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Research about Antartica

Source-linked reports with geographic coverage including Antartica.

8 recordsLinked to original sources

Mercury speciation and stable isotopes in emperor penguins: First evidence for biochemical demethylation of methylmercury to mercury-dithiolate and mercury-tetraselenolate complexes

Apex marine predators, such as toothed whales and large petrels and albatrosses, ingest mercury (Hg) primarily in the form of methylmercury (MeHg) via prey consumption, which they detoxify as tiemannite (HgSe). One of the most intriguing current questions in Hg research is how more abundant lower trophic level predators detoxify MeHg, particularly in marine environments where tissue Hg burdens can be elevated. To address this need, we used high energy-resolution X-ray absorption near edge structure spectroscopy paired with nitrogen (N) and Hg stable isotopes to identify the chemical forms of Hg, Hg source, and species-specific δ 202 Hg isotopic values in emperor penguin, a mesopredator feeding primarily on Antarctic silverfish. The penguin liver contains variable proportions of MeHg and two inorganic Hg species (IHg), Hg-dithiolate (Hg(SR) 2 ) and Hg-tetraselenolate (Hg(Sec) 4 ) complexes, each characterized by a specific isotopic value (δ 202 MeHg = 0.3 ± 0.2‰, δ 202 Hg(SR) 2 = −1.6 ± 0.2‰, δ 202 Hg(Sec) 4 = −2.0 ± 0.1‰). Using δ 15 N as tracer of food source, we show that Hg(SR) 2 is not dietary but a biochemical demethylation product of MeHg metabolism. Penguin females transfer Hg to the egg as MeHg in the egg albumen, 89% MeHg and 11% IHg in the membrane, and 32% MeHg and 68% Hg(Sec) 4 in the yolk, on average (n = 15). Despite IHg species in eggs, MeHg is the main species quantitatively transferred by the mother to the chick because of the disproportionate mass of the MeHg-rich albumen compared to the yolk (n = 18). Further research is needed to elucidate the MeHg to Hg(SR) 2 demethylation pathway firmly documented here for the first time in multicellular organisms, and to understand why the thiolate ligands are not exchanged for Se ligands to form Hg(Sec) 4 , as the liver does not suffer from Se deficiency.

Adelie Land

Large loss of CO2 in winter observed across pan-arctic permafrost region

Recent warming in the Arctic, which has been amplified during the winter 1 , 2 , 3 , greatly enhances microbial decomposition of soil organic matter and subsequent release of carbon dioxide (CO 2 ) 4 . However, the amount of CO 2 released in winter is not known and has not been well represented by ecosystem models or empirically based estimates 5 , 6 . Here we synthesize regional in situ observations of CO 2 flux from Arctic and boreal soils to assess current and future winter carbon losses from the northern permafrost domain. We estimate a contemporary loss of 1,662 TgC per year from the permafrost region during the winter season (October–April). This loss is greater than the average growing season carbon uptake for this region estimated from process models (−1,032 TgC per year). Extending model predictions to warmer conditions up to 2100 indicates that winter CO 2 emissions will increase 17% under a moderate mitigation scenario—Representative Concentration Pathway 4.5—and 41% under business-as-usual emissions scenario—Representative Concentration Pathway 8.5. Our results provide a baseline for winter CO 2 emissions from northern terrestrial regions and indicate that enhanced soil CO 2 loss due to winter warming may offset growing season carbon uptake under future climatic conditions.

northern permafrost region

The aeromagnetic method as a tool to identify Cenozoic magmatism in the West Antarctic Rift System beneath the West Antarctic Ice Sheet: a review; Thiel subglacial volcano as possible source of the ash layer in the WAISCOR

The West Antarctic Ice Sheet (WAIS) flows through the volcanically active West Antarctic Rift System (WARS). The aeromagnetic method has been the most useful geophysical tool for identification of subglacial volcanic rocks, since 1959–64 surveys, particularly combined with 1978 radar ice-sounding. The unique 1991–97 Central West Antarctica (CWA) aerogeophysical survey covering 354,000 km 2 over the WAIS, (5-km line-spaced, orthogonal lines of aeromagnetic, radar ice-sounding, and aerogravity measurements), still provides invaluable information on subglacial volcanic rocks, particularly combined with the older aeromagnetic profiles. These data indicate numerous 100–>1000 nT, 5–50-km width, shallow-source, magnetic anomalies over an area greater than 1.2 × 10 6 km 2 , mostly from subglacial volcanic sources. I interpreted the CWA anomalies as defining about 1000 “volcanic centers” requiring high remanent normal magnetizations in the present field direction. About 400 anomaly sources correlate with bed topography. At least 80% of these sources have less than 200 m relief at the WAIS bed. They appear modified by moving ice, requiring a younger age than the WAIS (about 25 Ma). Exposed volcanoes in the WARS are < 34 Ma, but at least four are active. If a few buried volcanic centers are active, subglacial volcanism may well affect the WAIS regime. Aerogeophysical data (Blankenship et al., 1993, Mt. Casertz; Corr and Vaughan, 2008, near Hudson Mts.) indicated active subglacial volcanism. Magnetic data indicate a caldera and a surrounding “low” in the WAISCORE vicinity possibly the result of a shallow Curie isotherm. High heat flow reported from temperature logging in the WAISCORE (Conway et al., 2011; Clow, personal commun.) and a volcanic ash layer (Dunbar, 2012) are consistent with this interpretation. A subaerially erupted subglacial volcano, (Mt Thiel), about 100 km distant, may be the ash source. The present rapid changes resulting from global warming, could be accelerated by subglacial volcanism.

Tectonophysics

Mantle to surface degassing of alkalic magmas at Erebus volcano, Antarctica

Continental intraplate volcanoes, such as Erebus volcano, Antarctica, are associated with extensional tectonics, mantle upwelling and high heat flow. Typically, erupted magmas are alkaline and rich in volatiles (especially CO 2 ), inherited from low degrees of partial melting of mantle sources. We examine the degassing of the magmatic system at Erebus volcano using melt inclusion data and high temporal resolution open-path Fourier transform infrared (FTIR) spectroscopic measurements of gas emissions from the active lava lake. Remarkably different gas signatures are associated with passive and explosive gas emissions, representative of volatile contents and redox conditions that reveal contrasting shallow and deep degassing sources. We show that this unexpected degassing signature provides a unique probe for magma differentiation and transfer of CO 2 -rich oxidised fluids from the mantle to the surface, and evaluate how these processes operate in time and space. Extensive crystallisation driven by CO 2 fluxing is responsible for isobaric fractionation of parental basanite magmas close to their source depth. Magma deeper than 4 kbar equilibrates under vapour-buffered conditions. At shallower depths, CO 2 -rich fluids accumulate and are then released either via convection-driven, open-system gas loss or as closed-system slugs that ascend and result in Strombolian eruptions in the lava lake. The open-system gases have a reduced state (below the QFM buffer) whereas the closed-system gases preserve their deep oxidised signatures (close to the NNO buffer).

Earth and Planetary Science Letters

Topographic controls on post-Oligocene changes in ice-sheet dynamics, Prydz Bay region, east Antarctica

Within the general trend of post-Eocene cooling, the largest and oldest outlet of the East Antarctic Ice Sheet underwent a change from ice-cliff to ice-stream and/or ice-shelf dynamics, with an associated switch from line-source to fan sedimentation. Available geological data reveal little about the causes of these changes in ice dynamics during the Miocene Epoch, or the subsequent effects on Pliocene-Pleistocene ice-sheet history. Ice-sheet numerical modeling reveals that bed morphology was probably responsible for driving changes in both ice-sheet extent and dynamics in the Lambert-Amery system at Prydz Bay. The modeling shows how the topography and bathymetry of the Lambert graben and Prydz Bay control ice-sheet extent and flow. The changes in bathymetric volume required for shelf-edge glaciation correlate well with the Prydz Channel fan sedimentation history. This suggests a negative feedback between erosion and glaciation, whereby the current graben is overdeepened to such an extent that shelf-edge glaciation is now not possible, even if a Last Glacial Maximum environment recurs. We conclude that the erosional history of the Lambert graben and Prydz Bay in combination with the uplift histories of the surrounding mountains are responsible for the evolution of this section of the East Antarctic Ice Sheet, once the necessary initial climatic conditions for glaciation were achieved at the start of the Oligocene Epoch. Keywords: Antarctica, ice sheets, numerical models, Miocene, Pliocene.

Geology

Seismic stratigraphic evidence of ice-sheet advances on the Wilkes Land margin of Antarctica

The Wilkes Land continental shelf, similar to other Antarctic shelves, is underlain by thick sequences of steeply prograded glacial diamictons. On the outer shelf, banks that are shallower than 400 m are separated by broad outer-shelf troughs that deepen landward. The prograded sequences are found preferentially in these broad outer-shelf troughs. We propose that these outer-shelf prograding wedges were deposited by fallout from deforming till-layer transport beneath ice streams at times of ice expansion onto the continental shelf. Such deforming till-layer transport has recently been proposed to explain seismic observations beneath ice stream B of the Ross Embayment. Two prominent erosional unconformities with stratal truncations of more than 500 m indicate erosional events that overdeepened the shelf and provided the accommodation space to allow the deposition of these prograding sequences in front of advancing ice streams at times of past glacial maxima. The erosional events that produced these extraordinary downcuts were caused by erosion by ice that expanded onto a shelf with water depths far too shallow for flotation. These two particular erosional surfaces developed either on an initially shallow shelf, or from an extraordinarily high flux of ice, or both.

Sedimentary Geology