial distribution of land use to transfer parameter values from calibrated to uncalibrated segments provided more consistent and rational predictions of flow, especially during the summer, and consequently, predictions of lower nutrient concentrations during the same period. For the segments where the similarity of spatial distribution of land use was not clearly established with a calibrated segment, the similarity of the location of the most impervious areas was also used as a criterion for the transference of parameter values. The model predictions from the 28 ungaged segments were verified through comparison with measured in-stream concentrations from local and nearby streams provided by the Delaware Department of Natural Resources and Environmental Control. Model results indicated that the predicted edge-of-stream total suspended solids loads in the Inland Bays watershed were low in comparison to loads reported for the Eastern Shore of Maryland from the Chesapeake Bay watershed model. The flatness of the terrain and the low annual surface runoff are important factors in determining the amount of detached sediment from the land that is delivered to streams. The highest predicted total suspended solids loads were found in the southern part of the watershed, where the values are associated with high total streamflow and a high surface-runoff component, and related to soil and aquifer permeability and land use. Nutrient loads from model segments in the southern part of the Inland Bays watershed were also higher than those measured in the northern part of the basin, due to relatively high runoff and the substantial amount of available organic fertilizer (animal waste) that results in over-application of organic fertilizer to crops. Time series of simulated hourly concentrations indicated a seasonal pattern in the simulated base flow for total nitrogen, with the lowest values occurring during the summer and the highest values during the winter months. Total phosphorus and total-suspended-solids concentrations were less seasonal and were more storm-dependent; in general, base-flow concentrations of total phosphorus and total suspended solids were low. During storm events, the total nitrogen concentrations tended to be diluted and total phosphorus concentrations tended to rise sharply. Nitrogen was transported mainly in the aqueous phase and largely through ground water, whereas phosphorus was strongly associated with sediment, which washes off during rainfall events.

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Alum amendment effects on phosphorus release and distribution in poultry litter-amended sandy soils

Increased poultry production has contributed to excess nutrient problems in Atlantic Coastal Plain soils due to land application of poultry litter (PL). Aluminum sulfate [alum, Al 2 (SO 4 ) 3 ·14H 2 O] amendment of PL effectively reduces soluble phosphorus (P) in the PL; however, the effects of these litters when added to acidic, sandy soils are not well understood. The objective of this study was to investigate the efficacy of alum-amended poultry litter in reducing P release from three Delaware Coastal Plain soils: Evesboro loamy sand (Ev; excessively drained, mesic, coated Typic Quartzipsamments), Rumford loamy sand (Ru; well drained, coarse-loamy, siliceous, subactive, thermic Typic Hapludults), and Pocomoke sandy loam (Pm; very poorly drained, coarse-loamy, siliceous, active, thermic Typic Umbraquults). Long-term (25 d) and short-term (24 h) desorption studies were conducted, in addition to chemical extractions and kinetic modeling, to observe the changes that alum-amended versus unamended PL caused in the soils. The Ev, Ru, and Pm soils were incubated with 9 Mg ha −1 of alum-amended or unamended PL. Long-term desorption (25 d) of the incubated material resulted in approximately 13.5% (Ev), 12.7% (Ru), and 13.3% (Pm) reductions in cumulative P desorbed when comparing soil treated with unamended and alum-amended PL. In addition, the P release from the soil treated with alum-amended litter was not significantly different from the control (soil alone). Short-term desorption (24 h) showed 7.3% (Ev), 15.4% (Ru), and 20% (Pm) reductions. The overall implication from this study is that the use of alum as a PL amendment is useful in coarse-textured soils of the Coastal Plain. With increased application of alum-amended PL, more significant decreases may be possible with little or no effect on soil quality. textured soils of the Coastal Plain. With increased application of alum-amended PL, more significant decreases may be possible with little or no effect on soil quality.

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Selected Streamflow Statistics for Streamgaging Stations in Delaware, 2003

Flow-duration and low-flow frequency statistics were calculated for 15 streamgaging stations in Delaware, in cooperation with the Delaware Geological Survey. The flow-duration statistics include the 1-, 2-, 5-, 10-, 20-, 30-, 40-, 50-, 60-, 70-, 80-, 90-, 95-, 98-, and 99-percent duration discharges. The low-flow frequency statistics include the average discharges for 1, 7, 14, 30, 60, 90, and 120 days that recur, on average, once in 1.01, 2, 5, 10, 20, 50, and 100 years. The statistics were computed using U.S. Geological Survey computer programs that can be downloaded from the World Wide Web at no cost. The computer programs automate standard U.S. Geological Survey methods for computing the statistics. Documentation is provided at the Web sites for the individual programs. The computed statistics are presented in tabular format on a separate page for each station, along with the station name, station number, the location, the period of record, and remarks.

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Distribution of methyl tert-butyl ether (MTBE) and selected water-quality constituents in the surficial aquifer at the Dover National Test Site, Dover Air Force Base, Delaware, 2001

A joint study by the Dover National Test Site, Dover Air Force Base, Delaware, and the U.S. Geological Survey was conducted from June 27 through July 18, 2001, to determine the spatial distribution of the gasoline oxygenate additive methyl tert-butyl ether and selected water-quality constituents in the surficial aquifer underlying the Dover National Test Site. This report provides a summary assessment of the distribution of methyl tert-butyl ether and a preliminary screening of selected constituents that may affect natural attenuation and remediation demonstrations at the Dover National Test Site. The information gathered during this study is designed to assist potential remedial investigators who are considering conducting a methyl tert-butyl ether remedial demonstration at the test site. In addition, the study supported a planned enhanced bioremediation demonstration and assisted the Dover National Test Site in identifying possible locations for future methyl tert-butyl ether remediation demonstrations. A direct-push drill rig was used to collect a total of 147 ground-water samples (115 VOC samples and 32 quality-assurance samples) at varying depths. Volatile organic compounds were above the method reporting limits in 59 of the 115 ground-water samples. The concentrations ranged from below detection limits to maximum values of 12.4 micrograms per liter of cis-1,2-dichloro-ethene, 1.14 micrograms per liter of trichloro-ethene, 2.65 micrograms per liter of tetrachloro-ethene, 1,070 micrograms per liter of methyl tert-butyl ether, 4.36 micrograms per liter of benzene, and 1.8 micrograms per liter of toluene. Vinyl chloride, ethylbenzene, p,m-xylene, and o-xylene were not detected in any of the samples collected during this investigation. Methyl tert-butyl ether was detected in 47 of the 115 ground-water samples. The highest concentrations of methyl tert-butyl ether were detected in the surficial aquifer from ?4.6 to 6.4 feet mean sea level; however, methyl tert-butyl ether was detected as deep as ?9.5 feet mean sea level. Increased methane concentrations and decreased dissolved oxygen concentrations that were found in association with the ground-water samples that contained methyl tert-butyl ether are preliminary indicators that will assist in determining if natural attenuation of methyl tert-butyl ether is occurring in the surficial aquifer. A full assessment of natural attenuation of methyl tert-butyl ether at the site is beyond the scope of this study, but the data collected during the study will be useful in selecting appropriate remedial methyl tert-butyl ether demonstrations.

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Ground-water sampling, analytical results, and water-level measurements at sites FT03, LF13, and WP14/LF15, East Management Unit, Dover Air Force Base, Delaware, January-October 2000

The U.S. Geological Survey, in cooperation with the U.S. Air Force, collected ground-water samples and made water-level measurements from January through October 2000 to monitor natural attenuation at four sites in the East Management Unit of Dover Air Force Base in Kent County, Delaware. The information in this report is based on data from ground-water samples collected during two sampling events, which occurred from January through March 2000 and September through October 2000. Ground-water samples and water-level measurements were collected from 36 monitor wells during the first sampling event. During the second sampling event, groundwater samples were collected from 34 monitor wells and water-level measurements were made in 29 monitor wells. Water-level measurements were also made in 103 wells during a synoptic in March 2000. The analytical results from the groundwater samples, the water-level measurements, and data-collection techniques are presented in this report. Analytical results indicate that the U.S. Environmental Protection Agency's maximum contaminant levels for constituents analyzed were exceeded in 10 samples collected during the first sampling event and 11 samples collected during the second sampling event. An independent quality-assurance data validation indicated that the water-quality data collected during this study were of good quality, reproducible, and unbiased.

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Isotope geochemistry and chronology of offshore ground water beneath Indian River Bay, Delaware

Results of geophysical surveys in Indian River Bay, Delaware, indicate a complex pattern of salinity variation in subestuarine ground water. Fresh ground-water plumes up to about 20 meters thick extending hundreds of meters offshore are interspersed with saline ground water, with varying degrees of mixing along the salinity boundaries. It is possible that these features represent pathways for nutrient transport and interaction with estuarine surface water, but the geophysical data do not indicate rates of movement or nutrient sources and reactions. In the current study, samples of subestuarine ground water from temporary wells with short screens placed 3 to 22 meters below the sediment-water interface were analyzed chemically and isotopically to determine the origins, ages, transport pathways, and nutrient contents of the fresh and saline components. Apparent ground-water ages determined from chlorofluorocarbons (CFCs), sulfur hexafluoride (SF6), tritium (3H), and helium isotopes (3He and 4He) commonly were discordant, but nevertheless indicate that both fresh and saline ground waters ranged from a few years to at least 50 years in age. Tritium-helium (3H-3He) ages, tentatively judged to be most reliable, indicate that stratified offshore freshwater plumes originating in distant recharge areas on land were bounded by relatively young saline water that was recharged locally from the overlying estuary. Undenitrified and partially denitrified nitrate of agricultural or mixed origin was transported laterally beneath the estuary in oxic and suboxic fresh ground water. Ammonium produced by anaerobic degradation of organic matter in estuarine sediments was transported downward in suboxic saline ground water around the freshwater plumes. Many of the chemical and isotopic characteristics of the subestuarine ground waters are consistent with conservative mixing of the fresh (terrestrial) and saline (estuarine) endmember water types. These data indicate that freshwater plumes detected by geophysical surveys beneath Indian River Bay represent lateral continuations of the active surficial nitrate-contaminated freshwater flow systems originating on land, but they do not indicate directly the magnitude of fresh ground-water discharge or nutrient exchange with the estuary. There is evidence that some of the terrestrial ground-water nitrate is reduced before discharging directly beneath the estuary. Local estuarine sediment-derived ammonium in saline pore water may be a substantial benthic source of nitrogen in offshore areas of the estuary.

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Assessment of natural attenuation of ground-water contamination at sites FT03, LF13, and WP14/LF15, Dover Air Force Base, Delaware

Water-quality, aquifer-sediment, and hydrologic data were used to assess the effectiveness of natural attenuation of ground-water contamination at Fire Training Area Three, the Rubble Area Landfill, the Liquid Waste Disposal Landfill, and the Receiver Station Landfill in the East Management Unit of Dover Air Force Base, Delaware. These sites, which are contaminated with chlorinated solvents and fuel hydrocarbons, are undergoing long-term monitoring to determine if natural attenuation continues to sufficiently reduce contaminant concentrations to meet regulatory requirements. This report is the first assessment of the effectiveness of natural attenuation at these sites since long-term monitoring began in 1999, and follows a preliminary investigation done in 1995-96. This assessment was done by the U.S. Geological Survey in cooperation with the U.S. Air Force. Since 1995-96, additional information has been collected and used in the current assessment. The conclusions in this report are based primarily on ground-water samples collected from January through March 2000. Previous analytical results from selected wells, available geologic and geophysical well logs, and newly acquired information such as sediment organic-carbon measurements, hydraulic-conductivity measurements determined from slug tests on wells in the natural attenuation study area, and water-level measurements from surficial-aquifer wells also were used in this assessment. This information was used to: (1) calculate retardation factors and estimate contaminant migration velocities, (2) improve estimates of ground-water flow directions and inferred contaminant migration pathways, (3) better define the areal extent of contamination and the proximity of contaminants to discharge areas and the Base boundary, (4) develop a better understanding of the vertical variability of contaminant concentrations and redox conditions, (5) evaluate the effects of temporal changes on concentrations in the plumes and source areas, and (6) determine whether intrinsic biodegradation is occurring at these sites. The water-quality data indicate that intrinsic biodegradation is occurring at all three sites. The strongest indication of intrinsic biodegradation is the detection of tetrachloroethene and trichloroethene breakdown products within and down-gradient of the source areas. The patterns of electron acceptors and metabolic by-products indicate that contaminant biodegradation has changed the prevailing geochemistry of the surficial aquifer, creating the strongly reducing conditions necessary for chlorinated solvent biodegradation. Geochemical changes include depleted dissolved oxygen and elevated ferrous iron and methane levels relative to concentrations in uncontaminated zones of the surficial aquifer. At Fire Training Area Three and the Rubble Area Landfill sites, natural attenuation appears to be adequate for controlling the migration of the contaminant plumes. At the third site, the Liquid Waste Disposal and Receiver Station Landfills, the plume is larger and the uncertainty about the effectiveness of natural attenuation in reducing contaminant concentrations and controlling plume migration is greater. Ground-water data indicate, however, that U.S. Environmental Protection Agency maximum contaminant levels were not exceeded in any point-of-compliance wells located along the Base boundary. The information presented in this report led to the development of improved conceptual models for these sites, and to the recognition of four issues that are currently unclear and may need further study. These issues include delineating the areal and vertical extent of the contaminant plumes in greater detail, determining the extent of intrinsic biodegradation downgradient of the Liquid Waste Disposal and Receiver Station Landfills, determining the fate of contaminants in the ground-water discharge areas, and determining the effect of temporal variability in source concentrations and ground-water flow patterns on the plume migrating from the Liquid Waste Disposal and Receiver Station Landfills. Some of these issues have been addressed with additional data collection since the January-March 2000 sampling round.

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Distribution and mass loss of volatile organic compounds in the surficial aquifer at sites FT03, LF13, and WP14/LF15, Dover Air Force Base, Delaware, November 2000–February 2001

Ground-water and surface-water sampling was conducted in the natural attenuation study area in the East Management Unit of Dover Air Force Base, Delaware to determine the distributions of volatile organic compounds in the vicinity of four sites?Fire Training Area Three, the Rubble Area Landfill, the Receiver Station Landfill, and the Liquid Waste Disposal Landfill. This work was done by the U.S. Geological Survey, in cooperation with the U.S. Air Force, as part of an ongoing assessment of the effectiveness of natural attenuation at these sites. The specific objectives of the study were to (1) determine the areal and vertical extent of the contaminant plumes and source areas, (2) measure volatile organic compound concentrations in ground-water discharge areas and in surface water under base-flow conditions, (3) evaluate the potential for off-site migration of the mapped plumes, and (4) estimate the amount of mass loss downgradient of the Liquid Waste Disposal and Receiver Station Landfills. A direct-push drill rig and previously installed multi-level piezometers were used to determine the three-dimensional distributions of volatile organic compounds in the 30?60-foot-thick surficial aquifer underlying the natural attenuation study area. A hand -driven mini-piezometer was used to collect ground-water samples in ground-water discharge areas. A total of 319 ground-water and 4 surface-water samples were collected from November 2000 to February 2001 and analyzed for chlorinated solvents and fuel hydrocarbons. The contaminant plumes migrating from Fire Training Area Three and the Rubble Area Landfill are approximately 500 feet and 800 feet, respectively, in length. These plumes consist predominantly of cis-1,2-dichloroethene, a daughter product, indicating that extensive dechlorination of tetrachloroethene and trichloroethene has occurred at these sites. With an approximate length of 2,200 feet, the plume migrating from the Receiver Station and Liquid Waste Disposal Landfills is the largest of the three plumes in the East Management Unit. In this plume, the parent compounds, tetrachloroethene and trichloroethene, as well as cis-1,2-dichloroethene, are present downgradient of the source. Vinyl chloride was not detected in the natural attenuation study area. Vertical water-quality profiles indicate that volatile organic compounds are present mainly in the upper part of the surficial aquifer. Plumes of fuel hydrocarbon constituents were not detected in the natural attenuation study area. Volatile organic compounds were present at concentrations above detection limits in 6 of 14 samples collected from the aquifer underlying the bed of Pipe Elm Branch and the drainage ditch adjacent to Fire Training Area Three, indicating that the plumes migrating from Fire Training Area Three and the Receiver Station and Liquid Waste Disposal Landfills are reaching these ground-water discharge areas. In contrast, sampling results indicated that the plume from the Rubble Area Landfill does not reach these ground-water discharge areas. Trichloroethene was present above detection limits in one of four surface-water samples collected from Pipe Elm Branch and the drainage ditch adjacent to Fire Training Area Three. The trichloroethene concentration is below applicable Delaware Department of Natural Resources and Environmental Control surface-water-quality standards for human health. An assessment of chlorinated-solvent mass loss in the plume migrating from the Receiver Station and Liquid Waste Disposal Landfills indicates that tetrachloroethene and trichloroethene mass loss downgradient of the source is negligible. Cis-1,2-dichloroethene, however, appears to biodegrade by an unidentified reaction in the plume. Plan-view maps of the plume migrating from the Receiver Station and Liquid Waste Disposal Landfills indicate that tetrachloroethene, trichloroethene, and cis-1,2-dichloroethene may migrate off Dover Air Force Base property approximately 1,500 f

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Organochlorine and metal contaminant exposure and effects in hatching Black-Crowned Night Herons (Nycticorax nycticorax) in Delaware Bay

Pea Patch Island in Delaware Bay is the site of the largest heronry north of Florida. From 1989–93, the population of nine species of wading birds numbered approximately 12,000 pairs, but has recently declined to about 7,000 pairs. Because Delaware Bay is a major shipping channel and receives anthropogenic releases of toxic substances from agricultural, industrial, and municipal point and nonpoint sources, contaminant exposure and effects to the heronry have been an ongoing concern. In 1997, pipping (early hatching stage) black-crowned night herons ( Nycticorax nycticorax ) were collected from separate nests at Pea Patch Island and from a coastal reference site, Middle Island in Rehoboth Bay, Delaware. There was no evidence of malformations or hepatic histopathological lesions in embryos, and their body and liver weights did not differ between sites. Biomarkers of petroleum hydrocarbons, polyhalogenated contaminant, and metal exposure (cytochrome P450 induction and oxidative stress responses) did not differ (p > 0.05) between sites, although activities of benzyloxy- O -dealkylase and ethoxyresorufin- O -dealkylase were somewhat elevated in 3 of the 15 embryos collected from Pea Patch Island. Concentrations of 21 organochlorine pesticides and metabolites were relatively low at both sites, with p,p′ -DDE values well below the threshold associated with eggshell thinning. Although total PCB concentration was modestly elevated (p < 0.05) in Pea Patch Island heron embryos, levels of arylhydrocarbon receptor-active PCB congeners, polychlorinated dibenzodioxins and dibenzofurans, and toxic equivalents were low and did not differ between sites. Concentrations of Cd and Mn in pipping embryos from Pea Patch Island were slightly greater (p < 0.05) than values observed in Middle Island embryos, but levels of these and the other metals and metalloids ( e.g. , Hg and Se) were below values associated with toxicity. In conclusion, it seems unlikely that chlorinated hydrocarbon and metal contaminant exposure constitutes a direct threat to the reproductive success of black-crowned night herons at Pea Patch Island. However, low-level exposure to these contaminants may constitute one of many stressors that in combination could adversely affect the stability of the wading bird population at this large heronry.

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Potentiometric maps and ground-water-level data for the industrial area, northwest of Delaware City, Delaware

Potentiometric maps of the water-table aquifer in the spring and fall of 1993 in the industrial area northwest of Delaware City, Delaware, are presented. The maps are based on continuously recorded ground-water-level data collected at eight wells screened in the water-table aquifer from October 15, 1993 through November 8, 1994. These data are presented on a 33" by 44" plate. The U.S. Army Corps of Engineers collected the synoptic water-level data used to construct contours of the potentiometric surface in the water-table aquifer. The U.S. Geological Survey collected the continuously recorded ground- water-level data.

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Hydrologic data for the Potomac Formation in New Castle County, Delaware

Hydrologic data for the Potomac Formation in New Castle County, Delaware, consist of records of historical ground-water pumpage, water levels, water quality, and surface-water discharge. This report includes records of 405 wells and hydro-graphs of water levels in 86 wells. Pumpage from 20 well fields is reported. Also included are stream-discharge hydrographs for 6 stations for water years 1979 and 1980 and historical low-flow measurements for 22 stations. In the analysis of 23 aquifer tests, transmissivity and storage coefficient values for the Potomac Formation range from 454 to 8,480 feet squared per day and 3.8X10-3 to 5.6X10-5, respectively. Vertical hydraulic conductivities of the confining bed range from 0.0083 to 3.2 feet per day.

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Ground-water temperature of the with application to ground-water-source heat pumps

Ground-water temperature was measured during a one-year period (1980-81) in 20 wells in the Wyoming Quadrangle in central Delaware. Data from thermistors set at fixed depths in two wells were collected twice each week, and vertical temperature profiles of the remaining 18 wells were made monthly. Ground-water temperature at 8 feet below land surface in well Jc55-1 ranged from 45.0 degrees F in February to 70.1 degrees F in September. Temperature at 35 feet below land surface in the same well reached a minimum of 56.0 degrees F in August, and a maximum of 57.8 degrees F in February. Average annual temperature of ground water at 25 feet below land surface in all wells ranged from 54.6 degrees F to 57.8 degrees F. Variations of average temperature probably reflect the presence or absence of forestation in the recharge areas of the wells. Ground-water-source heat pumps supplied with water from wells 30 or more feet below land surface will operate more efficiently in both heating and cooling modes than those supplied with water from shallower depths. (USGS)

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Technique for estimating magnitude and frequency of floods in Delaware

A flood-estimating method is presented which applies to drainage basins in Delaware without urban development and covers selected recurrence intervals from 2 to 100 years. The method was developed by multiple-regression techniques. The State is divided into two regions and sets of equations for calculating peak discharges based on physical basin characteristics are provided for each region. The boundary between regions generally corresponds with the division between the Piedmont and Coastal Plain provinces. In the northern region, flood-peak discharges were related to basin drainage area and storage. In the southern region, flood peaks were related to drainage area, slope, storage, forest cover, and two composite soil categories. Standard errors of estimate for the regression equations in the northern region ranged from 30 to 39 percent. For the southern region, the standard errors of estimate varied from 38 to 40 percent. Without using the two soil parameters in the southern region, the standard errors of estimate varied from 57 to 70 percent. Annual flood peaks, basin characteristics, and flood-frequency distributions are tabulated for the 60-gaged sites used in the regression analysis. At 23 of these sites, a rainfall-runoff model generated additional flood-peak data which were used in defining the flood-frequency distributions. (Woodard-USGS)

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