Carbon dioxide and hydrogen sulfide degassing and cryptic thermal input to Brimstone Basin, Yellowstone National Park, Wyoming
Brimstone Basin, a remote area of intense hydrothermal alteration a few km east of the Yellowstone Caldera, is rarely studied and has long been considered to be a cold remnant of an ancient hydrothermal system. A field campaign in 2008 confirmed that gas emissions from the few small vents were cold and that soil temperatures in the altered area were at background levels. Geochemical and isotopic evidence from gas samples ( 3 He/ 4 He ~ 3R A , δ 13 C-CO 2 ~ − 3‰) however, indicate continuing magmatic gas input to the system. Accumulation chamber measurements revealed a surprisingly large diffuse flux of CO 2 (~ 277 t d -1 ) and H 2 S (0.6 t d -1 ). The flux of CO 2 reduces the 18 O content of the overlying cold groundwater and related stream waters relative to normal meteoric waters. Simple isotopic modeling reveals that the CO 2 likely originates from geothermal water at a temperature of 93 ± 19 °C. These results and the presence of thermogenic hydrocarbons (C1:C2 ~ 100 and δ 13 C-CH 4 = − 46.4 to − 42.8‰) in gases require some heat source at depth and refute the assumption that this is a “fossil” hydrothermal system.