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Geology topics

Thomas M. Johnson

Publications and source records attributed to Thomas M. Johnson.

4 recordsLinked to original sources

Water

Ensuring a reliable supply of clean freshwater to individuals, communities, and ecosystems , together with effective management of floods and droughts, is the foundation of human and ecological health. The water sector is also central to the economy and contributes significantly to the resilience of many other sectors, including agriculture, energy, urban environments, and industry. Water systems face considerable risk , even without anticipated future climate changes. Limited surface water storage, as well as a limited ability to make use of long-term drought forecasts and to trade water across uses and basins, has led to a significant depletion of aquifers in many regions in the United States. Across the Nation, much of the critical water and wastewater infrastructure is nearing the end of its useful life. To date, no comprehensive assessment exists of the climate-related vulnerability of U.S. water infrastructure (including dams, levees, aqueducts, sewers, and water and wastewater distribution and treatment systems), the potential resulting damages, or the cost of reconstruction and recovery. Paleoclimate information (reconstructions of past climate derived from ice cores or tree rings) shows that over the last 500 years, North America has experienced pronounced wet/dry regime shifts that sometimes persisted for decades. Because such protracted exposures to extreme floods or droughts in different parts of the country are extraordinary compared to events experienced in the 20th century, they are not yet incorporated in water management principles and practice. Anticipated future climate change will exacerbate this risk in many regions. A central challenge to water planning and management is learning to plan for plausible future climate conditions that are wider in range than those experienced in the 20th century. Doing so requires approaches that evaluate plans over many possible futures instead of just one, incorporate real-time monitoring and forecast products to better manage extremes when they occur, and update policies and engineering principles with the best available geoscience-based understanding of planetary change. While this represents a break from historical practice, recent examples of adaptation responses undertaken by large water management agencies, including major metropolitan water utilities and the U.S. Army Corps of Engineers, are promising.

Report

Selenium, iron, and chromium stable isotope ratio measurements by the double isotope spike TIMS method

This chapter focuses on the double-spike calibrated thermal ionization mass spectrometry (TIMS) methods for measurement of mass dependent isotope fractionation in Se, Fe, and Cr. Current measurement precision is approximately ± 0.2 per mil on 80 Se / 76 Se, 56 Fe / 54 Fe, and 53 Cr / 52 Cr. Sample size requirements are 500ng, 1μg, and 250ng for Se, Fe, and Cr respectively. These measurements have been developed recently, and further improvements in precision and sample size are likely. The present purification procedures for these elements and the geochemical applications of the measurements are reviewed. TIMS instruments were usually limited to measurement of positive ions. One of the major recent developments in TIMS is the development of methods for measuring negative ions. An important future direction in mass spectrometry of Se, Fe, and Cr, is multi-collector inductively coupled plasma- mass spectrometry (MC-ICP-MS). This recent technique has a number of advantages over TIMS techniques and may eventually dominate. Instrumental discrimination is very large with MC-ICP-MS and must be monitored and modeled correctly.

Book chapter

Chromium isotopes and the fate of hexavalent chromium in the environment

Measurements of chromium (Cr) stable-isotope fractionation in laboratory experiments and natural waters show that lighter isotopes reacted preferentially during Cr(VI) reduction by magnetite and sediments. The 53 Cr/ 52 Cr ratio of the product was 3.4 ± 0.1 per mil less than that of the reactant. 53 Cr/ 52 Cr shifts in water samples indicate the extent of reduction, a critical process that renders toxic Cr(VI) in the environment immobile and less toxic.

Science

Groundwater “fast paths” in the Snake River Plain aquifer: Radiogenic isotope ratios as natural groundwater tracers

Preferential flow paths are expected in many groundwater systems and must be located because they can greatly affect contaminant transport. The fundamental characteristics of radiogenic isotope ratios in chemically evolving waters make them highly effective as preferential flow path indicators. These ratios tend to be more easily interpreted than solute-concentration data because their response to water-rock interaction is less complex. We demonstrate this approach with groundwater 87 Sr/ 86 Sr ratios in the Snake River Plain aquifer within and near the Idaho National Engineering and Environmental Laboratory. These data reveal slow-flow zones as lower 87 Sr/ 86 Sr areas created by prolonged interaction with the host basalts and a relatively fast flowing zone as a high 87 Sr/ 86 Sr area.

Idaho