Geology topics

William A. Battaglin

Publications and source records attributed to William A. Battaglin.

At least 37 records · Page 2Linked to original sources

USGS2015

Restored agricultural wetlands in Central Iowa: habitat quality and amphibian response

Amphibians are declining throughout the United States and worldwide due, partly, to habitat loss. Conservation practices on the landscape restore wetlands to denitrify tile drainage effluent and restore ecosystem services. Understanding how water quality, hydroperiod, predation, and disease affect amphibians in restored wetlands is central to maintaining healthy amphibian populations in the region. We examined the quality of amphibian habitat in restored wetlands relative to reference wetlands by comparing species richness, developmental stress, and adult leopard frog (Lithobates pipiens) survival probabilities to a suite of environmental metrics. Although measured habitat variables differed between restored and reference wetlands, differences appeared to have sub-lethal rather than lethal effects on resident amphibian populations. There were few differences in amphibian species richness and no difference in estimated survival probabilities between wetland types. Restored wetlands had more nitrate and alkaline pH, longer hydroperiods, and were deeper, whereas reference wetlands had more amphibian chytrid fungus zoospores in water samples and resident amphibians exhibited increased developmental stress. Restored and reference wetlands are both important components of the landscape in central Iowa and maintaining a complex of fish-free wetlands with a variety of hydroperiods will likely contribute to the persistence of amphibians in this landscape.

Iowa↗

USGS2015

Aerobic biodegradation potential of endocrine disrupting chemicals in surface-water sediment at Rocky Mountains National Park, USA

Endocrine disrupting chemicals (EDC) in surface water and bed sediment threaten the structure and function of aquatic ecosystems. In natural, remote, and protected surface-water environments where contaminant releases are sporadic, contaminant biodegradation is a fundamental driver of exposure concentration, timing, duration, and, thus, EDC ecological risk. Anthropogenic contaminants, including known and suspected EDC, were detected in surface water and sediment collected from 2 streams and 2 lakes in Rocky Mountains National Park (ROMO). The potential for aerobic EDC biodegradation was assessed in collected sediments using 6 14 C-radiolabeled model compounds. Aerobic microbial mineralization of natural (estrone and 17β-estradiol) and synthetic (17α-ethinylestradiol) estrogen was significant at all sites. ROMO bed sediment microbial communities also effectively degraded the xenoestrogens, bisphenol-A and 4-nonylphenol. The same sediment samples exhibited little potential for aerobic biodegradation of triclocarban, however, illustrating the need to assess a wider range of contaminant compounds. The current results support recent concerns over the widespread environmental occurrence of carbanalide antibacterials, like triclocarban and triclosan, and suggest that backcountry use of products containing these compounds should be discouraged.

Rocky Mountain National Park↗

USGS2015

Pesticide concentrations in frog tissue and wetland habitats in alandscape dominated by agriculture

Habitat loss and exposure to pesticides are likely primary factors contributing to amphibian decline in agricultural landscapes. Conservation efforts have attempted to restore wetlands lost through landscape modifications to reduce contaminant loads in surface waters and providing quality habitat to wildlife. The benefits of this increased wetland area, perhaps especially for amphibians, may be negated if habitat quality is insufficient to support persistent populations. We examined the presence of pesticides and nutrients in water and sediment as indicators of habitat quality and assessed the bioaccumulation of pesticides in the tissue of two native amphibian species Pseudacris maculata (chorus frogs) and Lithobates pipiens (leopard frogs) at six wetlands (3 restored and 3 reference) in Iowa, USA. Restored wetlands are positioned on the landscape to receive subsurface tile drainage water while reference wetlands receive water from overland run-off and shallow groundwater sources. Concentrations of the pesticides frequently detected in water and sediment samples were not different between wetland types. The median concentration of atrazine in surface water was 0.2 μg/L. Reproductive abnormalities in leopard frogs have been observed in other studies at these concentrations. Nutrient concentrations were higher in the restored wetlands but lower than concentrations thought lethal to frogs. Complex mixtures of pesticides including up to 8 fungicides, some previously unreported in tissue, were detected with concentrations ranging from 0.08 to 1500 μg/kg wet weight. No significant differences in pesticide concentrations were observed between species, although concentrations tended to be higher in leopard frogs compared to chorus frogs, possibly because of differences in life histories. Our results provide information on habitat quality in restored wetlands that will assist state and federal agencies, landowners, and resource managers in identifying and implementing conservation and management actions for these and similar wetlands in agriculturally dominated landscapes.

Iowa↗

USGS2014

Glyphosate and its degradation product AMPA occur frequently and widely in U.S. soils, surface water, groundwater, and precipitation

Glyphosate use in the United States increased from less than 5,000 to more than 80,000 metric tons/yr between 1987 and 2007. Glyphosate is popular due to its ease of use on soybean, cotton, and corn crops that are genetically modified to tolerate it, utility in no-till farming practices, utility in urban areas, and the perception that it has low toxicity and little mobility in the environment. This compilation is the largest and most comprehensive assessment of the environmental occurrence of glyphosate and aminomethylphosphonic acid (AMPA) in the United States conducted to date, summarizing the results of 3,732 water and sediment and 1,018 quality assurance samples collected between 2001 and 2010 from 38 states. Results indicate that glyphosate and AMPA are usually detected together, mobile, and occur widely in the environment. Glyphosate was detected without AMPA in only 2.3% of samples, whereas AMPA was detected without glyphosate in 17.9% of samples. Glyphosate and AMPA were detected frequently in soils and sediment, ditches and drains, precipitation, rivers, and streams; and less frequently in lakes, ponds, and wetlands; soil water; and groundwater. Concentrations of glyphosate were below the levels of concern for humans or wildlife; however, pesticides are often detected in mixtures. Ecosystem effects of chronic low-level exposures to pesticide mixtures are uncertain. The environmental health risk of low-level detections of glyphosate, AMPA, and associated adjuvants and mixtures remain to be determined.

Journal of the American Water Resources Associatio↗

USGS2014

Featured collection introduction: contaminants of emerging concern II

This collection of 13 articles focuses on CECs, and each of the articles highlights a specific aspect of this broad topic. The articles were solicited from researchers who participated in the second summer specialty conference on this topic, organized by the American Water Resources Association. The title of the conference was “CECs in Water Resources II: Research, Engineering and Community Action,” and the conference, as well as the articles in this featured collection, focus on a better and more comprehensive understanding of these contaminants. The conference was held in Denver, Colorado, on June 25-27, 2012, and approximately 125 conference attendees participated in an interdisciplinary forum of more than 75 presentations including keynote or plenary presentations by Dana Kolpin, Jorg Drewes, Heiko Schoenfuss, Chris Metcalfe, Vicki Blazer, and Tyrone Hayes. The first conference was held in 2007 and also produced a featured collection of articles (Battaglin and Kolpin, 2009).

Journal of the American Water Resources Associatio↗

USGS2014

Occurrence of pesticides in groundwater and sediments and mineralogy of sediments and grain coatings underlying the Rutgers Agricultural Research and Extension Center, Upper Deerfield, New Jersey, 2007

Water and sediment samples were collected from June through October 2007 from seven plots at the Rutgers Agricultural Research and Extension Center in Upper Deerfield, New Jersey, and analyzed for a suite of pesticides (including fungicides) and other physical and chemical parameters (including sediment mineralogy) by the U.S. Geological Survey. Plots were selected for inclusion in this study on the basis of the crops grown and the pesticides used. Forty-one pesticides were detected in 14 water samples; these include 5 fungicides, 13 herbicides, 1 insecticide, and 22 pesticide degradates. The following pesticides and pesticide degradates were detected in 50 percent or more of the groundwater samples: 1-amide-4-hydroxy-chorothalonil, alachlor sulfonic acid, metolachlor oxanilic acid, metolachlor sulfonic acid, metalaxyl, and simazine. Dissolved-pesticide concentrations ranged from below their instrumental limit of detection to 36 micrograms per liter (for metolachlor sulfonic acid, a degradate of the herbicide metolachlor). The total number of pesticides found in groundwater samples ranged from 0 to 29. Fourteen pesticides were detected in sediment samples from continuous cores collected within each of the seven sampled plots; these include 4 fungicides, 2 herbicides, and 7 pesticide degradates. Pesticide concentrations in sediment samples ranged from below their instrumental limit of detection to 34.2 nanograms per gram (for azoxystrobin). The total number of pesticides found in sediment samples ranged from 0 to 8. Quantitative whole-rock and grain-coating mineralogy of sediment samples were determined by x-ray diffraction. Whole-rock analysis indicated that sediments were predominantly composed of quartz. The materials coating the quartz grains were removed to allow quantification of the trace mineral phases present.

New Jersey↗

USGS2013

Transport of nitrate in the Mississippi river in July-August 1999

Lagrangian sampling was conducted on the Mississippi River in late July through early August 1999 to test the hypothesis that nitrate (NO 3 - ) is transported conservatively in the Mississippi River. Three different approaches were pursued to test the hypothesis: (1) a mass balance for NO 3 - was evaluated for evidence of net gains and losses, (2) stable isotopes of NO 3 - were measured (δ 15 N and δ 18 O) to determine if fractionation occurred, and (3) the concentrations of dissolved gases (N 2 O, N 2 and Ar) in river water were measured and compared to theoretical equilibrium concentrations. Integrated water samples and flow measurements were obtained at 10 sites on the Mississippi River and 7 sites near the mouths of major tributaries from northern Iowa to southern Louisiana, a distance of about 2,250 river kilometers. Mass balance calculations indicate that more than 80 percent of the NO 3 - mass discharged from the Mississippi River (1,930 metric tons/day) during the study period originated in the first 500 river kilometers of the study reach. The mass balance calculations also indicate that NO 3 - was not lost from the water column upstream of Vicksburg, MS, but that there might have been some loss of NO 3 - in the lower 700 kilometers of the study reach. The stable isotope ratios of N and O (δ 15 N and δ 18 O) of NO 3 - were consistent with mixing and transport in the absence of fractionating gains or losses. The concentrations of nitrogen (N 2 ) and argon (Ar) dissolved in river water decreased in the downstream direction, approximately in equilibrium with air at increasing temperatures, giving no evidence of gains or losses of N 2 by nitrogen fixation or denitrification. Nitrous oxide (N 2 O) concentrations in the Mississippi River were approximately 26 to 200 percent of air saturation, indicating relatively low net production by combination of nitrification and denitrification. Results from this study indicate that most (>90%) of the NO 3 - that entered the Mississippi River during July-August 1999 was transported to the Gulf of Mexico.

Mississippi River↗

USGS2012

Dissolved pesticides, dissolved organic carbon, and water-quality characteristics in selected Idaho streams, April--December 2010

Water-quality samples were collected from April through December 2010 from four streams in Idaho and analyzed for a suite of pesticides, including fungicides, by the U.S. Geological Survey. Water samples were collected from two agricultural and two nonagricultural (control) streams approximately biweekly from the beginning of the growing season (April) through the end of the calendar year (December). Samples were analyzed for 90 pesticides using gas chromatography/mass spectrometry. Twenty-three pesticides, including 8 fungicides, 10 herbicides, 3 insecticides, and 2 pesticide degradates, were detected in 45 water samples. The most frequently detected compounds in the two agricultural streams and their detection frequencies were metolachlor, 96 percent; azoxystrobin, 79 percent; boscalid, 79 percent; atrazine, 46 percent; pendimethalin, 33 percent; and trifluralin, 33 percent. Dissolved-pesticide concentrations ranged from below instrumental limits of detection (0.5-1.0 nanograms per liter) to 771 nanograms per liter (hexazinone). The total number of pesticides detected in any given water sample ranged from 0 to 11. Only three pesticides (atrazine, fipronil, and simazine) were detected in samples from the control streams during the sampling period.

Idaho↗

USGS2012

Occurrence of pesticides in water and sediment collected from amphibian habitats located throughout the United States, 2009-10

Water and bed-sediment samples were collected by the U.S. Geological Survey (USGS) in 2009 and 2010 from 11 sites within California and 18 sites total in Colorado, Georgia, Idaho, Louisiana, Maine, and Oregon, and were analyzed for a suite of pesticides by the USGS. Water samples and bed-sediment samples were collected from perennial or seasonal ponds located in amphibian habitats in conjunction with research conducted by the USGS Amphibian Research and Monitoring Initiative and the USGS Toxic Substances Hydrology Program. Sites selected for this study in three of the states (California, Colorado, and Orgeon) have no direct pesticide application and are considered undeveloped and remote. Sites selected in Georgia, Idaho, Louisiana, and Maine were in close proximity to either agricultural or suburban areas. Water and sediment samples were collected once in 2009 during amphibian breeding seasons. In 2010, water samples were collected twice. The first sampling event coincided with the beginning of the frog breeding season for the species of interest, and the second event occurred 10-12 weeks later when pesticides were being applied to the surrounding areas. Additionally, water was collected during each sampling event to measure dissolved organic carbon, nutrients, and the fungus, Batrachochytrium dendrobatidis , which has been linked to amphibian declines worldwide. Bed-sediment samples were collected once during the beginning of the frog breeding season, when the amphibians are thought to be most at risk to pesticides. Results of this study are reported for the following two geographic scales: (1) for a national scale, by using data from the 29 sites that were sampled from seven states, and (2) for California, by using data from the 11 sampled sites in that state. Water samples were analyzed for 96 pesticides by using gas chromatography/mass spectrometry. A total of 24 pesticides were detected in one or more of the 54 water samples, including 7 fungicides, 10 herbicides, 4 insecticides, 1 synergist, and 2 pesticide degradates. On a national scale, aminomethylphosphonic acid (AMPA), the primary degradate of the herbicide glyphosate, which is the active ingredient in Roundup®, was the most frequently detected pesticide in water (16 of 54 samples) followed by glyphosate (8 of 54 samples). The maximum number of pesticides observed at a single site was nine compounds in a water sample from a site in Louisiana. The maximum concentration of a pesticide or degradate observed in water was 2,880 nanograms per liter of clomazone (a herbicide) at a site in Louisiana. In California, a total of eight pesticides were detected among all of the low and high elevation sites; AMPA was the most frequently detected pesticide, but glyphosate was detected at the highest concentrations (1.1 micrograms per liter). Bed-sediment samples were analyzed for 94 pesticides by using accelerated solvent extraction, gel permeation chromatography for sulfur removal, and carbon/alumina stacked solid-phase extraction cartridges to remove interfering sediment matrices. In bed sediment, 22 pesticides were detected in one or more of the samples, including 9 fungicides, 3 pyrethroid insecticides, p,p' -dichlorodiphenyltrichloroethane ( p,p' -DDT) and its major degradates, as well as several herbicides. Pyraclostrobin, a strobilurin fungicide, and bifenthrin, a pyrethroid insecticide, were detected most frequently. Maximum pesticide concentrations ranged from less than their respective method detection limits to 1,380 micrograms per kilogram (tebuconazole in California). The number of pesticides detected in samples from each site ranged from zero to six compounds. The sites with the greatest number of pesticides were in Maine and Oregon with six pesticides detected in one sample from each state, followed by Georgia with four pesticides in one sample. For California, a total of 10 pesticides were detected among all sites, and 4 pesticides were detected at both low and high elevation sites; tebuconazole and pyraclostrobin were the two most frequently detected pesticides in California. For the other six selected states, the most frequently detected pesticides in bed sediment were pyraclostrobin (detected in 17 of 42 samples), bifenthrin (detected in 14 of 42 samples), and tebuconazole (detected in 10 of 42 samples). The fungus, Batrachochytrium dendrobatidis (Bd), was detected in water samples in sites from four of the seven states during 2009 and 2010, and the number of zoospore equivalents per liter of water in samples where Bd was detected ranged from 1.6 to 343. Bd was not detected in water samples from sites in Georgia, Louisiana, and Oregon.

Data Series↗

USGS2012

Watershed scale response to climate change--Yampa River Basin, Colorado

General Circulation Model simulations of future climate through 2099 project a wide range of possible scenarios. To determine the sensitivity and potential effect of long-term climate change on the freshwater resources of the United States, the U.S. Geological Survey Global Change study, "An integrated watershed scale response to global change in selected basins across the United States" was started in 2008. The long-term goal of this national study is to provide the foundation for hydrologically based climate change studies across the nation. Fourteen basins for which the Precipitation Runoff Modeling System has been calibrated and evaluated were selected as study sites. Precipitation Runoff Modeling System is a deterministic, distributed parameter watershed model developed to evaluate the effects of various combinations of precipitation, temperature, and land use on streamflow and general basin hydrology. Output from five General Circulation Model simulations and four emission scenarios were used to develop an ensemble of climate-change scenarios for each basin. These ensembles were simulated with the corresponding Precipitation Runoff Modeling System model. This fact sheet summarizes the hydrologic effect and sensitivity of the Precipitation Runoff Modeling System simulations to climate change for the Yampa River Basin at Steamboat Springs, Colorado.

Colorado↗

USGS2012

Watershed scale response to climate change--East River Basin, Colorado

Colorado↗

USGS2012

Integrated watershed-scale response to climate change for selected basins across the United States

A study by the U.S. Geological Survey (USGS) evaluated the hydrologic response to different projected carbon emission scenarios of the 21st century using a hydrologic simulation model. This study involved five major steps: (1) setup, calibrate and evaluated the Precipitation Runoff Modeling System (PRMS) model in 14 basins across the United States by local USGS personnel; (2) acquire selected simulated carbon emission scenarios from the World Climate Research Programme's Coupled Model Intercomparison Project; (3) statistical downscaling of these scenarios to create PRMS input files which reflect the future climatic conditions of these scenarios; (4) generate PRMS projections for the carbon emission scenarios for the 14 basins; and (5) analyze the modeled hydrologic response. This report presents an overview of this study, details of the methodology, results from the 14 basin simulations, and interpretation of these results. A key finding is that the hydrological response of the different geographical regions of the United States to potential climate change may be different, depending on the dominant physical processes of that particular region. Also considered is the tremendous amount of uncertainty present in the carbon emission scenarios and how this uncertainty propagates through the hydrologic simulations.

Scientific Investigations Report↗

USGS2010

Changes in streamflow and the flux of nutrients in the Mississippi-Atchafalaya River Basin, USA, 1980-2007

Nutrients and freshwater delivered by the Mississippi and Atchafalaya Rivers drive algal production in the northern Gulf of Mexico, which eventually results in the widespread occurrence of hypoxic bottom waters along the Louisiana and Texas coast. Researchers have demonstrated a relation between the extent of the hypoxic zone and the magnitude of streamflow, nutrient fluxes, and nutrient concentrations in the Mississippi River, with springtime streamflows and fluxes being the most predictive. In 1999 the U.S. Geological Survey (USGS) estimated the flux of nitrogen, phosphorus, and silica at selected sites in the Mississippi Basin and to the Gulf of Mexico for 1980-1996. These flux estimates provided the baseline information used by the Mississippi River/Gulf of Mexico Watershed Nutrient Task Force to develop an Action Plan for reducing hypoxia in the northern Gulf of Mexico. The primary goal of the Action Plan was to achieve a reduction in the size (areal extent) of the hypoxic zone from an average of approximately 14,000 square kilometers in 1996-2000 to a 5-year moving average of less than 5,000 square kilometers by 2015. Improved statistical models and adjusted maximum likelihood estimation using USGS Load Estimator (LOADEST) software were used to estimate annual and seasonal nutrient fluxes for 1980-2007 at selected sites on the Mississippi River and its tributaries. These data provide a means to evaluate the influence of natural and anthropogenic effects on delivery of water and nutrients to the Gulf of Mexico; to define subbasins that are the most important contributors of nutrients to the gulf; and to investigate the relations among streamflow, nutrient fluxes, and the size and duration of the Gulf of Mexico hypoxic zone. A comparative analysis between the baseline period of 1980-1996 and 5-year moving averages thereafter indicate that the average annual streamflow and fluxes of total nitrogen, nitrate, orthophosphate, and silica to the Gulf of Mexico have decreased. However, the flux of total phosphorus between the baseline period and subsequent 5-year periods has increased. The average spring (April, May, and June) streamflow and fluxes of silica, total nitrogen, nitrate, and orthophosphate to the Gulf of Mexico also decreased, whereas the spring flux of total phosphorus has increased. Similar changes in streamflow and nutrient flux were observed at many sites Buxtonwithin the basin. The inputs of water, total nitrogen, and total phosphorus from the major subbasins of the Mississippi-Atchafalaya River Basin as a percentage of the to-the-gulf totals have increased from the Ohio River Basin, decreased from the Missouri River Basin, and remained relatively unchanged from the Upper Mississippi, Red, and Arkansas River Basins. Changes in streamflow and nutrient fluxes are related, but short-term variations in sources of streamflow and nutrients complicate the interpretation of factors that affect nutrient delivery to the Gulf of Mexico. Parametric time-series models are used to try and separate natural variability in nutrient flux from changes due to other causes. Results indicate that the decrease in annual nutrient fluxes that has occurred between the 1980-1996 baseline period and more recent years can be largely attributed to natural causes (climate and streamflow) and not management actions or other human controlled activities in the Mississippi-Atchafalaya River Basin. The downward trends in total nitrogen, nitrate, ammonium, and orthophosphate that were detected at either the Mississippi River near St. Francisville, La., or the Atchafalaya River at Melville, La., occurred prior to 1995. In spite of the general decrease in nutrient flux, the average size of the Gulf of Mexico hypoxic zone has increased between 1997 and 2007. The reasons for this are not clear but could be due to the type or nature of nutrient delivery. Whereas the annual flux of total nitrogen to the Gulf of Mexico has decreased, the proporti

Scientific Investigations Report↗

USGS2009

Contaminants of emerging concern: Introduction to a featured collection

No abstract available.

Journal of the American Water Resources Associatio↗

USGS2008

The occurrence of glyphosate, atrazine, and other pesticides in vernal pools and adjacent streams in Washington, DC, Maryland, Iowa, and Wyoming, 2005-2006

Vernal pools are sensitive environments that provide critical habitat for many species, including amphibians. These small water bodies are not always protected by pesticide label requirements for no-spray buffer zones, and the occurrence of pesticides in them is poorly documented. In this study, we investigated the occurrence of glyphosate, its primary degradation product aminomethylphosphonic acid, and additional pesticides in vernal pools and adjacent flowing waters. Most sampling sites were chosen to be in areas where glyphosate was being used either in production agriculture or for nonindigenous plant control. The four site locations were in otherwise protected areas (e.g., in a National Park). When possible, water samples were collected both before and after glyphosate application in 2005 and 2006. Twenty-eight pesticides or pesticide degradation products were detected in the study, and as many as 11 were identified in individual samples. Atrazine was detected most frequently and concentrations exceeded the freshwater aquatic life standard of 1.8 micrograms per liter (μg/l) in samples from Rands Ditch and Browns Ditch in DeSoto National Wildlife Refuge. Glyphosate was measured at the highest concentration (328 μg/l) in a sample from Riley Spring Pond in Rock Creek National Park. This concentration exceeded the freshwater aquatic life standard for glyphosate of 65 μg/l. Aminomethylphosphonic acid, triclopyr, and nicosulfuron also were detected at concentrations greater than 3.0 μg/l.

Iowa, Maryland, Washington D.C., Wyoming↗

USGS2008

Occurrence of chlorothalonil, its transformation products, and selected other pesticides in Texas and Oklahoma streams, 2003-2004

The primary purpose of the study described in this report was to determine if the fungicide chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile), three of its transformation products, or selected other pesticides are transported to surface water after use on peanuts or other crops in Texas and Oklahoma. The results summarized here are part of a larger study that includes data from sites in Alabama, Florida, and Georgia. Chlorothalonil is classified as a probable carcinogen, and the 4-hydroxy of chlorothalonil transformation product is more soluble, more stable, and, for some species, more toxic than its parent compound. In 2003, water samples were collected from three surface-water sites in Texas and two surface-water sites in Oklahoma; in 2004, samples were collected from the two Oklahoma sites. Chlorothalonil was not detected in any of the 20 samples analyzed. The 4-hydroxy of chlorothalonil transformation product was detected in three samples collected in 2004, with a maximum concentration of 0.018 microgram per liter (?g/L); the other two transformation products (diamide chlorothalonil and 1-amide-4-hydroxy chlorothalonil) were not detected in any sample. In addition, 19 samples were analyzed for as many as 109 other pesticides and transformation products. Atrazine was detected in 13 samples and had a maximum concentration of 0.122 ?g/L. Deethylatrazine was detected in 10 samples and had a maximum concentration of 0.04 ?g/L. Metolachlor was detected in eight samples and had a maximum concentration of 0.019 ?g/L. Fifteen other pesticides or pesticide transformation products also were detected. In general, concentrations of pesticides were less than concentrations that are commonly observed in Midwestern streams. The results indicate that the use of chlorothalonil on peanut crops has not resulted in substantial contamination of the studied streams in Texas and Oklahoma.

Texas, Oklahoma↗

USGS2007

Streamflow and nutrient fluxes of the Mississippi-Atchafalaya River Basin and subbasins for the period of record through 2005

U.S. Geological Survey has monitored streamflow and water quality systematically in the Mississippi-Atchafalaya River Basin (MARB) for more than five decades. This report provides streamflow and estimates of nutrient delivery (flux) to the Gulf of Mexico from both the Atchafalaya River and the main stem of the Mississippi River. This report provides streamflow and nutrient flux estimates for nine major subbasins of the Mississippi River. This report also provides streamflow and flux estimates for 21 selected subbasins of various sizes, hydrology, land use, and geographic location within the Basin. The information is provided at each station for the period for which sufficient water-quality data are available to make statistically based flux estimates (starting as early as water year1 1960 and going through water year 2005). Nutrient fluxes are estimated using the adjusted maximum likelihood estimate, a type of regression-model method; nutrient fluxes to the Gulf of Mexico also are estimated using the composite method. Regression models were calibrated using a 5-year moving calibration period; the model was used to estimate the last year of the calibration period. Nutrient flux estimates are provided for six water-quality constituents: dissolved nitrite plus nitrate, total organic nitrogen plus ammonia nitrogen (total Kjeldahl nitrogen), dissolved ammonia, total phosphorous, dissolved orthophosphate, and dissolved silica. Additionally, the contribution of streamflow and net nutrient flux for five large subbasins comprising the MARB were determined from streamflow and nutrient fluxes from seven of the aforementioned major subbasins. These five large subbasins are: 1. Lower Mississippi, 2. Upper Mississippi, 3. Ohio/Tennessee, 4. Missouri, and 5. Arkansas/Red.

Louisiana, Mississippi↗

USGS2007

Concentrations of glyphosate, its degradation product, aminomethylphosphonic acid, and glufosinate in ground- and surface-water, rainfall, and soil samples collected in the United States, 2001-06

The U.S. Geological Survey conducted a number of studies from 2001 through 2006 to investigate and document the occurrence, fate, and transport of glyphosate, its degradation product, aminomethylphosphonic acid (AMPA), and glufosinate in 2,135 ground- and surface-water samples, 14 rainfall samples, and 193 soil samples. Analytical methods were developed to detect and measure glyphosate, AMPA, and glufosinate in water, rainfall, and soil. Results show that AMPA was detected more frequently and occurred at similar or higher concentrations than the parent compound, glyphosate, whereas glufosinate was seldom found in the environment. Glyphosate and AMPA were detected more frequently in surface water than in ground water. Trace levels of glyphosate and AMPA may persist in the soil from year to year. The methods and data described in this report are useful to researchers and regulators interested in the occurrence, fate, and transport of glyphosate and AMPA in the environment.

Scientific Investigations Report↗