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Zell E. Peterman

Publications and source records attributed to Zell E. Peterman.

53 records · Page 3Linked to original sources

Distribution of rubidium, strontium, and zirconium in tuff from two deep coreholes at Yucca Mountain, Nevada

Variations in concentrations of trace elements Rb, Sr, and Zr within the sequence of high-silica tuff and dacitic lava beneath Yucca Mountain reflect both primary composition and secondary alteration. Rb and K concentrations have parallel trends. Rb concentrations are significantly lower within intervals containing zeolitic nonwelded to partially welded and bedded tuffs and are higher in thick moderately to densely welded zones. Sr concentrations increase with depth from about 30 ppm in the Topopah Spring Member of the Paintbrush Tuff to almost 300 ppm in the older tuffs. Zr concentrations are about 100 ppm in the Topopah Spring Member and also increase with depth to about 150 ppm in the Lithic Ridge Tuff and upper part of the older tuffs. Conspicuous local high concentrations of Sr in the lower part of the Tram Member, in the dacite lava, and in unit c of the older tuffs in USW G-1, and in the densely welded zone of the Bullfrog Member in USW GU-3/G-3 closely correlate with high concentrations of less-mobile Zr and may reflect either primary composition or elemental redistribution resulting largely from smectitic alteration. Initial 87Sr/86Sr values from composite samples increase upward in units above the Bullfrog Member of the Crater Flat Tuff. The progressive tenfold increase in Sr with depth coupled with the similarity of initial 87Sr/86Sr values within the Bullfrog Member and older units to those of Paleozoic marine carbonates are consistent with a massive influx of Sr from water derived from a Paleozoic carbonate aquifer.

Conference Paper

Ostwald ripening of clays and metamorphic minerals

Analyses of particle size distributions indicate that clay minerals and other diagenetic and metamorphic minerals commonly undergo recrystallization by Ostwald ripening. The shapes of their particle size distributions can yield the rate law for this process. One consequence of Ostwald ripening is that a record of the recrystallization process is preserved in the various particle sizes. Therefore, one can determine the detailed geologic history of clays and other recrystallized minerals by separating, from a single sample, the various particle sizes for independent chemical, structural, and isotopic analyses.

Science

Strontium-isotope stratigraphy of Enewetak Atoll

87 Sr/ 86 Sr ratios determined for samples from a 350 m core of Neogene lagoonal, shallow-water limestones from Enewetak Atoll display a remarkably informative trend. Like the recently published data for Deep Sea Drilling Project (DSDP) carbonates, 87 Sr/ 86 Sr at Enewetak increases monotonically but not smoothly from the early Miocene to the Pleistocene. The data show intervals of little or no change in 87 Sr/ 86 Sr, punctuated by sharp transitions to lower values toward greater core depths. The sharp transitions correlate with observed solution disconformities caused by periods of subaerial erosion, whereas the intervals of little or no change in 87 Sr/ 86 Sr correspond to intervals of rapid accumulation of shallow-water carbonate sediments. When converted to numerical ages using the published DSDP 590B trend, the best-resolved time breaks are at 282 m (12.3 to 18.2 Ma missing) and 121.6 m (3.0 to 5.3 Ma missing) below the lagoon floor. At Enewetak, Sr isotopes offer a stratigraphic resolution for these shallow-marine Neogene carbonates comparable to that of nannofossil zonation in deep-sea carbonates (0.3-3 m.y.). In addition, the correlation of times of Sr-isotope breaks at Enewetak with times of rapid Sr-isotope change in the DSDP 590B samples confirms the importance off sea-level changes in the evolution of global-marine Sr isotopes and shows that the Sr-isotope response to sea-level falls is rapid.

Geology

Reconnaissance geology and geochronology of the Precambrian of the Granite Mountains, Wyoming

The Precambrian of the western part of the Granite Mountains, Wyoming, contains a metamorphic complex of gneisses, schists, and amphibolites that were derived through amphibolite-grade metamorphism from a sedimentary-volcanic sequence perhaps similar to that exposed in the southeastern Wind River Mountains. Whole-rock Rb-Sr dating places the time of metamorphism at 2,860?80 million years. A high initial 87Sr/ 86 S r ratio of 0.7048 suggests that either the protoliths or the source terrane of the sedimentary component is several hundred million years older than the time of metamorphism. Following an interval of 300:t100 million years for which the geologic record is lacking or still undeciphered, the metamorphic complex was intruded by a batholith and satellite bodies of medium- to coarse-grained, generally massive biotite granite and related pegmatite and aplite. The main body of granite is dated at 2,550?60 million years by the Rb-Sr method. Limited data suggest that diabase dikes were emplaced and nephrite veins were formed only shortly after intrusion of the granite. Emplacement of the granite at about 2,550 million years ago appears to be related to a major period of regional granitic plutonism in the Precambrian of southern and western Wyoming. Granites, in the strict sense, that are dated between 2,450 and 2,600 million years occur in the Teton Range, the Sierra Madre, the Medicine Bow Mountains and the Laramie Range. This episode of granitic plutonism occurred some 50 to 100 million years later than the major tonalitic to granitic plutonism in the Superior province of northern Minnesota and adjacent Ontario-the nearest exposed Precambrian W terrane that is analogous to the Wyoming province. Initial 87Sr / 86Sr ratios of some of the Wyoming granites are higher than expected if the rocks had been derived from juvenile magmas and it is likely that older crustal rocks were involved to some degree in the generation of these granites. Slightly to highly disturbed Rb-Sr and K-Ar mineral ages are obtained on rocks of the metamorphic complex and on the granite. These ages range from about 2,400 to 1,420 million years and are part of a regional pattern of lowered mineral ages of Precambrian W rocks of southern Wyoming. A major discontinuity in these mineral ages occurs along a line extending from the northern Laramie Range, through the northern part of the Granite Mountains, to the southeastern Wind River Mountains. North of this line, Rb-Sr and K-Ar biotite ages are 2,300 million years or greater, whereas to the south, the biotite ages decrease drastically over a short distance, to a common range of 1,600-1,400 million years. We suggest that these lowered ages represent regional cooling below the 300 0 C isotherm as a consequence of uplift and erosion of the large crustal block occurring south of the age discontinuity. In this interpretation, the westerly-trending age discontinuity would be a zone of major crustal dislocation that resulted from vertical tectonics in late Precambrian X or early Precambrian Y time.

Professional Paper

Reconstruction of crustal blocks of California on the basis of initial strontium isotopic compositions of Mesozoic granitic rocks

Initial 87Sr/ 86 Sr was determined for samples of Mesozoic granitic rocks in the vicinity of the Garlock fault zone in California. These data along with similar data from the Sierra Nevada and along the San Andreas fault system permit a reconstruction of basement rocks offset by the Cenozoic lateral faulting along both the San Andreas and Garlock fault systems. The location of the line of initial 87Sr/ 86 Sr = 0.7060 can be related to the edge of the Precambrian continental crust in the western United States. Our model explains the present configuration of the edge of Precambrian continental crust as the result of two stages of rifting that occurred about 1,250 to 800 m.y. ago, during Belt sedimentation, and about 600 to 350 m.y. ago, prior to and during the development of the Cordilleran geosyncline and to left-lateral translation along a locus of disturbance identified in the central Mojave Desert. The variations in Rb, Sr, and initial 87Sr/ 86 Sr of the Mesozoic granitic rocks are interpreted as due to variations in composition and age of the source materials of the granitic rocks. The variations of Rb, Sr, and initial 87Sr/ 86 Sr in Mesozoic granitic rocks, the sedimentation history during the late Precambrian and Paleozoic, and the geographic position of loci of Mesozoic magmatism in the western United States are related to the development of the continental margin and different types of lithosphere during rifting.

Professional Paper

Reconnaissance geology and geochronology of the Precambrian of the Granite Mountains, Wyoming

The Precambrian of the western part of the Granite Mountains contains a metamorphic complex of gneisses, schists and amphibolites that were derived through amphibolite-grade metamorphism from a sedimentary-volcanic sequence perhaps similar to that exposed in the southeastern Wind River Mountains. Whole-rock Rb-Sr dating places the time of metamorphism at 2925 ± 81 m.y. A high initial 87 Sr/ 86 Sr ratio of 0.7048 suggests that either the protoliths or the source terrane of the sedimentary component is several hundred million years older than the time of metamorphism. Following an interval of 300 ± 100 m.y. for which the geologic record is lacking or still undeciphered, the metamorphic complex was intruded by a batholith and satellite bodies of medium to coarse-grained, generally massive biotite granite and related pegmatite and aplite. The main body of granite is dated at 2602 ± 60 m.y. by the Rb-Sr method. Limited data suggest that diabase dikes were emplaced and nephrite veins were formed only shortly after intrusion of the granite. Emplacement of the granite at about 2600 m.y. ago appears to be related to a major period of regional granitic plutonism in the Precambrian of southern and western Wyoming. Granites sensu stricto that are dated between 2500 and 2600 m.y. occur in the Teton Range, the Sierra Madre, the Medicine Bow Mountains and the Laramie Range. This episode of granitic plutonism occurred some 50 to 100 m.y. later than the major tonalitic to granitic plutonism in the Superior Province of northern Minnesota and adjacent Ontario--the nearest exposed Precambrian W terrane that is analogous to the Wyoming Province. Initial 87 Sr/ 86 Sr ratios of some of the Wyoming granites are higher than expected if the rocks had been derived from juvenile magmas and it is likely that older crustal rocks were involved to some degree in the generation of these granites. Slightly to highly disturbed Rb-Sr and K-Ar mineral ages are obtained on rocks of the metamorphic complex arid on the granite. These ages range from about 2450 to 1450 m.y. and are part of a regional pattern of lowered mineral ages of Precambrian W rocks of southern Wyoming. A major discontinuity in these mineral ages occurs along a line extending from the northern Laramie Range, through the northern part of the Granite Mountains, to the southeastern Wind River Mountains. North of this line, Rb-Sr and K-Ar biotite ages are 2350 m.y. or greater whereas to the south, the biotite ages decrease drastically over a short distance to a common range of 1400-1600 m.y. We suggest that these lowered ages represent regional cooling below the 300° C isotherm as a consequence of uplift and erosion of the large crustal block occurring south of the age discontinuity. In this interpretation, the westerly-trending age discontinuity would be a zone of major crustal dislocation that resulted from vertical tectonics in late Precambrian X or early Precambrian Y time.

Wyoming

Geology and Rb-Sr age of Precambrian W Puritan Quartz Monzonite, northern Michigan

The Puritan Quartz Monzonite, in the western part of the Upper Peninsula of Michigan, composes a batholith at least 50 kilometres long and as much as 20 km wide on the south side of the Gogebic iron range. It is associated with subaqueous metavolcanic rocks assigned to the Precambrian W Ramsey Formation and with a complex gneissic unit of the same age. The quartz monzonite has a Rb-Sr isochron age of 2,710±140 million years and an initial 87 Sr/ 86 Sr of 0.7015±0.0017. The scatter of data points in excess of analytical error is interpreted as indicating that minor cataclasis and retrograde metamorphism produced slight open-system behavior in Precambrian X (circa 1,800 m.y.) time. The Puritan Quartz Monzonite and associated volcanic rocks are equated with similar Precambrian W greenstone-granite complexes in northern Minnesota, and clearly are a part of the Precambrian W greenstone terrane, as defined previously for the Lake Superior region.

Michigan, Wisconsin

Geology and Rb-Sr ages of reactivated Precambrian gneisses and granite in the Marenisco-Watersmeet area, northern Michigan

Rb-Sr dating of Precambrian W (lower Precambrian) gneisses and granitic rocks that form the cores of antiforms or domes mantled by metamorphosed Precambrian X (middle Precambrian) bedded rocks in the Marenisco-Watersmeet area, northern Michigan, shows that the rock systems have been disturbed to different degrees by complex tectonic and thermal events subsequent to primary crystallization. The disturbance is indicated by a lowering of the whole-rock Rb-Sr ages of many samples of gneiss from 2,600 m.y. or older to about 1,800 m.y. and by the scattering of data points, although some of the points can be fit to secondary isochrons; probably the major mechanism was redistribution of previously accumulated radiogenic Sr, which is indicated by the high initial 87 Sr/ 86 Sr of the resultant isochrons. The disturbance is interpreted as having resulted from internal cataclasis and recrystallization accompanied by metamorphic segregation and (or) partial melting during reactivation of the gneisses about 1,800 m.y. ago. Variations in the degree of reconstitution and mobility of individual bodies of basement rocks are indicated by differences in structural reconstitution of the basement rocks and in the metamorphic grade of the Precambrian X bedded rocks.

Michigan

Variations in Sr, Rb, K, Na, and Initial Sr87/Sr86 in Mesozoic Granitic Rocks and Intruded Wall Rocks in Central California

Initial Sr 87 /Sr 86 of granitic rocks which are exposed north of the Garlock fault in California, and which represent the entire 130-m.y. time span of emplacement during the Mesozoic, ranges mainly from 0.7031 to 0.7082, with one value of 0.7094. A systematic areal variation, independent of age, exists for initial Sr 87 /Sr 86 in these granitic rocks and is the same as the areal variation in initial Sr 87 /Sr 86 of superjacent upper Cenozoic basalts and andesites. Two values of initial Sr 87 /Sr 86 , 0.7040 and 0.7060, mark natural separations of granitic rock data on K-Rb, K-Sr, and Rb/Sr-Rb variation diagrams, and also, when contoured, seem to represent geographic markers of paleo-geographic, geochemical, and physiographic significance. Upper Precambrian sedimentary and metamorphic rocks in California crop out only in the region where initial Sr 87 /Sr 86 of granitic rocks is greater than 0.7060. A line of initial Sr 87 /Sr 86 = 0.7060 is approximately coincident with the boundary between Paleozoic eugeosynclinal and miogeosynclinal rocks. Granitic rocks intruded into Paleozoic miogeosynclinal rocks have initial Sr 87 /Sr 86 greater than 0.7060, whereas those intruded into eugeosynclinal Paleozoic rocks have initial Sr 87 /Sr 86 less than 0.7060. The line of initial Sr 87 /Sr 86 = 0.7040 is the eastern limit of principal exposures of ultramafic rocks, the western limit of Cretaceous granitic rocks, and is coincident with an abrupt change in “topographic expression” on the Bouguer gravity map of California. Correlation of the isotopic variations with these major crustal features suggests that there has been a sharp lateral contrast in crust-mantle chemistry across the region of study that has been fixed in position from the Precambrian to the present time. The chemical and isotopic variations observed are best explained if the parent magmas of the majority of granitic rocks investigated were derived in a region that was laterally variable in composition and in a zone of melting that intersected both upper mantle and lower crust. However, some igneous rocks, such as Jurassic volcanic rocks in wall rocks and roof pendants and some granitic rocks with high strontium concentrations and low Rb-Sr ratios, suggest that deeper sources are also involved in the total spectrum of igneous rocks in the region.

California

Related strontium isotopic and chemical variations in oceanic basalts

Sr 87 /Sr 86 values in oceanic basalts range from 0.7012 to 0.7057 and correlate with basalt composition as measured by the ratio K 2 O/(Na 2 O + K 2 O). The distribution of data points on this plot can be approximated by the following ranges in Sr 87 /Sr 86 and K 2 O/(K 2 O + Na 2 O) respectively: (l) ocean ridge tholeiites—0.7020 to 0.7035 (one value 0.7012), <0.10; (2) many island tholeiites and alkali basalts—0.7030 to 0.7045, 0.10 to 0.30; and (3) potassic island basaltic rocks—0.7040 to 0.7057, >0.30. If the volcanism occurring throughout much of geologic time preferentially depleted rubidium and potassium relative to strontium in the mantle, preservation of the resultant heterogeneities is necessary to explain the isotopic and chemical differences among oceanic basalts. As a corollary to this long-term depletion of rubidium and potassium of the mantle, the primitive mantle or total crust-mantle system would have an Sr 87 /Sr 86 value higher than many oceanic basalts derived from zones that have undergone multistage histories. Therefore, we suggest that the potassic lavas with Sr 87 /Sr 86 higher than those of ocean ridge tholeiites and many island basalts represent the least depleted or most primitive mantle sampled by young oceanic volcanism.

Bulletin of the Geological Society of America

Sr87/Sr86 ratios of Quaternary lavas of the Cascade Range, northern California

Quaternary lavas from Mount Lassen, Mount Shasta, and Medicine Lake, which range in composition from olivine basalt to rhyolite, have Sr 87 /Sr 86 values that fall between 0.7030 and 0.7043, corrected to 0.7080 for the Eimcr and Amend (MIT) SrCO 3 standard. These values are very close to average (corrected) strontium isotopic values of some other circum-Pacific volcanic suites and of lavas of oceanic islands. The low ratios suggest a mantle origin. The notably high strontium content (1400 ppm) in the andesites from Mount Shasta also indicates a mantle origin at depths where plagioclase is absent as a stable phase in the residual material.

California