Geology topics
Timothy S. Hayes
Publications and source records attributed to Timothy S. Hayes.
Fluorine
Fluorine compounds are essential in numerous chemical and manufacturing processes. Fluorspar is the commercial name for fluorite (isometric CaF 2 ), which is the only fluorine mineral that is mined on a large scale. Fluorspar is used directly as a fluxing material and as an additive in different manufacturing processes. It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. The United States was the world’s leading producer of fluorspar until the mid-1950s. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. Since then, U.S. fluorspar consumption has decreased substantially; the United States has nonetheless increased its imports of downstream fluorine compounds, such as, in order of tonnage imported, hydrofluoric acid, aluminum fluoride, and cryolite. This combination of no U.S. production (until recently) and high levels of consumption has made the United States the world’s leading fluorspar-importing country, in all its various forms. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs. In 2013, the United States imported the majority of its fluorspar from three countries, which were, in descending order of the amount imported, Mexico, China, and South Africa. Geologically, in igneous systems, fluorine is one of a number of elements that are “incompatible.” These incompatible elements become concentrated in the residual magma while the common silicates crystallize upon magma ascent and cooling, leading to relatively high fluorine concentrations in the more evolved or differentiated igneous rocks and in hydrothermal deposits associated with those evolved igneous rocks. In sedimentary rocks, fluorine’s highest concentrations are found in phosphorites because fluorine substitutes for hydroxyl ions in apatite, which leads to fluorine concentrations of, typically, from 2 to 4 weight percent in phosphorites. Because of the presence of fluorine, phosphate fertilizer manufacturers can produce a fluorosilicic acid byproduct. Most deposits mined for fluorine are hydrothermal, however, and consist of fluorine minerals that precipitated from hot water. Magmatic brines and brines from deep within sedimentary basins that have high concentrations of dissolved fluoride are the mineralizing fluids for various types of hydrothermal fluorspar deposits. Relatively dilute hydrothermal fluids that formed in some volcanic rocks can also transport sufficient fluoride to form a high-grade fluorspar deposit. Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (°C) down to 60 °C. The increasing fluorite solubility below 60 °C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. The geologic conditions that led to the high concentrations there are known to exist in a number of other places in the world as well, including, perhaps, places in the Basin and Range province of the United States. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnäsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. Fluorite is currently the only mineral that is mined for fluorine, and nomineral except fluorite is likely to become a source of commercially produced fluorine as a primary product as long as supplies from relatively thick and high-grade fluorite deposits continue to be available. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. An eighth class (not hydrothermal) is that of fluorspar deposits concentrated in soils and weathered zones; that is, residual fluorspar deposits. Generally, fluorspar deposits related to strongly differentiated granites have larger tonnages and lower grades than carbonatite-related fluorspar deposits, which, in turn, have larger tonnages and lower grades than fluorspar vein deposits from various other classes. The United States has a few identified resources of fluorspar, most notably the Klondike II property in the Illinois- Kentucky fluorspar district located about 8 kilometers southwest of Salem, Kentucky, which has a large vein that contains at least 1.6 million metric tons at a grade of 60 percent CaF 2 (Feytis, 2009). Additional fluorspar resources of lower grade but larger tonnage have been identified at Hicks Dome in the Illinois-Kentucky fluorspar district and at Lost River near the western tip of the Seward Peninsula in Alaska, along with a couple of dozen smaller, higher grade resources. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Province’s large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Among undiscovered resources, an interesting possibility might be to produce a fluorine product from evaporitic, high-fluorine, high-pH sodium-carbonate brines like Lake Magadi (Kenya) and Lake Natron (Tanzania) in Africa’s Eastern Rift Valley. In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Modern geophysical and geochemical exploration techniques have typically not been brought to bear in exploration for new fluorspar deposits, although such techniques are likely to be used in future exploration. The tendency for fluorine to dissolve in significant concentrations in water at low temperature allows both surface water and groundwater to be used as sampling media in geochemical exploration. Evolved granite-related fluorspar deposits may be particularly susceptible to geophysical exploration methods because crystalline rocks that form a basement to sedimentary sections can be approximately defined with gravity and magnetic methods, and magnetite-bearing skarns can be directly detected with magnetic surveys. Environmental considerations of fluorine mining focus especially on drinking water, where high fluorine concentrations can lead to tooth decay; dental and skeletal fluorosis; and bone and cartilage conditions, including genu valgum, which is the crippling bone deformity more commonly known as knock knee. Trace amounts of other elements in fluorspar ores are a concern at some deposits; for example, high beryllium concentrations in alkaline-volcanic-related epithermal deposits or high cadmium concentrations associated with Mississippi Valley-type and salt-related carbonate-hosted fluorspar deposits. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits’ possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. This knowledge could help focus new exploration.
Geology and mineral resources of the Southwestern and South-Central Wyoming Sagebrush Focal Area, Wyoming, and the Bear River Watershed Sagebrush Focal Area, Wyoming and Utah: Chapter E in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming
Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of locatable minerals in the Southwestern and South-Central Wyoming and Bear River Watershed, Wyoming and Utah, SFAs.
Qualitative assessment of selected areas of the world for undiscovered sediment-hosted stratabound copper deposits: Chapter Y in Global mineral resource assessment
A qualitative mineral resource assessment of sediment-hosted stratabound copper mineralized areas for undiscovered copper deposits was performed for 10 selected areas of the world. The areas, in alphabetical order, are (1) Belt-Purcell Basin, United States and Canada; (2) Benguela and Cuanza Basins, Angola; (3) Chuxiong Basin, China; (4) Dongchuan Group rocks, China; (5) Egypt–Israel–Jordan Rift, Egypt, Israel, and Jordan; (6) Maritimes Basin, Canada; (7) Neuquén Basin, Argentina; (8) Northwest Botswana Rift, Botswana and Namibia; (9) Redstone Copperbelt, Canada; and (10) Salta Rift System, Argentina. This assessment (1) outlines the main characteristics of the areas, (2) classifies known deposits by deposit model subtypes, and (3) ranks the areas according to their potential to contain undiscovered copper deposits. An analytic hierarchy process (AHP) was used to rank assessment areas according to their potential for undiscovered copper deposits. Once the main characteristics of each area were compiled (age of host rock, geologic setting, stratigraphy, host lithology, deposit subtype(s), known deposits and occurrences, and mineral system components), three criteria (mineralization, extent of study area, and lithostratigraphic framework, each with multiple subcriteria) were scored for all assessment areas. Relative weights and scores were assigned to all criteria by three geologists. In addition, the assessment areas were ranked for comparison exclusively on the basis of professional opinion. The AHP and professional opinion lists are similar but not the same. Both the professional opinion and the cumulative AHP lists rate the Northwest Botswana Rift in Botswana and Namibia as the area most likely to contain the most undiscovered copper deposits. The Salta Rift System in Argentina is rated lowest among the 10 qualitatively assessed areas.
GIS-Based Identification of Areas with Mineral Resource Potential for Six Selected Deposit Groups, Bureau of Land Management Central Yukon Planning Area, Alaska
This study, covering the Bureau of Land Management (BLM) Central Yukon Planning Area (CYPA), Alaska, was prepared to aid BLM mineral resource management planning. Estimated mineral resource potential and certainty are mapped for six selected mineral deposit groups: (1) rare earth element (REE) deposits associated with peralkaline to carbonatitic intrusive igneous rocks, (2) placer and paleoplacer gold, (3) platinum group element (PGE) deposits associated with mafic and ultramafic intrusive igneous rocks, (4) carbonate-hosted copper deposits, (5) sandstone uranium deposits, and (6) tin-tungsten-molybdenum-fluorspar deposits associated with specialized granites. These six deposit groups include most of the strategic and critical elements of greatest interest in current exploration. This study has used a data-driven, geographic information system (GIS)-based method for evaluating the mineral resource potential across the large region of the CYPA. This method systematically and simultaneously analyzes geoscience data from multiple geospatially referenced datasets and uses individual subwatersheds (12-digit hydrologic unit codes or HUCs) as the spatial unit of classification. The final map output indicates an estimated potential (high, medium, low) for a given mineral deposit group and indicates the certainty (high, medium, low) of that estimate for any given subwatershed (HUC). Accompanying tables describe the data layers used in each analysis, the values assigned for specific analysis parameters, and the relative weighting of each data layer that contributes to the estimated potential and certainty determinations. Core datasets used include the U.S. Geological Survey (USGS) Alaska Geochemical Database (AGDB2), the Alaska Division of Geologic and Geophysical Surveys Web-based geochemical database, data from an anticipated USGS geologic map of Alaska, and the USGS Alaska Resource Data File. Map plates accompanying this report illustrate the mineral prospectivity for the six deposit groups across the CYPA and estimates of mineral resource potential. There are numerous areas, some of them large, rated with high potential for one or more of the selected deposit groups within the CYPA.
Sediment-hosted stratabound copper deposit model
This report contains a descriptive model of sediment-hosted stratabound copper (SSC) deposits that supersedes the model of Cox and others (2003). This model is for use in assessments of mineral resource potential. SSC deposits are the second most important sources of copper in the world behind porphyry copper deposits. Around 20 percent of the copper in the world is produced from this class of deposits. They are also the most important sources of cobalt in the world, and they are fourth among classes of ore deposits in production of silver. SSC deposits are the basis of the economies of three countries: Democratic Republic of Congo, Poland, and Zambia. This report provides a description of the key features of SSC deposits; it identifies their tectonic-sedimentary environments; it illustrates geochemical, geophysical, and geoenvironmental characteristics of SSC deposits; it reviews and evaluates hypotheses on how these deposits formed; it presents exploration and assessment guides; and it lists some gaps in our knowledge about the SSC deposits. A summary follows that provides overviews of many subjects concerning SSC deposits.
Assessment of undiscovered copper resources associated with the Permian Kupferschiefer, Southern Permian Basin, Europe
This study synthesizes available information and estimates the location and quantity of undiscovered copper associated with a late Permian bituminous shale, the Kupferschiefer, of the Southern Permian Basin in Europe. The purpose of this study is to (1) delineate permissive areas (tracts) where undiscovered reduced-facies sediment-hosted stratabound copper deposits could occur within 2.5 kilometers of the surface, (2) provide a database of known reduced-facies-type sediment-hosted stratabound copper deposits and significant prospects, and (3) provide probabilistic estimates of amounts of undiscovered copper that could be present within each tract. This assessment is a contribution to a global assessment conducted by the U.S. Geological Survey (USGS). Permissive tracts are delineated by mapping the extent of the Kupferschiefer that overlies reservoir-facies red beds of the lower Permian Rotliegend Group. More than 78 million metric tons (Mt) of copper have been produced or delineated as resources in the assessed tracts, with more than 90 percent of the known mineral endowment located in Poland. Mines in Poland are developing the deposit at depths ranging from about 500 to 1,400 meters. Two approaches are used to estimate in-situ amounts of undiscovered copper. The three-part form of assessment was applied to the entire study area. In this approach, numbers of undiscovered deposits are estimated and combined with tonnage-grade models to probabilistically forecast the amount of undiscovered copper. For Poland, drill-hole data were available, and Gaussian geostatistical simulation techniques were used to probabilistically estimate the amount of undiscovered copper. The assessment was done in September 2010 using a three-part form of mineral resource assessment and in January 2012 using Gaussian geostatistical simulation. Using the three-part form of assessment, a mean of 126 Mt of undiscovered copper is predicted in 4 assessed permissive tracts. Seventy-five percent of the mean amount of undiscovered copper (96 Mt) is associated with a tract in southwest Poland. For this same permissive tract in Poland, Gaussian geostatistical simulation techniques indicate a mean of 62 Mt of copper based on copper surface-density data from drill holes.
A reconnaissance for signs of a Mississippi Valley-type lead-zinc mineralizing system on the eastern flank of the Rutbah Uplift, Anbar Province, Iraq
Reconnaissance field visits and rock sampling were conducted at eight geologically selected locations within Mesozoic rocks on the eastern flank of the Rutbah Uplift, Anbar Province, western Iraq, in an attempt to determine if these rocks have been affected by a Mississippi Valley-Type (MVT) lead-zinc mineralizing system. Samples subsequently were studied by carbonate mineral staining, transmitted and reflected light petrology, and scanning electron microscopy with semi-quantitative energy dispersive elemental analyses. Single samples were studied by each, inductively coupled plasma mass spectrometry analyses of trace elements and fluid inclusion microthermometry. Permissive evidence indicates that there has been a MVT system present, but none of the evidence is considered definitive.
Assessment of undiscovered sandstone copper deposits of the Kodar-Udokan area, Russia
Mineral resource assessments integrate and synthesize available information as a basis for estimating the location, quality, and quantity of undiscovered mineral resources. This probabilistic mineral resource assessment of undiscovered sandstone copper deposits within Paleoproterozoic metasedimentary rocks of the Kodar-Udokan area in Russia is a contribution to a global assessment led by the U.S. Geological Survey (USGS). The purposes of this study are to (1) delineate permissive areas (tracts) to indicate where undiscovered sandstone-hosted copper deposits may occur within 2 km of the surface, (2) provide a database of known sandstone copper deposits and significant prospects, (3) estimate numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provide probabilistic estimates of amounts of copper (Cu) and mineralized rock that could be contained in undiscovered deposits within each tract. The workshop for the assessment, held in October 2009, used a three-part form of mineral resource assessment as described by Singer (1993) and Singer and Menzie (2010). Permissive tracts were delineated by estimating the volume of rock that contains the stratigraphic section ranging from the Chitkanda to the Sakukan Formations of the Udokan Complex to a depth of 2 km and then projecting this rock volume to the surface. The six permissive tracts delineated in this assessment occur in several domains, referred to as troughs in Russian literature, which represent remnants of a much larger basin that likely covered the Kodar-Udokan region. Tracts range in size from about 100 km 2 to 800 km 2 . The mapped distributions of rocks as shown on 1:200,000-scale geologic maps, supplemented in some areas by prospect mapping and drilling, were used to delineate the tracts. In this study area, data are insufficient to constrain the original basin geometry or the structural or stratigraphic traps that would have localized copper mineralization. Some alteration is described, and the types of sandstone cements vary; however, no patterns are known that provide evidence for regional flow paths of metal-bearing brines that could localize deposits. This probabilistic assessment indicates that a significant amount of undiscovered copper is associated with sediment-hosted stratabound copper deposits in the Kodar-Udokan Trough. In the assessment, a mean of 21 undiscovered deposits is estimated to occur within the Kodar-Udokan area. There are two known deposits in the area that contain drill-identified resources of 19.6 million metric tons of copper. Using Monte Carlo simulation, probabilistic estimates of the numbers of undiscovered sandstone copper deposits for these tracts were combined with tonnage and grade distributions of sandstone copper deposits to forecast an arithmetic mean of 20.6 million metric tons of undiscovered copper. Significant value can be expected from associated metals, particularly silver.
Sandstone copper assessment of the Teniz Basin, Kazakhstan
The U.S. Geological Survey (USGS) conducts national and global resource assessments (mineral, energy, water, and biological) to provide data and scientific analyses to support decision making. Three-part mineral resource assessments result in informed, unbiased, quantitative, and probabilistic estimates of undiscovered mineral resources and deposits. In particular, mineral assessment results inform decisions concerning land-use and mineral-resource development. A probabilistic mineral resource assessment of the sandstone subtype of sediment-hosted stratabound copper deposits in the Teniz Basin, Kazakhstan, was undertaken by the USGS. The Teniz Basin is located in Akmola Oblast, central and western Kazakhstan. With an areal extent of almost 78,000 km 2 , the basin contains many sediment-hosted stratabound copper prospects, none of which are well described, and the majority of which may belong to the sandstone subtype of sediment-hosted copper deposits. There are no known locations within the Teniz Basin currently mined for copper. Within the basin, however, map units permissive for the sandstone subtype of sediment-hosted stratabound copper deposits include (from oldest to youngest): the Middle Carboniferous Kiery Suite; the Middle to Upper Carboniferous Vladimirov Suite (a stratigraphic equivalent of the Dzhezkazgan Suite, Chu-Sarysu Basin); and the Upper Carboniferous or lowest Permian Kayraktin Suite. The multicolored sedimentary rocks of the Vladimirov Suite, in which 14 potentially ore-bearing horizons of gray beds have been recorded, have the greatest potential for undiscovered, sandstone subtype, sediment-hosted stratabound copper deposits. A quantitative mineral resource assessment has been completed that (1) delineates one 49,714 km 2 tract permissive for undiscovered, sandstone subtype, sediment-hosted stratabound copper deposits, and (2) provides probabilistic estimates of numbers of undiscovered deposits and probable amounts of copper resource contained in those deposits. The permissive tract delineated in this assessment encompasses no previously known sandstone subtype, sediment-hosted stratabound copper deposits. However, this assessment estimates (with 30 percent probability) that a mean of nine undiscovered sandstone subtype copper deposits may be present in the Teniz Basin and could contain a mean total of 8.9 million metric tons of copper and 7,500 metric tons of silver.
Sediment-hosted stratabound copper assessment of the Neoproterozoic Roan Group, central African copperbelt, Katanga Basin, Democratic Republic of the Congo and Zambia
This study estimates the location, quality, and quantity of undiscovered copper in stratabound deposits within the Neoproterozoic Roan Group of the Katanga Basin in the Democratic Republic of the Congo and Zambia. The study area encompasses the Central African Copperbelt, the greatest sediment-hosted copper-cobalt province in the world, containing 152 million metric tons of copper in greater than 80 deposits. This study (1) delineates permissive areas (tracts) where undiscovered sediment-hosted stratabound copper deposits may occur within 2 kilometers of the surface, (2) provides a database of known sediment-hosted stratabound copper deposits and prospects, (3) estimates numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provides probabilistic estimates of amounts of copper and mineralized rock that could be contained in undiscovered deposits within each tract. The assessment, conducted in January 2010 using a three-part form of mineral resource assessment, indicates that a substantial amount of undiscovered copper resources might occur in sediment-hosted stratabound copper deposits within the Roan Group in the Katanga Basin. Monte Carlo simulation results that combine grade and tonnage models with estimates of undiscovered deposits indicate that the mean estimate of undiscovered copper in the study area is 168 million metric tons, which is slightly greater than the known resources at 152 million metric tons. Furthermore, significant value can be expected from associated metals, particularly cobalt. Tracts in the Democratic Republic of the Congo (DRC) have potential to contain near-surface, undiscovered deposits. Monte Carlo simulation results indicate a mean value of 37 million metric tons of undiscovered copper may be present in significant prospects.
Descriptive models, grade-tonnage relations, and databases for the assessment of sediment-hosted copper deposits: with emphasis on deposits in the Central Africa Copperbelt, Democratic Republic of the Congo and Zambia: Chapter J in Global mineral resource assessment
The Central African Copperbelt (CACB) is one of the most important copper-producing regions of the world. The majority of copper produced in Africa comes from this region defined by the Neoproterozoic Katanga sedimentary basin of the southern Democratic Republic of the Congo (DRC) and northern Zambia. Copper in the CACB is mined from sediment-hosted stratabound copper deposits associated with red beds and includes the giant deposits in the Kolwezi and Tenge-Fungurume districts in the DRC and the Konkola-Musoshi and Nchanga-Chingola districts in Zambia. In recent years, sediment-hosted structurally controlled replacement and vein (SCRV) copper deposits, such as the giant Kansanshi deposit in Zambia have become important exploration targets in the CACB region. In 2011, the CACB accounted for 7.2 percent of the estimated global mine production of copper. Global production of copper is principally derived from porphyry and sediment-hosted copper deposits (57 and 23 percent, respectively). Almost 50 percent of the copper known to exist in sediment-hosted deposits (past production plus identified resources) is contained in the CACB, 25 percent is contained in the Zechstein Basin of northern Europe, and the remainder is contained in an additional 29 sedimentary basins distributed around the globe. The U.S. Geological Survey (USGS) led an assessment of undiscovered copper resources in the CACB as part of a global mineral resource assessment for undiscovered resources of potash, copper, and platinum-group elements in selected mineral deposit types. As part of the assessment process, available data for the CACB were compiled and evaluated. This report describes the results of that work, including new descriptive mineral-deposit and grade and tonnage models and spatial databases for deposits and occurrences, ore bodies and open pits. Chapter 1 of this report summarizes a descriptive model of sediment-hosted stratabound copper deposits. General characteristics and subtypes of sediment-hosted stratabound copper deposits are described based upon worldwide examples. Chapter 2 provides a global database of 170 sediment-hosted copper deposits, along with a statistical evaluation of grade and tonnage data for stratabound deposits, a comparison of stratabound deposits in the CACB with those found elsewhere, a discussion of the distinctive characteristics of the subtypes of sediment-hosted copper deposits that occur within the CACB, and guidelines for using grade and tonnage distributions for assessment of undiscovered resources in sediment-hosted stratabound deposits in the CACB. Chapter 3 presents a new descriptive model of sediment-hosted structurally controlled replacement and vein (SCRV) copper deposits with descriptions of individual deposits of this type in the CACB and elsewhere. Appendix A describes a relational database of tonnage, grade, and other information for more than 100 sediment-hosted copper deposits in the CACB. These data are used to calculate the pre-mining mineral endowment for individual deposits in the CACB and serve as the basis for the grade and tonnage models presented in chapter 2. Appendix B describes three spatial databases (Esri shapefiles) for (1) point locations of more than 500 sediment-hosted copper deposits and prospects, (2) projected surface extent of 86 selected copper ore bodies, and (3) areal extent of 77 open pits, all within the CACB.
The Spar Lake strata-Bound Cu-Ag deposit formed across a mixing zone between trapped natural gas and metals-bearing brine
Ore formation at the Spar Lake red bed-associated strata-bound Cu deposit took place across a mixing and reaction zone between a hot oxidized metals-transporting brine and a reservoir of “sour” (H 2 S-bearing) natural gas trapped in the host sandstones. Fluid inclusion volatile analyses have very high CH 4 concentrations (≥1 mol % in most samples), and a sample from the fringe of the deposit has between 18 and 36 mol % CH 4 . The ratio of CH 4 /CO 2 in fluid inclusions appears to vary regularly across the deposit, with the lowest CH 4 /CO 2 ratios from high-grade chalcocite-bearing ore, and the highest from the chalcopyrite-bearing fringe. The helium R/R a isotope ratios (0.23–0.98) and concentrations define a mixture between crustal and atmospheric helium. The volatiles in fluid inclusions (CH 4 , CO 2 , H 2 S, SO 2 , H 2 , H 2 O, and other organic gases) and values of f O 2 and temperature calculated from the volatiles data all show gradations across the deposit that are completely consistent with such a mixing and reaction zone. Other volatiles from the fluid inclusions (HCl, HF, 3 He, Msup>4 He, N 2 , Ar) characterize the brine and give evidence for only shallow crustal fluids with no magmatic influences. The brine entered the gas reservoir from below and along the axis of the deposit and migrated out along bedding to the southwest, northeast, and northwest. Metals-transporting brines may have been fed into the host sandstones from the East Fault, but that remains uncertain. Abundant ore-stage Fe and Mn calcite cements from the reduced fringe have δ 13 C values as low as −18.4‰, and many values less than −10‰, which indicate that significant carbonate was generated by oxidation of organic carbon from the natural gas. The zone of calcite cements with very low δ 13 C values approximately envelopes chalcocite-bearing ore. Sulfur isotope data of Cu, Pb, and Fe sulfides and barite indicate derivation of roughly half of the orebody sulfide directly from sour gas H 2 S. That sour gas H 2 S had developed in steps known from other sedimentary basins, starting with (1) bacterial sulfate reduction (BSR) of seawater sulfate having δ 34 S of about 20‰ and sequestering of the sulfide in organic matter in source rocks stratigraphically below the deposit host rocks, followed by (2) maturation of the sulfide-bearing organic matter into liquid petroleum with relatively homogeneous sulfide having δ 34 S of 5 ± 5‰, then by (3) thermal cracking of the oil to CH 4 and H 2 S with relatively homogeneous sulfide having δ 34 S closely distributed, about 6‰. The CH 4 and H 2 S migrated and were trapped in sandstones of the upper member of the Revett Formation, where they were later met by the 200°C metals-transporting brine. There was additional contribution of sulfide to ore from later thermochemical sulfate reduction (TSR) operating on sulfate δ 34 S of 20 to 29‰ in both formation waters and metals-transporting solutions. A large range of δ 34 S in sulfides resulted as the 6‰ sour gas sulfide was supplemented with varying proportions of 20 to 29‰ sulfide from TSR.
SHRIMP U-Pb ages of xenotime and monazite from the Spar Lake red bed-associated Cu-Ag deposit, western Montana: Implications for ore genesis
Xenotime occurs as epitaxial overgrowths on detrital zircons in the Mesoproterozoic Revett Formation (Belt Supergroup) at the Spar Lake red bed-associated Cu-Ag deposit, western Montana. The deposit formed during diagenesis of Revett strata, where oxidizing metal-bearing hydrothermal fluids encountered a reducing zone. Samples for geochronology were collected from several mineral zones. Xenotime overgrowths (1–30 μm wide) were found in polished thin sections from five ore and near-ore zones (chalcocite-chlorite, bornite-calcite, galena-calcite, chalcopyrite-ankerite, and pyrite-calcite), but not in more distant zones across the region. Thirty-two in situ SHRIMP U-Pb analyses on xenotime overgrowths yield a weighted average of 207 Pb/ 206 Pb ages of 1409 ± 8 Ma, interpreted as the time of mineralization. This age is about 40 to 60 m.y. after deposition of the Revett Formation. Six other xenotime overgrowths formed during a younger event at 1304 ± 19 Ma. Several isolated grains of xenotime have 207 Pb/ 206 Pb ages in the range of 1.67 to 1.51 Ga, and thus are considered detrital in origin. Trace element data can distinguish Spar Lake xenotimes of different origins. Based on in situ SHRIMP analysis, detrital xenotime has heavy rare earth elements-enriched patterns similar to those of igneous xenotime, whereas xenotime overgrowths of inferred hydrothermal origin have hump-shaped (i.e., middle rare earth elements-enriched) patterns. The two ages of hydrothermal xenotime can be distinguished by slightly different rare earth elements patterns. In addition, 1409 Ma xenotime overgrowths have higher Eu and Gd contents than the 1304 Ma overgrowths. Most xenotime overgrowths from the Spar Lake deposit have elevated As concentrations, further suggesting a genetic relationship between the xenotime formation and Cu-Ag mineralization.
Sandstone copper assessment of the Chu-Sarysu Basin, Central Kazakhstan: Chapter E in Global mineral resource assessment
Mineral resource assessments represent a synthesis of available information to estimate the location, quality, and quantity of undiscovered mineral resources in the upper part of the Earth’s crust. This report presents a probabilistic mineral resource assessment of undiscovered sandstone copper deposits within the late Paleozoic Chu-Sarysu Basin in central Kazakhstan by the U.S. Geological Survey as a contribution to a global assessment of mineral resources. The purposes of this study are to: (1) provide a database of known sandstone copper deposits and significant prospects in this area, (2) delineate permissive areas (tracts) for undiscovered sandstone copper deposits within 2 km of the surface at a scale of 1:1,000,000, (3) estimate numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provide probabilistic estimates of amounts of copper (Cu), silver (Ag), and mineralized rock that could be contained in undiscovered deposits within each tract. The assessment uses the three-part form of mineral resource assessment based on mineral deposit models (Singer, 1993; Singer and Menzie, 2010). Delineation of permissive tracts for resources is based on the distribution of a Carboniferous oxidized nonmarine clastic (red bed) stratigraphic sequence that lies between overlying Permian and underlying Devonian evaporite-bearing sequences. Subsurface information on the extent and depth of this red bed sequence and structural features that divide the basin into sub-basins was used to define four permissive tracts. Structure contour maps, mineral occurrence databases, drill hole lithologic logs, geophysical maps, soil geochemical maps, locations of producing gas fields, and evidence for former gas accumulations were considered in conjunction with descriptive deposit models and grade and tonnage models to guide the assessment team’s estimates of undiscovered deposits in each tract. The four permissive tracts are structural sub-basins of the Chu-Sarysu Basin and range in size from 750 to 65,000 km². Probabilistic estimates of numbers of undiscovered sandstone copper deposits were made for the four tracts by a group of experts. Using these probabilistic estimates, Monte Carlo simulation was used to estimate the amount of metal contained within each tract. The results of the simulation serve as the basis for estimates of the metal endowment. The team estimates that 26 undiscovered deposits occur within the Chu-Sarysu Basin, and that these deposits contain an arithmetic mean of at least 21.5 million metric tons (Mt) of copper and 21,900 metric tons (t) of silver. The undiscovered deposits are in addition to the 7 known deposits that contain identified resources of 27.6 Mt of copper. Sixty percent of the estimated mean undiscovered copper resources are associated with the two permissive tracts that contain the identified resources; the remaining estimated resources are associated with the two tracts that have no known deposits. For the three tracts that contain 95 percent of the estimated undiscovered copper resources, the probability that each tract contains its estimated mean or more is about 40 percent. For the tract with 5 percent of the estimated undiscovered cop-per resources, the probability that it contains that amount or more is 25 percent.
Limestone - A Crucial and Versatile Industrial Mineral Commodity
Limestone, as used by the minerals industry, is any rock composed mostly of calcium carbonate (CaCO3). Although limestone is common in many parts of the United States, it is critically absent from some. Limestone is used to produce Portland cement, as aggregate in concrete and asphalt, and in an enormous array of other products, making it a truly versatile commodity. Portland cement is essential to the building industry, but despite our Nation's abundance of limestone, there have been cement shortages in recent years. These have been caused in part by a need to find new areas suitable for quarrying operations. To help manage our Nation's resources of such essential mineral commodities, the U.S. Geological Survey (USGS) provides crucial data and scientific information to industry, policymakers, and the public.
Cross sections showing stratigraphic and depositional lithofacies of upper Cambrian rocks and the relation of lithofacies to potential for Mississippi Valley-type mineralization in the Harrison 1° x 2° quadrangle, Missouri and Arkansas (folio of the Harrison 1 degree by 2 degrees quadrangle, Missouri and Arkansas)
These cross sections are the fifth publication in a folio of maps of the Harrison 1° x 2° quadrangle, Missouri and Arkansas, prepared under the Conterminous United States Mineral Assessment Program (CUSMAP). Previously published maps in this folio relate to the geochemistry of the subsurface carbonate rocks (Erickson and others, 1989), the geophysics of the basement terranes (McCafferty and others, 1989), the sedimentary rocks and mineralization of the Caulfield district (Hayes and others, 1992), the mineral resource potential of the quadrangle (Pratt and others, 1993), and the bedrock geology of the quadrangle (Middendorf and others, 1994 and in press). A final set of maps showing locations of known Mississippi Valley-type deposits and occurrences relative to Late Cambrian shaly lithofacies and other shales in the Harrison and adjoining quadrangle is in preparation (Palmer and Hayes, in press).
Arsenic loads in Spearfish Creek, western South Dakota, water years 1989-91
Numerous small tributaries on the eastern flank of Spearfish Creek originate within a mineralized area with a long history of gold-mining activity. Some streams draining this area are known to have elevated concentrations of arsenic. One such tributary is Annie Creek, where arsenic concentrations regularly approach the Maximum Contaminant Level of 50 mg/L (micrograms per liter) established by the U.S. Environmental Protection Agency. A site on Annie Creek was proposed for inclusion on the National Priorities List by the Environmental Protection Agency in 1991. This report presents information about arsenic loads and concentrations in Spearfish Creek and its tributaries, including Annie Creek. Stream types were classified according to geologic characteristics and in-stream arsenic concentrations. The first type includes streams that lack significant arsenic sources and have low in-stream arsenic concentrations. The second type has abundant arsenic sources and high in-stream concentrations. The third type has abundant arsenic sources but only moderate in-stream concentrations. The fourth type is a mixture of the first three types. Annual loads of dissolved arsenic were calculated for two reaches of Spearfish Creek to quantify arsenic loads at selected gaging stations during water years 1989-91. Mass-balance calculations also were performed to estimate arsenic concentrations for ungaged inflows to Spearfish Creek. The drainage area of the upstream reach includes significant mineralized areas, whereas the drainage area of the downstream reach generally is without known arsenic sources. The average load of dissolved arsenic transported from the upstream reach of Spearfish Creek, which is representative of a type 4 stream, was 158 kilograms per year, calculated for station 06430900, Spearfish Creek above Spearfish. Gaged headwater tributaries draining unmineralized areas (type 1) contributed only 16 percent of the arsenic load in 63 percent of the discharge. Annie Creek (type 2), which has the highest measured arsenic concentra- tions in the Spearfish Creek drainage, contributed about 15 percent of the arsenic load in about 2 percent of the discharge of the upstream reach. Squaw Creek, which drains another mineralized area, but has only moderate in-stream concentrations (type 3), contributed 4 percent of the arsenic load in 5 percent of the discharge. Ungaged inflows to the reach contributed the remaining 65 percent of the arsenic load in 30 percent of the discharge. The calculated loads from ungaged inflows include all arsenic contributed by surface- and ground-water sources, as well as any additions of arsenic from dissolution of arsenic-bearing solid phases, or from desorption of arsenic from solid surfaces, within the streambed of the upstream reach. Mass-balance calculations indicate that dissolved arsenic concentrations of the ungaged inflows in the upstream reach averaged about 9 mg/L. In-stream arsenic concentrations of ungaged inflows from the unmineralized western flank of Spearfish Creek probably are generally low (type 1). Thus, in-stream arsenic concentrations for ungaged inflows draining the mineralized eastern flank of Spearfish probably average almost twice that level, or about 18 mg/L. Some ungaged, eastern-flank inflows probably are derived from type 3 drainages, with only moderate arsenic concentrations. If so, other ungaged, eastern-flank inflows could have in-stream arsenic concentrations similar to those of Annie Creek. No significant arsenic sources were apparent in the downstream reach of Spearfish Creek. Over the course of the downstream reach, arsenic concentrations decreased somewhat, probably resulting from dilution, as well as from possible chemical adsorption to sediment surfaces or arsenic-phase precipitation. A decrease in arsenic loads resulted from various diversions from the creek and from the potential chemical removal processes. Because of a large margin of error associated with calculation of arsenic loads for the downstream reach, it is difficult to conclude decisively that chemical removal occurs. It can be concluded, however, that arsenic concentrations do not increase significantly in the downstream reach as a result of interactions with streambed and alluvial sediments. Thus, it also can be concluded that streambed interactions within the channel of Spearfish Creek probably are not a significant source of arsenic within the upstream reach