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Vincent T. DePaul

Publications and source records attributed to Vincent T. DePaul.

11 recordsLinked to original sources

Use of multi-resolution, three-dimensional hydrodynamic and water-quality models to assess response to nutrient load reductions in Barnegat Bay-Little Egg Harbor estuary, New Jersey, USA

A coupled three-dimensional hydrodynamic water-quality model has been applied to Barnegat Bay-Little Egg Harbor Estuary, a shallow, back-barrier lagoon located along the central New Jersey coastline. The study aims to enhance understanding of phytoplankton dynamics and nutrient cycling and to quantify estuarine response to potential nutrient load management strategies. The model was calibrated with data from Spring and Summer of 2012 and adequately reproduced spatiotemporal water-quality variability, distribution patterns, trends, and gradients throughout the system. The calibrated model was used to run scenarios for evaluating estuarine response to various nitrogen load reduction intensities. Model results show that geographically focused, variable nitrogen reductions can mitigate the effects of eutrophication and promote improvements in water quality. This study illustrates the role of modeling in developing informed management strategies, highlights complex, nonlinear responses of estuarine environments to anthropogenic influences, and demonstrates how models can be used to develop adaptive, location-specific nutrient management practices.

New Jersey

Predictive understanding of stream salinization in a developed watershed using machine learning

Stream salinization is a global issue, yet few models can provide reliable salinity estimates for unmonitored locations at the time scales required for ecological exposure assessments. Machine learning approaches are presented that use spatially limited high-frequency monitoring and spatially distributed discrete samples to estimate the daily stream-specific conductance across a watershed. We compare the predictive performance of space- and time-unaware Random Forest models and space- and time-aware Recurrent Graph Convolution Neural Network models (KGE: 0.67 and 0.64, respectively) and use explainable artificial intelligence methods to interpret model predictions and understand salinization drivers. These models are applied to the Delaware River Basin, a developed watershed with diverse land uses that experiences anthropogenic salinization from winter deicer applications. These models capture seasonality for the winter first flush of deicers, and the streams with elevated predictions correspond well with indicators of deicer application. This result suggests that these models can be used to identify potential salinity-impaired streams for winter best management practices. Daily salinity predictions are driven primarily by land cover (urbanization) trends that may represent anthropogenic salinization processes and weather at time scales up to three months. Such modeling approaches are likely transferable to other watersheds and can be applied to further understand salinization risks and drivers.

Environmental Science and Technology

Simulation of flow and eutrophication in the central Salem River, New Jersey

The central Salem River in New Jersey is subject to periods of water-quality impairment, marked by elevated concentrations of phosphorus and chlorophyll- a , and low concentrations of and large diurnal swings in concentrations of dissolved oxygen. These seasonal eutrophic conditions are controlling factors for water quality in lower reaches, where the river is more lacustrine than in upper reaches, as a result of downstream damming. This biological productivity is supported by nutrient wash-off from agricultural areas in the surrounding watershed. To investigate this impairment, flow measurement and water-quality sampling were conducted during 2007–08 in support of development of a one-dimensional surface-water-quality model that simulates nutrient cycling and transformation processes. The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, used the U.S. Environmental Protection Agency Water Quality Analysis Simulation Program (WASP) to develop a receiving-water-quality model of the central Salem River between Woodstown and Deepwater, New Jersey, from April 2007 to October 2008. The main-stem river and largest tributary were simulated. In the flow model, kinematic wave flow is used to simulate flow in upper reaches and ponded weir flow is used to simulate flow in lower reaches. The water-quality model makes use of a mass-balance equation to simulate the fate and transport of nutrients, phytoplankton chlorophyll- a , dissolved oxygen, and oxygen demands (an indicator rather than a substance) in the river. Model input included channel characteristics, boundary conditions for flow and water quality, environmental parameters, vertical dispersion coefficients, settling rates, and kinetic constants. Inputs were estimated where field data were lacking, notably for tributary flows and nutrient loads. The model was calibrated to observed flow variables and concentrations of dissolved oxygen, chlorophyll- a , and nutrients at sampling locations, with emphasis on growing-season conditions. Calibration was achieved through graphical and statistical comparison of simulated results to observed data. Sensitivity analyses were performed, and model limitations and applicability were evaluated. Simulated results closely matched observed data in most cases, although some were overpredicted slightly. The most important causes of overprediction were estimated tributary flows for the flow model and estimated tributary watershed loads for the water-quality model. Calibration of dissolved-oxygen concentrations was closer, and predicted diurnal variations were consistent with high algal photosynthesis/respiration, although lack of continuous dissolved-oxygen data precluded verifying these predictions. A similar caveat applies to predicted diurnal variations in chlorophyll- a . Simulated limitations on algal growth were consistent with those based on observed data and indicated phosphorus was the main limiting nutrient, except during certain periods when nitrogen was limiting. Two water-quality management scenarios were simulated with the model to assess the effect of point- and nonpoint-source nutrient reductions on water-quality conditions in the river. Scenarios involved (1) a return of watershed land use to predevelopment natural conditions and (2) an extreme reduction in nutrient input. Although the extreme-nutrient-reduction scenario yielded improvements in water quality, the natural-conditions scenario yielded the largest improvements as indicated by minimal violations of surface-water-quality standards or thresholds. However, years may be needed to attain the full benefit of these management scenarios as a result of accumulation of phosphorus and organic carbon in riverbed sediments in lacustrine reaches. The results of this study indicate that the quality of water in the central Salem River will improve if management policies that mitigate the effects of nutrient-loading practices in the watershed, particularly those related to agriculture, are implemented.

New Jersey

In situ benthic nutrient flux and sediment oxygen demand in Barnegat Bay, New Jersey

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, measured sediment oxygen demand (SOD) and benthic nutrient fluxes throughout Barnegat Bay, New Jersey. SOD was determined in situ using chambers equipped with optical dissolved oxygen sensors. The benthic nutrient fluxes of ammonia (NH3), nitrite + nitrate (plus ions; here, referred to as NO32), soluble reactive phosphorous (SRP), and dissolved silica (SiO2) were measured with in situ equilibrium dialysis samplers. Measurements were made at nine stations around the periphery and at three mid-Bay locations from August 2012 to October 2013. The SOD ranged from −1.5 to −8.4 g of oxygen (O2) m−2 d−1. The SOD rates varied as a function of water temperature and followed the van't Hoff rate equation for change in reaction rate with temperature, with a temperature coefficient (Θ) that varied among sites and averaged 1.083. The highest SOD rates in the bay were measured near the mouth of the Toms River embayment. Concentrations in the upper 1 m of sediment pore water were found up to 23 mg N L−1 for NH4+ and 6.7 mg P L−1 for SRP. Maximum measured fluxes into the overlying water were 3.0 × 10−2 g NH3–N m−2 d−1, 7.0 × 10−4 g NO32–N m−2 d−1, 1.9 × 10−3 g P m−2 d−1, and 3.6 × 10−3g SiO2 m−2 d−1. Using the measured benthic N and P fluxes, daily nutrient inputs derived from sediment recycling are shown to be comparable in scale to freshwater tributary inputs to the bay.

New Jersey

Towards a comprehensive water quality modeling of Barnegat Bay: Development of ROMS to WASP Coupler

The Regional Ocean Modeling System (ROMS) has been coupled with the Water Quality Analysis Simulation Program (WASP) to be used in a comprehensive analysis of water quality in Barnegat Bay, New Jersey. The coupler can spatially aggregate hydrodynamic information in ROMS cells into larger WASP segments. It can also be used to resample ROMS output at a finer temporal scale to meet WASP time-stepping requirements. The coupler aggregates flow components, temperature, and salinity in ROMS output for input to WASP via a hydrodynamic linkage file. The coupler was tested initially with idealized cases designed to verify the water mass balance and conservation of constituent mass using one-to-one and one-to-many connectivity options between segments. A realistic example from the Toms River embayment, a subdomain of Barnegat Bay, was used to demonstrate the functionality of the coupling. A WASP eutrophication model accounting for dissolved oxygen (DO), nitrogen, and constant phytoplankton concentrations was applied to explore the distribution and trends in DO and nitrogen in the embayment for the period of July–August 2012. Results of DO modeling indicate satisfactory agreement with measurements collected at in-bay stations and also indicate that this coupled approach, despite substantial differences in spatiotemporal discretization between the models, provides adequate predictive capabilities.

New Jersey

Water-level conditions in the confined aquifers of the New Jersey Coastal Plain, 2008

Groundwater-level altitudes in 10 confined aquifers of the New Jersey Coastal Plain were measured and evaluated to provide an overview of regional groundwater conditions during fall 2008. Water levels were measured in more than 900 wells in New Jersey, eastern Pennsylvania, and northern Delaware and potentiometric surface maps prepared for the confined Cohansey aquifer of Cape May County, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, the Piney Point, Vincentown, and the Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Upper, Middle, and Lower aquifers of the Potomac-Raritan-Magothy aquifer system. In 2008, the highest water-level altitudes were observed in the Vincentown aquifer (median, 78 ft) and the lowest in the Atlantic City 800-foot sand (median, -45 ft). Persistent, regionally extensive cones of depression were present within the potentiometric surfaces of the Englishtown aquifer system in east-central New Jersey, the Wenonah-Mount Laurel aquifer in east-central and southern New Jersey, the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers in southern New Jersey, and the Atlantic City 800-foot sand in the southeastern part of the State. Cones of depression in the potentiometric surfaces of the Upper Potomac-Raritan-Magothy and the Piney Point aquifers in east-central and southwestern New Jersey had broadened and deepened since 2003. Declining water levels in many of New Jersey’s confined Coastal Plain aquifers intensified during the late 1970s and early 1980s, prompting the designation of two water-supply Critical Areas by the New Jersey Department of Environmental Protection; Critical Areas 1 and 2 continued to be of concern. To address that concern, water-level changes were assessed in nearly 800 wells measured during the fall of 2003 and 2008, and potentiometric-surface difference maps for each aquifer were constructed and evaluated. In addition, water-level trends were calculated for 77 wells for the periods 2003–8 and 1998–2008 and for 73 wells for the period 1978–2008. From 2003 to 2008 small to moderate water-level changes were observed in many Coastal Plain aquifers in New Jersey, but in places, groundwater levels continued to decline substantially as a result of pumping. Groundwater levels in the Atlantic City 800-foot sand were lower in 2008 than in 2003; declines were greatest near pumping centers in eastern Atlantic County. Changes were less pronounced in Cape May County where water levels were, on average, 1 to 3 feet (ft) lower than those during the previous study (2003), except near Rio Grande where a localized cone of depression had formed as a result of increased withdrawals. Large and widespread declines occurred in the Piney Point aquifer in Cumberland County where water levels in and around the city of Bridgeton had fallen in excess of 100 ft since 2003, and by 30 ft to more than 60 ft in surrounding areas. Groundwater levels in the Wenonah-Mount Laurel aquifer and Englishtown aquifer system continued to recover in east-central New Jersey; however, groundwater levels in the Wenonah-Mount Laurel aquifer throughout the southern part of the State continued to decline. In the Upper Potomac-Raritan-Magothy aquifer, groundwater levels were substantially lower than in 2003 in parts of northern Ocean County but were stable in the area adjacent to Raritan Bay (Critical Area 1), and water levels continued to recover in southern New Jersey. In the Middle Potomac-Raritan-Magothy aquifer, water levels rose near Raritan Bay in Middlesex County; however, modest declines were recorded in interior areas of Monmouth and Ocean Counties. Groundwater levels in both the Middle and Lower Potomac-Raritan-Magothy aquifers were stable or rising within the regional cone of depression in Critical Area 2; beyond the critical area in southern New Jersey, however, water levels were slightly lower than in 2003. Analyses of long-term water-level changes indicate that from 1978 to 2008 downward trends occurred at 20 wells (27 percent), upward trends at 27 wells (37 percent), and trends at 26 wells (36 percent) were insubstantial. Sustained, long-term declines were observed most often at wells within the Atlantic City 800-foot sand and at wells in the Piney Point aquifer in southern New Jersey, in which rates of decline were as great as 1.4 feet/year. Upward water-level trends were observed frequently at wells screened in the Englishtown aquifer system and the Wenonah-Mount Laurel aquifer in Critical Area 1 in east-central New Jersey, and in the Potomac-Raritan-Magothy aquifer system in parts of Critical Area 1 and throughout most of Critical Area 2 in southern New Jersey. Annual rates of upward change were as great as 3.9 and 5.6 ft/yr in the Englishtown aquifer system and Wenonah-Mount Laurel aquifer, respectively. Among the units of the Potomac-Raritan-Magothy aquifer system, annual rates of recovery were greatest in the Lower aquifer. From 1998 to 2008, downward water-level trends were observed at 22 wells (29 percent), upward trends were observed at 21 wells (27 percent), and insubstantial trends at 34 wells (44 percent). Downward trends were detected most often at wells open to the Piney Point aquifer and the Atlantic City 800-foot sand. Upward water-level trends were most frequent in wells open to the Englishtown aquifer system in Critical Area 1 and in wells within the Potomac-Raritan-Magothy aquifer system in southern New Jersey.

New Jersey

Water-level conditions in selected confined aquifers of the New Jersey and Delaware coastal plain, 2003

The Coastal Plain aquifers of New Jersey provide an important source of water for more than 2 million people. Steadily increasing withdrawals from the late 1800s to the early 1990s resulted in declining water levels and the formation of regional cones of depression. In addition to decreasing water supplies, declining water levels in the confined aquifers have led to reversals in natural hydraulic gradients that have, in some areas, induced the flow of saline water from surface-water bodies and adjacent aquifers to freshwater aquifers. In 1978, the U.S. Geological Survey began mapping the potentiometric surfaces of the major confined aquifers of New Jersey every 5 years in order to provide a regional assessment of ground-water conditions in multiple Coastal Plain aquifers concurrently. In 1988, mapping of selected potentiometric surfaces was extended into Delaware. During the fall of 2003, water levels measured in 967 wells in New Jersey, Pennsylvania, northeastern Delaware, and northwestern Maryland were used estimate the potentiometric surface of the principal confined aquifers in the Coastal Plain of New Jersey and five equivalent aquifers in Delaware. Potentiometric-surface maps and hydrogeologic sections were prepared for the confined Cohansey aquifer of Cape May County, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, the Vincentown aquifer, and the Englishtown aquifer system in New Jersey, as well as for the Piney Point aquifer, the Wenonah-Mount Laurel aquifer, and the Upper Potomac-Raritan-Magothy, the Middle and undifferentiated Potomac-Raritan-Magothy, and the Lower Potomac-Raritan-Magothy aquifers in New Jersey and their equivalents in Delaware. From 1998 to 2003, water levels in many Coastal Plain aquifers in New Jersey remained stable or had recovered, but in some areas, water levels continued to decline as a result of pumping. In the Cohansey aquifer in Cape May County, water levels near the center of the cone of depression underlying the southern part of the peninsula remained about the same as in 1998. To the south, recoveries up to 8 feet were observed in southern Lower Township as withdrawals had decreased since 1998. In the northern part of Cape May County, water levels had not changed substantially from historic conditions. In the Rio Grande water-bearing zone, water levels rose by as much as 13 ft at the Rio Grande well field; elsewhere across the aquifer, little change had occurred. In the Atlantic City 800-foot sand, water-level changes were greatest in southern Cape May County; at the Cape May desalination wells, water levels were as much as 32 ft lower in 2003 than in 1998. In contrast, water levels at the center of a regional cone of depression near Atlantic City rose by as much as 10 ft. Within the Piney Point aquifer water levels rose by 46 ft near Seaside Park. Similarly, water levels increased by more than 30 ft in and around the major cone of depression underlying Dover, Delaware. In the Vincentown aquifer, water levels stabilized or recovered by 2 ft to 6 ft from 1998 to 2003 in most of the wells measured; the exception is near Adelphia in Monmouth County, where water levels rose by as much as 18 ft. From 1998 to 2003, water levels near the center of a large cone of depression that extends from Monmouth to Ocean County recovered by as much as 20 ft in the Wenonah-Mount Laurel aquifer. Concurrently, ground-water levels within the Englishtown aquifer system declined by as much as 13 ft in the same area. Water levels across much of the Upper Potomac-Raritan-Magothy aquifer in the northern Coastal Plain remained about the same as 5 years previous, except in northern Ocean County where ground-water levels declined 10 ft to 33 ft. Water levels in the Middle Potomac-Raritan-Magothy aquifer declined from 5 to 9 ft along the border between Monmouth and Middlesex County. Elsewhere, across the northern part of the Coastal Plain, water levels stabilized within the Cretaceous-a

Delaware, New Jersey

Reconnaissance of volatile organic compounds in the subsurface at Rutgers University, Busch Campus, Piscataway Township, New Jersey

During 1991-92, the U.S. Geological Survey conducted a hydrogeologic reconnaissance at a site near the Rutgers University, Busch Campus, Chemical Engineering building, C-Wing. Results of analyses of the soil-gas samples, which were collected at 43 locations, indicated the presence of volatile organic compounds, primarily carbon tetrachloride, near the C-Wing building and about 550 feet downgradient from and southwest of the C-Wing building. Concentrations of the compound in soil-gas samples were highest (2.1 ug/L (micrograms per liter)) along the southwestern wall of the C-Wing building. Ground-water samples were collected at depths as great as 55 feet from five wells and piezometers near the C-Wing building. Samples collected along the southwestern wall of the building also contained the highest concentrations of volatile organic compounds. Concentrations of carbon tetrachloride in the ground-water samples ranged from < 0.35 ug/L to 3,400 ug/L, and concentrations of tetrachloro- ethylene ranged from < 0.28 ug/L to 85 ug/L. Ground-water samples collected at depths of 55 feet or more from two wells located on the Rutgers University Golf Course about 2,400 feet down- gradient from the C-Wing building contained concentrations of tetrachloroethylene as great as 17.7 ug/L. Water levels measured in six wells and six piezometers indicated that the general flow direction in the shallow part of the aquifer is to the southwest of the C-Wing building. An electrical-resistivity survey was conducted by azimuthal resistivity techniques. The results of the survey were consistent with field measurements, and the dominant vertical fractures near the Busch Campus trend northeast. An electromagnetic survey was ineffective as a result of cultural interferences and could not be used to determine the hydrogeologic characteristics of the site.

New Jersey