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Thomas E. Imbrigiotta

Publications and source records attributed to Thomas E. Imbrigiotta.

At least 19 recordsLinked to original sources
USGS2023

Distribution of chlorinated volatile organic compounds and per- and polyfluoroalkyl substances in groundwater and surface water at the former Naval Air Warfare Center, West Trenton, New Jersey, 2018

Groundwater wells and surface-water storm sewers contaminated with volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFASs) at the former Naval Air Warfare Center (NAWC) site in West Trenton, New Jersey were sampled in 2018 as part of the Navy’s long-term monitoring program. Trichloroethene (TCE), cis-1,2-dichloroethene (cisDCE), and vinyl chloride concentrations were plotted in map view and selected cross sections to elucidate the vertical and horizontal extent and distribution of contamination, along with a tabular comparison between 2018 and previous analytical results. The 2018 data showed that the areas of VOC contamination (>1 microgram per liter) decreased slightly on the north and east sides of the NAWC site from previous sampling dates; these decreases are attributed to the influence of the pump-and-treat system, natural attenuation processes, and various engineered bioaugmentation experiments that have occurred onsite. Off-site groundwater samples indicate the VOC contaminated groundwater is likely hydraulically constrained by the pump-and-treat system and appears to not be moving offsite to the south and west of NAWC. Only one offsite well, 50BR, located along the eastern margin of the site, was found to have detectable TCE and cisDCE concentrations, indicating that VOC contamination continues to migrate a short distance offsite to the east. Detectable VOC contamination was found in wells as deep as 200 and 221 feet on both the east and west sides of the NAWC site. Comparisons of present-day data to data from past sampling efforts indicate that TCE concentrations in most wells have decreased slowly over time. Results from surface-water samples indicate that VOCs enter surface water predominantly through the West Ditch drainage system. Concentrations and fluxes of VOCs are higher when groundwater levels are higher, indicating contaminated groundwater discharges into the surface water system. Higher VOC concentrations at the Interceptor site relative to other sites in the West Ditch indicate the contamination in the West Ditch system is likely caused by contaminated groundwater discharging to the West Ditch storm sewer near manhole MH-140 when water table levels are high. The pump-and-treat extraction wells at the former NAWC site were sampled for per- and polyfluoroalkyl substances (PFAS) in 2018. The suite of reported PFAS include perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluorononanoic acid, and perfluorobutane sulfonate. Concentrations were plotted in map view to determine the areal extent of the PFAS contamination at the site. Extraction well 48BR sampled on the eastern half of the site was found to have PFOS and PFOA concentrations greater than the New Jersey Department of Environmental Protection Drinking Water maximum contaminant levels (MCLs), which is consistent with the distribution of highest PFAS concentrations in surface water in the OF-4 storm sewer system that drains that area, as well as previously collected PFAS concentrations in monitoring wells. On the western half of the site, the extraction well 08BR sample exceeded MCLs for PFOA and PFOS and the extraction well 22BR sample exceeded the MCL for PFOA, but samples from all other extraction wells were below the MCLs or other criteria for all PFAS analyzed. Concentrations of PFOA exceeded concentrations of PFOS on the west side of NAWC in both groundwater and surface water, which contrasts with the conditions on the east side of NAWC where PFOS concentrations exceeded PFOA concentrations. However, this observation was based on a limited number of samples on the west side of NAWC from 2018 and previous years, so more PFAS sampling is needed on the west side to assess this further.

New Jersey↗
USGS2022

Microbial community response to a bioaugmentation test to degrade trichloroethylene in a fractured rock aquifer, Trenton, N.J

Bioaugmentation is a promising strategy for enhancing trichloroethylene (TCE) degradation in fractured rock. However, slow or incomplete biodegradation can lead to stalling at degradation byproducts such as 1,2-dichloroethene ( cis -DCE) and vinyl chloride (VC). Over the course of 7 years, we examined the response of groundwater microbial populations in a bioaugmentation test where an emulsified vegetable oil solution (EOS ® ) and a dechlorinating consortium (KB-1 ® ), containing the established dechlorinator Dehalococcoides (DHC), were injected into a TCE-contaminated fractured rock aquifer. Indigenous microbial communities responded within 2 days to added substrate and outcompeted KB-1 ® , and over the years of monitoring, several other notable turnover events were observed. Concentrations of ethene, the end product in reductive dechlorination, had the strongest correlations ( P < .05) with members of Candidatus Colwellbacteria but their involvement in reductive dechlorination is unknown and warrants further investigation.DHC never exceeded 0.6% relative abundance of groundwater microbial communities, despite its previously presumed importance at the site. Increased concentrations of carbon dioxide, acetic acid, and methane were positively correlated with increasing ethene concentrations; however, concentrations of cis- DCE and VC remained high by the end of the monitoring period suggesting preferential enrichment of indigenous partial dechlorinators over bioaugmented complete dechlorinators. This study highlights the importance of characterizing in situ microbial populations to understand how they can potentially enhance or inhibit augmented TCE degradation.

New Jersey↗
USGS2022

A borehole test for chlorinated solvent diffusion and degradation rates in sedimentary rock

We present a new field measurement and numerical interpretation method (combined termed ‘test’) to parameterize the diffusion of trichloroethene (TCE) and its biodegradation products (DPs) from the matrix of sedimentary rock. The method uses a dual-packer system to interrogate a low-permeability section of the rock matrix adjacent to a previously contaminated borehole and uses the borehole monitoring history to establish the pre-test condition. TCE and its DPs are removed from the groundwater between the packers at the onset of the testing. The parameters estimated by fitting a radial diffusion model to the concentration history and borehole concentration data, also termed back-diffusion, are the tortuosity factor and sorption coefficients of TCE and DPs in the rock matrix and the TCE and DP biodegradation rate coefficients in the borehole. We demonstrate the equipment design and the interpretive method using a borehole accessing the grey mudstone at a TCE contaminated site in the Newark Basin. In this test, both nonreactive (bromide) and reactive (trichlorofluoroethene) tracers are used to constrain the estimated parameters; however, the bromide tracer was not needed to estimate the parameters in this test. The parameters estimated from the field test are consistent with values measured independently in laboratory experiments using field samples of similar lithology. From the interpretation, we compute the TCE and DP concentration distributions in the rock matrix prior to the test to illustrate how the results can be used to enhance understanding of contaminant distribution in the rock matrix.

Groundwater Monitoring and Remediation↗
USGS2021

Distribution of chlorinated volatile organic compounds and per- and polyfluoroalkyl substances in monitoring wells at the former Naval Air Warfare Center, West Trenton, New Jersey, 2014–17

A study was conducted by the U.S. Geological Survey in cooperation with the U.S. Navy (the Navy) to determine the status of volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFASs) in groundwater at the former Naval Air Warfare Center (NAWC) in West Trenton, New Jersey. Wells contaminated with VOCs were sampled in 2014, 2015, 2016, and 2017 as part of the Navy’s long-term monitoring program. The results for trichloroethene (TCE), cis-1,2-dichloroethene (cisDCE), and vinyl chloride (VC) were plotted in map view to determine whether the areal extent of the contamination had changed over the 4-year period. TCE, cisDCE, and VC concentrations were plotted along nine lines of section across the former NAWC site to determine whether the vertical distribution of VOCs had changed during 2014–17. TCE, cisDCE, and VC concentrations over time were plotted on graphs for each well to determine long-term trends and changes in VOC concentrations. Data from 1990 to 2017 were used, if available, to make these graphs. Results show that the areas of VOC concentrations greater than or equal to 1 microgram per liter decreased slightly on the northwestern side and the northeastern side of the NAWC site from 2014 to 2017 under the influence of a pump-and-treat system, natural attenuation processes, and engineered bioaugmentation experiments ongoing at the site. The pump-and-treat system continued to hydraulically contain the VOC contamination and kept it from moving offsite to the south and west of NAWC. One well northeast of the NAWC site, 50BR, was found to have detectable TCE and cisDCE concentrations. These detections indicated that VOC contamination had migrated offsite and that the pump-and-treat system was not containing the VOC contamination on the eastern side of the facility. Detectable VOC concentrations were present in wells as deep as 200 and 221 feet on the eastern and western sides of the NAWC site. TCE concentrations in most wells were found to be stable or to have slowly decreased since the facility closed in 1999. Only 7 wells, including 3 pump-and-treat extraction wells, showed substantial increases in TCE concentration from 2014 to 2017. Continuing sources of TCE to the system are desorption of TCE from organic materials in the aquifer, back diffusion of TCE from the contaminated bedrock matrix, and dissolution of remaining dense nonaqueous phase TCE in the aquifer. Wells at the former NAWC site were sampled for PFASs in 2015, 2016, and 2017. Perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), and perfluorononanoic acid (PFNA) results were plotted in map and cross-section views to determine the areal and vertical extent of the PFAS contamination at the site. PFOS, PFOA, and PFNA concentrations greater than their established maximum contaminant levels were detected in 25, 24, and 21 of the 26 wells sampled, respectively, on the eastern side of NAWC in 2017. Vertically, the highest PFAS concentrations were present in shallow wells along the fence near the firehouse and along the railroad tracks where the aqueous film-forming foam discharge reportedly occurred back in 1990. PFAS concentrations were detected in one well (54BR) as deep as 200 feet on the eastern side of the NAWC site. PFASs were present in wells east of the railroad tracks, indicating that PFAS-contaminated groundwater had moved offsite. In a limited test of five wells, samples collected with regenerated cellulose dialysis membrane (RCDM) passive samplers contained PFAS concentrations equal to those in samples from low-flow purging.

New Jersey↗
USGS2020

Passive sampling of groundwater wells for determination of water chemistry

Introduction Passive groundwater sampling is defined as the collection of a water sample from a well without the use of purging by a pump or retrieval by a bailer (Interstate Technology and Regulatory Council [ITRC], 2006; American Society for Testing and Materials [ASTM], 2014). No purging means that advection of water is not involved in collecting the water sample from the well. Passive samplers rely on diffusion as the primary process that drives their collection of chemical constituents. Diffusion is the transport of chemicals caused by the presence of a chemical gradient. Chemicals tend to move or diffuse from areas of higher concentration to areas of lower concentration to reach an average or equilibrium concentration. Passive sampling of groundwater relies on the ambient exchange of groundwater in the formation with water in the screened or open interval of a well. In this report, the term formation is used to describe all saturated hydrogeologic units that yield water to a well. If the well opening is unclogged and free of a film of deposits from physical turbidity or chemical precipitation, then the exchange of groundwater is likely adequate, and the water in the open interval will be representative of water in the formation. In some cases, the passive sample from the well opening can be more representative of groundwater from the formation than a sample collected by pumping if pumping induces mixing of water in the open interval with stagnant casing water that has undergone chemical alteration (Harte and others, 2018). In most cases, passive sampling will better represent the ambient groundwater chemistry flowing through the open interval of a well because pumping may capture water of different chemistry from downgradient or lateral areas that would not normally pass through the well. Three basic types of passive samplers are discussed in this report. The first type of passive sampler is the equilibrium-membrane type, which includes a semi-permeable membrane through which chemicals diffuse or permeate. Permeation is simply the process of water or chemicals moving through openings in the membrane. The authors contend that permeation is dominated by diffusion for many of the passive samplers discussed in this report. Some passive equilibrium-membrane-type samplers allow most types of chemical constituents through, whereas others allow the diffusion of only selected groups of chemicals. Once the chemical constituents are inside the membrane, they are retained by the equilibration of concentrations inside the sampler with those outside the sampler. The second type of passive sampler is an equilibrium-thief type, which has no semi-permeable membrane. Chemical constituents simply move through the openings in the body of the sampler either initially through advection and dispersion or over time primarily by diffusion. Chemical constituents reach equilibrium between the water in the sampler and the water in the well and are captured in the sampler when the sampler is closed. The third type of passive sampler is an accumulation-type sampler that contains sorptive media. Selected chemical constituents are sorbed onto the media that the sampler contains for later extraction and analysis. Although passive samplers have been available for more than 15 years (from present [2020]), their use by U.S. Geological Survey (USGS) hydrologists and hydrologic technicians to monitor groundwater quality largely has been limited to selected research studies. The authors believe that this may be the result of (1) a lack of exposure of most USGS personnel to passive samplers and the uses of these samplers and (2) the lack of a USGS-approved protocol for the proper use of these samplers by USGS personnel. This report is an effort to fill those two needs. The focus of this report is on hydraulic, hydrologic, and chemical considerations in the application of passive samplers and interpretation of groundwater chemistry results obtained using passive samplers in wells. This report describes the differences between purging and passive sampling methods in groundwater and explains how and why passive samplers work. The report points out the advantages and limitations of passive samplers in general and for each particular type of passive sampler. Important considerations to be taken into account prior to the use of passive samplers are discussed, such as defining the data-quality objectives, the water-quality constituents to be sampled, sample volumes required for analysis, well construction of the sampling network, and the geologic formations that will be sampled. Potential applications of passive samplers also are discussed, such as chemical-vertical profiling of wells. A general field protocol for the deployment, recovery, and sample collection using these devices is described, and some overall guidance for the practitioner with application examples is given. Comparison methods used to evaluate results from passive sampling versus purge sampling also are discussed.

Techniques and Methods↗
USGS2019

The complex spatial distribution of trichloroethene and the probability of NAPL occurrence in the rock matrix of a mudstone aquifer

Methanol extractions for chloroethene analyses are conducted on rock samples from seven closely spaced coreholes in a mudstone aquifer that was subject to releases of the nonaqueous phase liquid (NAPL) form of trichloroethene (TCE) between the 1950's and 1990's. Although TCE concentration in the rock matrix over the length of coreholes is dictated by proximity to subhorizontal bedding planefractures, elevated TCE concentrations in the rock matrix are not continuous along the most permeable bedding plane fractures. A complex configuration of subvertical and subhorizontal fractures appears to be responsible for the TCE distribution from prior TCE releases at land surface. Phase partitioning calculations of TCE in the rock matrix show that most TCE is adsorbed to solid surfaces because of the large fraction of organic carbon ( f oc ) in the mudstone. Large TCE content in some cores indicate the likely presence of the NAPL form of TCE in the rock matrix. Using average values of porosity ( n ) and f oc in phase partitioning calculations identifies a number of locations of possible NAPL occurrence in the rock matrix. Samples of mudstone analyzed for n and f oc show variability in these properties over several orders of magnitude. Accounting for this variability in phase partitioning calculations identifies a probability of NAPL occurrence, P NAPL . The spatial variability of P NAPL along coreholes identifies a configuration that may be attributed to a TCE source zone that has evolved after emplacement due to NAPL dissolution, adsorption, and matrix diffusion.

New Jersey↗
USGS2017

Bioremediation in fractured rock: 1. Modeling to inform design, monitoring, and expectations

Field characterization of a trichloroethene (TCE) source area in fractured mudstones produced a detailed understanding of the geology, contaminant distribution in fractures and the rock matrix, and hydraulic and transport properties. Groundwater flow and chemical transport modeling that synthesized the field characterization information proved critical for designing bioremediation of the source area. The planned bioremediation involved injecting emulsified vegetable oil and bacteria to enhance the naturally occurring biodegradation of TCE. The flow and transport modeling showed that injection will spread amendments widely over a zone of lower‐permeability fractures, with long residence times expected because of small velocities after injection and sorption of emulsified vegetable oil onto solids. Amendments transported out of this zone will be diluted by groundwater flux from other areas, limiting bioremediation effectiveness downgradient. At nearby pumping wells, further dilution is expected to make bioremediation effects undetectable in the pumped water. The results emphasize that in fracture‐dominated flow regimes, the extent of injected amendments cannot be conceptualized using simple homogeneous models of groundwater flow commonly adopted to design injections in unconsolidated porous media (e.g., radial diverging or dipole flow regimes). Instead, it is important to synthesize site characterization information using a groundwater flow model that includes discrete features representing high‐ and low‐permeability fractures. This type of model accounts for the highly heterogeneous hydraulic conductivity and groundwater fluxes in fractured‐rock aquifers, and facilitates designing injection strategies that target specific volumes of the aquifer and maximize the distribution of amendments over these volumes.

Groundwater↗
USGS2017

Bioremediation in fractured rock: 2. Mobilization of chloroethene compounds from the rock matrix

A mass balance is formulated to evaluate the mobilization of chlorinated ethene compounds (CE) from the rock matrix of a fractured mudstone aquifer under pre- and postbioremediation conditions. The analysis relies on a sparse number of monitoring locations and is constrained by a detailed description of the groundwater flow regime. Groundwater flow modeling developed under the site characterization identified groundwater fluxes to formulate the CE mass balance in the rock volume exposed to the injected remediation amendments. Differences in the CE fluxes into and out of the rock volume identify the total CE mobilized from diffusion, desorption, and nonaqueous phase liquid dissolution under pre- and postinjection conditions. The initial CE mass in the rock matrix prior to remediation is estimated using analyses of CE in rock core. The CE mass mobilized per year under preinjection conditions is small relative to the total CE mass in the rock, indicating that current pump-and-treat and natural attenuation conditions are likely to require hundreds of years to achieve groundwater concentrations that meet regulatory guidelines. The postinjection CE mobilization rate increased by approximately an order of magnitude over the 5 years of monitoring after the amendment injection. This rate is likely to decrease and additional remediation applications over several decades would still be needed to reduce CE mass in the rock matrix to levels where groundwater concentrations in fractures achieve regulatory standards.

New Jersey↗
USGS2015

Chemical and ancillary data associated with bed sediment, young of year Bluefish ( Pomatomus saltatrix ) tissue, and mussel ( Mytilus edulis and Geukensia demissa ) tissue collected after Hurricane Sandy in bays and estuaries of New Jersey and New York, 2013–14

This report describes the methods and data associated with a reconnaissance study of young of year bluefish and mussel tissue samples as well as bed sediment collected as bluefish habitat indicators during August 2013&ndash;April 2014 in New Jersey and New York following Hurricane Sandy in October 2012. This study was funded by the Disaster Relief Appropriations Act of 2013 (PL 113-2) and was conducted by the U.S. Geological Survey (USGS) in cooperation with the National Oceanic and Atmospheric Administration (NOAA). Young of year Pomatomus saltatrix (bluefish) were collected from nine sites in New Jersey (N.J.) and New York (N.Y.) including Barnegat Bay, N.J., Sandy Hook Bay, N.J., Jamaica Bay, N.Y., and Great South Bay, N.Y., and analyzed for indicators of health and chemical contamination. At each bluefish sampling location, bed sediment was also collected and analyzed for a suite of contaminants. Resident mussels, Mytilus edulis (blue mussels) and (or) Geukensia demissa (ribbed mussels), were collected from 11 historic NOAA Mussel Watch Program sites along the N.J. and N.Y. coastlines in the winter/spring of 2014 and analyzed for contaminants. Individual age of a subset of the mussels sampled was also determined at each site. Bed sediment samples were analyzed for a suite of organic contaminants including 34 polychlorinated biphenyl (PCB) congeners, 28 polybrominated diphenyl ether (PBDE) congeners, 24 organochlorine pesticides (OCPs), 53 polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs, 33 aliphatic hydrocarbons (AHs), and 10 petroleum biomarkers (steranes and hopanes). Bed sediment collected from the Navesink River (Sandy Hook, N.J.), Metedeconk River (Barnegat Bay, N.J.), and Toms River (Barnegat Bay, N.J.) had the highest concentrations of contaminants compared to the other sites. Bluefish and mussel tissue collected throughout the study area was analyzed for 34 PCB congeners, 28 PBDE congeners, and 24 OCPs. Thirty-three PCB congeners, 22 PBDE congeners, and 24 OCPs were detected in the bluefish analyzed. The highest median concentrations of total PCBs were present in tissue from Jamaica Bay, N.Y., whereas the highest median concentrations of total PBDEs and total OCPs were present in tissue from Sandy Hook Bay. Of the OCPs detected, p,p&rsquo; -DDE was found in 99 percent (%) of the tissue samples and at the highest median concentrations compared to the other OCPs. Fish health assessments were conducted on 20 fish from the 4 bays. Results indicate that the sex ratio and the mean total length varied by site. Physical fish damage, such as lesions and parasites, was observed in fish from all four bays. The most common parasite observed visually was the presence of Livoneca redmanii , an ectoparasitic gill isopod, which can cause localized gill erosion. The prevalence of the gill isopod infestation ranged from 20% at Great South Bay, N.Y., to 35% at Jamaica Bay, N.Y. Twenty three PCB congeners, 9 PBDE congeners, and 20 OCPs were detected in composite mussel samples collected throughout the study area. The co-eluting PCB congeners 153 and 132, PBDE 47, 99, and 100, and p,p&rsquo; -DDE were detected in samples from each site. The highest median concentrations of PCBs and PBDEs were present in mussels from Raritan Bay, N.Y., whereas the highest median concentrations of OCPs were present in mussels from Fire Island Inlet, N.Y., and Shark River, N.J. Mytilus edulis (blue mussels) and Geukensia demissa (ribbed mussels) were thin-sectioned and aged. The blue mussels collected ranged in age from 4 to 13 years, and the ribbed mussels ranged in age from 3 to 12 years.

New Jersey, New York↗
USGS2015

Imaging pathways in fractured rock using three-dimensional electrical resistivity tomography

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three-dimensional cross borehole electrical resistivity tomography (ERT) in a 9&thinsp;m (diameter)&thinsp;&times;&thinsp;15&thinsp;m well field to capture high-resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time-lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone.

New Jersey↗
USGS2015

Estuarine bed-sediment-quality data collected in New Jersey and New York after Hurricane Sandy, 2013

This report describes a reconnaissance study of estuarine bed-sediment quality conducted June&ndash;October 2013 in New Jersey and New York after Hurricane Sandy in October 2012 to assess the extent of contamination and the potential long-term human and ecological impacts of the storm. The study, funded through the Disaster Relief Appropriations Act of 2013 (PL 113-2), was conducted by the U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency and the National Oceanographic and Atmospheric Administration. In addition to presenting the bed-sediment-quality data, the report describes the study design, documents the methods of sample collection and analysis, and discusses the steps taken to assure the quality of the data. Bed-sediment samples were collected from June to October 2013 from 167 estuarine sites extending from Cape May, New Jersey, to the New York Harbor and the eastern end of Long Island. Each sampling location and study region was characterized by using geographic information to identify potential contaminant sources. Characterizations included land cover, locations and types of businesses (industrial, financial, and others), spills (sewage, chemical, and others), bulk storage facilities, effluent discharges within 2 kilometers of the sampling point, and discharges within inundated and non-inundated regions near the sampling location. Samples were analyzed for particle size, total organic carbon, metals and trace elements, semivolatile organic compounds, wastewater compounds, hormones, and sediment toxicity. Samples were also screened using x-ray fluorescence, Fourier transform infrared spectroscopy, and x-ray diffraction. In addition, bioassays for endocrine disruptors and protein phosphatase 2A inhibition were conducted. The study was designed to provide the data needed to understand the extent and sources of contamination resulting from Hurricane Sandy, to compare the chemistry and toxicity of estuarine bed sediments before and after the storm, and to evaluate the usefulness of rapid screening and bioassay approaches in disaster settings.

New Jersey, New York↗
USGS2014

Integration of stable carbon isotope, microbial community, dissolved hydrogen gas, and 2 H H 2 O tracer data to assess bioaugmentation for chlorinated ethene degradation in fractured rocks

An in situ bioaugmentation (BA) experiment was conducted to understand processes controlling microbial dechlorination of trichloroethene (TCE) in groundwater at the Naval Air Warfare Center (NAWC), West Trenton, NJ. In the BA experiment, an electron donor (emulsified vegetable oil and sodium lactate) and a chloro-respiring microbial consortium were injected into a well in fractured mudstone of Triassic age. Water enriched in 2 H was also injected as a tracer of the BA solution, to monitor advective transport processes. The changes in concentration and the δ 13 C of TCE, cis-dichloroethene (cis-DCE), and vinyl chloride (VC); the δ 2 H of water; changes in the abundance of the microbial communities; and the concentration of dissolved H2 gas compared to pre- test conditions, provided multiple lines of evidence that enhanced biodegradation occurred in the injection well and in two downgradient wells. For those wells where the biodegradation was stimulated intensively, the sum of the molar chlorinated ethene (CE) concentrations in post-BA water was higher than that of the sum of the pre-BA background molar CE concentrations. The concentration ratios of TCE/(cis-DCE + VC) indicated that the increase in molar CE concentration may result from additional TCE mobilized from the rock matrix in response to the oil injection or due to desorption/diffusion. The stable carbon isotope mass-balance calculations show that the weighted average 13 C isotope of the CEs was enriched for around a year compared to the background value in a two year monitoring period, an effective indication that dechlorination of VC was occurring. Insights gained from this study can be applied to efforts to use BA in other fractured rock systems. The study demonstrates that a BA approach can substantially enhance in situ bioremediation not only in fractures connected to the injection well, but also in the rock matrix around the well due to processes such as diffusion and desorption. Because the effect of the BA was intensive only in wells where an amendment was distributed during injection, it is necessary to adequately distribute the amendments throughout the fractured rock to achieve substantial bioremediation. The slowdown in BA effect after a year is due to some extend to the decrease abundant of appropriate microbes, but more likely the decreased concentration of electron donor.

New Jersey↗
USGS2014

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: depth- and strata-dependent spatial variability from rock-core sampling

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently dipping mudstones. Despite more than 18 years of pump and treat (P&T) remediation, and natural attenuation processes, CVOC concentrations in aqueous samples pumped from these deeper strata remain elevated in isolated intervals. DNAPL was detected in one borehole during coring at a depth of 27 m. In contrast to core samples from the weathered zone, concentrations in core samples from deeper unweathered and unfractured strata are typically below detection. However, high CVOC concentrations were found in isolated samples from fissile black carbon-rich strata and fractured gray laminated strata. Aqueous-phase concentrations were correspondingly high in samples pumped from these strata via short-interval wells or packer-isolated zones in long boreholes. A refined conceptual site model considers that prior to P&T remediation groundwater flow was primarily subhorizontal in the higher-permeability near surface strata, and the bulk of contaminant mass was shallow. CVOCs diffused into these fractured and weathered mudstones. DNAPL and high concentrations of CVOCs migrated slowly down in deeper unweathered strata, primarily along isolated dipping bedding-plane fractures. After P&T began in 1995, using wells open to both shallow and deep strata, downward transport of dissolved CVOCs accelerated. Diffusion of TCE and other CVOCs from deeper fractures penetrated only a few centimeters into the unweathered rock matrix, likely due to sorption of CVOCs on rock organic carbon. Remediation in the deep, unweathered strata may benefit from the relatively limited migration of CVOCs into the rock matrix. Synthesis of rock core sampling from closely spaced boreholes with geophysical logging and hydraulic testing improves understanding of the controls on CVOC delineation and informs remediation design and monitoring.

New Jersey, New York, Pennsylvania↗
USGS2011

Demonstration and validation of a regenerated cellulose dialysis membrane diffusion sampler for monitoring groundwater quality and remediation progress at DoD sites: Perchlorate and ordnance compounds

This final technical report documents the demonstration and validation of regenerated cellulose dialysis membrane diffusion samplers (RCDM samplers) for use in collecting groundwater samples for perchlorate and a suite of explosives compounds. This project, ER-0313, was funded by the Environmental Security Technology Certification Program (ESTCP). The primary objectives of the project were; (1) to determine the usefulness of RCDM samplers in collecting perchlorate and a suite of explosives compounds from groundwater, (2) to determine the optimum equilibration times for these constituents to diffuse into the RCDM sampler, (3) to compare water-quality results and sampling costs from samples collected with RCDM samplers to samples collected with a low-flow purging technique, and (4) to transfer the technology while gaining regulatory acceptance. Equilibration times were determined in bench-scale testing for perchlorate and 14 nitroaromatic and nitramine explosives compounds. Field comparisons were conducted at two Department of Defense (DoD) sites: (1) Aberdeen Proving Grounds (APG), Maryland, and, (2) Picatinny Arsenal, New Jersey. Samples collected with the two sampling techniques were compared graphically and statistically to determine the significance of any differences found. RCDM samplers were found to cost significantly less than samples collected with a low-flow purging procedure. Sampling time was reduced by 84%, compared to low-flow purging. The total sampling costs per sample were calculated to be 71% less with an RCDM sampler, compared to low-flow purging.

Maryland, New Jersey↗
USGS2011

Demonstration/validation of the Snap sampler passive groundwater sampling device

Laboratory studies and a field demonstration were conducted to determine the ability of the Snap Sampler to recover representative concentrations of several types of inorganic analytes from ground water. Analytes included non-metals, transition metals, alkaline earth metals, alkali metals, and a metalloid. In the laboratory studies, concentrations of analytes in Snap Sampler samples were com-parable with concentrations of the analytes in samples collected from a standpipe (i.e., control samples). For the field demonstration, there were sampling events at the former Pease Air Force Base. Samples taken using a Snap Sampler were compared with samples collected using conventional low-flow purging and sampling and a regenerated cellulose passive diffusion sampler. Based upon statistical analyses, analyte concentrations were found to be equivalent to those in the low-flow samples with one exception – unfiltered iron, where concentrations were significantly higher in the Snap Sampler samples. Differences were most pronounced in samples collected from the two stainless steel wells and from wells with higher turbidity levels. Elevated turbidities may have resulted from installing additional sampling equipment (including the baffle, pump, samplers, and bottom weight) in the well before sampling. We will examine this issue further at our next test site.

New Hampshire↗
USGS2007

Comparison of downhole and surface sampling for the determination of volatile organic compounds (VOCs) in ground water

The relative precision and accuracy of sampling and analysis methods for the determination of trace concentrations of volatile organic compounds (VOCs) in ground water were compared. Samples were collected from a well containing nanogram‐per‐liter (ng/L) to microgram‐per‐liter (μg/L) levels of VOCs. A Keck helical rotor submersible pump was used to collect samples at the surface for analysis by purge and trap (P&T) and for analysis by adsorption/thermal desorption (ATD). Downhole samples were collected by passing water through an ATD cartridge. Although slight spontaneous bubble outgassing occurred when the water was brought to the surface, the relative precisions and comparabilities of the surface and downhole methods were generally found to be equivalent from a statistical point of view. A main conclusion of this study is that bringing sample water to the surface for placement in VOC vials (and subsequent analysis by P&T) can be done reliably under many circumstances. However, care must still be taken to prevent adsorption losses and cross contamination. Samples subject to strong bubble outgassing will need to be handled in a special fashion (e.g., by downhole ATD) to minimize volatilization losses. Additionally, the higher sensitivity of the ATD method allows lower detection limits than are possible with P&T. For example, several compounds present at the ng/L level could be determined with confidence by ATD, but not by P&T.

New Jersey↗