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Wayne C. Shanks

Publications and source records attributed to Wayne C. Shanks.

52 records · Page 3Linked to original sources

The deep structure of a sea-floor hydrothermal deposit

Hydrothermal circulation at the crests of mid-ocean ridges plays an important role in transferring heat from the interior of the Earth. A consequence of this hydrothermal circulation is the formation of metallic ore bodies known as volcanic-associated massive sulphide deposits. Such deposits, preserved on land, were important sources of copper for ancient civilizations and continue to provide a significant source of base metals (for example, copper and zinc). Here we present results from Ocean Drilling Program Leg 169, which drilled through a massive sulphide deposit on the northern Juan de Fuca spreading centre and penetrated the hydrothermal feeder zone through which the metal-rich fluids reached the sea floor. We found that the style of feeder-zone mineralization changes with depth in response to changes in the pore pressure of the hydrothermal fluids and discovered a stratified zone of high-grade copper-rich replacement mineralization below the massive sulphide deposit. This copper-rich zone represents a type of mineralization not previously observed below sea-floor deposits, and may provide new targets for land-based mineral exploration.

Nature

Hydrogen isotope systematics of phase separation in submarine hydrothermal systems: Experimental calibration and theoretical models

Hydrogen isotope fractionation factors were measured for coexisting brines and vapors formed by phase separation of NaCl/H2O fluids at temperatures ranging from 399-450??C and pressures from 277-397 bars. It was found that brines are depleted in D compared to coexisting vapors at all conditions studied. The magnitude of hydrogen isotope fractionation is dependent on the relative amounts of Cl in the two phases and can be empirically correlated to pressure using the following relationship: 1000 ln ??(vap-brine) = 2.54(??0.83) + 2.87(??0.69) x log (??P), where ??(vap-brine) is the fractionation factor and ??P is a pressure term representing distance from the critical curve in the NaCl/H2O system. The effect of phase separation on hydrogen isotope distribution in subseafloor hydrothermal systems depends on a number of factors, including whether phase separation is induced by heating at depth or by decompression of hydrothermal fluids ascending to the seafloor. Phase separation in most subseafloor systems appears to be a simple process driven by heating of seawater to conditions within the two-phase region, followed by segregation and entrainment of brine or vapor into a seawater dominated system. Resulting vent fluids exhibit large ranges in Cl concentration with no measurable effect on ??D. Possible exceptions to this include hydrothermal fluids venting at Axial and 9??N on the East Pacific Rise. High ??D values of low Cl fluids venting at Axial are consistent with phase separation taking place at relatively shallow levels in the oceanic crust while negative ??D values in some low Cl fluids venting at 9??N suggest involvement of a magmatic fluid component or phase separation of D-depleted brines derived during previous hydrothermal activity.

Geochimica et Cosmochimica Acta

Variations in the chemical and stable isotope composition of carbon and sulfur species during organic-rich sediment alteration: An experimental and theoretical study of hydrothermal activity at Guaymas Basin, Gulf of California

Organic-rich diatomaceous ooze was reacted with seawater and a Na-Ca-K-Cl fluid of seawater chlorinity at 325–400°C, 400–500 bars, and fluid/sediment mass ratios of 1.56–2.35 to constrain factors regulating the abundance and stable isotope composition of C and S species during hydrothermal alteration of sediment from Guaymas Basin, Gulf of California. Alteration of inorganic and organic sedimentary components resulted in extensive exchange reactions, the release of abundant H 2 S, CO 2 , CH 4 , and C organic , to solution, and recrystallization of the sediment to an assemblage containing albitic plagioclase, quartz, pyrrhotite, and calcite. The δ 34 S cdt "> δ 34 S cdt values of dissolved H 2 S varied from −10.9 to +4.3‰ during seawater-sediment interaction at 325 and 400°C and from −16.5 to −9.0‰ during Na-Ca-K-Cl fluid-sediment interaction at 325 and 375°C. In the absence of seawater SO 4 , H 2 S is derived from both the transformation of pyrite to pyrrhotite and S released during the degradation of organic matter. In the presence of seawater SO 4 , reduction of SO 4 contributes directly to H 2 S production. Sedimentary organic matter acts as the reducing agent during pyrite and SO 4 reduction. Requisite acidity for the reduction of SO 4 is provided by Mg fixation during early-stage sediment alteration and by albite and calcite formation in Mg-free solutions. Organically derived CH 4 was characterized by δ 13 C pdb "> δ13Cpdb values ranging between −20.8 and −23.1‰, whereas δ 13 C pdb "> δ 13 C pdb values for dissolved C organic ranged between −14.8 and −17.7%. Mass balance calculations indicate that δ 13 C values for organically derived CO 2 were ≥ − 14.8%. Residual solid sedimentary organic C showed small (≤ 0.7‰) depletions in 13 C relative to the starting sediment. The experimental results are consistent with the isotopic and chemical composition of natural hydrothermal fluids and minerals at Guaymas Basin and permit us to better constrain sources and sinks for C and S species in subseafloor hydrothermal systems at sediment-covered spreading centers. Our data show that the sulfur isotope composition of hydrothermal Sulfide minerals in Guaymas Basin can be explained by derivation of S from diagenetic sulfide and seawater sulfate. Basaltic S may also contribute to hydrothermal sulfide precipitates but is not required to explain their isotopic composition. Estimates of seawater/ sediment mass ratios based on sulfur isotopic composition of sulfide minerals and the abundance of dissolved NH 3 in vent fluids range from 3–29 during hydrothermal circulation. Sources of C in Guaymas Basin hydrothermal fluids include thermal degradation of organic matter, bacteriogenic methane production, and dissolution of diagenetic carbonate.

Baja California Sur

Karstification without carbonic acid: Bedrock dissolution by gypsum- driven dedolomitization

Aggressive karstification can take place where dolomite and gypsum are in contact with the same aquifer. Gypsum dissolution drives the precipitation of calcite, thus consuming carbonate ions released by dolomite. Lake Banyoles, in northeastern Spain, is a karst lake supplied by sublacustrine springs, and karstic collapse is occurring in the immediate vicinity of the lake. Lake water is dominated by Mg-Ca and SO 4 -HCO 3 , and is supersaturated with calcite that is actively accumulating in lake sediments. Water chemistry, sulfur isotope composition, local stratigraphy, and mass-balance modelling suggest that the primary karst-forming process at at Lake Banyoles is dedolomitization of basement rocks driven by gypsum dissolution. Karstification takes place along the subsurface contact between the gypsiferous Beuda Formation and the dolomitic Perafita Formation. This process is here recognized for the first time to cause karstification on a large scale; this is significant because it proceeds without the addition of soil-generated carbonic acid. Gypsum-driven dedolomitization may be responsible for other karstic systems heretofore attributed to soil-generated carbonic acid.

Geology

Volcanic eruption of the mid-ocean ridge along the East Pacific Rise crest at 9°45-52'N: direct submersible observations of seafloor phenomena associated with an eruption event in April, 1991

In April, 1991, we witnessed from the submersible Alvin a suite of previously undocumented seafloor phenomena accompanying an in-progress eruption of the mid-ocean ridge on the East Pacific Rise crest at 9&deg;45&prime;N&ndash;52&prime;N. The volume of the eruption could not be precisely determined, although comparison of pre- and post-eruption SeaBeam bathymetry indicate that any changes in ridge crest morphology resulting from the eruption were < 10 m high. Effects of the eruption included: (1) increased abundance and redistribution of hydrothermal vents, disappearance of numerous vent communities, and changes in characteristics of vent fauna and mineral deposits within the eruption area since December, 1989; (2) murkiness of bottom waters up to tens of meters above the seafloor due to high densities of suspended mineral and biogenic particulates; (3) destruction of a vent community by lava flows, mass wasting, and possible hydrovolcanic explosion at a site known as &lsquo;Tubeworm Barbecue&rsquo; in the axial summit caldera (ASC) at 9&deg;50.6&prime;N; (4) near-critical temperatures of hydrothermal vent fluids, ranging up to 403&deg;C; (5) temporal variations over a 2 week interval in both temperatures and chemical/isotopic compositions of hydrothermal fluids; (6) unusual compositions of end-member vent fluids, with pH values ranging to a record low of 2.5, salinities ranging as low as 0.3 wt% NaCl (one-twelfth that of seawater), and dissolved gases reaching high concentrations (> 65 mmol/l for both CO 2 and H 2 S); (7) venting at temperatures above 380&deg;C of visually detectable white vapor that transformed to plumes of gray smoke a few centimeters above vent orifices; (8) disorganized venting of both high-temperature fluids (black and gray smoke) and large volumes of cooler, diffuse hydrothermal fluids directly from the basaltic seafloor, rather than from hydrothermal mineral constructions; (9) rapid and extensive growth of flocculent white bacterial mats (species unknown) on and under the seafloor in areas experiencing widespread venting of diffuse hydrothermal fluid; and (10) subseafloor downslope migration of magma normal to the ridge axis in a network of small-scale (1&ndash;5 m diameter) lava tubes and channels to distances at least 100&ndash;200 m outside the ASC. We suggest that, in April, 1991, intrusion of dikes in the eruption area to < 200 m beneath the ASC floor resulted in phase separation of fluids near the tops of the dikes and a large flux of vapor-rich hydrothermal fluids through the overlying rubbly, cavernous lavas. Low salinities and gas-rich compositions of hydrothermal fluids sampled in the eruption area are appropriate for a vapor phase in a seawater system undergoing subcritical liquid-vapor phase separation (boiling) and phase segregation. Hydrothermal fluids streamed directly from fissures and pits that may have been loci of lava drainback and/or hydrovolcanic explosions. These fissures and pits were lined with white mats of a unique fast-growing bacteria that was the only life associated with the brand-new vents. The prolific bacteria, which covered thousands of square meters on the ridge crest and were also abundant in subseafloor voids, may thrive on high levels of gases in the vapor-rich hydrothermal fluids initially escaping the hydrothermal system. White bacterial particulates swept from the seafloor by hydrothermal vents swirled in an unprecedented biogenic &lsquo;blizzard&rsquo; up to 50 m above the bottom. The bacterial proliferation of April, 1991 is likely to be a transient bloom that will be checked quickly either by decline of dissolved gas concentrations in the fluids as rapid heat loss brings about cessation of boiling, and/or by grazing as other organisms are re-established in the biologically devastated area.

Earth and Planetary Science Letters

Cycling of sulfur in subduction zones: The geochemistry of sulfur in the Mariana Island Arc and back-arc trough

The sulfur contents and sulfur isotopic compositions of 24 glassy submarine volcanics from the Mariana Island Arc and back-arc Mariana Trough were determined in order to investigate the hypothesis that subducted seawater sulfur (δ 34 S= 21‰) is recycled through arc volcanism. Our results for sulfur are similar to those for subaerial arc volcanics: Mariana Arc glasses are enriched in 34 S (δ 34 S=up to10.3‰,mean= 3.8‰) and depleted in S (20–290 ppm, mean = 100 ppm) relative to MORB (850 ppm S,δ 34 S= 0.1 ± 0.5‰). The back-arc trough basalts contain 200–930 ppm S and haveδ 34 S values of1.1 ± 0.5‰, which overlap those for the arc and MORB. The low sulfur contents of the arc and some of the trough glasses are attributed to (1) early loss of small amounts of sulfur through separation of immiscible sulfide and (2) later vapor-melt equilibrium control of sulfur contents and loss of sulfur in a vapor phase from sulfide-undersaturated melts near the minimum in sulfur solubility atƒO 2 ≈NNO (nickel-nickel oxide). Although these processes removed sulfur from the melts their effects on the sulfur isotopic compositions of the melts were minimal. Positive trends ofδ 34 S with 87 Sr/ 86 Sr, LILE and LREE contents of the arc volcanics are consistent with a metasomatic seawater sulfur component in the depleted sub-arc mantle source. The lack of a 34 S-rich slab signature in the trough lavas may be attributed to equilibration of metasomatic fluid with mantle material along the longer pathway from the slab to the source of the trough volcanics. Sulfur is likely to have been transported into the mantle wedge by metasomatic fluid derived from subducted sediments and pore fluids.

Earth and Planetary Science Letters

Sulfur isotopic disequilibrium and fluid-rock interaction during metamorphism of sulfidic black shales from the Waterville-Augusta area, Maine, USA

Sulfur isotope ratios of pyrite (py) and pyrrhotite (po) from regionally metamorphosed graphitic sulfidic schists and related rocks from south-central Maine, USA, were analysed using SO 2 and SF 6 techniques. There is a broad range in δ 34 S values for both pyrite and pyrrhotite at most outcrops, up to 8%. and overall the values are isotopically light, averaging ~ −27‰ for the entire data set, suggesting that the rocks have not been grossly isotopically disturbed by regional metamorphism from their inferred organic-rich sedimentary origins. At all temperatures from chlorite to sillimanite grades, sulfide analysed from veins and blebs within the schists show predominantly disequilibrium fractionations ranging from &#x394; 34 S py-po &#x2212;3.0 to +3.5&#x2030; "> Δ 34 S py-po −3.0to+3.5‰ , as do matrix sulfides from rocks that attained temperatures <500°C. Only at T > 500° C do matrix pyrite-pyrrhotite pairs with polygonal or aligned granoblastic microstructures approach isotopic equilibrium at millimeter to centimeter scales, suggesting that the process that favoured equilibration was recrystallization accompanying metamorphism and deformation. This disequilibrium may be a function of preferential interaction of one of the phases with an infiltrating fluid, but the lack of any systematic trends in the data, particularly with both negative and positive Δ 34 S py-po at some outcrops, does not permit ready identification of fluid sources, fluxes, or compositions. By combining published fluid fluxes for the area and a knowledge of the mass of sulfur contained in the rocks and the inferred infiltrating fluid, it appears that sulfur should have been homogenized over at least 10's to 1000's of meters, if equilibrium had been attained between rock sulfides and an infiltrating fluid of constant composition. That this did not occur was probably due to lack of equilibration between sulfides and the fluid but may also have arisen because of channelling of fluid flow along rather than across layers, or a lack of fluid infiltration through this unit.

Geochimica et Cosmochimica Acta

Sulfur, carbon, and oxygen isotope variations in submarine hydrothermal deposits of Guaymas Basin, Gulf of California, USA

Sulfur, carbon, and oxygen isotope values were measured in sulfide, sulfate, and carbonate from hydrothermal chimney, spire, and mound samples in the southern trough of Guaymas Basin, Gulf of California, USA. δ 34 S values of sulfides range from −3.7 to 4.5%. and indicate that sulfur originated from several sources: 1. (1) dissolution of 0‰ sulfide contained within basaltic rocks, 2. (2) thermal reduction of seawater sulfate during sediment alteration reactions in feeder zones to give sulfide with positive δ 34 S , and 3. (3) entrainment or leaching of isotopically light (negative- δ 34 S ) bacteriogenic sulfide from sediments underlying the deposits. δ 34 S of barite and anhydrite indicate sulfur derivation mainly from unfractionated seawater sulfate, although some samples show evidence of sulfate reduction and sulfide oxidation reactions during mixing within chimneys. Oxygen isotope temperatures calculated for chimney calcites are in reasonable agreement with measured vent fluid temperatures and fluid inclusion trapping temperatures. Hydrothermal fluids that formed calcite-rich chimneys in the southern trough of Guaymas Basin were enriched in 18 O with respect to seawater by about 2.4‰ due to isotopic exchange with sedimentary and/or basaltic rocks. Carbon isotope values of calcite range from −9.6 to −14.0‰ δ 34 C pDB , indicating that carbon was derived in approximately equal quantities from the dissolution of marine carbonate minerals and the oxidation of organic matter during migration of hydrothermal fluid through the underlying sediment column. Statistically significant positive, linear correlations of δ 34 S , δ 34 C , and δ 18 O of sulfides and calcites with geographic location within the southern trough of Guaymas Basin are best explained by variations in water/rock ( w r "> wr ) ratios or sediment reactivity within subsurface alteration zones. Low w r "> wr ratios and the leaching of detrital carbonates and bacteriogenic sulfides at the southern vent sites result in relatively high δ 13 C and low δ 34 S in chimney carbonates and sulfides, respectively. In the north, where the depletion of alkalis in vent fluids indicates higher w r "> wr ratios, positive δ 34 S and more negative δ 13 c are due to increased contributions from organic matter oxidation and sulfate reduction reactions.

Geochimica et Cosmochimica Acta

Thermal springs in Lake Baikal

Pore waters extracted from sediment cores were analyzed for their oxygen and hydrogen isotopic compositions and major ion chemistry to determine the source of water from a vent area for diffuse lake-bottom thermal springs or seeps in Frolikha Bay, northeastern Lake Baikal. The δ 18 O values of pore waters range from -15.2‰ to -16.7‰, and δD values range from -119‰ to -126‰ (both isotopes determined relative to standard mean ocean water [SMOW]). Bottom water in Lake Baikal has a δ 18 O value of -5.6‰ and a δD value of -120‰ Pore waters in the vent area are significantly enriched in Mg, B, Ca, and especially Na and have the lowest δD and δ 18 O values; these pore waters are isotopically and chemically distinct from pore waters in other, more typical parts of the lake. The pore-water isotopic data fall on a local meteoric water line, and covariations in water isotopes and chemistry are not consistent with evaporation or hydrothermal water-rock interaction. The thermal springs represent discharging meteoric waters that have been gently heated during subsurface circulation and are largely unaltered isotopically. Chemical variations are most likely due to dissolution of subsurface evaporites.

Geology

Deep-water hydrocarbon seeps in Guaymas Basin, Gulf of California

Acoustically discovered hydrocarbon seeps along a transform fault zone on the Sonoran margin of Guaymas Basin and in the Southern Trough of Guaymas Basin were examined and sampled during dives of DSV Alvin . Seepage of methane and heavier hydrocarbons occurs through shallow pockmarks along the eroding crest of a steep anticline, 1600 m below sea level. Extensive ledges of aragonite crop out around the rims of the pockmarks; isotopic analysis indicates that carbonate precipitation is a result of methane oxidation. Seepage zones within the pockmarks support dense communities of Calyptogena , half buried in the mud; tubeworms ( Lamellibracheae sp.) have colonized many of the aragonite outcrops. Though the margin site is only a few kilometers from a high-temperature sulfide-precipitating and petroleum-discharging vent system at a nearby center, its structural setting is more akin to pockmarks described from continental shelves, and its chemosynthetic fauna is more like that around low temperature seeps on other continental slopes and margins (e.g. Oregon, U.S.A., and Japan). The seep in the Southern Trough is a condensate-type petroleum (C 1 -C 40 ) and rises as a plume from a young vent-mound system about 2000 m below sea level.

Gulf of California

Isotopic studies of epigenetic features in metalliferous sediment, Atlantis II Deep, Red Sea

The unique depositional environment of the Atlantis II Deep brine pool in the Red Sea produces a stratiform metalliferous deposit of greater areal extent than deposits formed by buoyant-plume systems typical of the midocean ridges because of much more efficient metal entrapment. Isotopic analyses of strontium, sulfur, carbon, and oxygen from the metalliferous sediments indicate that three major sources contribute dissolved components to the hydrothermal system: seawater, Miocene evaporites, and rift-zone basalt. An areally restricted magnetite-hematite-pyroxene assemblage formed at high temperatures, possibly in response to hydrothermal convection initiated by intrusion of basalt into the metalliferous sediment. A correlation between smectite Fe/(Fe+Mg) ratios and oxygen isotope temperatures suggests that smectite is a potentially important chemical geothermometer, and confirms geochemical calculations indicating that Mg-rich smectite is more stable than Fe-rich smectite at elevated temperatures.

Canadian Mineralogist

Composition of massive sulfide deposits from the sediment-covered floor of Escanaba Trough, Gorda Ridge: implications for depositional processes

Massive sulfide deposits with two distinct compositions are spatially related to volcanic edifices that penetrate up to 500 m of turbiditic sediment in Escanaba Trough (ET), southern Gorda Ridge. The mineralogy, metal content, sulfur isotope composition, and hydrocarbon content of massive sulfides from ET reflect the extensive interaction between underlying turbiditic sediment and hydrothermal fluid. Pyrrhotite-rich sulfide mounds are inferred to have formed under gentle temperature and chemical gradients related to diffuse, low-velocity flow through disrupted sediment near the sediment-capped hills.

Canadian Mineralogist

Sulfur and lead isotope studies of stratiform Zn-Pb-Ag deposits, Anvil Range, Yukon: Basinal brine exhalation and anoxic bottom-water mixing (Canada)

Five stratiform Zn-Pb-Ag deposits are known in Early Cambrian metapelitic rocks along a curvilinear trend in the Anvil Range, central Yukon. The Anvil Range deposits occur along the southwestern boundary of the Selwyn basin in the stratigraphic transition zone between metapelites of the Mt. Mye unit and calcareous phyllites of the overlying Vangorda unit. The massive sulfides are associated closely with anomalously thick graphitic phyllites, apparently related to a second-order basin. A typical Anvil cycle of mineralization begins with a ribbon-banded graphitic-quartzitic-pyritic unit. This grades upward into sulfide-bearing quartzite, quartzitic massive sulfide, massive sulfide, and finally a baritic massive sulfide horizon. Sericitic alteration envelopes irregularly encompass each deposit and locally are developed best in footwall rocks. Detailed sulfur isotope studies have been carried out on the DY and Grum deposits and on one representative drill hole from the Faro deposit. The delta 34 S values of sulfide minerals generally range from 10 to 22 per mil and are similar in all three deposits. The delta 34 S values of pyrite in unmineralized samples from the district exhibit a wider range, from 6 to 34 per mil, and show distinct upward stratigraphic increase due to a stagnation cycle in the basin. The delta 34 S values of barite samples are strongly dependent on bottom-water conditions and mode of mixing during brine exhalation. They range from 22 to 26 per mil in the Faro deposit to 36 to 42 per mil in the DY deposit. These variations are due to mixing of isotopically light sulfate (18-20ppm) in Ba-bearing ore fluid and isotopically heavy residual sulfate (30-60ppm) in anoxic seawater. Thirty-eight samples of galena from the DY, Grum, Faro, SB, and Swim deposits have been analyzed for lead isotope ratios. In general, the lead isotope ratio data indicate an upper crustal lead source, with the Proterozoic Grit unit which is inferred to underlie the district being the most likely source rock. A small component of mantle leads from mafic igneous rocks or due to source rock inhomogeneity is also indicated. Graphitic host lithologies, lack of stratiform iron oxides, delta 34 S values of sedimentary pyrite, and sulfide sulfur-organic carbon variations in unmineralized cores indicate formation of the Anvil deposits in strongly reduced bottom water related to a previously unknown Early Cambrian anoxic event.

Economic Geology

Seawater sulfate reduction and sulfur isotope fractionation in basaltic systems: interaction of seawater with fayalite and magnetite at 200–350°C

Sulfate reduction during seawater reaction with fayalite and with magnetite was rapid at 350&deg;C, producing equilibrium assemblages of talc-pyrite-hematite-magnetite at low water/rock ratios and talc-pyrite-hematite-anhydrite at higher water/rock ratios. At 250&deg;C, seawater reacting with fayalite produced detectable amounts of dissolved H 2 S, but extent of reaction of solid phases was minor after 150 days. At 200&deg;C, dissolved H 2 S was not detected, even after 219 days, but mass balance calculations suggest a small amount of pyrite may have formed. Reaction stoichiometry indicates that sulfate reduction requires large amounts of H + , which, in subseafloor hydrothermal systems is provided by Mg metasomatism. Seawater contains sufficient Mg to supply all the H + necessary for quantitative reduction of seawater sulfate. Systematics of sulfur isotopes in the 250 and 350&deg;C experiments indicate that isotopic equilibrium is reached, and can be modeled as a Rayleigh distillation process. Isotopic composition of hydrothermally produced H 2 S in natural systems is strongly dependent upon the seawater/basalt ratio in the geothermal system, which controls the relative sulfide contributions from the two important sulfur sources, seawater sulfate and sulfide phases in basalt. Anhydrite precipitation during geothermal heating severely limits sulfate ingress into high temperature interaction zones. Quantitative sulfate reduction can thus be accomplished without producing strongly oxidized rocks and resultant sulfide sulfur isotope values represent a mixture of seawater and basaltic sulfur.

Geochimica et Cosmochimica Acta

Ore transport and deposition in the Red Sea geothermal system: a geochemical model

Thermodynamic calculation of distribution of dissolved aqueous species in the Red Sea geothermal brine provides a model of ore transport and deposition in good agreement with observed accumulations of base metal sulfides, anhydrite, and barite. The Red Sea brine is recirculated seawater that acquires high salinity by low-temperature interaction with Miocene evaporites and is subsequently heated to temperatures in excess of 200°C by interaction with recent rift zone intrusive rocks. At temperatures up to 250°C, NaSO − 4 and MgSO 0 4 are the dominant sulfur-bearing species. H 2 S forms by inorganic sulfate reduction at the higher temperatures but is maintained at a uniform concentration of about 2 ppm by the strength of the sulfate complexes. Chloride complexes solubilize metals at the higher temperatures, and thus sulfide and metals are carried together into the Atlantis II Deep. Below 150°C, the brine becomes supersaturated with respect to chalcopyrite, sphalerite, galena, and iron monosulfide due to chloride-complex dissociation. Sulfide precipitation rates, based on the rate of brine influx, are in good agreement with measured sedimentation rates. Anhydrite precipitates as crystalline fissure infillings from high-temperature inflowing brine. Barite forms from partial oxidation of sulfides at the interface between the lower hot brine and the transitional brine layer.

Geochimica et Cosmochimica Acta