Geology topics

W.B. Durham

Publications and source records attributed to W.B. Durham.

22 records · Page 2Linked to original sources

USGS1997

Synthesis of polycrystalline methane hydrate, and its phase stability and mechanical properties at elevated pressure

Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.

ACS Division of Fuel Chemistry, Preprints↗

USGS1996

Rheology of water ices V and VI

We have measured the mechanical strength (σ) of pure water ices V and VI under steady state deformation conditions. Constant displacement rate compressional tests were conducted in a gas apparatus at confining pressures from 400 < P < 800 MPa, temperatures from 209 < T < 270 K, and strain rates 7 × 10 −7 < < 7 × 10 −4 s −1 . Most of the results fit to an empirical flow law of the form = A σ n exp {−( E * + PV *)/ RT }, where the four material constants A , n , E *, and V * are (for in inverse seconds and P and σ in megapascals) 10 23.0 , 6.0, 136 kJ/mol, and 29 cm 3 /mol, respectively, for ice V; and 10 6.7 , 4.5, 66 kJ/mol, and 11 cm 3 /mol, respectively, for ice VI. Ice VI may weaken to a mechanism of higher E * at T > 250 K. Ices V and VI are thus rheologically distinct but by coincidence have approximately the same strength under the conditions chosen for these experiments. To avoid misidentification, these tests are therefore accompanied by careful observations of the occurrences and characteristics of phase changes. One sample each of ice V and VI was quenched at pressure to metastably retain the high-pressure phase and the acquired deformation microstructures; X ray diffraction analysis of these samples confirmed the phase identification. Surface replicas of the deformed and quenched samples suggest that ice V probably deforms largely by dislocation creep, while ice VI deforms by a more complicated process involving substantial grain size reduction through recrystallization.

Journal of Geophysical Research B: Solid Earth↗

USGS1991

Mantle phase changes and deep-earthquake faulting in subducting lithosphere

Inclined zones of earthquakes are the primary expression of lithosphere subduction. A distinct deep population of subduction-zone earthquakes occurs at depths of 350 to 690 kilometers. At those depths ordinary brittle fracture and frictional sliding, the faulting processes of shallow earthquakes, are not expected. A fresh understanding of these deep earthquakes comes from developments in several areas of experimental and theoretical geophysics, including the discovery and characterization of transformational faulting, a shear instability connected with localized phase transformations under nonhydrostatic stress. These developments support the hypothesis that deep earthquakes represent transformational faulting in a wedge of olivine-rich peridotite that is likely to persist metastably in coldest plate interiors to depths as great as 690 km. Predictions based on this deep structure of mantle phase changes are consistent with the global depth distribution of deep earthquakes, the maximum depths of earthquakes in individual subductions zones, and key source characteristics of deep events.

Science↗

USGS1987

Inelastic properties of ice Ih at low temperatures and high pressures

The aim of our research programme is to explore the rheological behavior of H 2 O ices under conditions appropriate to the interiors of the icy satellites of the outer planets in order to give insight into their deformation. To this end, we have performed over 100 constant-strain-rate compression tests at pressures to 500 MPa and temperatures as low as 77 K. At P > 30 MPa, ice I h fails by a shear instability producing faults in the maximum shear stress orientation and failure strength typically is independent of pressure. This unusual faulting behavior is thought to be connected with phase transformations localized in the shear zones. The steady-state strength follows rheological laws of the thermally-activated power-law type, with different flow law parameters depending on the range of test temperatures. The flow laws will be discussed with reference to the operating deformation mechanisms as deduced from optical-scale microstructures and comparison with other work.

Journal de Physique Colloques↗