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William P. Leeman

Publications and source records attributed to William P. Leeman.

3 recordsLinked to original sources
USGS2015

Tracing chlorine sources of thermal and mineral springs along and across the Cascade Range using halogen and chlorine isotope compositions

In order to provide constraints on the sources of chlorine in spring waters associated with arc volcanism, the major/minor element concentrations and stable isotope compositions of chlorine, oxygen, and hydrogen were measured in 28 thermal and mineral springs along the Cascade Range in northwestern USA. Chloride concentrations in the springs range from 64 to 19,000 mg/L and View the MathML source values range from +0.2‰ to +1.9‰ (average=+1.0±0.4‰), with no systematic variation along or across the arc, nor correlations with their presumed underlying basement lithologies. Additionally, nine geochemically well-characterized lavas from across the Mt. St. Helens/Mt. Adams region of the Cascade Range (Leeman et al., 2004 and Leeman et al., 2005) were analyzed for their halogen concentrations and Cl isotope compositions. In the arc lavas, Cl and Br concentrations from the volcanic front are higher than in lavas from the forearc and backarc. F and I concentrations progressively decrease from forearc to backarc, similar to the trend documented for B in most arcs. View the MathML source values of the lavas range from −0.1 to +0.8‰ (average = +0.4±0.3‰). Our results suggest that the predominantly positive View the MathML source values observed in the springs are consistent with water interaction with underlying 37Cl-enriched basalt and/or altered oceanic crust, thereby making thermal spring waters a reasonable proxy for the Cl isotope compositions of associated volcanic rocks in the Cascades. However, waters with View the MathML source values >+1.0‰ also suggest additional contributions of chlorine degassed from cooling magmas due to subsurface vapor–liquid HCl fractionation in which Cl is lost to the aqueous fluid phase and 37Cl is concentrated in the ascending magmatic HCl vapor. Future work is necessary to better constrain Cl isotope behavior during volcanic degassing and fluid–rock interaction in order to improve volatile flux estimates through subduction zones.

Cascade Range↗
USGS2005

Petrologic constraints on the thermal structure of the Cascades arc

Primitive late Cenozoic basaltic lavas from the Cascades volcanic arc near latitude 46°N comprise two distinct compositional groups. Group I includes samples with low Ba/Nb (<20) and other compositional similarities to oceanic island and MORB lavas from within-plate settings. In contrast, Group II exhibits enrichment of Ba and large-ion lithophile elements (LILE) and depletion of Nb and high-field strength elements (HFSE) as seen commonly in calcalkalic lavas from other volcanic arcs. Lavas of both groups are widely distributed across the transect, and Group I lavas are found as much as 30–40 km trenchward of stratovolcanoes that define the High Cascades ‘volcanic front (VF)’. The most primitive lavas are sparsely porphyritic, have elevated Ni, Cr, and Mg#, high calculated magmatic temperatures (1200–1300 °C), and lack evidence of shallow (crustal level) storage and crystallization. Compositions of parental liquids were calculated for each primitive sample on the premise of Fe–Mg equilibrium with mantle peridotite. Assuming that such magmas ascended rapidly from accumulation zones in the mantle, we estimate P and T of segregation. We infer that (a) Group I magmas ascended from systematically greater depths (∼50–70 km) than Group II (∼30–50 km), implying the possible existence of compositional stratification in the mantle wedge; (b) Group I basalts show the least evidence for slab-derived contributions in their sources despite their apparently greater segregation depths (approaching the locus of the Cascadia slab beneath the frontal arc region); (c) Group II lavas with the strongest slab compositional signature have temperatures far exceeding the wet peridotite solidus at high pressure; and (d) the inferred thermal structure of the mantle wedge is very warm, implying a significant component of mantle upwelling and convection. Group I lavas are interpreted as decompression melts from this mantle, and their compositions suggest that their source was little modified by slab-derived contributions. We speculate that melting to produce Group II magmas occurs in the shallow mantle, possibly in response to heating by hot ascending Group I magmas. If true, it seems unlikely that the slab-like signal in Group II lavas can be attributed to modern slab inputs; rather, we postulate that this signature may reflect melting of lithospheric mantle domains containing a ‘stored’ slab-derived component inherited from earlier stages of Cascadia subduction. This scenario differs from the standard paradigm for subduction zones (SZs), and stresses the importance of convecting asthenospheric mantle in driving arc magmatism, particularly in warm subduction zones where slab fluid contributions likely are minimal. In contrast, because tectonic conditions in more typical volcanic arcs favor subduction of cooler, less dehydrated oceanic lithosphere, slab-derived fluids may promote extensive flux-melting in the wedge. Such melts may dominate the magmatic output and mask wedge contributions. The Cascade arc thus provides rarely afforded insights into arc magma genesis.

British Columbia, California, Oregon, Washington↗
USGS1983

Oxygen and strontium isotopic studies of basaltic lavas from the Snake River plain, Idaho

The Snake Creek-Williams Canyon pluton of the southern Snake Range crops out over an area of about 30 km2, about 60 km southeast of Ely, Nev. This Jurassic intrusion displays large and systematic chemical and mineralogical zonation over a horizontal distance of 5 km. Major-element variations compare closely with Dalyls average andesite-dacite-rhyolite over an SiO2 range of 63 to 76 percent. For various reasons it was originally thought that assimilation played a dominant role in development of the Snake Creek-Williams Canyon pluton. However, based on modeling of more recently obtained trace element and isotopic data, we have concluded that the zonation is the result of in-situ fractional crystallization, with little assimilation at the level of crystallization. This report summarizes data available for each of the mineral species present in the zoned intrusion. Special attention has been paid to trends We present oxygen and strontium isotopic data for olivine tholeiites, evolved (that is, differentiated and (or) contaminated) lavas, rhyolites, and crustal- derived xenoliths from the Snake River Plain. These data show that the olivine tholeiites are fairly uniform in d80 (5.1 to 6.2) and 87Sr/86Sr (0.7056 to 0.7076) and reveal no correlation between these ratios. The tholeiites are considered representative of mantle-derived magmas that have not interacted significantly with crustal material or meteoric water. The evolved lavas display a wider range in d 80 (5.6 to 7.6) and 87Sr/86Sr (0.708 to 0.717) with positive correlations between these ratios in some suites but not in others. Crustal xenoliths have high and variable 8?Sr/86Sr (0.715 to 0.830) and d80 values that vary widely (6.7 to 9.2) and are a few permil greater than d80 values of the Snake River basalts. Thus, isotopic data for the evolved lavas are permissive of small degrees of contamination by crustal rocks similar to the most d80-depleted xenoliths. The d80 enrichments in some evolved lavas also are consistent with crystal fractionation processes and do not necessarily require bulk interaction with crustal rocks. Enrichment in d80 but not in 87Sr/86Sr in one suite of evolved lavas suggests that crustal contamination may not be essential to the petrogenesis of those lavas. Other suites of evolved lavas display large variations in 87Sr/86Sr that reflect at least some selective contamination with 87St. Bulk solid/liquid oxygen-isotope fractionation factors (a's) calculated for the evolved lavas from Craters of the Moon National Monument are comparatively large. These a's are dependent upon the nature and proportions of phases removed by crystal fractionation; basaltic lava a's differ from latitic lava a?s in accordance with different phenocryst assemblages in these rocks. Snake River Plain rhyolites are isotopically distinct from both the analyzed crustal xenoliths and olivine tholeiites. Their origin remains poorly understood, but crustal or sub-crustal sources may be viable. In the first case, they must be derived by anatexis of material distinct from the analyzed crustal xenoliths. In the second case, they must be derived from material unlike the source for tholeiites. No cogenetic relation with the tholeiites seems likely on the basis of available data. that might relate to the variation in the chemical petrology of the pluton.

Open-File Report↗