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Walter E. Dean

Publications and source records attributed to Walter E. Dean.

At least 55 records · Page 3Linked to original sources
USGS1993

Elk Lake in perspective

Elk Lake is located in the forested region of north-central Minnesota at the headwaters of the Mississippi River and occupies one of countless basins left behind as the last great Pleistocene ice sheet retreated northward into Canada. In this respect it resembles many other moderately deep, dimictic, hard-water lakes in the north-central United States, the sediments of which contain a history of postglacial and Holocene climatic and environmental change. Elk Lake is different, however, because the Holocene sediments in the deeper part of the lake form an uninterrupted sequence of annual laminations or varves. The varves are a chronometer for timing precisely the biologic, geochemical, and sedimentological responses in the lake to cyclic and progressive changes in climate. The varves also, through profound changes in their composition, divide the history of Elk Lake into three, sharply defined episodes; a postglacial lake, a prairie lake, and a modern, mesic-forest lake. We use these episodes and the character of the varves as a framework to guide the reader to the chapters and discussions found in this volume.

Minnesota↗
USGS1993

Geochemistry of surface sediments of Minnesota lakes

Analyses of 36 trace, minor, and major elements were used to classify the sediments of 46 Minnesota lakes. Q-mode factor analyses grouped Minnesota lake sediments according to clastic-, carbonate-, organic-, and redox-related elements. Carbonate lakes occur in west-central Minnesota; their sediments have relatively high concentrations of CaCO 3 , Ba, and Sr. Lakes with sediments containing more than 30% organic matter occur in east-central and northeastern Minnesota; these sediments have high concentrations of organic C, N, and H, and slightly elevated concentrations of Pb. Only three lakes have sediments included in the “redox” group, with relatively high concentrations of Fe, Mn, Mo, La, and Zn. High concentrations of redox-sensitive elements appear to be associated with oxidized iron and manganese minerals, but in Elk Lake, one of the three lakes in this group, a significant amount of iron and manganese is contained in iron phosphate, iron sulfide, and manganese carbonate. Clastic lake sediments are not diluted by large amounts of organic matter, carbonate minerals, or iron-manganese minerals, and are of two types: a western group derived largely from Cretaceous shales in the prairie regions, and a northeastern group derived from Precambrian crystalline rocks in the forested arrowhead region. Western clastic lake sediments have higher concentrations of Al, Na, K, B, Ba, V, Mg, and Sr. Most northeastern clastic lake sediments contain higher concentrations of Cu, Y, Be, and Ni, but several are chemically more similar to those of western prairie lakes.

Minnesota↗
USGS1993

Physical properties, mineralogy, and geochemistry of Holocene varved sediments from Elk Lake, Minnesota

Elk Lake in northwestern Minnesota is situated close to a climatically sensitive ecotone, the forest-prairie border, that migrated back and forth over the drainage basin of the lake during the Holocene. The entire postglacial (Holocene) sediment record in the deepest part of Elk Lake is composed of annual layers (varves) that record the seasonal pulses of many sediment components, and, most important, provide high-resolution (seasonal) time calibration of rates and timing of environmental change. These varved sediments contain many allochthonous and autochthonous components that are sensitive to changing environmental conditions in the drainage basin and the lake. The mineral components of Elk Lake sediments consist mainly of authigenic calcium, magnesium, and manganese carbonate minerals (low-Mg calcite, high-Mg calcite, dolomite, and rhodochrosite), opaline silica (from diatoms), X-ray amorphous iron and manganese oxyhydroxides, and an iron phosphate mineral tentatively identified as rock-bridgeite [(Fe, Mn)Fe 4 (PO 4 ) 3 (OH) 5 ], plus minor contributions from fine-grained detrital quartz, feldspar, illite, and kaolinite. The most notable characteristic of the sediments in Elk Lake is that most of the components were formed in the lake. Q-mode factor analysis of sediment geochemistry reduced 23 observed compositional variables, expressed as percent or parts per million of elements, to three composite variables (factor loadings) whose “concentrations” are expressed on a scale of −1.0 to 1.0. Factor 1 expresses the composition of the inorganic clastic fraction based on concentrations of Mg, Na, Al, Cr, V, Y, Sc, Ni, Sr, Co, and Cu. Factor 2 expresses the similarities in variations of Fe, Mn, P, organic carbon, and Mo. Factor 3 loadings are a synthesis of concentrations of Mn, S, Ca, La, and Ba. Geochemical characteristics define three distinct chemical stages in the development of Elk lake: (1) a carbonate-, manganese-, iron-, sulfur-rich early-lake stage that lasted from 10,400 to 8200 varve yr; (2) a clastic- and diatom-rich mid-Holocene prairie-lake stage that lasted from 8200 to 4000 varve yr; and (3) a final iron-, manganese-, phosphate-, and organic-rich modern-lake stage that developed over the past 4000 yr. The chemical characteristics of the sediments deposited during these three lake phases can be represented by the average compositions of three groups of samples: (1) the average composition of sediments deposited over the past 2000 yr, representing the modern-lake stage; (2) the composition of a 50 varve sample centered on 5700 varve yr that represents the maximum clastic influx into the lake during the prairie period; and (3) the average composition of sediments deposited over the initial 2000 yr of the lake’s existence (10,400 to 8400 varve yr). The amplitudes of climatic oscillations, as reflected by changes in concentration of many climatically sensitive elements, were greatest during the prairie period, pronounced cycles having periodicities of several hundred years. The extremes of these oscillations occurred within several centuries or less, which suggests that significant changes in climate may occur abruptly and rapidly. Most notably, the end of the mid-Holocene prairie period, marked by a sudden decrease in the influx of detrital clastic material, occurred within a few decades.

Minnesota↗
USGS1993

Stable carbon and oxygen isotope studies of the sediments of Elk Lake, Minnesota

Variations in the ratios of 18 O: 16 O and 13 C: 12 C in calcite throughout the Holocene in Elk Lake, Minnesota, are recorded in three varve-calibrated carbonate cores. Marl in a varved deep-basin (29.6 m) core consists mainly of calcite precipitated from surface waters during the summer and probably provides the least complicated isotope record. Marl in a sublittoral (10 m) core consists of calcite contributed from several inorganic and organic sources and probably is the most complicated of the three isotope records. Calcite from shells of the ostracod Candona ohioensis in the sublittoral core provides a record of shallow-water conditions in Elk Lake for the period between 10,500 and 5500 varve yr. Variations in the 13 C: 12 C ratio of organic carbon deposited in Elk Lake during the Holocene are recorded in organic matter in the deep-basin core. All three oxygen isotope records show that, in general, the 18 O: 16 O ratio in carbonate was enriched in 18 O by several parts per mil during the mid-Holocene relative to the past few thousand years. This pattern of oxygen isotope variation is similar to that observed for carbonate materials from other lakes in the northeastern and north-central United States. Oxygen isotope records from these other lakes also show that the 18 O: 16 O ratio during the early Holocene was lower than during the mid-Holocene, and this pattern has been interpreted as representing a response to a generally warmer and drier climate during the mid-Holocene beginning about 8000 varve yr (the so-called hypsithermal). Ostracod and diatom assemblages from Elk Lake cores show, however, that the lake was colder and more saline than at present until at least 6700 varve yr, with conditions similar to those that exist today in cold prairie lakes of Canada. It may be more appropriate, therefore, to refer to the mid-Holocene in northwestern Minnesota as the “prairie period” rather than the hypsithermal, indicating that the climate was drier, but with no connotation regarding temperature. The oxygen isotope data from the three Elk Lake records for this period are somewhat equivocal. Values of δ 18 O in the marl from the sublittoral core and shells of Candona increase from 10,000 to about 6800 varve yr. However, values of δ 18 O in the marl that accumulated in the deepest part of the lake over the same interval (10,000–6800 varve yr) are more or less constant and enriched in 18 O; this probably reflects the cold, saline prairie-lake conditions predicted from the ostracod and diatom assemblage data. All three oxygen isotope records show decreases in 18 O: 16 O ratios after about 6800 varve yr in response to an increase in temperature and decrease in salinity of the lake. The 13 C: 12 C ratios in carbonates from all three Elk Lake records show a distinct pattern; the ratio increased gradually from 10,000 to 8000 varve yr going into the mid-Holocene prairie period and then decreased gradually coming out of the prairie period between about 5500 and 2500 varve yr. These changes in the 13 C: 12 C ratio could have been related to temperature through its effect on solubility of carbon dioxide; however, this interpretation is not supported by the oxygen isotope data. Another possibility is that changes in the 13 C: 12 C ratio are related to organic productivity that removes 13 C-depleted organic carbon and results in 13 C-enriched surface waters. This interpretation implies that organic productivity was higher in Elk Lake during the mid-Holocene prairie period. Support for the high-productivity, 13 C-enriched surface-water model for the mid-Holocene prairie period in Elk Lake is provided by changes in the 13 C: 12 C ratio of organic carbon in the deep-basin core. These changes parallel almost exactly those in the 13 C: 12 C ratio of carbonate carbon, but are about 2% larger (about 6% as opposed to about 4% for carbonate carbon). The difference of about 2% may represent 13 C depletion due to CO 2 limitation. The percentage of organic carbon in the sediment did not increase during the prairie period because it was diluted by an increased flux of detrital clastic material. The ultimate burial rate of organic carbon increased considerably, however, indicating that organic productivity was higher and/or the degree of preservation increased. Diatom assemblages and plant-pigment concentrations indicate that productivity was higher during the prairie period. Pyrolysis hydrogen and oxygen indices show that the 13 C-enriched organic matter that accumulated during the prairie period was hydrogen rich and oxygen poor relative to organic matter that accumulated before and after. These two indices demonstrate that the organic matter that accumulated during the prairie period was much better preserved.

Minnestoa↗
USGS1993

Climatic and limnologic setting of Elk Lake

Elk Lake is located on the Itasca moraine near the source of the Mississippi River in northwestern Minnesota. The basin is in calcareous glacial drift, and the lake water is a dilute solution of calcium and magnesium bicarbonate. Low-magnesian calcite formed by precipitation from the lake water has been a major component of the sediment throughout the lake’s history. The sediment also is laminated with alternating light and dark, millimeter-thick layers containing diatoms, organic matter, Fe(OH) 3 , and CaCO 3 . The sediment microstratigraphy has been preserved because the lake is unusually deep (maximum depth is 30 m) for its size (surface area is 1.01 km 2 ). Oxygen is present in low concentrations or absent in the deepest water during summer and winter. Water movements in the deepest part of the lake are insufficient some years for the complete aeration of the deepst water during spring and autumn circulation periods. Phytoplankton photosynthesis, which occurs mostly in the surficial 6 m of water, typically removes 0.5 g C m −2 day −1 from the epilimnion, which becomes strongly oversaturated with calcite during late spring and summer as the pH increases above the equilibrium pH (7.73) for calcite saturation. Most of the CaCO 3 that makes up the light-colored layers of sediments probably is formed during the late summer, when concentrations of calcium in the epilimnion decrease most rapidly. The silica and organic matter that form the darker sediment laminae are deposited earlier in the year, during a period extending from April to late June, when silica decreases fastest in the epilimnion.

Minnesota↗
USGS1993

Holocene climatic and limnologic history of the north-central United States as recorded in the varved sediments of Elk Lake, Minnesota: A synthesis

Integration of the results and interpretations of geochemical, paleoecological, and sedimentological analyses of a varved sediment record provides a detailed chronicle of limnological and climatic changes for the past 10 ka at Elk Lake, west-central Minnesota. The early Holocene record at Elk Lake was controlled by circumstances of glacial history (e.g., basin morphometry and surrounding till lithology) in combination with global warming at the end of the Pleistocene. Later, the interplay of climate change and a disintegrating ice sheet determined the character of local environments that were affected by reduction of precipitation and increased windiness during the middle Holocene. Elk Lake became more productive and clastic sediment increased to dominate the record as the forests thinned and prairie vegetation characterized the region. During this prairie period, winters may have been cold because disintegrating northern ice sheets ceased to block winter outbreaks of Arctic air. Correlations of wind-deposited materials throughout much of the eastern two-thirds of the United States suggest that drought conditions and strong winds were widespread between 8 and 4 ka. The mid-Holocene was climatically variable, however, with strong fluctuations in varve thickness at decadal, centennial, and millennial scales testifying to rapid climatic changes. Although the cause of such climatic cycles is not yet clear, correlations between 14 C anomalies and varve thickness suggest that variations in solar flux and resulting magnetic storms and zonal winds may have induced strong climatic changes. A particularly strong 600 yr fluctuation to cool and wet climates that may document neoglacial conditions around 5 ka interrupted the prairie period. After 4 ka, the climate at Elk Lake was dominated by a tropical airstream during the summer, and dry arctic and Pacific airstreams during the winter. Large-scale variations ceased, although decadal and multi-decadal variations in varve thickness chronicle changes similar, but not clearly correlative, to historically documented climatic episodes such as the Medieval Warm Period and the Little Ice Age.

Minnesota↗
USGS1993

Chronology of Elk Lake sediments: Coring, sampling, and time-series construction

A 22 m series of cores from a continuously laminated sequence of postglacial sediment was recovered from 29.6 m of water from the deepest part of Elk Lake, Clearwater County, Minnesota, by piston and freeze-coring methods during the winters of 1978 and 1982. A varve time series constructed and used as a basis for subsampling the cores and samples, based on the varve chronology, allows precise determination of fluxes of geochemical and biological sediment components. Chronological and petrographic studies have shown that the laminations are varves and their measurement and enumeration has produced a 10,400 year time series that estimates the rates and timing of paleolimnologic and paleoenvironmental changes in Elk Lake and its drainage. A radiocarbon date from surface sediment is 850 years. The difference between radiocarbon and varve dates continues down core; varve dates are older than radiocarbon dates, probably because of systematic incorporation of dead carbon (as bicarbonate) in organic matter in the sediment. Varve-dated boundaries of pollen zones in the Elk Lake cores compare closely with the ages of the same zones in cores from nearby lakes that have been radiocarbon dated.

Minnestoa↗
USGS1993

Modern sedimentation in Elk Lake, Clearwater County, Minnesota

The varved sediments of Elk Lake, Clearwater County, Minnesota, contain a 10,000 year record of climatic and limnologic events. Sediment traps deployed in the lake’s water column from 1979 to 1981 and from 1983 to 1984 collected samples that permitted us to identify materials, to see the timing of sedimentation events, and to deduce processes that form the microlaminae within varves. Fall and spring microlaminae consist mainly of sequential accumulations of biogenic silica and resuspended calcific and siliceous materials. Precipitates of iron, manganese, and organic detritus dominate the thin winter microlaminae. Calcific microlaminae are deposited in summer. Concentrated iron and manganese precipitates form when the onset of seasonal circulation (especially in autumn) oxygenates the lower water column, but precipitation of these metals also continues throughout periods of seasonal stratification, when these dissolved elements migrate upward and are converted to particles that rain back to the bottom. Mineraloids dominate the sediment; minerals compose only a minor part and include quartz, calcite, rhodochrosite, and rockbridgeite (iron phosphate). The bulk of the bottom accumulation occurs during the longer, calmer summer and winter periods, but important contributions are also made during spring and autumn overturn events. Sediment resuspended from the shallows accumulates together with newly formed endogenic sediment, and can even briefly dominate the seston in autumn and spring. Vigor and duration of seasonal circulations in the upper water column dictate the amount of resuspended sediment contributed annually to a varve. When abrupt warming within days after ice-out stratifies the lake, sedimentation in that year is diminished by resultant suppression of plankton blooms and lack of vernal resuspension that would normally move sediment from the littoral areas into the deep parts of Elk Lake. Thin sections of varves confirm that resuspension during autumn and spring is a varve-forming process that has probably varied in importance as a function of climate and changing morphometry due to infilling. Through an entire year, sediment traps catch a greater proportion of material from spring and autumn overturns than accumulates on the bottom. Lake morphometry is the most important factor governing sediment resuspension and associated annual accumulation rates in traps.

Minnesota↗
USGS1993

Environment of deposition of CaCO3 in Elk Lake, Minnesota

Elk Lake is near the present forest-prairie border in northwestern Minnesota, and is also located on the boundary between hard-water lakes that are typical of once-glaciated parts of the north-central United States and more saline prairie lakes of western Minnesota and the Dakotas. The sediments of the prairie lakes just west of Elk Lake are unusual in that they commonly contain high-Mg calcite and dolomite in addition to low-Mg calcite, which is the dominant carbonate mineral in most marl lakes. During the mid-Holocene dry period, prairie conditions expanded eastward into the forested regions of Minnesota. Variations in types and abundances of carbonate minerals in the Holocene sediments of Elk Lake recorded this climatic change. Studies of primary productivity, carbonate saturation, water chemistry, and sediment-trap samples show that low-Mg calcite precipitates during the summer, triggered by algal photosynthesis. The epilimnion of Elk Lake is always oversaturated with calcite, and the degree of oversaturation increases progressively during the summer. The pH of the epilimnion increases from <8.0 after spring overturn to almost 9.0 in late summer in response to photosynthetic removal of CO 2 during the summer months. The rate of calcium depletion from the epilimnion is proportional to the increase in pH and the rate of photosynthetic carbon fixation. Today the only carbonate minerals that are accumulating in the sediments of Elk Lake are low-Mg calcite and manganese carbonate (rhodochrosite). Rhodochrosite, and probably manganese oxyhydroxide, precipitates when manganese-rich anoxic bottom waters come in contact with carbonate-rich oxic surface waters. During the arid mid-Holocene prairie period, however, low-Mg calcite, dolomite, aragonite, and rhodochrosite all accumulated in the sediments of Elk Lake. Dolomite formed in Elk Lake during this period in response to a higher Mg:Ca ratio in the water, just as it is forming today in lakes of the prairie regions of western Minnesota. The coincident occurrence of aragonite and biological indicators of high salinity suggests that the salinity of Elk Lake and the Mg:Ca ratio were higher than in any of the present prairie lakes of western Minnesota.

Minnesota↗
USGS1989

Geochemical and paleoenvironmental variations across the Cretaceous/Tertiary boundary at Braggs, Alabama

The Cretaceous/Tertiary (K/T) boundary in southern Alabama occurs in a sequence of interbedded shallow-marine limestones and marls deposited during a Late Maastrichtian regression and subsequent Danian transgression. The presence of a diverse assemblage of Cretaceous and Paleocene benthic micro- and macrofossils has allowed detailed examination of paleoenvironmental changes in this shallow-marine setting at the time of the K/T boundary extinctions. Although extensive diagenesis has resulted in the recrystallization and cementation of whole rock carbonate, a few molluscan macrofossils have retained their original calcitic structure. The oxygen isotopic record of these macrofossils shows a gradual cooling of 2–3°C over a 3 m.y. period which began in the late Maastrichtian and continued into the Danian. The characteristic depletion in δ 13 C across the K/T boundary displayed by planktonic microfossils from pelagic sequences is not recorded at Braggs. Major changes in whole rock trace and minor element chemistry reflect the decrease in terrigenous mineral fluxes to this location brought about by the rapid Early Paleocene transgression.

Alabama↗
USGS1989

Geochemical evidence for suppression of pelagic marine productivity at the Cretaceous/Tertiary boundary

The normal, biologically productive ocean is characterized by a gradient of the 13 C/ 12 C ratio from surface to deep waters. Here we present stable isotope data from planktonic and benthic micro-fossils across the Cretaceous/Tertiary boundary in the North pacific, which reveal a rapid and complete breakdown in this biologically mediated gradient. The fluxes of barium (a proxy for organic carbon) and CaCO 3 also decrease significantly at the time of the major marine plankton extinctions. The implied substantial reduction in oceanic primary productivity persisted for ∼ 0.5 Myr before the carbon isotope gradient was gradually re-established. In addition, the stable isotope and preservational data indicate that environmental change, including cooling, began at least 200 kyr before the Cretaceous/Tertiary boundary, and a peak warming of ∼ 3 °C occurred 600 kyr after the boundary event.

Nature↗
USGS1989

Geochemical expression of early diagenesis in middle Eocene-lower Oligocene pelagic sediments in the southern Labrador Sea, Site 647, ODP Leg 105

Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below sea floor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic inability in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.Y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biagenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarser-grained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.

Proceedings of the Ocean Drilling Program: Scienti↗
USGS1988

Sediment deposition in the Late Holocene abyssal Black Sea with climatic and chronological implications

The temporal sedimentary patterns in the Late Holocene central eastern and western Black Sea are very similar. The sedimentary history was most visibly affected by the coccolithophorid species Emiliania huxleyi which briefly invaded the Black Sea for the first time (“First Invasion Period”), nearly disappeared again shortly afterwards (“Transition Sapropel”), but returned permanently several centuries later (“Final Invasion Period”). The temporary near-disappearance of E. huxleyi was probably caused by a temporary drop in salinity. Accumulation of E. huxleyi was on average about 40% higher in the western than in the eastern Black Sea. Highest coccolithophorid production occurred basin-wide during part of the Little Ice Age. The accumulation of terrigenous matter was generally higher in the eastern than in the western Black Sea by about 20%.

Deep Sea Research Part A, Oceanographic Research P↗