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Research about Adirondack Mountains

Source-linked reports with geographic coverage including Adirondack Mountains.

At least 19 recordsLinked to original sources

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York↗

Regional target loads of atmospheric nitrogen and sulfur deposition for the protection of stream and watershed soil resources of the Adirondack Mountains, USA

Acidic deposition contributes to a range of environmental impacts across forested landscapes, including acidification of soil and drainage water, toxic aluminum mobilization, depletion of available soil nutrient cations, and impacts to forest and aquatic species health and biodiversity. In response to decreasing levels of acidic deposition, soils and drainage waters in some regions of North America have become gradually less acidic. Thresholds of atmospheric deposition at which adverse ecological effects are manifested are called critical loads (CLs) and/or target loads (TLs). Target loads are developed based on approaches that account for spatial and temporal aspects of acidification and recovery. Exceedance represents the extent to which current or projected future levels of acidic deposition exceed the level expected to cause ecological harm. We report TLs of sulfur (S) and nitrogen (N) deposition and the potential for ecosystem recovery of watershed soils and streams in the Adirondack region of New York State, resources that have been less thoroughly investigated than lakes. Regional TLs were calculated by statistical extrapolation of hindcast and forecast simulations of 25 watersheds using the process-based model PnET-BGC coupled with empirical observations of stream hydrology and established sensitivity of sugar maple ( Acer saccharum ) to soil base saturation and brook trout ( Salvelinus fontinalis ) to stream acid neutralizing capacity (ANC). Historical impacts and the expected recovery timeline of regional soil and stream chemistry and fish community condition within the Adirondack Park were evaluated. Analysis suggests that many low-order Adirondack streams and associated watershed soils have low TLs (<40 meq/m 2 /yr of N+S deposition) to achieve specified benchmarks for recovery of soil base saturation or stream ANC. Acid-sensitive headwater and low-order streams and watershed soils in the region are expected to experience continued adverse effects from N and S deposition well into the future even under aggressive emissions reductions. Watershed soils and streams in the western Adirondack Park are particularly vulnerable to acidic deposition and currently in exceedance of TLs. The methods used for linking statistical and process-based models to consider chemical and biological response under varying flow conditions at the regional scale in this study can be applied to other areas of concern.

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Methylmercury-Total mercury ratios in predator and primary consumer insects from Adirondack streams (New York, USA)

Mercury (Hg) is a global pollutant that affects biota in remote settings due to atmospheric deposition of inorganic Hg, and its conversion to methylmercury (MeHg), the bioaccumulating and toxic form. Characterizing biotic MeHg is important for evaluating aquatic ecosystem responses to changes in Hg inputs. Aquatic insects possess many qualities desired for MeHg biomonitoring, but are not widely used, largely because of limited information regarding percentages of total mercury (THg) composed of MeHg (i.e., MeHg%) in various taxa. Here, we examine taxonomic, spatial, and seasonal variation in MeHg% of stream-dwelling predator and primary-consumer insects from nine streams in the Adirondack region (NY, USA). Predator MeHg% was high (median 94%) and did not differ significantly among five taxa. MeHg% in selected dragonflies (the most abundant predators, Odonata: Aeshnidae and Libellulidae) exhibited little seasonal and spatial variation, and THg concentration was strongly correlated with aqueous (filtered) MeHg (FMeHg; r s = 0.76). In contrast, MeHg% in primary consumers—shredders (northern caddisflies [Trichoptera: Limnephilidae]) and scrapers (flathead mayflies [Ephemeroptera: Heptageniidae]), were lower (medians 52% and 35%, respectively), and differed significantly between taxa, among sites, and seasonally. Correlations of THg with FMeHg were weak (shredders, r s = 0.45, p = 0.09) or not significant (scrapers, p = 0.89). The higher MeHg% of predators corresponded with their higher trophic positions (indicated by nitrogen stable isotopes). Results suggest obligate predators hold the most promise for the use of THg as a surrogate for MeHg biomonitoring with aquatic insects within the Adirondack region.

Adirondack Mountains↗

Predictive relations between acid-base chemistry and fish assemblages in streams of the Adirondack Mountains

Surface waters across much of New York State’s Adirondack Mountains were acidified in the late 20th century but began to recover following the 1990 Title IV Amendments to the Clean Air Act. Previous assessments of acidification recovery in the Adirondacks have generally been based on surface water chemistry data and inferred relationships to fish and other aquatic biota. Little data, however, has been available to characterize biological impacts and predict recovery of fish assemblages in streams of the region. Here, we use quantitative fish surveys combined with chemistry data from 48 headwater streams sampled during summer 2014–2016 to develop logistic (probability) models that characterize the status of contemporary fish assemblages and predict how different N and S deposition loads may affect future fish assemblages. Statistical models for inorganic aluminum (Al i ) and richness ≥1 species; and for acid neutralizing capacity (ANC) and total density >400 fish/0.1 ha, total biomass >1500 g/0.1 ha, brook trout Salvelinus fontinalis density >0 or >200 fish/0.1 ha, and brook trout biomass >1000 g/0.1 ha were suitable for evaluating community and population responses to changes in acid-base chemistry. Predictions of fish-assemblage responses using several of these models demonstrated that anticipated changes in national (U.S.) secondary standards for atmospheric emissions of NO x and SO x to achieve target N and S deposition loads are likely to alter the acid-base chemistry and the probabilities of observing various levels of brook trout population and fish-community metrics in streams across the region and elsewhere.

New York↗

Decreases in aluminum toxicity and mortality of caged brook trout in Adirondack Mountain Streams

Mortality of juvenile brook trout and water chemistry were characterized in six western Adirondack streams in northern New York State during spring 2015, 2016, and 2017 and compared with results from comparable tests done between 1980 and 2003 in many of the same streams to assess temporal changes in inorganic monomeric aluminum (Ali) concentrations, Ali-toxicity, and the role of Ali-exposure duration on mortality. Ali concentrations of 2 and 4 micromoles per liter (µmol L-1) corresponded to chronic- and acute-mortality thresholds for brook trout, but prolonged exposure to ≥ 1 µmol Ali L-1 also produced low-to-moderate mortality levels. The variability, mean, and highest Ali concentrations in Buck Creek (BUC) year-round, and in several other streams during spring, decreased significantly over the past 30 years. Predictive models indicate that Ali surpassed highly toxic concentrations at BUC for three to four months annually during 2001–2003 but for only two to three weeks annually during 2015–2017. The current lack of extremely high Ali concentrations indicate toxicity has declined markedly between the 1989–1990, 2001–2003, and 2015–2017 test periods, yet acid- Ali episodes can still cause moderate-to-high levels of brook trout mortality during high springtime flows. Assembled models show how mortality of brook trout in several Adirondack streams likely declined in response to the 1990 Clean Air Act Amendments and offer a means to predict how changes in United States regulations that limit the atmospheric emissions of nitrogen (N) and sulfur (S) oxides, and the deposition of N and S, could affect brook trout survival and impaired stream ecosystems in the western Adirondack region.

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Declining aluminum toxicity and the role of exposure duration on brook trout mortality in acidified streams of the Adirondack Mountains, New York, USA

Mortality of brook trout Salvelinus fontinalis and water chemistry were characterized in 6 headwater streams in the western Adirondacks of New York during spring 2015, 2016, and 2017 and compared with results from analogous tests done between 1980 and 2003 in many of the same streams, to assess temporal changes in toxicity and inorganic monomeric aluminum (Al i ) concentrations, and the role of Al i exposure duration on brook trout survival. The Al i concentrations of 2 and 4 µmol L –1 corresponded to low‐to‐moderate and high mortality thresholds, but prolonged exposure to ≥1 µmol Al i L –1 also produced mortality. The variability, mean, and highest Al i concentrations in Buck Creek year round, and in several other streams during spring, have decreased significantly over the past 3 decades. Logistic models indicate that Al i surpassed highly toxic concentrations in Buck Creek for 3 to 4 mo annually during 2001 to 2003 and for 2 to 3 wk annually during 2015 to 2017. The loss of extremely high Al i episodes indicates that toxicity has declined markedly between the 1989 to 1990, 2001 to 2003, and 2015 to 2017 test periods, yet Al i concentrations can still cause moderate‐to‐high and complete (100%) mortality. The logistic models illustrate how mortality of brook trout in several Adirondack streams likely decreased in response to the 1990 Amendments to the United States' Clean Air Act (which decreased acidity, Al i concentrations, and duration of toxic episodes) and offer a means to predict how changes in US regulations that limit emissions of NO x and SO x (and N and S deposition loads) could affect fish survival and stream ecosystems in this region and across the Northeast.

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Syn-collisional exhumation of hot middle crust in the Adirondack Mountains (New York, USA): Implications for extensional orogenesis in the southern Grenville province

Extensional deformation in the lower to middle continental crust is increasingly recognized and shown to have significant impact on crustal architecture, magma emplacement, fluid flow, and ore deposits. Application of the concept of extensional strain to ancient orogenic systems, like the Grenville province of eastern North America, has helped decipher the structural evolution of these regions. The Marcy massif is a ~3000 km2 Mesoproterozoic anorthosite batholith in the Adirondack Mountains (New York, USA) of the southern Grenville province. Bedrock geology mapping at 1:24,000 scale paired with characterization of bedrock exposed by recent landslides provides a glimpse into the structural architecture of the massif and its margin. New data demonstrate granulite- to amphibolite-facies deformational fabrics parallel the margin of the batholith, and that the Marcy massif is draped by a southeast-directed detachment zone. Within the massif, strain is localized into mutually offsetting conjugate shear zones with antithetic kinematic indicators. These relationships indicate that strain was coaxial within the Marcy massif, and that subsimple shear components of strain were partitioned along its margin. In situ U–Th–total Pb monazite analysis shows that deformation around and over the Marcy massif occurred from 1070 to 1060 Ma during granulite-facies metamorphism, and monazite from all samples record evidence for fluid-mediated dissolution reprecipitation from 1050 to 980 Ma. We interpret that rocks cooled isobarically after accretionary orogenesis and emplacement of the anorthosite- mangerite- charnockitegranite plutonic suite at ca. 1160–1140 Ma. Gravitational collapse during the Ottawan phase of the Grenville orogeny initiated along a southeast-directed detachment zone (Marcy massif detachment zone), which accommodated intrusion of the Lyon Mountain Granite Gneiss, and facilitated substantial fluid flow that catalyzed the formation of major ore deposits in the Adirondack Highlands.

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Probabilistic relationships between acid-base chemistry and fish assemblages in streams of the western Adirondack Mountains, New York, USA

Surface waters across much of the Adirondacks of New York were acidified in the late 20th century but began to recover after the 1990 amendments to the Clean Air Act. Little data, however, were available to characterize biological impacts and predict recovery of fish assemblages in regional streams. Quantitative fish and chemistry surveys were completed in 47 headwater streams during summer 2014-16 to develop logistic (probabilistic) models that characterize the status of contemporary fish assemblages and predict how different N and S deposition loads may affect future fish assemblages. Models for Ali and richness ≥1 species, ANC and total density >400 fish/0.1 ha, ANC and total biomass >1500 g/0.1, presence of Brook Trout, trout density >200 fish/0.1 ha, and trout biomass >1000 g/0.1 ha were suitable for evaluating community and population responses to changes in acid-base chemistry. Anticipated changes in national (US) secondary standards for atmospheric emissions of NOx and SOx to achieve target N and S deposition loads will alter acid-base chemistry and the probabilities for observing various levels of fish metrics in streams across the region and elsewhere.

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Variation in fish mercury concentrations in streams of the Adirondack region, New York: A simplified screening approach using chemical metrics

Simple screening approaches for the neurotoxicant methylmercury (MeHg) in aquatic ecosystems may be helpful in risk assessments of natural resources. We explored the development of such an approach in the Adirondack Mountains of New York, USA, a region with high levels of MeHg bioaccumulation. Thirty-six perennial streams broadly representative of 1st and 2nd order streams in the region were sampled during summer low flow and analyzed for several solutes and for Hg concentrations in fish. Several landscape and chemical metrics that are typically strongly related to MeHg concentrations in aquatic biota were explored for strength of association with fish Hg concentrations. Data analyses were based on site mean length-normalized and standardized Hg concentrations (assumed to be dominantly MeHg) in whole juvenile and adult Brook Trout Salvelinus fontinalis , Creek Chub Semotilus atromaculatus , Blacknose Dace Rhinichthys atratulus , and Central Mudminnow Umbra limi , as well as on multi-species z-scores. Surprisingly, none of the landscape metrics was related significantly to regional variation in fish Hg concentrations or to z-scores across the study streams. In contrast, several chemical metrics including dissolved organic carbon (DOC) concentrations, sulfate concentrations (SO 4 2− ), pH, ultra-violet absorbance (UV 254 ), and specific ultra-violet absorbance were significantly related to regional variation in fish Hg concentrations. A cluster analysis based on DOC, SO 4 2− , and pH identified three distinct groups of streams: (1) high DOC, acidic streams, (2) moderate DOC, slightly acidic streams, and (3) low DOC circum-neutral streams with relatively high SO 4 2− . Preliminary analysis indicated no significant difference in fish Hg z-scores between the moderate and high DOC groups, so these were combined for further analysis. The resulting two groups showed strong differences (p < 0.001) in DOC and SO 4 2− concentrations as well as in pH and UV 254 values. Median fish z-scores were significantly higher (p = 0.002) in the group of streams with higher DOC and UV 254 and lower pH and SO 4 2− . Screening values of DOC >6.9 mg/L, SO 4 2− <2.8 mg/L, pH <6.6, and UV 254 >0.31 cm −1 were tested as thresholds to identify Adirondack stream sites likely to have higher fish Hg concentrations. By applying a combined threshold of exceedance for either pH or UV 254 , sites with fish Hg concentrations that exceeded a wildlife guideline of 100 ng/g were correctly identified about 75% of the time among the 36 study streams. An estimate of Hg risk applied to a data set of 391 streams based on DOC concentrations showed that about 28% were likely to pose high risk to wildlife; most of these streams were located in the western Adirondacks.

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Efficacy of environmental DNA to detect and quantify Brook Trout populations in headwater streams of the Adirondack Mountains, New York

Environmental DNA (eDNA) analysis is rapidly evolving as a tool for monitoring the distributions of aquatic species. Detection of species’ populations in streams may be challenging because the persistence time for intact DNA fragments is unknown and because eDNA is diluted and dispersed by dynamic hydrological processes. During 2015, the DNA of Brook Trout Salvelinus fontinalis was analyzed from water samples collected at 40 streams across the Adirondack region of upstate New York, where Brook Trout populations were recently quantified. Study objectives were to evaluate different sampling methods and the ability of eDNA to accurately predict the presence and abundance of resident Brook Trout populations. Results from three-pass electrofishing surveys indicated that Brook Trout were absent from 10 sites and were present in low (<100 fish/0.1 ha), moderate (100–300 fish/0.1 ha), and high (>300 fish/0.1 ha) densities at 9, 11, and 10 sites, respectively. The eDNA results correctly predicted the presence and confirmed the absence of Brook Trout at 85.0–92.5% of the study sites; eDNA also explained 44% of the variability in Brook Trout population density and 24% of the variability in biomass. These findings indicate that eDNA surveys will enable researchers to effectively characterize the presence and abundance of Brook Trout and other species’ populations in headwater streams across the Adirondack region and elsewhere.

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Regional growth decline of sugar maple ( Acer saccharum ) and its potential causes

Sugar maple ( Acer saccharum Marsh) has experienced poor vigor, regeneration failure, and elevated mortality across much of its range, but there has been relatively little attention to its growth rates. Based on a well-replicated dendrochronological network of range-centered populations in the Adirondack Mountains (USA), which encompassed a wide gradient of soil fertility, we observed that the majority of sugar maple trees exhibited negative growth trends in the last several decades, regardless of age, diameter, or soil fertility. Such growth patterns were unexpected, given recent warming and increased moisture availability, as well as reduced acidic deposition, which should have favored growth. Mean basal area increment was greater on base-rich soils, but these stands also experienced sharp reductions in growth. Growth sensitivity of sugar maple to temperature and precipitation was non-stationary during the last century, with overall weaker relationships than expected. Given the favorable competitive status and age structure of the Adirondack sugar maple populations sampled, evidence of widespread growth reductions raises concern over this ecologically and economically important tree. Further study will be needed to establish whether growth declines of sugar maple are occurring more widely across its range.

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Effects of acidic deposition and soil acidification on sugar maple trees in the Adirondack Mountains, New York

We documented the effects of acidic atmospheric deposition and soil acidification on the canopy health, basal area increment, and regeneration of sugar maple (SM) trees across the Adirondack region of New York State, in the northeastern United States, where SM are plentiful but not well studied and where widespread depletion of soil calcium (Ca) has been documented. Sugar maple is a dominant canopy species in the Adirondack Mountain ecoregion, and it has a high demand for Ca. Trees in this region growing on soils with poor acid&ndash;base chemistry (low exchangeable Ca and % base saturation [BS]) that receive relatively high levels of atmospheric sulfur and nitrogen deposition exhibited a near absence of SM seedling regeneration and lower crown vigor compared with study plots with relatively high exchangeable Ca and BS and lower levels of acidic deposition. Basal area increment averaged over the 20th century was correlated (p < 0.1) with acid&ndash;base chemistry of the Oa, A, and upper B soil horizons. A lack of Adirondack SM regeneration, reduced canopy condition, and possibly decreased basal area growth over recent decades are associated with low concentrations of nutrient base cations in this region that has undergone soil Ca depletion from acidic deposition.

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Influence of dietary carbon on mercury bioaccumulation in streams of the Adirondack Mountains of New York and the Coastal Plain of South Carolina, USA

We studied lower food webs in streams of two mercury-sensitive regions to determine whether variations in consumer foraging strategy and resultant dietary carbon signatures accounted for observed within-site and among-site variations in consumer mercury concentration. We collected macroinvertebrates (primary consumers and predators) and selected forage fishes from three sites in the Adirondack Mountains of New York, and three sites in the Coastal Plain of South Carolina, for analysis of mercury (Hg) and stable isotopes of carbon (δ 13 C) and nitrogen (δ 15 N). Among primary consumers, scrapers and filterers had higher MeHg and more depleted δ 13 C than shredders from the same site. Variation in δ 13 C accounted for up to 34 % of within-site variation in MeHg among primary consumers, beyond that explained by δ 15 N, an indicator of trophic position. Consumer δ 13 C accounted for 10 % of the variation in Hg among predatory macroinvertebrates and forage fishes across these six sites, after accounting for environmental aqueous methylmercury (MeHg, 5 % of variation) and base-N adjusted consumer trophic position (Δδ 15 N, 22 % of variation). The δ 13 C spatial pattern within consumer taxa groups corresponded to differences in benthic habitat shading among sites. Consumers from relatively more-shaded sites had more enriched δ 13 C that was more similar to typical detrital δ 13 C, while those from the relatively more-open sites had more depleted δ 13 C. Although we could not clearly attribute these differences strictly to differences in assimilation of carbon from terrestrial or in-channel sources, greater potential for benthic primary production at more open sites might play a role. We found significant variation among consumers within and among sites in carbon source; this may be related to within-site differences in diet and foraging habitat, and to among-site differences in environmental conditions that influence primary production. These observations suggest that different foraging strategies and habitats influence MeHg bioaccumulation in streams, even at relatively small spatial scales. Such influence must be considered when selecting lower trophic level consumers as sentinels of MeHg bioaccumulation for comparison within and among sites.

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Landscape controls on total and methyl Hg in the Upper Hudson River basin, New York, USA

Approaches are needed to better predict spatial variation in riverine Hg concentrations across heterogeneous landscapes that include mountains, wetlands, and open waters. We applied multivariate linear regression to determine the landscape factors and chemical variables that best account for the spatial variation of total Hg (THg) and methyl Hg (MeHg) concentrations in 27 sub-basins across the 493 km 2 upper Hudson River basin in the Adirondack Mountains of New York. THg concentrations varied by sixfold, and those of MeHg by 40-fold in synoptic samples collected at low-to-moderate flow, during spring and summer of 2006 and 2008. Bivariate linear regression relations of THg and MeHg concentrations with either percent wetland area or DOC concentrations were significant but could account for only about 1/3 of the variation in these Hg forms in summer. In contrast, multivariate linear regression relations that included metrics of (1) hydrogeomorphology, (2) riparian/wetland area, and (3) open water, explained about 66% to >90% of spatial variation in each Hg form in spring and summer samples. These metrics reflect the influence of basin morphometry and riparian soils on Hg source and transport, and the role of open water as a Hg sink. Multivariate models based solely on these landscape metrics generally accounted for as much or more of the variation in Hg concentrations than models based on chemical and physical metrics, and show great promise for identifying waters with expected high Hg concentrations in the Adirondack region and similar glaciated riverine ecosystems.

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Changes in faunal and vegetation communities along a soil calcium gradient in northern hardwood forests

Depletion of Ca from forest soils due to acidic deposition has had potentially pervasive effects on forest communities, but these impacts remain largely unknown. Because snails, salamanders, and plants play essential roles in the Ca cycle of northern hardwood forests, we hypothesized that their community diversity, abundance, and structure would vary with differences in biotic Ca availability. To test this hypothesis, we sampled 12 upland hardwood forests representing a soil Ca gradient in the Adirondack Mountains, New York (USA), where chronic deposition has resulted in acidified soils but where areas of well-buffered soils remain Ca rich due to parent materials. Along the gradient of increasing soil [Ca 2+ ], we observed increasing trends in snail community richness and abundance, live biomass of redback salamanders (Plethodon cinereus (Green, 1818)), and canopy tree basal area. Salamander communities were dominated by mountain dusky salamanders (Desmognathus ochrophaeus Cope, 1859) at Ca-poor sites and changed continuously along the Ca gradient to become dominated by redback salamanders at the Ca-rich sites. Several known calciphilic species of snails and plants were found only at the highest-Ca sites. Our results indicated that Ca availability, which is shaped by geology and acidic deposition inputs, influences northern hardwood forest ecosystems at multiple trophic levels, although the underlying mechanisms require further study.

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Manganese biogeochemistry in a small Adirondack forested lake watershed

I n September and October 1981, manganese (Mn) concentrations and p H were intensively monitored in a small forested lake watershed in the west-central Adirondack Mountains, New York, during two large acidic storms (each ∼5 cm rainfall, p H 4.61 and 4.15). The data were evaluated to identify biogeochemical pathways of Mn and to assess how these pathways are altered by acidic atmospheric inputs. Concentrations of Mn averaged 1.1 μg/L in precipitation and increased to 107 μg/L in canopy throughfall, the enrichment reflecting active biological cycling of Mn. Rain p H and throughfall Mn were negatively correlated, suggesting that foliar leaching of Mn was enhanced by rainfall acidity. The pulselike input of Mn to the forest floor in the high initial concentrations in throughfall (∼1000 μg/L) did not affect Mn concentrations in soil water (< 20 μg/L) or groundwater (usually < 40 μg/L), which varied little with time. In the inlet stream, Mn concentrations remained constant at 48 μg/L as discharge varied from 1.1 to 96 L/s. Manganese was retained in the vegetative cycle and regulated in the stream by adsorption in the soil organic horizon. The higher Mn levels in the stream may be linked to its high acidity (pH 4.2–4.3). Mixing of Mn-rich stream water with neutral lake water ( p H 7.0) caused precipitation of Mn and deposition in lake sediment.

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Wolf restoration to the Adirondacks: the advantages and disadvantages of public participation in the decision

The first time I ever saw a wolf in New York State's Adirondack Mountains was in 1956. It was a brush wolf, or coyote ( Canis latrans ), not a real wolf, but to an eager young wildlife student this distinction meant little. The presence of this large deer-killing canid let my fresh imagination view the Adirondacks as a real northern wilderness. Since then I have spent the last 40 years studying the real wolf: the gray wolf ( Canis lupus ). Although inhabiting nearby Quebec and Ontario, the gray wolf still has not made its way back to the Adirondacks as it has to Wisconsin, Michigan, and Montana. Those three states had the critical advantages of a nearby reservoir population of wolves and wilderness corridors through which dispersers from the reservoirs could immigrate. The Adirondacks, on the other hand, are geographically more similar to the greater Yellowstone area in that they are separated from any wolf reservoir by long distances and intensively human-developed areas aversive to wolves from the reservoir populations. If wolves are to return to the Adirondacks, they almost certainly will have to be reintroduced, as they were to Yellowstone National Park. Wolf reintroduction, as distinct from natural recovery, is an especially contentious issue, for it entails dramatic, deliberate action that must be open to public scrutiny, thorough discussion and review, and highly polarized debate. This is as it should be because once a wolf population is reintroduced to an area, it must be managed forever. There is no turning back. The wolf was once eradicated not just from the Adirondacks but from almost all of the 48 contiguous states. That feat was accomplished by a primarily pioneering society that applied itself endlessly to the task, armed with poison. We can never return to those days, so once the wolf is reintroduced successfully, it will almost certainly be here to stay.

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