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Research about Arkansas, Louisiana, Oklahoma, Texas

Source-linked reports with geographic coverage including Arkansas, Louisiana, Oklahoma, Texas.

6 recordsLinked to original sources

Sulfur-to-iron ratio as a proxy for degree of organic sulfurization

The degree of organic sulfurization is broadly relevant yet underreported. We present a statistically significant correlation between whole rock S/Fe and the measured degree of organic sulfurization in the thermally immature Cenomanian–Turonian Eagle Ford Group. This relationship shows a sink switch for sulfur from pyrite to organic matter. Excess iron and excess sulfur relative to pyrite, which are mathematically related to S/Fe, provide better insights into organic sulfurization than previous approaches that calculate excess iron relative to detrital iron based on aluminum concentrations. Organic sulfurization and S/Fe are tightly coupled in the Eagle Ford partially due to limited sulfur- and iron-bearing components. Similar relationships could exist in other thermally immature, organic-rich, anoxia-prone, calcareous mudstones. The degree of organic sulfurization was estimated from S/Fe, which was used to map stratigraphic and regional variations of organic sulfurization across the Eagle Ford and to investigate how organic sulfurization relates to organic enrichment, organic preservation, and depositional redox chemistry. The extent of organic sulfurization is more tightly linked to organic preservation than enrichment. Together, organic sulfurization and Mo provide concordant evidence for depositional euxinia. The relationship between Mo and degree of organic sulfurization could indicate that sulfurized organic matter provides a pathway for Mo enrichment, but future work needs to disentangle direct mechanisms from indirect covariations between Mo, organic content, and degree of organic sulfurization. Whole rock elemental chemistry and programmed pyrolysis provide insights into organic sulfurization variations that can be upscaled and can guide subsequent detailed organic sulfur analyses.

Arkansas, Louisiana, Oklahoma, Texas

Evaluating the context dependency of large river nursery habitats for fishes in the lower Red River catchment

Both fine- and coarse-scale physicochemical conditions affect the quantity and quality of nursery habitats within riverine ecosystems. Nursery habitats in large, braided, and sandbed streams such as the lower Red River of Oklahoma, Texas, and Arkansas are not well described and likely vary among species. Identification of nursery habitats is important for developing proper conservation and management actions. We used an occupancy model framework to determine how hierarchical habitat factors related to the occupancy of 38 juvenile fish species. Our findings indicate that large river nursery habitats can generally be defined by reaches with off-channel slackwater habitat, having deep pools but shallow thalweg depths, typically located further away from dams, and with low percentages of limestone lithology. Species within the same genera often exhibited variable relationships with river slope, amount of large woody debris, channel shape, discharge, and position of reaches within the stream network. Our results indicate important species-specific relationships that define nursery habitats, indicating an important context dependency of nursery habitats even within fishes that are taxonomically similar. If the goal is to improve recruitment by native fishes, then consideration of the important species-specific differences would be beneficial if improvements are made to nursery habitats. Moreover, careful consideration of the effects of dam operations will help maintain proper connectivity to off-channel habitats important in downriver portions of the river network.

Arkansas, Louisiana, Oklahoma, Texas

An integrated perspective of paleoenvironmental change in the Western Interior Seaway before and during OAE-2 reveals how organic-rich mudstones form in dynamic environments

Organic and inorganic geochemistry was integrated with sedimentology from the Eagle Ford Group in the U.S. Geological Survey Gulf Coast-3 drill core to investigate why organic matter enrichment and anoxia predate the Cenomanian–Turonian oceanic anoxic event (OAE-2) at the southern Western Interior Seaway (WIS). The relationship between the degree of organic matter sulfurization and preservation in the southern WIS is comparable to OAE-2 sites outside of the WIS, but enhanced organic matter sulfurization and preservation predated OAE-2, distinguishing the southern WIS from other OAE-2 localities. Persistent euxinia and organic matter sulfurization before and during the mid-Cenomanian event (MCE) facilitated maximum organic matter enrichment and preservation to coincide with extensive lateral sediment transport. The new perspective detailed here reconciles geochemical evidence of depositional euxinia with sedimentological evidence of sediment transport, which informs how organic-rich mudstones form in dynamic environments. After the MCE but before OAE-2, reducing conditions weakened as relative sea-level continued to rise, resulting in an oxygen-depleted environment that was prone to transient euxinia. The extent of organic matter sulfurization, preservation, and enrichment declined as euxinia became intermittent. As maximum sea-level was established during OAE-2, boreal water masses flowed into the southern WIS and unrestricted, oxygenated marine conditions developed, which resulted in degradation of marine organic matter and less organic enrichment. The highest relative contribution of marine bacterial organic matter occurred during the persistently euxinic interval before and during the MCE. The relative input of algal organic matter increased as the depositional conditions became less reducing after the MCE but before OAE-2. Prasinophyte green algae contributed to the consistent dominance of C 28 steranes preceding OAE-2, which is becoming a widely observed feature across the southern and central WIS. A sharp drop in the C 28 sterane relative abundance reflects a decline in the abundance of prasinophytes as oxic depositional conditions developed during OAE-2. Relative abundances of 2-methylhopanes increased during OAE-2, which is a common signature of OAEs, suggesting a modified nitrogen cycle in the offshore southern WIS despite oxic depositional conditions during OAE-2.

Arkansas, Louisiana, Oklahoma, Texas

Understanding recurrent land use processes and long-term transitions in the dynamic south-central United States, c. 1800 to 2006

Forests have historically been under significant land use pressures that cause periods of degradation, clearance, and recovery. To understand these changes, studies are needed that place trends in a historical landscape context and also examine recent dynamics. Here, we use historical investigation (c. 1800) and an examination of land use and land cover change between 1973 and 2006 to establish a baseline trajectory of the forested system of the south-central United States (US) plains. The study culminates in a highly detailed accounting of the processes and causes of land change between 2001 and 2006. In the study region, the forest transitioned from early low-intensity use, to clearance for farming and timber, to widespread recovery from degradation beginning in the 1930s. By 1970, the region was transitioning from recovered woodlands to an intensive regime of recurrent timber harvest and replanting. The recurring cycle inherent in intensive silviculture has been the main cause of land change for the past several decades, accounting for more than 95% of the total extent of change between 2001 and 2006. The transition to forest recovery in the south-central US was an important historical occurrence. However, the dynamic post-transition landscape needs to be better understood.

Arkansas, Louisiana, Oklahoma, Texas

A geographic information system tool for aquatic resource conservation in the Red and Sabine River Watersheds of the southeast United States

Our goal was to build a geographic information system (GIS) tool to enhance modeling and hypothesis testing relevant to watersheds and fish fauna of the Red and Sabine Rivers in the southeastern United States. Species of concern were identified from wildlife action plans and Web sites. Spatial distributions of fish species and mercury in fillets were delineated using data from states. Public georeferenced data were obtained on land cover, soil type, forest canopy, impervious surfaces, wastewater facilities and 303(d) impaired waters. Overlay maps highlighted patterns across 8-digit hydrologic unit codes (HUCs). Bossier City, Louisiana and Beaumont, Texas areas displayed impervious surfaces over 10% and 303(d) waters per HUC were 20% and 8%, respectively. Because bowfin (Amia calva) (n=299) and bass (Micropterus spp.) (n=1493) occurred in up to 44% of HUCs and fillets contained elemental mercury concentrations across ranges monitored, they were appropriate indicators of bioavailable mercury. Of the total fish number showing >0.5ppm, 81% of records were derived from bowfin and bass, and stepwise multiple linear regressions indicated fish with mercury at these concentrations correlated with environmental variables. Detrended correspondence analysis showed total species occurrence and environmental relationships significant, where 81.6% of the variability in fish occurrence was explained by impervious surface, land cover other than canopy or impervious surface (such as wetlands and agricultural area) and canopy (forest type). Two-way indicator species analysis delineated species co-occurrence in HUCs (14 groups) and similarity of species composition (nine groups). Results identified three HUC groupings as potential targets for managerial interest. Quality control concerns for GIS development included site name data and priority rankings of critical fish species. This tool can be used to support modeling and trend analyses for several purposes, such as those relevant for developing and reporting on water quality standards and critical habitat assessments.

Arkansas, Louisiana, Oklahoma, Texas