Geology topics

Yi Fang

Publications and source records attributed to Yi Fang.

3 recordsLinked to original sources

USGS2022

Compression behavior of hydrate-bearing sediments

This work experimentally explores porosity, compressibility, and the ratio of horizontal to vertical effective stress ( K 0 ) in hydrate-bearing sandy silts from Green Canyon Block 955 in the deep-water Gulf of Mexico. The samples have an in situ porosity of 0.38 to 0.40 and a hydrate saturation of more than 80%. The hydrate-bearing sediments are stiffer than the equivalent hydrate-free sediments; the K 0 stress ratio is greater for hydrate-bearing sediments relative to the equivalent hydrate-free sediments. The porosity decreases by 0.01 to 0.02 when the hydrate is dissociated at the in situ effective stress. We interpret that the hydrate in the sediment pores is a viscoelastic material that behaves like a fluid over experimental time scales, yet it cannot escape the sediment skeleton. During compression, the hydrate bears a significant fraction of the applied vertical load and transfers this load laterally, resulting in the apparent increased stiffness and a larger apparent K 0 stress ratio. When dissociation occurs, the load carried by the hydrate is transferred to the sediment skeleton, resulting in further compaction and a decrease in the lateral stress. The viewpoint that the hydrate is a trapped viscous phase provides a mechanism for how stiffness and stress ratio ( K 0 ) are greater when hydrate is present in the porous media. This study provides insight into the initial stress state of hydrate-bearing reservoirs and the geomechanical evolution of these reservoirs during production.

Louisiana↗

USGS2022

Permeability of methane hydrate-bearing sandy silts in the deep-water Gulf of Mexico (Green Canyon Block 955)

Permeability is one of the most crucial properties governing fluid flow in methane hydrate reservoirs. This paper presents a comprehensive permeability analysis of hydrate-bearing sandy silt pressure-cored from Green Canyon Block 955 (GC 955) in the deep-water Gulf of Mexico. We developed an experimental protocol to systematically characterize the transport and petrophysical properties in pressure cores. The in situ effective permeability ranges from 0.1 md (1.0 × 10 −16 m 2 ) to 2.4 md (2.4 × 10 −15 m 2 ) in these natural sandy silts cores with hydrate occupying 83%–93% of the pore space. When hydrate dissociates from these cores, the measured intrinsic permeability ( k 0 ) is 0.3 md (3.0 × 10 −16 m 2 ) to 9.3 md (9.3 × 10 −15 m 2 ); these results are affected by fines migration during hydrate dissociation. We analyzed samples reconstituted from these sandy silts and found k 0 to range from ∼12 md (∼1.2 × 10 −14 m 2 ) to ∼41 md (∼4.1 × 10 −14 m 2 ). The water relative permeabilities ( k rw ) of GC 955 pressure cores are large relative to other natural pressure cores from offshore Japan, offshore India, and onshore Alaska. These k rw values are also higher than predicted by current conceptual relative permeability models where hydrate fills the pores or coats the grains of the sediments. This fundamental conundrum requires further study. Our work provides essential parameters to reservoir simulation models seeking to predict hydrate formation in geological systems, evaluate the gas production potential, and explore the best way to produce this energy resource in sandy silt reservoirs.

Louisiana↗

USGS2015

Uranium Sequestration During Biostimulated Reduction and In Response to the Return of Oxic Conditions In Shallow Aquifers

A proposed approach for groundwater remediation of uranium contamination is to generate reducing conditions by stimulating the growth of microbial populations through injection of electron donor compounds into the subsurface. Sufficiently reducing conditions will result in reduction of soluble hexavalent uranium, U(VI), and precipitation of the less soluble +4 oxidation state uranium, U(IV). This process is termed biostimulated reduction. A key issue in the remediation of uranium (U) contamination in aquifers by biostimulated reduction is the long term stability of the sequestered uranium. Three flow-through column experiments using aquifer sediment were used to evaluate the remobilization of bioreduced U sequestered under conditions in which biostimulation extended well into sulfate reduction to enhance precipitation of reduced sulfur phases such as iron sulfides. One column received added ferrous iron, Fe(II), increasing production of iron sulfides, to test their effect on remobilization of the sequestered uranium, either by serving as a redox buffer by competing for dissolved oxygen, or by armoring the reduced uranium. During biostimulation of the ambient microbial population with acetate, dissolved uranium was lowered by a factor of 2.5 or more with continued removal for over 110 days of biostimulation, well after the onset of sulfate reduction at ~30 days. Sequestered uranium was essentially all U(IV) resulting from the formation of nano-particulate uraninite that coated sediment grains to a thickness of a few 10’s of microns, sometimes in association with S and Fe. A multicomponent biogeochemical reactive transport model simulation of column effluents during biostimulation was generally able to describe the acetate oxidation, iron, sulfate, and uranium reduction for all three columns using parameters derived from simulations of field scale biostimulation experiments. Columns were eluted with artificial groundwater at equilibrium with atmospheric oxygen to simulate the upper limit of dissolved oxygen in recharge water. Overall about 9% of total uranium removed from solution during biostimulation was remobilized. Release of U during oxic elution was a continuous process over 140 days with dissolved uranium concentrations about 0.2 and 0.8 aM for columns with and without ferrous iron addition, respectively. Uranium remaining on the sediment was in the reduced form. The prolonged period of biostimulation and concomitant sulfate reduction appears to limit the rate of U(IV) oxidative remobilization in contrast to a large release observed for columns in previous studies that did not undergo sulfate reduction. Although continued sulfate reduction may cause decreased permeability from precipitation of iron sulfide, the greater apparent stability of the sequestered U(IV) provided by the sustained biostimulation should be considered in design of field scale remediation efforts. Remobilization of uranium following biostimulated reduction should be tested further at the field scale.

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