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Research about Czech Republic

Source-linked reports with geographic coverage including Czech Republic.

6 recordsLinked to original sources

Stability of mercury concentration measurements in archived soil and peat samples

Archived soil samples can provide important information on the history of environmental contamination and by comparison with recently collected samples, temporal trends can be inferred. Little previous work has addressed whether mercury (Hg) concentrations in soil samples are stable with long-term storage under standard laboratory conditions. In this study, we have re-analyzed using cold vapor atomic adsorption spectroscopy a set of archived soil samples that ranged from relatively pristine mountainous sites to a polluted site near a non-ferrous metal smelter with a wide range of Hg concentrations (6 - 6485 µg kg-1). Samples included organic and mineral soils and peats with a carbon content that ranged from 0.2 to 47.7%. Soil samples were stored in polyethylene bags or bottles and held in laboratory rooms where temperature was not kept to a constant value. Mercury concentrations in four subsets of samples were originally measured in 2000, 2005, 2006 and 2007, and re-analyzed in 2017, i.e. after 17, 12, 11 and 10 years of storage. Statistical analyses of either separated or lumped data yielded no significant differences between the original and current Hg concentrations. Based on these analyses, we show that archived soil and peat samples can be used to evaluate historical soil mercury contamination.

Chemosphere

Mercury in stream water at five Czech catchments across a Hg and S deposition gradient

The Czech Republic was heavily industrialized in the second half of the 20th century but the associated emissions of Hg and S from coal burning were significantly reduced since the 1990s. We studied dissolved (filtered) stream water mercury (Hg) and dissolved organic carbon (DOC) concentrations at five catchments with contrasting Hg and S deposition histories in the Bohemian part of the Czech Republic. The median filtered Hg concentrations of stream water samples collected in hydrological years 2012 and 2013 from the five sites varied by an order of magnitude from 1.3 to 18.0 ng L − 1 . The Hg concentrations at individual catchments were strongly correlated with DOC concentrations r from 0.64 to 0.93 and with discharge r from 0.48 to 0.75. Annual export fluxes of filtered Hg from individual catchments ranged from 0.11 to 13.3 μg m − 2 yr − 1 and were highest at sites with the highest DOC export fluxes. However, the amount of Hg exported per unit DOC varied widely; the mean Hg/DOC ratio in stream water at the individual sites ranged from 0.28 to 0.90 ng mg − 1 . The highest stream Hg/DOC ratios occurred at sites Pluhův Bor and Jezeří which both are in the heavily polluted Black Triangle area. Stream Hg/DOC was inversely related to mineral and total soil pool Hg/C across the five sites. We explain this pattern by greater soil Hg retention due to inhibition of soil organic matter decomposition at the sites with low stream Hg/DOC and/or by precipitation of a metacinnabar (HgS) phase. Thus mobilization of Hg into streams from forest soils likely depends on combined effects of organic matter decomposition dynamics and HgS-like phase precipitation, which were both affected by Hg and S deposition histories.

Journal of Geochemical Exploration

Cross-borehole flow analysis to characterize fracture connections in the Melechov Granite, Bohemian-Moravian Highland, Czech Republic

Application of the cross-borehole flow method, in which short pumping cycles in one borehole are used to induce time-transient flow in another borehole, demonstrated that a simple hydraulic model can characterize the fracture connections in the bedrock mass between the two boreholes. The analysis determines the properties of fracture connections rather than those of individual fractures intersecting a single borehole; the model contains a limited number of adjustable parameters so that any correlation between measured and simulated flow test data is significant. The test was conducted in two 200-m deep boreholes spaced 21 m apart in the Melechov Granite in the Bohemian-Moravian Highland, Czech Republic. Transient flow was measured at depth stations between the identified transmissive fractures in one of the boreholes during short-term pumping and recovery periods in the other borehole. Simulated flows, based on simple model geometries, closely matched the measured flows. The relative transmissivity and storage of the inferred fracture connections were corroborated by tracer testing. The results demonstrate that it is possible to assess the properties of a fracture flow network despite being restricted to making measurements in boreholes in which a local population of discrete fractures regulates the hydraulic communication with the larger-scale aquifer system.

Bohemian-moravian Highland

Factors determining Pochard nest predation along a wetland gradient

Waterfowl management on breeding grounds focuses on improving nest success, but few studies have compared waterfowl nest success and factors affecting nest survival along a wetland gradient and simultaneously identified nest predators. We monitored nests (n = 195) of common pochards ( Aythya ferina ) in Trebon Basin Biosphere Reserve, Czech Republic, during 1999–2002. Daily nest survival rates (DSRs, logistic-exposure) declined from island (0.985, 95% confidence interval, 0.978–0.991) to overwater (0.962, 0.950–0.971) and terrestrial (0.844, 0.759–0.904) nests. The most parsimonious model for DSRs included habitat class (DSRs: island > overwater > terrestrial) and nest visibility. Nest survival was improved by reduced nest visibility, increased water depth, and increased distance from the nest to habitat edge in littoral habitats. On islands, nest success increased with advancing date and increased distance to open water. A model of constant nest survival best explained the data for terrestrial nests. There were no observer effects on DSRs in any habitat. In 2003, artificial nests ( n = 180; 120 contained a wax-filled egg) were deployed on study plots. The model that best explained variation in DSRs for artificial nests included only 1 variable: habitat class (DSRs: island ≥ overwater > terrestrial). Mammalian predation of artificial nests (by foxes [ Vulpes vulpes ] and martens [ Martes spp.]) was more likely in terrestrial habitats than in littoral habitats or on islands. By contrast, corvids and marsh harriers ( Circus aeruginosus ) prevailed among predators of overwater and island nests. Our data indicate that artificial islands and wide strips of littoral vegetation may represent secure breeding habitats for waterfowl because those habitats allow nests to be placed in areas that are not accessible to, or that are avoided by, mammalian predators. Management actions should be aimed at preserving these habitats. This, along with creation of new artificial islands, could help to enhance breeding productivity of pochards and possibly other waterfowl species inhabiting man-made ponds.

Trebon Basin Biosphere Reserve

Spalled, aerodynamically modified moldavite from Slavice, Moravia, Czechoslovakia

A Czechoslovakian tektite or moldavite shows clear, indirect evidence of aerodynamic ablation. This large tektite has the shape of a teardrop, with a strongly convex, deeply corroded, but clearly identifiable front and a planoconvex, relatively smooth, posterior surface. In spite of much erosion and corrosion, demarcation of the posterior and the anterior part of the specimen (the keel) is clearly preserved locally. This specimen provides the first tangible evidence that moldavites entered the atmosphere cold, probably at a velocity exceeding 5 kilometers per second; the result was selective heating of the anterior face and perhaps ablation during the second melting. This provides evidence of the extraterrestial origin of moldavites.

Science

Paleozoic mollusk: Hyolithes

An unusually well-preserved Ordovician fossil from Czechoslovakia shows that the enigmatic paired structures once thought to be outgrowths of the operculum of Hyolithes are really independent structures lying between the operculum and the aperture of the shell. The find seems to provide conclusive proof of the morphologic uniqueness of hyolithids.

Science