Geology topics

Zachary Shephard

Publications and source records attributed to Zachary Shephard.

3 recordsLinked to original sources

USGS2026

Using sediment chemical fractions and multivariate statistics on water to identify sources, mobility, and bioavailability of aluminum in the Florida River near Durango, Colorado

The Florida River in southwestern Colorado, USA, flows through the Southern Ute Reservation and is a cultural and water resource to Tribal and non-Tribal communities. High concentrations of total Al, up to 16 400 µg l –1 , have been detected in the Florida River. Elevated Al concentrations in water may affect aquatic organisms’ ability to regulate ions and inhibit respiratory functions. Water chemistry collected during three sampling events in 2022 from the Florida River and two of its tributaries are used here to better understand the spatial distribution, seasonality, and sources of Al concentrations in the Florida River. Streambed sediment and rock chemistry is also used to infer geologic sources of Al in the watershed. A five-stage sequential extraction was performed on streambed sediment and rock samples to help determine Al transport processes. We assessed relations between major and trace elements in water using a principal component analysis, finding that high Al concentrations in the Florida River (>3500 µg l –1 total Al) are caused by the erosion of Al-laden sediments. We used a stepwise multiple linear regression to investigate the relationship between land use and Al concentrations. Land use did not reliably predict Al concentration, though increased streamflow connected to reservoir releases – particularly in the Salt Creek tributary – were found to contribute Al to the Florida River during the irrigation season. In this study, we demonstrate that successful metal source appropriation may be achieved through limited field sampling when performed with sufficient water chemistry analysis, sequential chemical extraction of stream sediments, and statistical and land-use analysis.

Colorado↗

USGS2025

Tracking the sources of metals to the San Juan River, Four Corners Region, USA: An introduction to the thematic issue

Surface water quantity and quality is important for arid and semi-arid regions where many people, including underserved and Indigenous communities, rely on a scarce resource for drinking water, irrigation, livestock and ceremonial uses. The southwestern United States, and specifically the Four Corners Region (Colorado, Arizona, New Mexico and Utah), is an example of this situation. Elevated concentrations of metals including aluminium, arsenic and lead were identified in previous studies and this study in the San Juan River from below the Navajo Dam, through the Navajo Nation to Mexican Hat, Utah. An interdisciplinary team applied approaches and principles of geology, geochemistry, geomorphology, hydrology and statistics to gain a better understanding of the tributaries supplying the source(s) of metals to the San Juan River. This introductory paper provides an overview of the ‘Metal geochemical fingerprinting to identify sub-watershed source contributions to surface water at a regional arid watershed scale, Four Corners Region, USA’ thematic collection . An overview of sampling sites, techniques and potential sources of metals is provided. Approaches used in this study could be applied to investigations in similar systems globally.

Four Corners region↗

USGS2025

Morphometric and geological characterization with statistical correlations for 33 tributary drainage basins of the San Juan River watershed in the Four Corners region, USA

Basin morphometry, climate and geology control how a hydrological network evolves over time, controlling the efficiency of weathering of elements from geological materials, and ultimately the input of sediment and dissolved constituents to river systems. Exceedances to the Navajo Nation surface water quality standards for trace metals have been reported in the San Juan River watershed. Because metals are transported adsorbed to fine-grain sediment, the identification of areas with elevated sources of trace metals and/or areas with increased erosion and sediment transport potential is an important first step in protecting water quality. Physical factors such as elevation, slope, relief and stream order were used to quantify morphometric parameters that effect the contribution of trace metals into the stream network. By correlating these parameters with water quality data that were collected from tributaries along the San Juan River, we identified statistically significant regressions between morphometric parameters and total Al, Pb, U, Fe and Mn in surface water. Positive correlations with trace metals include tributary drainage basin perimeter, pour point elevation and total number of streams, while negative correlations include stream length ratio, ruggedness number and longest basin axis. Stream reach measurements within geological units that contain known trace metal constituents reveal that Gallegos Canyon and Desert Creek are the most susceptible to sediment mobilization and transport, while other tributary drainage basins, such as Desert, Recapture and Salt creeks, are associated with naturally elevated concentrations of Al, As, Pb and U.

Arizona, Colorado, New Mexico, Utah↗