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Todd K. Hinkley

Publications and source records attributed to Todd K. Hinkley.

7 recordsLinked to original sources

Comment on "Next-Generation Ice Core Technology Reveals True Minimum Natural Levels of lead (Pb) in the atmosphere: Insights from the Black Death" by More et al.

Results and interpretation of the subject article are surprising and conflict with expectations about atmospheric deposition of lead (Pb) Before interpretation of subject article is accepted a body of information about natural deposition of lead (Pb) must be considered This body of information includes knowledge of volcano emissions, chemistry of natural dusts, and isotopes of lead (Pb)

Geohealth News

Rock-forming metals and Pb in modern Alaskan snow

Metal concentrations in annual and subannual increments of snowpack from the accumulation zone of a south central Alaska glacier indicate that the deposition of Pb with and upon snow is decoupled from that of rock dusts. Rock dusts accumulate, apparently as dry deposition, on the topmost, exposed surfaces of snowpacks in spring and summer, whereas Pb does not. Pb concentration is elevated throughout the latest one third of an annual snowpack, whereas that of rock dusts is not. For whole-year snowpacks, there is a generally sympathetic relationship among concentration of Pb, concentration of rock dust, degree of dominance of rock dusts over ocean solutes, and ferromagnesian character of the rock dusts; however, the fractional abundance of Pb in whole year samples may decrease when rock dust masses become large and/or when rock dusts dominate most strongly over salts. The metal suite chosen to characterize rock dusts and to distinguish them from ocean solutes gives detailed information about rock type of dust source areas and about the nature of the degraded rock products that are taken up, transported, and deposited by the atmosphere. Rock dusts are present at concentrations of only about 300 nanograms (ng) of dust per gram of snow in the Alaskan snowpacks. Concentrations of Pb in the Alaska snow samples are moderate, ranging from 0.1 to 0.3 ng Pb/g snow. This contrasts with larger Pb concentrations of 0.4 to 0.9 ng Pb/g snow in whole-year snowpack samples from the Sierra Nevada, California; with similar to smaller concentrations from north and south Greenland of about 0.04 ng Pb/g snow or less, and about 0.2 ng Pb/g snow or less, respectively, and with much smaller concentrations from Antarctica, now believed to range from a minimum of about 0.001 to a maximum of 0.005 (or 0.01) ng Pb/g snow.

Journal of Geophysical Research D: Atmospheres

Determination of lead, cadmium, indium, thallium and silver in ancient ices from Antarctica by isotope dilution-thermal ionization mass spectrometry

The concentrations of five chalcophile elements (Pb, Cd, In, Tl and Ag) and the lead isotope ratios in ancient ices from the Taylor Dome near coastal Antarctica, have been determined by the isotope dilution-thermal ionization mass spectrometry (ID-TIMS), with ultra-clean laboratory techniques. The samples were selected from segments of cores, one of which included a visible ash layer. Electric conductivity measurement (ECM) or dielectric properties (DEP) gave distinctive sharp peaks for some of the samples chosen. Exterior portions of the sample segments were trimmed away by methods described here. Samples were evaporated to dryness and later separated into fractions for the five elements using an HBr-HNO 3 anion exchange column method. The concentrations are in the range 2.62-36.7 pg Pb/g of ice, 0.413-2.83 pg Cd/g, 0.081-0.34 pg ln/g, 0.096-2.8 pg Tl/g and 0.15-0.84 pg Ag/g, respectively. The dispersions in duplicate analyses are about ±1% for lead and cadmium, ±2% for indium, ±4% for thallium and ±6% for silver, respectively. The concentrations of lead obtained are commonly higher than those in the present-day Antarctic surface snows, but the isotope ratios are distinctively higher than those of the present-day snows and close to those of the other ancient ice collected from a different Antarctic area.

Geochemical Journal

Overburden chemistry and mineralogy at Hanging Woman Creek, Big Horn County, Montana, and recommendations for sampling at similar sites

Cored overburden rock of the Fort Union Formation at the Hanging Woman Creek potential coal mine site was classified in hand specimen on the basis of color and grain size into 3 types: sandstone. siltstone-plus-shale, and dark shale. The samples were analyzed for bulk chemistry and mineralogy. In general the samples of sandstone contain the lowest concentrations of elements of environmental concern (arsenic, beryllium, mercury. molybdenum, selenium and sulfur), and samples of the dark shale contain the highest. Comparison of samples within each rock type shows that chemical composition does not change systematically across the study site (a distance of 5 km), and almost as much information about overburden chemistry could have been obtained from a single hole drilled anywhere on the site. Overburden data from other sites in the region show that rocks at the Hanging Woman Creek site are chemically similar to those of the region as a whole, which suggests that the rock chemistry at other sites in the region could also be estimated from a low-density drilling and sampling pattern.

Montana