W. H. Ficklin — Page 3

USGS1976

Flameless atomic absorption determination of bismuth in soils and rocks

Recent advances in flameless atomic absorption allow determinations of bismuth in concentrations as small as 50 ppb in 0.2 g of rock or soil sample. The sample is fused with sodium bisulfate and the fusion product is leached with hot 2 M hydrochloric acid and treated with ammonium citrate, (ethylenedinitrilo) tetraacetic acid disodium salt, and finally with ammonium 1-pyrrolidinedithiocarbamate to form a complex which is extracted into methyl isobutyl ketone. Aliquots of the latter are pipetted into a graphite furnace and then subjected to an established and automated program of drying, charring, and atomizing. Recorded peak heights provide a measure of the amount of bismuth present.

Journal of Research of the U.S. Geological Survey↗

USGS1975

Ion-selective electrode determination of iodine in rocks and soils

Use of an iodide-ion-selective electrode permits rapid and fairly accurate determination of iodine (as iodide) in rocks and soils. When a 1-g sample is used, concentrations as small as 0.5 ppm can be determined with a precision of about 25-percent relative standard deviation. When bromine concentration is greater than 5 ppm, the same method can be used for bromine determination. The procedure merits further investigation as a possible tool in geochemical prospecting.

Journal of Research of the U.S. Geological Survey↗