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William M. Kappel

Publications and source records attributed to William M. Kappel.

At least 19 recordsLinked to original sources

Hydrogeology and water quality of the unconsolidated aquifer system in the lower Fall Creek valley, Tompkins County, New York

The U.S. Geological Survey, in cooperation with Tompkins County and the Town of Dryden, conducted a hydrogeologic investigation of the lower Fall Creek unconsolidated aquifer system in Tompkins County, New York. This study is part of an ongoing effort to characterize major valley-fill aquifers in the region to support sustainable groundwater management. The lower Fall Creek valley, encompassing the Village of Freeville, the unincorporated communities of Etna, and the hamlets of McLean and Varna, has experienced moderate development and relies heavily on groundwater for residential, agricultural, and commercial use. The study area spans approximately 51 square miles along the boundary of the Allegheny Plateau and North Rim of the Allegheny Plateau physiographic provinces. The aquifer system, composed primarily of glacially derived sand and gravel deposits, includes both unconfined and confined aquifer units. For the approximately 2,300 people who live over the aquifers, groundwater is the sole source of drinking water. In some areas, such as the Village of Freeville, artesian conditions exist, with potentiometric heads exceeding 25 feet above land surface. This report describes the hydrogeologic framework, aquifer distribution, groundwater-flow dynamics, and water quality of the lower Fall Creek aquifer system. Groundwater is generally hard and contains elevated concentrations of redox-sensitive constituents, such as iron and manganese relative to U.S. Environmental Protection Agency secondary maximum contaminant levels. Arsenic was not detected above the U.S. Environmental Protection Agency maximum contaminant level during this study but remains a regional concern due to past detections in the study area and nearby aquifers. The findings provide data for local planners and resource managers to use in understanding and protecting this water resource.

New York↗

Hydrogeology and water quality of the unconsolidated aquifer system in the Lower Fall Creek Valley, Tompkins County, New York

The U.S. Geological Survey, in cooperation with Tompkins County and the Town of Dryden, conducted a hydrogeologic investigation of the lower Fall Creek unconsolidated aquifer system in Tompkins County, New York. This study is part of an ongoing effort to characterize major valley-fill aquifers in the region to support sustainable groundwater management. The lower Fall Creek valley, encompassing the Village of Freeville, the unincorporated communities of Etna, and the hamlets of McLean and Varna, has experienced moderate development and relies heavily on groundwater for residential, agricultural, and commercial use. The study area spans approximately 51 square miles along the boundary of the Allegheny Plateau and North Rim of the Allegheny Plateau physiographic provinces. The aquifer system, composed primarily of glacially derived sand and gravel deposits, includes both unconfined and confined aquifer units. For the approximately 2,300 people who live over the aquifers, groundwater is the sole source of drinking water. In some areas, such as the Village of Freeville, artesian conditions exist, with potentiometric heads exceeding 25 feet above land surface. This report describes the hydrogeologic framework, aquifer distribution, groundwater-flow dynamics, and water quality of the lower Fall Creek aquifer system. Groundwater is generally hard and contains elevated concentrations of redox-sensitive constituents, such as iron and manganese relative to U.S. Environmental Protection Agency secondary maximum contaminant levels. Arsenic was not detected above the U.S. Environmental Protection Agency maximum contaminant level during this study but remains a regional concern due to past detections in the study area and nearby aquifers. The findings provide data for local planners and resource managers to use in understanding and protecting this water resource.

EarthArXiv↗

Hydrogeology of the Tully Valley and characterization of mudboil activity, Onondaga County, New York

Mudboil activity in the Tully Valley, in central New York, is causing turbidity in nearby Onondaga Creek, where it has caused a bridge to collapse; it also has threatened or damaged other structures and has caused extensive land subsidence. Mudboil activity was intermittent from its first reported appearance in the 1890's until the 1970's, when the rates of mudboil discharge and land subsidence began to increase. Historically, the water discharged from mudboils was reported as fresh, but chemical analyses in the late 1970's indicated an increase in specific conductance and chloride concentration. Mudboil discharge is driven by artesian pressure in unconsolidated sediments that are confined by a 60-foot layer of silt and red clay. This process, once begun, has been self-propagating. Artesian pressures are about 20 feet above land surface over most of the valley floor but exceed 30 feet above land surface along Onondaga Creek where Rattlesnake Gulf and Rainbow Creek enter the Tully Valley. The source of artesian pressure is recharge from the Tully (Valley Heads) Moraine at the south end of the valley, and the alluvial fans of Rattlesnake Gulf and Rainbow Creek. The mudboils are found within a 300-foot-wide by 1,500-foot-long corridor along Onondaga Creek just upstream from the two alluvial fans, and in a 5-acre subsided area just west of that corridor. Remediation efforts have entailed (1) diversion of flow from the tributary that feeds the subsided area, (2) installation of depressurizing wells at several locations, and (3) construction of a dam and settling impoundment to detain mudboil sediment that would normally discharge to Onondaga Creek. These efforts have been partly successful, but further work is needed to slow the mudboil activity, which is expected to persist in both areas. Mudboil activity is normally greatest during the early spring and late fall, when artesian pressures increase in response to seasonal ground-water recharge. Suspended-sediment concentrations at the out-flow of the subsidence area ranged from 31,210 mg/L (milligrams per liter) in October 1991 to 17 mg/L after remediation efforts in the summer of 1993. Yearly average suspended-sediment loads to Onondaga Creek from the subsidence area for water years 1992, 1993, 1994, and 1995 were 29.8, 9.75, 1.41, and 1.80 tons per day, respectively. Sediment discharged from the mudboils initially was 30 to 60 percent clay and 80 to 100 percent silt-sized or smaller sediment, and the sand fraction never exceeded 20 percent. After the remediation projects, 50 to 80 percent was clay, and nearly all sediment was silt size or smaller. Analyses of water from upstream and downstream of the subsidence area, as well as from mudboil vents within that area, indicate that the source of water for some mudboils is a confined freshwater aquifer, whereas for others it is an underlying, brackish-water aquifer. Water from the freshwater aquifer has specific conductance values ranging from about 400 ( μS /cm (microsiemens per centimeter at 25° Celsius) to almost 900 ( μS /cm, dissolved chloride concentrations range from 37 to 430 mg/L, and dissolved-solids concentrations range from 215 to 463 mg/L. Specific conductance of water from the brackish-water aquifer ranges from 17,000 to 28,000 ( μS /cm, chloride concentrations range from 2,000 to 7,100 mg/L, and dissolved-solids concentrations range from 4,200 to 12,800 mg/L. The largest landslide in New York State in the last 75 years occurred at the foot of Bare Mountain, 1 mile downstream from the mudboil area, in April 1993 and was the fourth in a series of slides that have occurred at the base of this hill. Slope instability was reported as early as May 1990. After the slide, intermittent mudboil-like activity was observed at several springs within the backscarp of the slide; water from these springs ranged from fresh to brackish. The chemical similarity between water from some springs in the backscarp area and water in the lower (brackish) aquifer beneath the mudboil area may indicate a hydraulic connection between this aquifer and the surficial deposits. Hydrologic changes in the valley during the last 100 years have been attributed to salt-solution mining in the upstream (southern) end of the valley. The removal of nearly 150 feet of salt from four evaporite beds in the Syracuse Shale of the Salina Group has caused the collapse of bedrock and unconsolidated deposits in and near the brine field, 3 miles south of the mudboil area. These collapses have created a hydraulic connection among bedding plane aquifers in the bedrock and increased the hydraulic connection with unconsolidated aquifers. The ground-water flow system after brine field closure in 1988 may have reached a new semiequilibrium, but mudboil activity will likely continue because artesian pressures remain. Whether mudboils were present before salt solution-mining began is unknown.

New York↗

Shallow hydrogeologic framework of the Tully Valley mudboil area, Onondaga County, New York

Mudboils have been documented in the Tully Valley in southern Onondaga County, New York, since the late 1890s. Sediment-laden water from the mudboils flows into Onondaga Creek, which empties into Onondaga Lake at Syracuse 15 miles to the north. Turbidity from the mudboils has degraded the water quality of Onondaga Creek despite a series of mitigation efforts that began in the early 1990s. Turbidity mitigation actions presently (2025) being considered include creek relocation and offline sediment settling. In support of these proposed actions during 2021–23, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, U.S. Environmental Protection Agency, Onondaga Nation, Onondaga Environmental Institute, and Central New York Regional Planning and Development Board, collected and analyzed geologic, hydrologic, geophysical, and geotechnical data to characterize the shallow hydrogeology along four proposed creek-relocation paths and in the proposed offline settling basin area. The investigation indicated that the four proposed creek-relocation paths, two east of Onondaga Creek and two west of Onondaga Creek, are underlain by sediments including muck, alluvium, mudboil deposits, alluvial-fan sand and gravel, and lacustrine fines. The proposed excavations would penetrate partially to fully saturated conditions: generally, the water table is shallow near the creek and deep on the alluvial fans. The shallowest excavation, about 5 feet below land surface, would be near the creek and primarily in alluvium, and the deepest excavation, as much as 30 feet below land surface, would be in the alluvial-fan deposits. Brackish waters would be penetrated by proposed channel excavations on the eastern side of Onondaga Creek in an area downgradient from a potentially leaking historical salt-exploration borehole and near the main mudboil area. Excavation in these areas likely would provide a continuous source of brackish groundwater to the relocated creek. Proposed channel excavations of muck, soft to very soft lacustrine fines, and mudboil-type sediments in mudboil and suspected mudboil areas would pose an excavation and slope stability challenge and would have the greatest potential to create new mudboils. Proposed channel excavations below the water table on the Rattlesnake Gulf and Rainbow Creek alluvial fans would intercept groundwater and make the constructed streambank susceptible to seepage-induced slope instability. The substantial water-level fluctuation in the sediments of both alluvial fans would aggravate the stability condition. In addition, excavation on the Rattlesnake Gulf alluvial fan would have the potential to affect water-supply springs at the toe of the fan. The proposed offline settling basin area is in the northern part of the Rattlesnake Gulf alluvial fan. Natural and man-made diversions of Rattlesnake Gulf have resulted in saturated conditions in the general area of the proposed basin. The proposed offline settling basin would be excavated in, and berms would be constructed on, alluvial-fan deposits and lacustrine fines. In the proposed basin area, the alluvial deposits overlying the lacustrine fines are less than 10 feet thick. Excavation, berm construction, and loading of the saturated, soft to very soft lacustrine fines may be problematic and require soil strengthening.

New York↗

Hydrogeologic framework and considerations for drilling and grouting of closed-loop geothermal bores in the Erie-Ontario Lowlands and Allegheny Plateau of New York State

The hydrogeologic framework at closed-loop geothermal sites in the Erie-Ontario Lowlands and Allegheny Plateau of central and western New York is the result of the complex interaction of bedrock geology, glacial geology, and groundwater hydrology, and the occurrence of petroleum and gas. Considerations for closed-loop geothermal bore installation include the thickness and character of glacial deposits, bedrock solubility and depth to competent rock, karst development, the distribution of highly permeable zones and their hydraulic heads, and the presence of saline water, gas, and oil. The hydrogeology of the Erie-Ontario Lowlands and Allegheny Plateau poses challenges to closed-loop geothermal bore drilling and casing; managing drill cuttings, discharge water, and gas; and grouting. The potential to encounter severe challenges typically increases with bore depth. This report highlights hydrogeologic considerations for closed-loop geothermal bore installation in New York’s Erie-Ontario Lowlands and Allegheny Plateau to help guide the efficient and safe development of geothermal resources in the regions.

New York↗

Monitoring and simulation of hydrology, suspended sediment, and nutrients in selected tributary watersheds of Lake Erie, New York

The U.S. Geological Survey, in cooperation with Erie County, New York, the New York State Department of Environmental Conservation, and the Great Lakes Restoration Initiative, collected water-quality samples in nine selected New York tributaries to Lake Erie, computed estimates of suspended sediment and nutrient loads using the R scripting package rloadest and used the Soil and Water Assessment Tool (SWAT) to simulate hydrology and suspended sediment and nutrient loads from these tributaries. This project was undertaken to better understand the water quality of New York’s inputs into eastern Lake Erie. Water-quality samples for suspended sediment, nitrogen, and phosphorus were collected at 19 sampling sites in the Lake Erie Basin in New York. Daily and monthly suspended sediment and nutrient loads were computed with regressions of streamflow and suspended sediment and nutrient concentrations using rloadest. SWAT models of nine watersheds were created using publicly available data; and the loads calculated by rloadest. Twenty-six SWAT model scenarios were created to explore the effects that best management practices (BMPs; 21 scenarios), point source discharges (4 scenarios), and green infrastructure (1 scenario) can have on the water quality of the nine tributaries to Lake Erie. BMP scenarios for the watershed models included combinations of agricultural BMPs applied at varying implementation levels across the study watersheds, including cover crops, reduced tillage, nutrient management plans, and filter strips. The BMP scenarios showed small reductions of total nitrogen and total phosphorus. The scenarios have variable suspended sediment load results, with both increases and decreases of sediment modeled. The point source scenarios result in lower total phosphorus loads. The green infrastructure scenario shows only minimal reduction of suspended sediment and nutrient loads from the Buffalo River watershed but shows substantial reductions locally.

New York↗

Geohydrology and water quality of the northern and central parts of the Tug Hill glacial aquifer, Jefferson and Oswego Counties, north-central New York

The northern and central parts of the Tug Hill glacial aquifer consist of a 29-mile-long, crescent-shaped, mixture of glaciofluvial, glaciolacustrine, and recent alluvial deposits of predominantly sand and gravel on the western side of the Tug Hill Plateau in Jefferson and Oswego Counties in north-central New York. Approximately 11,400 people are supplied by groundwater that is withdrawn from municipal and nonmunicipal wells in the northern and central parts of the aquifer. In addition, many farms, several industries, and a large New York State fish hatchery also rely on the water from the aquifer. In the early 2000s, anticipated developmental pressures from potential new industries (including a proposed water-bottling plant in the central part of the Tug Hill glacial aquifer) and expansion of the Fort Drum military base north of Watertown (with the projected increase in population extending into the northern part of the aquifer) prompted the Tug Hill Commission, local municipal officials, and representatives from the New York State Department of Environmental Conservation to initiate a geohydrologic study with the U.S. Geological Survey. The information from this study is intended to help the state, counties, and local communities make sound policy decisions about their use of this large groundwater resource. The northern part of the Tug Hill glacial aquifer is a combination of glaciofluvial outwash and alluvial sand and gravel in the Sandy Creek Valley northeast of Adams, New York, and mostly glaciolacustrine beach and deltaic sand or sand and gravel north and south of the village of Adams. The southern and eastern areas of the central part of the aquifer are composed mostly of glaciofluvial sediments such as kames, kame moraines, and kame terraces, whereas most of the western areas of the central part are composed mostly of glaciolacustrine sediments such as deltaic sand and beach sand and gravel. The northern and central parts of the aquifer are unconfined. Recharge to the northern and central parts of the aquifer is from three main sources: (1) precipitation that falls directly onto the aquifer; (2) unchannelized runoff (overland flow) and groundwater from till and bedrock in the Tug Hill Plateau that seeps into the eastern side of the aquifer; and (3) streams that drain the Tug Hill Plateau and flow across and lose water to the aquifer. Groundwater discharges to springs, seeps, headwaters of streams, and wetlands in the middle area of the central part of the aquifer and along the entire western boundary of the northern and central parts of the aquifer; pumping wells; artificial ditches; and deeply incised streams in the northern and central parts of the aquifer. The groundwater discharge to such streams is critical in supporting the salmonid fishery in the central part of the aquifer. Groundwater levels were measured on July 17, 2014, at 22 wells throughout the northern and central parts of the aquifer. Water-table contours were drawn on the basis of the measured July 2014 water levels, historical water-level data, and surface-water levels where surface water in the channels was expected to be hydraulically connected to the groundwater system. The water table generally slopes from east to west throughout the northern and central parts of the aquifer; this slope also indicates that the direction of groundwater flow is generally from east to west. Water-quality samples were collected from 23 stream sites during base-flow conditions, and groundwater-quality and other types of environmental samples were collected from 20 wells in the northern and central parts of the Tug Hill glacial aquifer. The results of the sampling indicate that surface water and groundwater are generally of good quality. Comparison of the median concentration values of major ions in groundwater samples indicated that hardness in the northern part of the aquifer was about twice as great, and concentrations of calcium and sodium were more than three times as great, as in the central part of the aquifer. As was the case with surface water, the much greater median concentrations in groundwater of calcium, hardness, and alkalinity in the northern part of the aquifer are due to the dissolution of limestone that underlies most of that area and to the high-carbonate content of the clasts in the sand and gravel. There was little to no difference among the median values for bromide, fluoride, silica, and iron in the two parts of the aquifer. Concentrations of most other major ions were slightly greater in the northern part than in the central part of the Tug Hill glacial aquifer, except for magnesium, whose concentration was greater in the central part. Median concentrations of nutrients were generally greatest in surface water and groundwater in the northern part of the aquifer.

New York↗

Incorporating snowmelt into daily estimates of recharge using a state-space model of infiltration

A state-space model (SSM) of infiltration estimates daily groundwater recharge using time-series of groundwater-level altitude and meteorological inputs (liquid precipitation, snowmelt, and evapotranspiration). The model includes diffuse and preferential flow through the unsaturated zone, where preferential flow is a function of liquid precipitation and snowmelt rates and a threshold rate, above which there is direct recharge to the water table. Model parameters are estimated over seasonal periods and the SSM is coupled with the Kalman Filter (KF) to assimilate recent observations (hydraulic head) and meteorological inputs into recharge estimates. The approach can take advantage of real-time hydrologic and meteorological data to deliver real-time recharge estimates. The model is demonstrated on daily observations from two bedrock wells in carbonate aquifers of northwestern New York (USA) between 2013 and 2018. Meteorological inputs for liquid precipitation and snowmelt are compiled from SNODAS (2021). Results for recharge during winter and spring seasons show preferential flow events to the water table from liquid precipitation, snowmelt, or a combination of the two. Recharge estimates summed annually are consistent with previous estimates of recharge reported from groundwater flow and surface-process models. Results from the SSM and KF point to errors in meteorological inputs, such as the snowmelt rate, that are not compatible with hydraulic head observations. Whereas liquid and solid precipitation are measured at discrete stations and extrapolated to 1-km 2 grid cells, snowmelt is a meteorological modeled outcome that may not represent conditions in the vicinity of monitoring well locations.

Groundwater↗

Methods of data collection and analysis for an assessment of karst aquifer systems between Albany and Buffalo, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, catalogued aquifers and closed depressions in a karst-prone area between Albany and Buffalo, New York to provide resource managers information to more efficiently manage and protect groundwater resources. The New York State Department of Environmental Conservation has been working with the agricultural industry to raise awareness of karst aquifer contamination susceptibility and how to reduce effects on surface water and groundwater resources, especially in karst areas. There is also a need to make industries, State and local regulators, planners, and the public aware of New York’s karst resources to properly protect and manage these resources and the quality of surface water and groundwater that flows through the karst aquifer. Publicly available geospatial data were identified, collated, and analyzed for a region of karst terrain extending from Albany to Buffalo. The region was divided into 10 subareas. A series of geospatial datasets were assembled to determine the location and extent of karstic rock; bedrock geology and depth to bedrock; average water-table configuration; surficial geology; soil type, thickness, and hydraulic conductivity; land cover; and closed depressions in the land surface. Repeated glaciation and recession across New York have left the landscape pockmarked with closed depressions, which may or may not be related to the underlying bedrock. Closed depressions in areas where carbonate or evaporite karst are present are of primary concern to this study because of the increased potential of karst aquifer contamination from focused recharge. Closed depressions present in areas not associated with karst bedrock can also be evaluated to better understand their ability to transmit surface water to the groundwater system. Information on closed depressions can be used to develop land-management plans to protect local and regional water resources.

New York↗

Geohydrology and water quality of the stratified-drift aquifers in West Branch Cayuga Inlet and Fish Kill Valleys, Newfield, Tompkins County, New York

From 2011 to 2016, the U.S. Geological Survey, in cooperation with the Town of Newfield and the Tompkins County Planning Department, performed a study of the stratified-drift aquifers in the West Branch Cayuga Inlet and Fish Kill Valleys in Newfield, Tompkins County, New York. Both confined and unconfined aquifers were identified, mostly in the valleys. The confined aquifer consists of a discontinuous sand and gravel layer that overlies bedrock and is commonly confined by overlying fine-grained sediments. The unconfined aquifer consists of surficial ice contact sand and gravel, alluvial silt, sand and gravel, and areas where several large tributary streams deposited alluvial fans in the valley, all of which were deposited during and after the last glacial recession. The unconfined aquifers are primarily recharged by direct infiltration of precipitation at the land surface, by surface runoff and shallow subsurface flow from adjacent hillsides, and by seepage loss from streams crossing the aquifer, especially on alluvial fans. The confined aquifers are primarily recharged by groundwater stored in the overlying sand and gravel aquifer that slowly seeps downward through the underlying confining layer. Other sources of recharge are precipitation that falls directly on the surficial confining unit and adjacent valley walls, which then slowly seeps downward and enters the confined aquifer, and groundwater flow from bordering till and bedrock and from bedrock below the valley. There may also be some recharge where confining units are absent or where parts of the confining units contain sediments with moderate permeability. The groundwater naturally discharges to the Fish Kill and West Branch Cayuga Inlet streams and to wetlands overlying the aquifer boundaries, with additional losses due to evapotranspiration. Groundwater is pumped from the aquifers by domestic, municipal, and agricultural wells. Approximately 57.9 million gallons per year was withdrawn from the stratified-drift (sand and gravel) aquifers. Groundwater samples were collected from 11 wells, and surface water samples were collected at 2 sites, one each from Fish Kill and West Branch Cayuga Inlet. None of the common ions (for example, sodium, chloride, and magnesium) exceeded existing drinking water standards at either surface water site. The concentration of nitrate plus nitrite detected was 0.4 milligram per liter as nitrogen in the West Branch Cayuga Inlet site. Total phosphorus was detected at 0.01 milligram per liter as phosphate for both sites. Of the 11 wells sampled, 8 were finished in confined sand and gravel aquifers, 1 was finished in unconfined sand and gravel, and 2 were finished in shale bedrock. Groundwater quality in the study area generally met Federal and State drinking-water standards. However, of the 11 samples taken, 2 exceeded the U.S. Environmental Protection Agency drinking water advisory taste threshold of 20 milligrams per liter for sodium, 8 exceeded the secondary maximum contaminant level of 300 micrograms per liter for iron, and 9 exceeded the secondary maximum contaminant level of 50 micrograms per liter for manganese.

New York↗

Time-domain electromagnetic soundings and passive-seismic measurements for delineation of saline groundwater in the Genesee Valley-fill aquifer system, western New York, 2016–17

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, used noninvasive surface geophysics in the investigation of the distribution of saline groundwater in the valley-fill aquifer system of the Genesee River Valley near the former Retsof salt mine in western New York. In 1994, the Retsof salt mine, the largest of its kind in the western hemisphere, underwent a catastrophic roof collapse that resulted in groundwater inflow from the valley-fill aquifer system and bedrock fracture zones into the mine through two bedrock-rubble chimneys and the subsequent dissolution and filling of the mine with saturated brine. Since the early 2000s, except for a period of remedial pumping in 2006 to 2013, high-salinity water has migrated upward through the rubble chimneys into the basal part the aquifer system. The extent of saline-water migration within the aquifer system had not been evaluated since the end of remedial pumping when all the monitoring wells were grouted shut and abandoned. Installation of a monitoring-well network would be expensive and difficult given the thickness and heterogeneous character of valley fill. An investigation of the current extent of saline water in the aquifer system was warranted because the basal part of the aquifer is shallow to the north and it is used for water supply. In fall 2016 and fall 2017, the U.S. Geological Survey collected time-domain electromagnetic soundings at 105 sites along 13 cross-valley transects north and south of the mine-collapse area, east of Piffard, and on the Fowlerville Moraine. The time-domain electromagnetic soundings were colocated with passive-seismic measurements to estimate the bedrock-surface elevation through use of a regression equation developed from measurements at well sites with reported bedrock depths in the study area. An integrated analysis of the time-domain electromagnetic soundings with the depth-to-bedrock estimates, well logs, and past chloride-monitoring data suggests the presence of a zone of high electrical conductivity associated with saline water in the confined lower part of the valley-fill aquifer system. This high-salinity zone delineated in the lower confined aquifer extends from the mine-collapse area northward for more than 2.5 miles (4.0 kilometers). The chloride concentration in groundwater within this high-conductivity zone may be about 20,000 milligrams per liter. Saline water flowing upward through the bedrock-rubble chimneys and mixing with northward groundwater flow in the lower confined aquifer likely is a major source of chlorides for this high-conductivity zone. The northern extent of the zone is unclear because of the presence of highly saline water zones that were delineated by time-domain electromagnetic soundings in the lower confined aquifer and uppermost bedrock and are probably associated with historic salt-solution wells in Piffard or possibly sourced from natural brine pools.

New York↗

Statewide assessment of karst aquifers in New York with an inventory of closed-depression and focused-recharge features

Karst is a landscape formed from the dissolution of soluble rock or rock containing minerals that are easily dissolved from within the rock. The landscape is characterized by sinkholes, caves, losing streams, springs, and underground drainage systems, which rapidly move water through the karst. The two forms of karst in New York State include carbonate karst, which forms in carbonate rock (limestone, marble, and dolostone), and evaporite karst, which forms in rock that contains the evaporite minerals gypsum and halite. Past and recent studies of karst across the State have shown that areas of focused recharge in karstic carbonate rock allow contaminants to enter aquifer systems with little attenuation. Focused areas of recharge need to be identified to help prevent such contamination from sources on or adjacent to the karst. The New York State Departments of Environmental Conservation and Health are collaborating with the agricultural community to make farmers and farm-planning advisors more aware of karst and how to manage daily farming activities to reduce their impact on surface water and groundwater resources, especially in karst areas. There is also a need to make regulators, planners, and the general public aware of New York’s karst resources and to properly protect and manage these resources to protect the quality of groundwater and surface water that can flow into, through, and from karst bedrock. Using publicly available geospatial data, karst bedrock and closed depressions over or near karst rock were identified across New York. Carbonate, evaporite, and marble geologic units were selected from a statewide 1:250,000-scale bedrock geology dataset. The selected geologic units were intersected with 7.5-minute quadrangle maps to define the study area. The U.S. Geological Survey has compiled an inventory of closed depressions from statewide digital contour data, scanned 7.5-minute topographic maps known as a digital raster graphics, and light detection and ranging (lidar) digital elevation models. Analysis of the data resulted in the identification of 5,023 closed depressions statewide. The inventory was conducted to eliminate duplication of results from analysis of the three data sources. A series of overlay analyses was conducted using the closed depressions and thematic data known to be key factors in determining the probability of a closed depression contributing to focused groundwater recharge; the thematic data include bedrock geology, soil type, soil infiltration rate, and land cover. Though the extent of karst development is important in understanding the interaction between surface water and groundwater in karst terrains, some of the worst cases of groundwater contamination in karst can occur where only minor karst features might be present. The presence of karst—be it a short section of a solutioned fracture or an extensive cave system—requires careful consideration, forward-looking environmental planning, and consistent water-quality protection to preserve New York State’s water resources.

New York↗

Geohydrology and water quality of the unconsolidated aquifers in the Enfield Creek Valley, town of Enfield, Tompkins County, New York

From 2013 to 2018, the U.S. Geological Survey, in cooperation with the Town of Enfield and the Tompkins County Planning Department, studied the unconsolidated aquifer in the Enfield Creek Valley in the town of Enfield, Tompkins County, New York. The valley will likely undergo future development as the population of Tompkins County increases and spreads out from the metropolitan areas. The Town of Enfield, Tompkins County, and the New York State Departments of Health and Environmental Conservation need geohydrologic information to help planners develop a more comprehensive approach to water-resource management in Tompkins County. The Enfield Creek Valley is underlain by an unconfined aquifer that consists of saturated alluvium, alluvial-fan deposits, and ice-contact (kame) sand and gravel. A confined aquifer of discontinuous ice-contact sand and gravel overlies bedrock. Depth to bedrock in the valley ranges from about 50 feet below land surface from just north of the Enfield Creek divide in the northern part of the aquifer to the confluence of Fivemile Creek to at least 140 feet below land surface from Fivemile Creek to where the valley orientation changes from north-south to northwest-southeast. Depth to bedrock is much shallower from the valley orientation change to the southeastern part of the aquifer because Enfield Creek has carved through overlying sediments into bedrock as the creek drops 450 feet into the Cayuga Inlet Valley. A small buried valley running south to north was identified within the Fivemile Creek drainage along the western edge of the town. However, the valley fill consists of glacial till, and no sand-and-gravel aquifer is present. The unconfined aquifers are recharged by direct infiltration of precipitation, surface runoff, and shallow subsurface flow from hillsides, and by seepage loss from streams overlying the aquifer. The confined aquifers are recharged mostly by precipitation that enters the adjacent valley walls, by groundwater flowing from bordering till or bedrock, and by flow from the bottom of the valley. Also, some recharge may be occurring where confining units are absent or from confining units with sediments of moderate permeability. Groundwater discharges to Enfield Creek, its tributaries, and wetlands and is lost through evapotranspiration from the water table or is withdrawn from domestic, commercial, and agricultural wells. About 700 individual well owners depend on the unconsolidated aquifers for their water supply. An estimated 28,300,000 gallons per year are withdrawn. Groundwater samples were collected from eight test wells drilled for this study, and six surface-water samples were collected from five locations on Enfield Creek. Of the eight wells sampled, two were finished in unconfined sand-and-gravel aquifers, two were finished in confined sand-and-gravel aquifers, and four were finished at or near the shale bedrock surface. Water quality in the study area generally met State and Federal drinking-water standards. However, some samples exceeded maximum contaminant levels for barium (25 percent of samples) and secondary maximum containment levels for chloride (25 percent), dissolved solids (25 percent of samples), iron (70 percent of samples), and manganese (75 percent of samples). Groundwater from 75 percent of the wells sampled for methane had concentrations greater than the Office of Surface Mining Reclamation and Enforcement recommended action level of 10 to 28 milligrams per liter. The two deepest wells sampled, TM1075 and TM1077, had the highest specific conductance, chloride, and sodium concentrations of all wells sampled. The chloride/bromide ratios of these samples suggest the source may represent a mixture of saline formation waters with shallow dilute groundwater and may receive recharge contribution from two tributaries overlying bedrock to the west and southwest of the aquifer. In general, the highest yields are from wells completed within about 50 feet below land surface, which may tap either type of aquifer.

New York↗

Time-domain electromagnetic soundings for the delineation of saline groundwater in the Genesee River Valley, Western New York, 2016-2017

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, is investigating the distribution of saline groundwater in the Genesee River Valley near the former Retsof salt mine (fig. 1). As part of this study, paired time-domain electromagnetic (TEM) soundings and horizontal-to-vertical spectral ratio (HVSR) seismic soundings were made at 39 locations during the fall of 2016 to determine the presence of saline groundwater and depth to the bedrock surface, respectively. All measurement sites were west of Geneseo, New York, on the Genesee River valley floor north and south of the sinkhole area that developed as a result of the roof collapse and flooding of the Retsof mine in 1994 (fig. 1). An integrated analysis of the TEM and HVSR soundings with borehole logs, coupled with groundwater-sample data from previous investigations, allowed the delineation of zones of high electrical conductivity associated with saline water in the lower part of the valley fill and underlying bedrock to depths greater than 1,000 feet (ft). This article describes the TEM sounding method and its application in the ongoing investigation, presents results of the TEM analysis at two of the sounding sites, and identifies proposed sites for additional TEM/HVSR sounding data collection during the fall of 2017. Supporting data for this study are available in a separate data release (Johnson and others, 2017).

New York↗

Hydrogeology of the Owego-Apalachin Elementary School geothermal fields, Tioga County, New York

The hydrogeology of the Owego-Apalachin Elementary School geothermal fields, which penetrate saline water and methane in fractured upper Devonian age bedrock in the Owego Creek valley, south-central New York, was characterized through the analysis of drilling and geophysical logs, water-level monitoring data, and specific-depth water samples. Hydrogeologic insights gained during the study proved beneficial for the design of the geothermal drilling program and protection of the overlying aquifer during construction, and may be useful for the development of future geothermal fields and other energy-related activities, such as drilling for oil and natural gas in similar fractured-bedrock settings. The southwest geothermal field consists of 204 closed-loop wells that penetrate a major saline water-bearing zone associated with bedding-plane fractures near the middle of an interbedded sandstone and shale interval at depths of 238 to 263 feet below land surface (ft bls). The northeast geothermal field consists of 80 closed-loop wells that penetrate a major saline water-bearing zone associated with bedding-plane fractures near the base of the interbedded sandstone and shale interval at depths of 303 to 323 ft bls. Transmissivity estimates for the major saline water-bearing fractured zones range from 735 to 3,400 feet squared per day. The saline water-bearing zone in the southwest field is hydraulically connected over a horizontal distance of at least 350 feet. The hydraulic connection between subhorizontal, stacked bedding-plane fractures is limited by the number and transmissivity of interspersed higher angle fractures; locally, greater stratigraphic separation results in reduced connectivity to a greater degree than does horizontal distance. The specific conductance of the saline water from the shallower fractured zone in the southwest field was about 16,000 microsiemens per centimeter at 25 degrees Celsius (μS/cm at 25°C), and that from the fractured zone in the northeast field was about 65,000 μS/cm at 25°C. The saline waters were characterized by a chemical composition similar to that of deep formation brines collected from oil and gas wells in the Appalachian Basin. About 40 percent of the geothermal wells discharged methane gas to land surface during and (or) following drilling. Sandstone beds at depths of 348 to 378 ft bls are the likely source of the methane gas, which was determined to be early thermogenic in origin.

New York↗

Hydrogeology of the Susquehanna River valley-fill aquifer system in the Endicott-Vestal area of southwestern Broome County, New York

The village of Endicott, New York, and the adjacent town of Vestal have historically used groundwater from the Susquehanna River valley-fill aquifer system for municipal water supply, but parts of some aquifers in this urban area suffer from legacy contamination from varied sources. Endicott would like to identify sites distant from known contamination where productive aquifers could supply municipal wells with water that would not require intensive treatment. The distribution or geometry of aquifers within the Susquehanna River valley fill in western Endicott and northwestern Vestal are delineated in this report largely on the basis of abundant borehole data that have been compiled in a table of well records. Early in deglaciation, meltwater deposited sand and gravel in channels within or beneath the decaying ice and as narrow terraces along the valley walls. These ice-contact deposits vary widely over short distances from clean (free of silt) and highly permeable to clogged with silt and poorly permeable, but collectively constitute the principal aquifers in Endicott and Vestal. Some ice-contact deposits form a buried ridge, deposited in a meltwater channel within the ice sheet, that approximately underlies the Susquehanna River and (or) its north bank from Endwell westward to Nanticoke Creek and has been tapped by several municipal and industrial wells. Similar but thinner ice-contact deposits discontinuously underlie the valley floor to the south in Vestal, and a smaller buried ridge of ice-contact deposits is likely beneath or west of Nanticoke Creek south of West Corners. As deglaciation continued, a large lake developed; thick deposits of gray silt with red clay layers are continuous north of the Susquehanna River from Endwell to West Endicott, and similar deposits are present discontinuously elsewhere. Late in deglaciation, meltwater deposited highly permeable pebbly sand atop the valley fill, generally atop lacustrine silt. The saturated thickness of this surficial sand is seldom great enough to support large-capacity wells, but where it directly overlies ice-contact deposits it facilitates recharge from precipitation and infiltration of river water to the deeper aquifers. Three localities in Endicott were identified where thick ice-contact deposits capable of supporting municipal supply wells are documented by test wells or extrapolated to be present from nearby data and depositional history. Chemical analyses of water samples disclosed no contaminants in these localities when sampled, but the presence of contaminants or natural high iron a few thousand feet away from each locality is documented.

New York↗

Assessment of surface water chloride and conductivity trends in areas of unconventional oil and gas development — Why existing national data sets cannot tell us what we would like to know

Heightened concern regarding the potential effects of unconventional oil and gas development on regional water quality has emerged, but the few studies on this topic are limited in geographic scope. Here we evaluate the potential utility of national and publicly available water-quality data sets for addressing questions regarding unconventional oil and gas development. We used existing U.S. Geological Survey and U.S. Environmental Protection Agency data sets to increase understanding of the spatial distribution of unconventional oil and gas development in the U.S. and broadly assess surface water quality trends in these areas. Based on sample size limitations, we were able to estimate trends in specific conductance (SC) and chloride (Cl − ) from 1970 to 2010 in 16% ( n = 155) of the watersheds with unconventional oil and gas resources. We assessed these trends relative to spatiotemporal distributions of hydraulically fractured wells. Results from this limited analysis suggest no consistent and widespread trends in surface water quality for SC and Cl − in areas with increasing unconventional oil and gas development and highlight limitations of existing national databases for addressing questions regarding unconventional oil and gas development and water quality.

Water Resources Research↗

Natural heat storage in a brine-filled solar pond in the Tully Valley of central New York

The Tully Valley, located in southern Onondaga County, New York, has a long history of unusual natural hydrogeologic phenomena including mudboils (Kappel, 2009), landslides (Tamulonis and others, 2009; Pair and others, 2000), landsurface subsidence (Hackett and others, 2009; Kappel, 2009), and a brine-filled sinkhole or “Solar pond” (fig. 1), which is documented in this report. A solar pond is a pool of salty water (brine) which stores the sun’s energy in the form of heat. The saltwater naturally forms distinct layers with increasing density between transitional zones (haloclines) of rapidly changing specific conductance with depth. In a typical solar pond, the top layer has a low salt content and is often times referred to as the upper convective zone (Lu and others, 2002). The bottom layer is a concentrated brine that is either convective or temperature stratified dependent on the surrounding environment. Solar insolation is absorbed and stored in the lower, denser brine while the overlying halocline acts as an insulating layer and prevents heat from moving upwards from the lower zone (Lu and others, 2002). In the case of the Tully Valley solar pond, water within the pond can be over 90 degrees Fahrenheit (°F) in late summer and early fall. The purpose of this report is to summarize observations at the Tully Valley brine-filled sinkhole and provide supplemental climate data which might affect the pond salinity gradients insolation (solar energy).

New York↗