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William C. Evans

Publications and source records attributed to William C. Evans.

At least 19 recordsLinked to original sources

Geochemistry and fluxes of gases from hydrothermal features at Newberry Volcano, Oregon, USA

We present the chemical and isotopic compositions of gases and fluxes of CO 2 from the hydrothermal features of Newberry Volcano, a large composite volcano located in Oregon's Cascade Range with a summit caldera that hosts two lakes, Paulina and East Lakes. Gas samples were collected from 1982 to 2021 from Paulina Hot Springs (PHS) on the shore of Paulina Lake, East Lake Hot Springs (ELHS) on the shore of East Lake, and Obsidian Flow Gas Seep (OFGS), an area of diffuse gas emissions. Surveys of CO 2 flux were conducted in 2020 at OFGS (1400 m 2 ) and East Lake (4.1 km 2 ). Gases from all three sites were CO 2 -rich (≥79 mol% in dry gas) but showed considerable compositional variability over time due to interaction with ground and surface water. An increase in H 2 S concentrations and decline in CO 2 /H 2 S ratios in ELHS gases coincided with a drop in East Lake water level from 1999 to 2021. ELHS and OFGS gases were high in CH 4 relative to PHS and the δ 13 C of CH 4 values for ELHS gases (−72.2 and − 63.6 ‰) reflected a predominantly biogenic origin. The dominant source of N 2 and Ar in PHS, ELHS, and OFGS samples was likely groundwater. Helium isotopic ratios (6.47 to 8.02 R c /R a ) support a persistent source of magmatic He beneath Newberry caldera and consistently high values measured at OFGS and PHS relative to ELHS suggest distinct fluid flow paths from depth to the surface features. The δ 13 C of CO 2 and CO 2 / 3 He values (−8.9 to −5.35 ‰ and 1.3 × 10 9 to 4.6 × 10 10 , respectively) measured in gases reflect contributions of CO 2 from both mantle and crustal sources. Measured CO 2 fluxes at OFGS and East Lake ranged from 1 to 8808 and < 1 to 364 g m −2 d −1 , respectively. A CO 2 emission rate of 0.5 t d −1 was calculated for OFGS. The CO 2 emission rate estimated for East Lake was 30 t d −1 and when compared to prior estimates, reflects steady-state lake degassing. An enhanced geochemical monitoring plan, including annual sampling of gases at ELHS, OFGS, and PHS for geochemical analysis, installation of a continuous lake-level monitoring station at East Lake, and annual CO 2 flux surveys at OFGS, would provide valuable background data and insights into any precursor volcanic activity. Integrating geochemical data with data from the real-time seismic and GPS network at Newberry Volcano could better resolve and interpret potential changes in its magma-hydrothermal system.

Oregon

Groundwater dynamics at Kīlauea Volcano and vicinity, Hawaiʻi

Kīlauea Volcano, on the Island of Hawaiʻi, is surrounded and permeated by active groundwater systems that interact dynamically with the volcanic system. A generalized conceptual model of Hawaiian hydrogeology includes high-level dike-impounded groundwater, very permeable perched and basal aquifers, and a transition (mixing) zone between freshwater and saltwater. Most high-level groundwater is associated with the low-permeability intrusive complexes that underlie volcanic rift zones and calderas and also act to compartmentalize the groundwater system. Hydrogeologic studies of Kīlauea in recent decades, accompanied by deep research drilling, have shown that high-level groundwater is more widespread than once understood, that permeability decreases dramatically at depth, particularly in rift zones, and that freshwater can occur at depths of as much as several kilometers below the local water table. Copious groundwater recharge causes near-surface conductive heat flow to be near zero over much of Kīlauea. Approximately 95 percent of groundwater discharge occurs offshore, accompanied by approximately 99 percent of the approximately 6,000 megawatts of heat supplied by magmatic intrusion. Here, we summarize current understanding of the groundwater system of Kīlauea Volcano and describe transient changes during the decade or more preceding the 2018 eruption sequence. The changes in groundwater chemistry and thermal structure beneath Kīlauea summit hold implications for volcanic-volatile transport and the potential for explosive volcanism. Between 2008 and 2018, the magma conduit beneath the lava lake likely created an adjacent zone of very hot rock that significantly delayed liquid groundwater inflow to the draining magma conduit. Sulfate concentrations in groundwater beneath Kīlauea summit, sampled at the National Science Foundation-funded drill hole 1.5 kilometers south-southwest of the lava lake, declined substantially between 2010 and present. This decline likely reflects, at least in part, the decreased effectiveness of volatile condensation and solution into groundwater (scrubbing). The vent opening in 2008 presumably focused volatile flux into the vicinity of the vent, and progressive drying of the surroundings further restricted interaction with the groundwater system. The decrease in sulfate concentrations in the drill hole between 2010 and 2018 likely reflects decreased effectiveness of scrubbing.

Hawaii

A post-eruption study of gases and thermal waters at Okmok Volcano, Alaska

We report here on the first focused study of gas discharges and thermal spring waters at Okmok Volcano since the 2008 phreatomagmatic eruptions. Results include the first compositional gas data from Okmok with minimal air contamination and the first data on magmatic carbon in Okmok spring waters. Chemical and isotopic analyses of the waters and gases are used to assess the character of Okmok fluids eight years after the eruptions ceased. Gases from vents on intracaldera Cone C have high concentrations of H2 and contain H2S rather than SO2, demonstrating the influence of a hydrothermal system, while isotope values of carbon ( 10.2 to 8.9‰) and helium (~8 RA) confirm the presence of magma-derived volatiles. Estimates of equilibrium temperatures for the Cone C gas are ~230 ± 30 ºC. A much cooler reservoir with a maximum temperature of ~55 ºC feeds the intracaldera warm springs. Based on discharge measurements of creeks draining the caldera, the total heat output of the warm springs is estimated to be about 32 MW. Gas data from a single location of steaming ground at the Geyser Bight geothermal area southwest of the Okmok Caldera are given. The gas is typical of geothermal gases with high concentrations of H2S and an air-corrected helium isotope ratio of 7.15 RA.

Alaska

Hydraulic, geochemical, and thermal monitoring of an aquifer system in the vicinity of Mammoth Lakes, Mono County, California, 2015–17

Since 2014, the U.S. Geological Survey has been working in cooperation with the Bureau of Land Management, Mono County, Ormat Technologies, Inc., and the Mammoth Community Water District to design and implement a groundwater-monitoring program for the proposed Casa Diablo IV Geothermal Power Project in Long Valley Caldera, California, to characterize baseline groundwater-level, water-temperature, and water-chemistry conditions at dedicated monitoring wells and municipal supply wells. The publicly available data and the analyses provided here represent quality-assured and peer-reviewed information to help with the management of the thermal and non-thermal water resources beneath and in the vicinity of the town of Mammoth Lakes, California. The methods of data collection for continuous water levels and quarterly water-temperature profiles for two 600-foot-deep monitoring wells during 2016 through 2017 are discussed. Also discussed are the methods of water-sample collection and characterizations of the water chemistry in numerous wells in the multilayered aquifer system beneath Mammoth Lakes. Additionally, the methodology used to develop digital (mathematical) filters to remove or reduce the effects of barometric pressure and solid Earth tides on the continuous water-level records is discussed. Digitally filtered water levels for a 2017 flow test of a deep geothermal production well are described, and various aquifer responses observed during the flow test are discussed. These are further considered in a companion evaluation of potential physical and chemical influences on the water-level data collected during the flow test. The digitally filtered water-level data indicated that some hydraulic communication exists between the deep geothermal aquifer and shallow groundwater aquifer at the location of the flow test, northeast of Mammoth Lakes. Groundwater-chemistry data from three wells indicated that shallow groundwater naturally mixes with a small component of geothermal water along the northern periphery of the shallow aquifer system at Mammoth Lakes.

California

Rate of magma supply beneath Mammoth Mountain, California based on helium isotopes and CO2 emissions

Mammoth Mountain, California, has exhibited unrest over the past ~30 years, characterized by seismicity over a broad range of depths, elevated 3 He/ 4 He ratios in fumarolic gas, and large-scale diffuse CO 2 emissions. This activity has been attributed to magmatic intrusion, but minimal ground deformation and the presence of a shallow crustal gas reservoir beneath Mammoth Mountain pose a challenge for estimating magma supply rate. Here, we use the record of fumarolic 3 He/ 4 He ratios and CO 2 emissions to estimate that of the ~5.2 Mt of CO 2 released from Mammoth Mountain between 1989 and 2016, 1.6 Mt was associated with active intrusion and degassing of ~0.05–0.07 km 3 of basaltic magma. Intrusion at an average rate of ~0.002–0.003 km 3 /year into a postulated zone of partial melt at ~15-km depth could occur without detection by local Global Navigation Satellite System stations.

California

Potential for increased hydrothermal arsenic flux during volcanic unrest: Implications for California water supply

The hydrothermal systems associated with the restless high-threat volcanoes at Lassen and Long Valley, California, each release large amounts of arsenic (As) to surface waters – ~6 and ~8 metric tons/yr, respectively. The hydrothermal As output can increase during volcanic unrest, as illustrated by a two-fold increase during unrest at Lassen in 2014–15. During that period of unrest, increased As concentrations and fluxes were measured up to 75 km downstream from the Lassen source, in Mill Creek near the confluence with the Sacramento River. In eastern California, the Long Valley hydrothermal system feeds into the Los Angeles Aqueduct (LAA), and the Los Angeles Department of Water and Power (LADWP) actively manages the LAA system to remove hydrothermal As. In 1980, during a series of ~ M w 6 earthquakes, the discharge of a particular group of hydrothermal vents in Long Valley increased approximately 7-fold, though the total increase in As flux to the LAA system at that time is unknown. The likely mechanism for increased hydrothermal discharge in each case is permeability enhancement due to strong ground motion. A review of the global literature on earthquake hydrology suggests a worst-case scenario of a roughly 10-fold increase in permeability, with commensurate increase in the hydrothermal As flux persisting for days to months. Here we evaluate the potential impact of such increases in hydrothermal As flux on the California water-supply system.

California

Hot water in the Long Valley Caldera—The benefits and hazards of this large natural resource

The volcanic processes that have shaped the Long Valley Caldera in eastern California have also created an abundant supply of natural hot water. This natural resource provides benefits to many users, including power generation at the Casa Diablo Geothermal Plant, warm water for a state fish hatchery, and beautiful scenic areas such as Hot Creek gorge for visitors. However, some features can be dangerous because of sudden and unpredictable changes in the location and flow rate of boiling water. The U.S. Geological Survey monitors several aspects of the hydrothermal system in the Long Valley Caldera including temperature, flow rate, and water chemistry.

California

Multi-year high-frequency hydrothermal monitoring of selected high-threat Cascade Range volcanoes

From 2009 to 2015 the U.S. Geological Survey (USGS) systematically monitored hydrothermal behavior at selected Cascade Range volcanoes in order to define baseline hydrothermal and geochemical conditions. Gas and water data were collected regularly at 25 sites on 10 of the highest-risk volcanoes in the Cascade Range. These sites include near-summit fumarole groups and springs/streams that show clear evidence of magmatic influence (high 3 He/ 4 He ratios and/or large fluxes of magmatic CO 2 or heat). Site records consist mainly of hourly temperature and hydrothermal-flux data. Having established baseline conditions during a multiyear quiescent period, the USGS reduced monitoring frequency from 2015 to present. The archived monitoring data are housed at (doi:10.5066/F72N5088). These data (1) are suitable for retrospective comparison with other continuous geophysical monitoring data and (2) will provide context during future episodes of volcanic unrest, such that unrest-related variations at these thoroughly characterized sites will be more clearly recognizable. Relatively high-frequency year-round data are essential to achieve these objectives, because many of the time series reveal significant diurnal, seasonal, and inter-annual variability that would tend to mask unrest signals in the absence of baseline data. Here we characterize normal variability for each site, suggest strategies to detect future volcanic unrest, and explore deviations from background associated with recent unrest.

California, Oregon, Washington

The saltiest springs in the Sierra Nevada, California

The five saltiest springs in the Sierra Nevada in California are found between 38.5° and 38.8° N. latitude, on the South Fork American River; on Caples Creek, a tributary of the Silver Fork American River; and on the North Fork Mokelumne River. The springs issue from Cretaceous granitic rocks in the bottoms of these major canyons, between 1,200- and 2,200-m elevation. All of these springs were well known to Native Americans, who excavated meter-sized basins in the granitic rock, within which they produced salt by evaporation near at least four of the five spring sites. The spring waters are dominated by Cl, Na, and Ca; are enriched relative to seawater in Ca, Li, and As; and are depleted in SO 4 , Mg, and K. Tritium analyses indicate that the spring waters have had little interaction with rainfall since about 1954. The waters are apparently an old groundwater of meteoric origin that resided at depth before moving up along fractures to the surface of the exhumed granitic rocks. However, along the way these waters incorporated salts from depth, the origin of which could have been either from marine sedimentary rocks intruded by the granitic magmas or from fluid inclusions in the granitic rocks. Prolonged storage at depth fostered water-rock interactions that undoubtedly modified the fluid compositions.

California

Groundwater resources of the Devils Postpile National Monument—Current conditions and future vulnerabilities

This study presents an extensive database on groundwater conditions in and around Devils Postpile National Monument. The database contains chemical analyses of springs and the monument water-supply well, including major-ion chemistry, trace element chemistry, and the first information on a list of organic compounds known as emerging contaminants. Diurnal, seasonal, and annual variations in groundwater discharge and chemistry are evaluated from data collected at five main monitoring sites, where streams carry the aggregate flow from entire groups of springs. These springs drain the Mammoth Mountain area and, during the fall months, contribute a significant fraction of the San Joaquin River flow within the monument. The period of this study, from fall 2012 to fall 2015, includes some of the driest years on record, though the seasonal variability observed in 2013 might have been near normal. The spring-fed streams generally flowed at rates well below those observed during a sequence of wet years in the late 1990s. However, persistence of flow and reasonably stable water chemistry through the recent dry years are indicative of a sizeable groundwater system that should provide a reliable resource during similar droughts in the future. Only a few emerging contaminants were detected at trace levels below 1 microgram per liter (μg/L), suggesting that local human visitation is not degrading groundwater quality. No indication of salt from the ski area on the north side of Mammoth Mountain could be found in any of the groundwaters. Chemical data instead show that natural mineral water, such as that discharged from local soda springs, is the main source of anomalous chloride in the monument supply well and in the San Joaquin River. The results of the study are used to develop a set of recommendations for future monitoring to enable detection of deleterious impacts to groundwater quality and quantity

California

Evidence for degassing of fresh magma during the 2004-2008 eruption of Mount St. Helens: Subtle signals from the hydrothermal system

Results from chemical and isotopic analyses of water and gas collected between 2002 and 2016 from sites on and around Mount St. Helens are used to assess magmatic degassing related to the 2004-2008 eruption. During 2005 the chemistry of hot springs in The Breach of Mount St. Helens showed no obvious response to the eruption, and over the next few years, changes were subtle, giving only slight indications of perturbations in the system. By 2010 however, water chemistry, temperatures, and isotope compositions (δD and δ 18 O) clearly indicated some inputs of volatiles and heat associated with the eruption, but the changes were such that they could be attributed to a pre-existing, gas depleted magma. An increase of ~ 1.5‰ in the δ 13 C values of dissolved carbon in the springs was noted in 2006 and continued through 2009, a change that was mirrored by a similar shift in δ 13 C-CO 2 in bubble gas emissions. These changes require input of a new source of carbon to the hydrothermal system and provide clear evidence of CO 2 from an undegassed body of magma. Rising trends in 3 He/ 4 He ratios in gas also accompanied the increases in δ 13 C. Since 2011 maximum R C /R A values are ≥ 6.4 and are distinctly higher than 5 samples collected between 1986 and 2002, and provide additional evidence for some involvement of new magma as early as 2006, and possibly earlier, given the unknown time needed for CO 2 and He to traverse the system and arrive at the springs.

Washington

Experimental studies and model analysis of noble gas fractionation in porous media

The noble gases, which are chemically inert under normal terrestrial conditions but vary systematically across a wide range of atomic mass and diffusivity, offer a multicomponent approach to investigating gas dynamics in unsaturated soil horizons, including transfer of gas between saturated zones, unsaturated zones, and the atmosphere. To evaluate the degree to which fractionation of noble gases in the presence of an advective&ndash;diffusive flux agrees with existing theory, a simple laboratory sand column experiment was conducted. Pure CO2 was injected at the base of the column, providing a series of constant CO2 fluxes through the column. At five fixed sampling depths within the system, samples were collected for CO2 and noble gas analyses, and ambient pressures were measured. Both the advection&ndash;diffusion and dusty gas models were used to simulate the behavior of CO2 and noble gases under the experimental conditions, and the simulations were compared with the measured depth-dependent concentration profiles of the gases. Given the relatively high permeability of the sand column (5 &acute; 10&minus;11 m2), Knudsen diffusion terms were small, and both the dusty gas model and the advection&ndash;diffusion model accurately predicted the concentration profiles of the CO2 and atmospheric noble gases across a range of CO2 flux from ?700 to 10,000 g m&minus;2 d&minus;1. The agreement between predicted and measured gas concentrations demonstrated that, when applied to natural systems, the multi-component capability provided by the noble gases can be exploited to constrain component and total gas fluxes of non-conserved (CO2) and conserved (noble gas) species or attributes of the soil column relevant to gas transport, such as porosity, tortuosity, and gas saturation.

Vadose Zone Journal

Dissolved gases in hydrothermal (phreatic) and geyser eruptions at Yellowstone National Park, USA

Multiphase and multicomponent fluid flow in the shallow continental crust plays a significant role in a variety of processes over a broad range of temperatures and pressures. The presence of dissolved gases in aqueous fluids reduces the liquid stability field toward lower temperatures and enhances the explosivity potential with respect to pure water. Therefore, in areas where magma is actively degassing into a hydrothermal system, gas-rich aqueous fluids can exert a major control on geothermal energy production, can be propellants in hazardous hydrothermal (phreatic) eruptions, and can modulate the dynamics of geyser eruptions. We collected pressurized samples of thermal water that preserved dissolved gases in conjunction with precise temperature measurements with depth in research well Y-7 (maximum depth of 70.1 m; casing to 31 m) and five thermal pools (maximum depth of 11.3 m) in the Upper Geyser Basin of Yellowstone National Park, USA. Based on the dissolved gas concentrations, we demonstrate that CO 2 mainly derived from magma and N 2 from air-saturated meteoric water reduce the near-surface saturation temperature, consistent with some previous observations in geyser conduits. Thermodynamic calculations suggest that the dissolved CO 2 and N 2 modulate the dynamics of geyser eruptions and are likely triggers of hydrothermal eruptions when recharged into shallow reservoirs at high concentrations. Therefore, monitoring changes in gas emission rate and composition in areas with neutral and alkaline chlorine thermal features could provide important information on the natural resources (geysers) and hazards (eruptions) in these areas.

Idaho, Montana, Wyoming

The Lassen hydrothermal system

The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 &deg;C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 &plusmn; 10 kg/s of steam (~115 MW) and 23 &plusmn; 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km 3 /Ma, and the ongoing rates of heat and magmatic CO 2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4&ndash;5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km 2 , the average conductive heat flux over that area is >25 W/m 2 , and the conductive-boundary length <50 m. Observational records of hydrothermal discharge are likely too short to document long-term transients, whether they are intrinsic to the system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914&ndash;1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009&ndash;present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

California

Hydrothermal response to a volcano-tectonic earthquake swarm, Lassen, California

The increasing capability of seismic, geodetic, and hydrothermal observation networks allows recognition of volcanic unrest that could previously have gone undetected, creating an imperative to diagnose and interpret unrest episodes. A November 2014 earthquake swarm near Lassen Volcanic National Park, California, which included the largest earthquake in the area in more than 60&thinsp;years, was accompanied by a rarely observed outburst of hydrothermal fluids. Although the earthquake swarm likely reflects upward migration of endogenous H 2 O-CO 2 fluids in the source region, there is no evidence that such fluids emerged at the surface. Instead, shaking from the modest sized (moment magnitude 3.85) but proximal earthquake caused near-vent permeability increases that triggered increased outflow of hydrothermal fluids already present and equilibrated in a local hydrothermal aquifer. Long-term, multiparametric monitoring at Lassen and other well-instrumented volcanoes enhances interpretation of unrest and can provide a basis for detailed physical modeling.

California

Developing a new, passive diffusion sampling array to detect helium anomalies associated with volcanic unrest

Helium (He) concentration and 3 He/ 4 He anomalies in soil gas and spring water are potentially powerful tools for investigating hydrothermal circulation associated with volca- nism and could perhaps serve as part of a hazards warning system. However, in operational practice, He and other gases are often sampled only after volcanic unrest is detected by other means. A new passive diffusion sampler suite, intended to be collected after the onset of unrest, has been developed and tested as a relatively low-cost method of determining He- isotope composition pre- and post-unrest. The samplers, each with a distinct equilibration time, passively record He concen- tration and isotope ratio in springs and soil gas. Once collected and analyzed, the He concentrations in the samplers are used to deconvolve the time history of the He concentration and the 3 He/ 4 He ratio at the collection site. The current suite consisting of three samplers is sufficient to deconvolve both the magnitude and the timing of a step change in in situ con- centration if the suite is collected within 100 h of the change. The effects of temperature and prolonged deployment on the suite &rsquo; s capability of recording He anomalies have also been evaluated. The suite has captured a significant 3 He/ 4 He soil gas anomaly at Horseshoe Lake near Mammoth Lakes, California. The passive diffusion sampler suite appears to be an accurate and affordable alternative for determining He anomalies associated with volcanic unrest.

Bulletin of Volcanology

Origins of geothermal gases at Yellowstone

Gas emissions at the Yellowstone Plateau Volcanic Field (YPVF) reflect open-system mixing of gas species originating from diverse rock types, magmas, and crustal fluids, all combined in varying proportions at different thermal areas. Gases are not necessarily in chemical equilibrium with the waters through which they vent, especially in acid sulfate terrain where bubbles stream through stagnant acid water. Gases in adjacent thermal areas often can be differentiated by isotopic and gas ratios, and cannot be tied to one another solely by shallow processes such as boiling-induced fractionation of a parent liquid. Instead, they inherit unique gas ratios (e.g., CH 4 /He) from the dominant rock reservoirs where they originate, some of which underlie the Quaternary volcanic rocks. Steam/gas ratios (essentially H 2 O/CO 2 ) of Yellowstone fumaroles correlate with Ar/He and N 2 /CO 2 , strongly suggesting that H 2 O/CO 2 is controlled by addition of steam boiled from water rich in atmospheric gases. Moreover, H 2 O/CO 2 varies systematically with geographic location, such that boiling is more enhanced in some areas than others. The &delta; 13 C and 3 He/CO 2 of gases reflect a dominant mantle origin for CO 2 in Yellowstone gas. The mantle signature is most evident at Mud Volcano, which hosts gases with the lowest H 2 O/CO 2 , lowest CH 4 concentrations and highest He isotope ratios (~16Ra), consistent with either a young subsurface intrusion or less input of crustal and meteoric gas than any other location at Yellowstone. Across the YPVF, He isotope ratios ( 3 He/ 4 He) inversely vary with He concentrations, and reflect varied amounts of long- stored, radiogenic He added to the magmatic endmember within the crust. Similarly, addition of CH4 from organic-rich sediments is common in the eastern thermal areas at Yellowstone. Overall, Yellowstone gases reflect addition of deep, high-temperature magmatic gas (CO 2 -rich), lower-temperatures crustal gases ( 4 He- and CH 4 -bearing), and those gases (N 2 , Ne, Ar) added principally through boiling of the meteoric-water-derived geothermal liquid found in the upper few kilometers. We also briefly explore the pathways by which Cl, F, and S, move through the crust.

Montana, Wyoming

Monitoring ground-surface heating during expansion of the Casa Diablo production well field at Mammoth Lakes, California

The Long Valley hydrothermal system supports geothermal power production from 3 binary plants (Casa Diablo) near the town of Mammoth Lakes, California. Development and growth of thermal ground at sites west of Casa Diablo have created concerns over planned expansion of a new well field and the associated increases in geothermal fluid production. To ensure that all areas of ground heating are identified prior to new geothermal development, we obtained high-resolution aerial thermal infrared imagery across the region. The imagery covers the existing and proposed well fields and part of the town of Mammoth Lakes. Imagery results from a predawn flight on Oct. 9, 2014 readily identified the Shady Rest thermal area (SRST), one of two large areas of ground heating west of Casa Diablo, as well as other known thermal areas smaller in size. Maximum surface temperatures at 3 thermal areas were 26&ndash;28 &deg;C. Numerous small areas with ground temperatures >16 &deg;C were also identified and slated for field investigations in summer 2015. Some thermal anomalies in the town of Mammoth Lakes clearly reflect human activity.Previously established projects to monitor impacts from geothermal power production include yearly surveys of soil temperatures and diffuse CO2 emissions at SRST, and less regular surveys to collect samples from fumaroles and gas vents across the region. Soil temperatures at 20 cm depth at SRST are well correlated with diffuse CO2 flux, and both parameters show little variation during the 2011&ndash;14 field surveys. Maximum temperatures were between 55&ndash;67 &deg;C and associated CO2 discharge was around 12&ndash;18 tonnes per day. The carbon isotope composition of CO2 is fairly uniform across the area ranging between &ndash;3.7 to &ndash;4.4 &permil;. The gas composition of the Shady Rest fumarole however has varied with time, and H2S concentrations in the gas have been increasing since 2009.

California