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Geology topics

W.E. Dean

Publications and source records attributed to W.E. Dean.

51 records · Page 3Linked to original sources
USGS1986

Geochemical variability of soils and biogeochemical variability of plants in the Piceance Basin, Colorado

Geochemical baselines for native soils and biogeochemical baselines for plants in the Piceance basin provide data that can be used to assess geochemical and biogeochemical effects of oil-shale development, monitor changes in the geochemical and biogeochemical environment during development, and assess the degree of success of rehabilitation of native materials after development. Baseline values for 52 properties in native soils, 15 properties in big sagebrush, and 13 properties in western wheatgrass were established. Our Study revealed statistically significant regional variations of the following properties across the basin: in soil&-aluminum, cobalt, copper, iron, manganese, sodium, nickel, phosphorus, lead, scandium, titanium, vanadium, zinc, organic and total carbon, pH, clay, dolomite, sodium feldspar, and DTPA-extractable calcium, cadmium, iron, potassium, manganese, nickel, phosphorus, yttrium, and zinc; in big sagebrush-barium, calcium, copper, magnesium, molybdenum, sodium, strontium, zinc, and ash; and in western wheatgrass-boron, barium, calcium, magnesium, manganese, molybdenum, strontium, zinc, and ash. These variations show up as north-south trends across the basin, or they reflect differences in elevation, hydrology, and soil parent material. Baseline values for properties that do not have statistically significant regional variations can be represented by geometric means and deviations calculated from all values within the basin. Chemical and mineralogical analyses of soil and chemical analyses of western wheatgrass samples from Colorado State University's experimental revegetation plot at Anvil Points provide data useful in assessing potential effects on soil and plant properties when largescale revegetation operations begin. The concentrations of certain properties are related to the presence of topsoil over spent shale in the lysimeters. In soils, calcium, fluorine, lithium, magnesium, sodium, phosphorus, strontium, carbonate and total carbon, and DTPA-extractable boron, copper, iron, magnesium, and nickel have lower concentrations in topsoil than in the spent oil shale; whereas, silicon, titanium, ytterbium, clay, quartz, and DTPA-extractable potassium have greater concentrations in the topsoil than in the spent oil shale. In western wheatgrass, molybdenum has a lower concentration in grasses growing on the topsoil than in grasses on the spent oil shale; whereas, barium, calcium, manganese, strontium, zinc, and ash have greater concentrations in grasses growing on the topsoil than on the spent oil shale. When compared to baseline values, soils in the revegetation plot are significantly higher in concentrations of lead, zinc, organic and total carbon, and DTP A-extractable cadmium, iron, manganese, nickel, phosphorus, and zinc. Whereas, western wheatgrass grown within the revegetation plot has concentrations which fall within the baseline values established in the regional study. The equations used in predicting concentrations of elements in plants from native and altered sites are cumbersome because of the large number of variables required to adequately predict expected concentrations and are of limited use because many explained only a small proportion of the total variation.

Professional Paper↗
USGS1985

Anomalous 13C enrichment in modern marine organic carbon

Marine organic carbon is heavier isotopically (13C enriched) than most land-plant or terrestrial organic C1. Accordingly, ??13C values of organic C in modern marine sediments are routinely interpreted in terms of the relative proportions of marine and terrestrial sources of the preserved organic matter2,3. When independent geochemical techniques are used to evaluate the source of organic matter in Cretaceous or older rocks, those rocks containing mostly marine organic C are found typically to have lighter (more-negative) ??13C values than rocks containing mostly terrestrial organic C. Here we conclude that marine photosynthesis in mid-Cretaceous and earlier oceans generally resulted in a greater fractionation of C isotopes and produced organic C having lighter ??13C values. Modern marine photosynthesis may be occurring under unusual geological conditions (higher oceanic primary production rates, lower PCO2) that limit dissolved CO2 availability and minimize carbon isotope fractionation4. ?? 1985 Nature Publishing Group.

Nature↗
USGS1984

Accumulation of organic matter in Cretaceous oxygen-deficient depositional environments in the central Pacific Ocean

Complete records of organic-carbon-rich Cretaceous strata were continuouslycored on the flanks of the Mid-Pacific Mountains and southern Hess Rise in the central North Pacific Ocean during DSDP Leg 62. Organic-carbon-rich laminated silicified limestones were deposited in the western Mid-Pacific Mountains during the early Aptian, a time when that region was south of the equator and considerably shallower than at present. Organic-carbon-rich, laminated limestone on southern Hess Rise overlies volcanic basement and includes 136 m of stratigraphic section of late Albian to early Cenomanian age. This limestone unit was deposited rapidly as Hess Rise was passing under the equatorial high-productivity zone and was subsiding from shallow to intermediate depths. The association of volcanogenic components with organic-carbon-rich strata on Hess Rise in the Mid-Pacific Mountains is striking and suggests that there was a coincidence of mid-plate volcanic activity and the production and accumulation of organic matter at intermediate water depths in the tropical Pacific Ocean during the middle Cretaceous. Pyrolysis assays and analyses of extractable hydrocarbons indicate that the organic matter in the limestone on Hess Rise is composed mainly of lipid-rich kerogen derived from aquatic marine organisms and bacteria. Limestones from the Mid-Pacific Mountains generally contain low ratios of pyrolytic hydrocarbons to organic carbon and low hydrogen indices, suggesting that the organic matter may contain a significant proportion of land-derived material, possibly derived from numerous volcanic islands that must have existed before the area subsided. The organic carbon in all samples analyzed is isotopically light ( δ 13 C − 24 to − 29 per mil) relative to most modern rine organic carbon, and the lightest carbon is also the most lipid-rich. There is a positive linear correlation between sulfur and organic carbon in samples from Hess Rise and from the Mid-Pacific Mountains. The slopes and intercepts of C-S regression lines however, are different for each site and all are different from regression lines for samples from modern anoxic marine sediments and from Black Sea cores. The organic-carbon-rich limestones on Hess Rise, the Mid-Pacific Mountains, and other plateaus and seamounts in the Pacific Ocean are not synchronous but do occur within the same general middle Cretaceous time period as organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean. Strata of equivalent age in the deep basins of the Pacific Ocean are not rich in organic carbon, and were deposited in oxygenated environments. This observation, together with the evidence that the plateau sites were considerably shallower and closse to the equator during the middle Creataceous suggests that local tectonic and hydrographic conditions may have resulted in high surface-water productivity and the preservation of organic matter in an oxygen-deficient environment where an expanded mid-water oxygen minimum developed and impinged on elevated platforms and seamounts.

Organic Geochemistry↗
USGS1984

Sinking of volcanic ash in uncompacted sediment in Williams Lake, Washington

Volcanic ash from the eruption of Mount St. Helens on 18 May 1980 fell into Williams Lake in eastern Washington and was temporarily suspended at the sediment-water interface. After several months of compaction, the ash layer broke up and sank into lower density uncompacted lake sediment. Stratigraphic time displacements of several hundred years and a failure to recognize discontinuous ash layers in sediment cores are possible consequences of this process.

Washington↗
USGS1983

Major and trace elements in Mahogany zone oil shale in two cores from the Green River Formation, piceance basin, Colorado

The Parachute Creek Member of the lacustrine Green River Formation contains thick sequences of rich oil-shale. The richest sequence and the richest oil-shale bed occurring in the member are called the Mahogany zone and the Mahogany bed, respectively, and were deposited in ancient Lake Uinta. The name "Mahogany" is derived from the red-brown color imparted to the rock by its rich-kerogen content. Geochemical abundance and distribution of eight major and 18 trace elements were determined in the Mahogany zone sampled from two cores, U. S. Geological Survey core hole CR-2 and U. S. Bureau of Mines core hole O1-A (Figure 1). The oil shale from core hole CR-2 was deposited nearer the margin of Lake Uinta than oil shale from core hole O1-A. The major- and trace-element chemistry of the Mahogany zone from each of these two cores is compared using elemental abundances and Q-mode factor modeling. The results of chemical analyses of 44 CR-2 Mahogany samples and 76 O1-A Mahogany samples are summarized in Figure 2. The average geochemical abundances for shale (1) and black shale (2) are also plotted on Figure 2 for comparison. The elemental abundances in the samples from the two cores are similar for the majority of elements. Differences at the 95% probability level are higher concentrations of Ca, Cu, La, Ni, Sc and Zr in the samples from core hole CR-2 compared to samples from core hole O1-A and higher concentrations of As and Sr in samples from core hole O1-A compared to samples from core hole CR-2. These differences presumably reflect slight differences in depositional conditions or source material at the two sites. The Mahogany oil shale from the two cores has lower concentrations of most trace metals and higher concentrations of carbonate-related elements (Ca, Mg, Sr and Na) compared to the average shale and black shale. During deposition of the Mahogany oil shale, large quantities of carbonates were precipitated resulting in the enrichment of carbonate-related elements and dilution of most trace elements as pointed out in several previous studies. Q-mode factor modeling is a statistical method used to group samples on the basis of compositional similarities. Factor end-member samples are chosen by the model. All other sample compositions are represented by varying proportions of the factor end-members and grouped as to their highest proportion. The compositional similarities defined by the Q-mode model are helpful in understanding processes controlling multi-element distributions. The models for each core are essentially identical. A four-factor model explains 70% of the variance in the CR-2 data and 64% of the O1-A data (the average correlation coefficients are 0. 84 and 0. 80, respectively). Increasing the number of factors above 4 results in the addition of unique instead of common factors. Table I groups the elements based on high factor-loading scores (the amount of influence each element has in defining the model factors). Similar elemental associations are found in both cores. Elemental abundances are plotted as a function of core depth using a five-point weighted moving average of the original data to smooth the curve (Figure 3 and 4). The plots are grouped according to the four factors defined by the Q-mode models and show similar distributions for elements within the same factor. Factor 1 samples are rich in most trace metals. High oil yield and the presence of illite characterize the end-member samples for this factor (3, 4) suggesting that adsorption of metals onto clay particles or organic matter is controlling the distribution of the metals. Precipitation of some metals as sulfides is possible (5). Factor 2 samples are high in elements commonly associated with minerals of detrital or volcanogenic origin. Altered tuff beds and lenses are prevalent within the Mahogany zone. The CR-2 end-member samples for this factor contain analcime (3) which is an alteration product within the tuff beds of the Green River Formation. Th

Conference Paper↗
USGS1981

Manganese cycles and the origin of manganese nodules, Oneida Lake, New York, U.S.A.

Oneida Lake is a large shallow lake in central New York that is characterized by high algal productivity and concentrated deposits of freshwater manganese nodules. Budgets for Mn in the lake and its tributaries show a net loss of 23 metric tons of manganese within the lake per year with ???95% deposited in manganese nodules and the rest incorporated in the sediments. Erosion of nodules in the shallow well-oxygenated central part of the lake produces fragments of nodules as well as Mn-coated sand grains that are transported to adjacent deeper, more reducing parts of the lake where they sink into the anoxic sediments and MnO2 is reduced to Mn2+. This produces a high concentration of Mn2+ in the pore waters of these sediments and Mn2+ diffuses back into the water column. Growth of manganese nodules in Oneida Lake is characterized by periods of rapid accretion (> 1 mm 100 yr.) alternating with periods of no-growth or erosion. Rapid growth of nodules may be aided by the stripping of Mn from the water column by algae and bacteria. In addition, the high algal productivity of Oneida Lake produces a high-pH high-oxygen environment during the summer months that is maintained throughout the water column in the central part of the lake by almost continuous wind mixing. Thus, the cycle of Mn within the lake involves an interaction of the weather, the biota, the sediments, the nodules, and Mn dissolved in the lake and interstitial waters. ?? 1981.

Chemical Geology↗
USGS1980

Growth rates of manganese nodules in Oneida Lake, New York

226 Ra is used to document the growth histories of six manganese nodules from Oneida Lake, New York. Detailed sectioning and analysis reveal that there are discontinuous gradients in 226 Ra content in these samples. These gradients result from periods of rapid growth (>1 mm/100 years) separated by periods of no growth of erosion. Although the 226 Ra “age” of the nodules approximates the age of Oneida Lake, the nodules are not sediment-covered because they occur only in areas of the lake where fine-grained sediments are not accumulating.

New York↗
USGS1980

Sedimentology and geochemistry of surface sediments, outer continental shelf, southern Bering Sea

Present-day sediment dynamics, combined with lowerings of sea level during the Pleistocene, have created a mixture of sediments on the outer continental shelf of the southern Bering Sea that was derived from the Alaskan Mainland, the Aleutian Islands, and the Pribilof ridge. Concentrations of finer-grained, higher-organic sediments in the region of the St. George basin have further modified regional distribution patterns of sediment composition. Q-mode factor analysis of 58 variables related to sediment size and composition - including content of major, minor, and trace elements, heavy and light minerals, and clay minerals - reveals three dominant associations of sediment: 1. (1) The most significant contribution, forming a coarse-grained sediment scattered over most of the shelf consists of felsic sediment derived from the generally quartz-rich rocks of the Alaskan mainland. This sediment contains relatively high concentrations of Si, Ba, Rb, quartz, garnet, epidote, metamorphic rock fragments, potassium feldspar, and illite. 2. (2) The next most important group, superimposed on the felsic group consists of andesitic sediment derived from the Aleutian Islands. This more mafic sediment contains relatively high concentrations of Na, Ca, Ti, Sr, V, Mn, Cu, Fe, Al, Co, Zn, Y, Yb, Ga, volcanic rock fragments, glass, clinopyroxene, smectite, and vermiculite. 3. (3) A local group of basaltic sediment, derived from rocks of the Pribilof Islands, is a subgroup of the Aleutian andesite group. Accumulation of fine-grained sediment in St. George basin has created a sediment group containing relatively high concentrations of C, S, U, Li, B, Zr, Ga, Hg, silt, and clay. Sediment of the Aleutian andesite group exhibits a strong gradient, or "plume", with concentrations decreasing away from Unimak Pass and toward St. George basin. The absence of present-day currents sufficient to move even clay-size material as well as the presence of Bering submarine canyon between the Aleutian Islands and the outer continental shelf and slope, indicates that Holocene sediment dynamics cannot be used to explain the observed distribution of surface sediment derived from the Aleutian Islands. We suggest that this pattern is relict and resulted from sediment dynamics during lower sea levels of the Pleistocene.

Alaska↗