Geology topics
Publications and source records attributed to William H. Craddock.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean conventional resources of 96 trillion cubic feet of gas in the Northern Alaska Province.
The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean conventional resources of 12 million barrels of oil and 184 billion cubic feet of gas in the Buda Limestone of Texas.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean resources of 5 million barrels of oil and 25 billion cubic feet of gas in conventional reservoirs and 361 million barrels of oil and 10,978 billion cubic feet of gas in continuous reservoirs in the Western Gulf Basin Province of the U.S. Gulf Coast region.
Using a geology-based assessment methodology, the U.S. Geological Survey (USGS) estimated undiscovered, technically recoverable mean resources of 16 million barrels of oil and 348 billion cubic feet of gas in conventional reservoirs of the Norphlet Formation in the U.S. Gulf Coast region.
The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.
Detrital zircon data from modern barrier island and estuarine environments in the Outer Banks (Atlantic Coast, USA) were statistically compared to sands from nearby rivers to assist in determining source-to-sink pathways. Fluvial samples, collected from near the Fall Line contact between the Appalachian Orogen and sediments of the coastal plain, all have age unique distributions, making them ideal for tracing provenance. Three samples from the Atlantic foreshore showed high similarities to one another, as well as to three samples from the estuarine (back-barrier) Pamlico and Albemarle Sounds. Mixture modeling with multiple data reduction methods and three different statistical tests for similarity consistently indicated that the nearby Potomac River was the primary source for all Atlantic foreshore and estuarine zircons, followed by minor contributions from the James River in some models. The models indicate little or no sediment contribution from the Susquehanna, Roanoke, Tar, Neuse, Cape Fear, and Peedee Rivers. Both Atlantic foreshore and estuarine sands are therefore interpreted to have initially originated from Appalachian bedrock to the north of their present-day location, and subsequently to have been transported southward through the Chesapeake Bay watershed before deposition in Virginia and North Carolina. Prior to barrier island formation in the last several thousand years, differing geomorphology of the Chesapeake Bay facilitated southward movement of sediments from its constituent rivers via longshore drift, where they were deposited in coastal settings on the mainland. The modern barrier islands, formed during the most recent post-glacial transgression, may be reworked from these deposits, but may also include a contribution from sediments that were derived more recently from relict deposits on the shelf. Oceanographic and sedimentological evidence suggests that movement of sand-sized grains from southern rivers across the back-barrier sounds is unlikely. These findings can assist with coastal resilience planning and resource management in a region under severe threat from climate change and rising sea levels.
Fluvial sediments are the product of erosion, weathering, and transport of bedrock within a well-defined catchment area, and their constituent grains may therefore record valuable information about the lithological and geochemical properties of geologic units within the upstream drainage. Analysis of U-Pb ages and Lu/Hf isotopic values in detrital zircon grains from major rivers in the eastern USA characterizes these parameters within broad areas of the Appalachian orogen. In this study, five modern fluvial sediment samples, collected across ~1500 km and representing 216,000 km2 of total catchment area, reveal that the relative proportions of Mesoproterozoic to Paleozoic U-Pb crystallization ages vary widely across the former Laurentian margin. However, εHft values in the same samples are largely consistent regardless of their geographic location. Mesoproterozoic (Grenville orogen) zircons display a more limited range of εHft values (approximately 0 to +10 εHft units) compared to the more negative, more variable values (-15 to +10) found in grains from the Paleozoic orogenies. When compared to other published modern detrital samples from the Gulf Coastal Plain, Appalachian samples show more similarity to each other and to the Pleistocene of Florida than to those from the Mississippi River mouth, likely because the latter also sources sediments from the Cordillera of western North America. More negative εHft values in Paleozoic zircons may be genetically related to older Mesoproterozoic grains, as they are compatible with the continued isotopic evolution of Lu/Hf derived from the mantle between 1.2 and 2.0 Ga. Hafnium geochemistry in detrital grains may therefore have some utility in discerning sediment provenance between the Appalachians and other regions, and may also provide useful information regarding the nature of crustal generation through time.
Although the Atlantic continental margin of the eastern United States is an archetypal passive margin, episodes of rejuvenation following continental breakup are increasingly well documented. To better constrain this history of rejuvenation along the southern portion of this continental margin, we present zircon U-Pb (ZUPb) age, zircon fission-track (ZFT) age, apatite U-Pb (AUPb) age, and apatite fission-track (AFT) age and length data from six bedrock samples. The samples were collected along the boundary between the exposed Appalachian hinterland (Piedmont province) and the updip limit of passive margin strata (Coastal Plain province). The samples were collected from central Virginia southward to the South Carolina–Georgia border. ZUPb age distributions are generally consistent with geologic mapping in each of the sample areas. The AUPb data are highly discordant owing to high common-Pb abundances, but for two plutons at the northern and southern ends of the sample area, they define a discordia regression line that indicates substantial Permo-Triassic exhumation-driven cooling. ZFT age distributions are highly dispersed but define central values ranging from Permian to Jurassic. AFT data mostly appear to define a singular underlying cooling age, generally approximately Jurassic or Early Cretaceous. Apatite fission tracks are moderately long (mean lengths in the range of ~13.5 µm), however track lengths for one sample in central North Carolina are shorter (~12.5 µm). To interpret the post-breakup thermal history, we present inverse models of time-temperature history for the five plutonic samples. The models show a history of (1) rapid cooling (>10 °C/m.y.) from deep-crustal to near-surface temperatures by the Triassic, (2) hundreds of degrees of Triassic reheating, (3) Jurassic–Early Cretaceous cooling (at rates of 1–10 °C/m.y.), and (4) slow Late Cretaceous–Cenozoic cooling (~1 °C/m.y.). An additional suite of forward models is presented to further evaluate the magnitude of maximum Triassic reheating at one sample site that is particularly well constrained by thermal maturity data. The model results and geologic reasoning suggest that the inverse models may overestimate Triassic paleotemperatures but that other aspects of the inverse modeling are robust. Overall, this thermal history can be reconciled with several aspects of the lithostratigraphy of distal parts of the continental margin, including the lack of Jurassic–earliest Cretaceous strata beneath the southern Atlantic coastal plain and Cretaceous–Cenozoic grain-size trends.
Chemically, petroleum is an extraordinarily complex mixture of different types of hydrocarbons that are now possible to isolate and identify because of advances in geochemistry. Here, we use biomarkers and carbon isotopes to establish genetic differences and similarities among oil samples. Conventional approaches for evaluating biomarker and carbon isotope relative abundances include statistical techniques such as principal component and cluster analysis. Considering that proportions of the different hydrocarbon molecules are relative parts of a laboratory sample, the data are compositional in nature, thus requiring the use of log-ratio approaches for adequate mathematical modeling. We apply both traditional and compositional modeling approaches to crude oil samples from an onshore area of about 50,000 square miles in southeast Texas. The data comprise 177 crude oil samples from producing oil fields that include key biomarkers, elemental, and isotopic values commonly used in source rock correlation studies. Our results indicate that compositional modeling has higher discriminating power and lower uncertainty than the traditional approach, allowing the identification of up to 16 clusters. Each cluster represents one oil family from a source rock organofacies ranging from Carboniferous to Paleogene. The families provide new insights into important petroleum systems in the Texas onshore region of the Gulf of Mexico sedimentary basin.
Geological carbon sequestration (GCS) is necessary to help meet emissions reduction goals, but groundwater contamination may occur if CO 2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of southwest Utah, water with moderate salinity and high CO 2 concentrations is leaking upward into shallow aquifers that contain heavy metal-bearing concretions. The aquifer system is comprised of the Navajo and Kayenta formations, which are pervasive across southern Utah and have been considered as a potential GCS injection unit where they are sufficiently deep. Numerical models of the site were constructed based on measured water chemistry and head distributions from previous studies. Simulations were used to improve understanding of the rate and distribution of the upwelling flow into the aquifers, and to assess the reactive transport processes that may occur if the upwelling fluids were to interact with a zone of iron oxide and other heavy metals, representing the concretions that are common in the area. Various mineralogies were tested, including one in which Pb +2 was adsorbed onto ferrihydrite, and another in which it was bound within a solid mixture of litharge (PbO) and hematite (Fe 2 O 3 ). Results indicate that metal mobilization depends strongly on the source zone composition and that Pb +2 transport can be naturally attenuated by gas phase formation and carbonate mineral precipitation. These findings could be used to improve risk assessment and mitigation strategies at geological carbon sequestration sites.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated a mean of 1,407 billion (1.4 trillion) cubic feet of gas in conventional accumulations in Upper Devonian to Lower Cretaceous strata of the western North Slope, Alaska.
Recently reported detrital zircon (DZ) data help to associate the Paleogene strata of the Gulf of Mexico region to various provenance areas. By far, recent work has emphasised upper Paleocene-lower Eocene and upper Oligocene strata that were deposited during the two episodes of the highest sediment supply in the Paleogene. The data reveal a dynamic drainage history, including (1) initial routing of western Cordilleran drainages towards the Gulf of Mexico in the Paleocene, (2) an eastward shift of the western continental divide, from the Jura-Cretaceous cordilleran arc to the eastern edge of the Laramide province after the Paleocene and (3) a southward shift, along the eastern Laramide province, of the headwaters of river systems draining to the Mississippi and Houston embayments at some time between the early Eocene and Oligocene. However, DZ characterisation of most (~20 Myr) of the middle Eocene-lower Oligocene section remains limited. We present 60 DZ age spectra, most of which are from the middle or upper Eocene outcrop belts, with 50–200-km spacing. We define six to eight distinct groups of DZ age spectra for middle and upper Eocene strata. Data from this and other studies resolve at least six substantial temporal changes in age spectra at various positions along the continental margin. The evolving age spectra constrain the middle and upper Eocene drainage patterns of large parts of interior North America. The most well-resolved aspects of these drainage patterns include (1) persistent rivers that flowed from erosional landscapes across the Paleozoic Appalachian orogen either into the low-lying Mississippi embayment or directly into the eastern Gulf; (2) at least during marine regressions, a trunk channel that likely flowed southward along the axial part of Mississippi Embayment and integrated tributaries from the east and west; and (3) rivers that flowed to the Houston embayment in the middle Eocene that likely originated in the Laramide province in central Colorado and southern Wyoming, as Precambrian basement highs in those source areas were being unroofed.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean resources of 3.6 billion barrels of oil and 8.9 trillion cubic feet of natural gas (associated and nonassociated) in conventional accumulations in Mississippian through Paleogene strata in the central North Slope of Alaska.
We report data for 112 apatite and 31 zircon fission track (AFT and ZFT) outcrop sandstone samples along a transect that spans the western Brooks Range. Sampling targeted structures that modify the Middle Jurassic‐Early Cretaceous early Brookian orogen. The AFT samples record latest Cretaceous to Eocene in situ exhumational cooling and resolve two kinematic phases. The first phase was focused at 65–60 Ma. To the north, cooling age patterns at this time are attributable to wide‐spaced fault‐related folding. Farther south, within the allochthon belt, exhumation was related to uplift of a broad region, likely in the hanging wall of deep‐seated faults that extend into basement rocks. The second kinematic phase occurred around ~45 Ma. It was characterized by north and east directed thrusting to the north, and coeval extension in the allochthon belt to the south. The ZFT cooling ages are all Early Cretaceous or older and put an upper limit on the magnitude of Cenozoic exhumation across the western Brooks Range. Synthesis of exhumation patterns and structural styles show that Paleocene rejuvenation of contraction was roughly contemporaneous along the entire ~1,000‐km orogen. Later, around ~45 Ma in the Eocene, contraction in the frontal parts of the orogen was contemporaneous with extension interior to the orogen. Following previous authors, we suggest that the Paleocene rejuvenation was a far‐field response to subduction of a mid‐ocean ridge in southern Alaska. However, by the Eocene, strain patterns in the western Brooks Range changed, possibly to accommodate rotations of fault blocks in southwestern Alaska.
This chapter presents information pertinent to the geologic carbon dioxide (CO 2 ) sequestration potential within saline aquifers located in the Atlantic Coastal Plain and Eastern Mesozoic Rift Basins of the Eastern United States. The Atlantic Coastal Plain is underlain by a Jurassic to Quaternary succession of sedimentary strata that onlap westward onto strata of the Appalachian Piedmont physiographic province and generally thicken eastward toward the present-day Atlantic coastline and onto the present-day continental shelf. Although no significant petroleum discoveries have been made on the coastal plain, the deep saline aquifers of the region appear to contain porous strata (potential reservoirs, or “storage formations”) that are overlain by fine-grained, laterally continuous strata (potential seals), which are prospective CO 2 sequestration targets. For the Atlantic Coastal Plain, we identify two storage assessment units (SAUs), both of which consist of Cretaceous strata. The two SAUs are the Lower Cretaceous Composite SAU C50700101 and the Upper Cretaceous Composite SAU C50700102. The Eastern Mesozoic Rift Basins are a chain of generally southwest- to northeast-trending, elongate sedimentary basins that either underlie the Atlantic Coastal Plain or crop out within adjacent geologic provinces to the west. Similar to the Atlantic Coastal Plain, there has been no significant oil and gas production from any of the basins, although there is a proven petroleum system in several of them. At least three of these basins appear to contain potential storage formations overlain by potential seal units. Most of the other basins were not assessed because a storage and (or) seal formation could not be established in the timeframe of the assessment, often because of the paucity of subsurface data for these basins in comparison to other petroliferous basins of the United States. Thus, we present information supporting one quantitative assessment in the Newark basin, as well as information supporting two nonquantitative assessments, one for strata in the Gettysburg basin and the other for strata in the Culpeper basin. We briefly discuss six other basins within the Eastern Mesozoic Rift Basins that were not assessed. For all SAUs, we discuss the areal distribution of suitable CO 2 reservoir rock. We also describe the overlying sealing unit and the geologic characteristics that influence the potential CO 2 storage volume and reservoir characteristics. These characteristics include storage formation depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this chapter, the geologic information included herein was used to calculate the potential storage space in the SAUs.
Using a geology-based assessment methodology, the U.S. Geological Survey assessed mean undiscovered, technically recoverable continuous resources of 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas in the Upper Cretaceous Tuscaloosa marine shale in onshore and State waters of Louisiana, Mississippi, Alabama, and Florida in the U.S. Gulf Coast region.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable conventional resources of 100 million barrels of oil and 16.5 trillion cubic feet of gas in the downdip Paleogene formations in onshore lands and State waters of the U.S. Gulf Coast region.