Geology topics

Theodore K. Greeman

Publications and source records attributed to Theodore K. Greeman.

6 recordsLinked to original sources

USGS2007

Hydrogeology, Ground-Water-Age Dating, Water Quality, and Vulnerability of Ground Water to Contamination in a Part of the Whitewater Valley Aquifer System near Richmond, Indiana, 2002-2003

Assessments of the vulnerability to contamination of ground-water sources used by public-water systems, as mandated by the Federal Safe Drinking Water Act Amendments of 1996, commonly have involved qualitative evaluations based on existing information on the geologic and hydrologic setting. The U.S. Geological Survey National Water-Quality Assessment Program has identified ground-water-age dating; detailed water-quality analyses of nitrate, pesticides, trace elements, and wastewater-related organic compounds; and assessed natural processes that affect those constituents as potential, unique improvements to existing methods of qualitative vulnerability assessment. To evaluate the improvement from use of these methods, in 2002 and 2003, the U.S. Geological Survey, in cooperation with the City of Richmond, Indiana, compiled and interpreted hydrogeologic data and chemical analyses of water samples from seven wells in a part of the Whitewater Valley aquifer system in a former glacial valley near Richmond. This study investigated the application of ground-water-age dating, dissolved-gas analyses, and detailed water-quality analyses to quantitatively evaluate the vulnerability of ground water to contamination and to identify processes that affect the vulnerability to specific contaminants in an area of post-1972 greenfield development. The aquifer system in the study area includes an unconfined sand and gravel aquifer used for public-water supply (upper aquifer) and a confined sand and gravel aquifer (lower aquifer) separated by a till confining unit. Several hydrogeologic and cultural measures indicate that the upper aquifer is qualitatively vulnerable to contamination: the upper aquifer is unconfined and has a shallow depth to the water table (from about 4.75 to 14 feet below land surface), low-permeability sediments in the unsaturated zone are thin (less than 10 feet thick), estimated ground-water-flow rates through the upper aquifer are relatively rapid (the highest estimated rates ranged from 0.44 to about 5.0 feet per day), and potential contaminant sources were present. Ground-water-age dates indicate that ground-water samples represented recharge from about the time greenfield development began south of the ground-water-flow divide and that changes in water quality would lag changes in contaminant inputs. Estimates of ground-water age, computed with dichlorodifluoromethane (CFC-12) and trichlorotrifluoroethane (CFC-113) concentrations in water samples collected from seven observation wells in February and March 2003, indicated that water in the upper aquifer had recharged within about 13 to 30 years before sampling. Ground-water ages were youngest (from about 13 to 15 years since recharge) in water from the shallow wells along the glacial-valley margin and oldest (30 years) in water from a well at the base of the aquifer in the valley center. Ground-water ages determined for the shallow wells may be affected by mixing of recent recharge with older ground water from deeper in the aquifer, as indicated by upward hydraulic gradients between paired shallow and deep wells in the upper aquifer. Other parts of the Whitewater Valley aquifer system with similar hydrogeologic characteristics could be expected to have similarly young ground-water ages and residence times. Analyses of water samples collected from the seven observation wells in August and September 2002 indicated that concentrations of chloride, sodium, and nitrate generally were larger in ground water from the upper aquifer than in other parts of the Whitewater Valley aquifer system. Drinking-water-quality standards for Indiana were exceeded in water samples from one well for chloride concentrations, from four wells for dissolved-solids concentrations, and from one well for nitrate concentrations. Application of low-level methods for trace-element analyses determined that concentrations of aluminum, cobalt, iron, lithium, molybdenum, nickel, selenium, uranium, vanadium, and zinc were less than or equal to 8 micrograms per liter; concentrations of arsenic, cadmium, chromium, and copper were less than or equal to 1 microgram per liter. Application of low-level analytical methods to water samples enabled the detection of several pesticides and volatile, semivolatile, and wastewater-related organic compounds; concentrations of individual pesticides and volatile organic compounds were less than 0.1 microgram per liter and concentrations of individual wastewater organic compounds were less than 0.5 microgram per liter. The low-level analytical methods will provide useful data with which to compare future changes in water quality. Results of detailed water-quality analyses, ground-waterage dating, and dissolved-gas analyses indicated the vulnerability of ground water to specific types of contamination, the sequence of contaminant introduction to the aquifer relative to greenfield development, and processes that may mitigate the contamination. Concentrations of chloride and sodium and chloride/bromide weight ratios in sampled water from five wells indicated the vulnerability of the upper aquifer to roaddeicer contamination. Ground-water-age estimates from these wells indicated the onset of upgradient road-deicer use within the previous 25 years. Nitrate in the upper aquifer predates the post-1972 development, based on a ground-water-age date (30 years) and the nitrate concentration (5.12 milligrams per liter as nitrogen) in water from a deep well. Vulnerability of the aquifer to nitrate contamination is limited partially by denitrification. Detection of one to four atrazine transformation products in water samples from the upper aquifer indicated biological and hydrochemical processes that may limit the vulnerability of the ground water to atrazine contamination. Microbial processes also may limit the aquifer vulnerability to small inputs of halogenated aliphatic compounds, as indicated by microbial transformations of trichlorofluoromethane and trichlorotrifluoroethane relative to dichlorodifluoromethane. The vulnerability of ground water to contamination in other parts of the aquifer system also may be mitigated by hydrodynamic dispersion and biologically mediated transformations of nitrate, pesticides, and some organic compounds. Identification of the sequence of contamination and processes affecting the vulnerability of ground water to contamination would have been unlikely with conventional assessment methods.

Indiana, Ohio↗

USGS1998

Hydrology and geochemistry of a slag-affected aquifer and chemical characteristics of slag-affected ground water, northwestern Indiana and northeastern Illinois

Slag is a by-product of steel manufacturing and a ubiquitous fill material in northwestern Indiana. Ground water associated with slag deposits generally is characterized by high pH and elevated concentrations of many inorganic water-quality constituents. The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, conducted a study in northwestern Indiana from June 1995 to September 1996 to improve understanding of the effects of slag deposits on the water quality of a glacial-outwash aquifer. The Bairstow Landfill, a slag-fill deposit overlying the Calumet aquifer near Hammond, Indiana, was studied to represent conditions in slag-deposit settings that are common in northwestern Indiana. Ground water from 10 observation wells, located in four nests at the site, and surface water from the adjacent Lake George were analyzed for values of field-measured parameters and concentrations of major ions, nutrients, trace elements, and bulk properties. Solid-phase samples of slag and aquifer sediment collected during drilling were examined with X-ray diffraction and geochemical digestion and analysis. Concentrations of calcium, potassium, sodium, and sulfate were highest in wells screened partly or fully in slag. Potassium concentrations in ground water ranged from 2.9 to 120 milligrams per liter (mg/L), were highest in water from slag deposits, and decreased with depth. The highest concentrations for aluminum, barium, molybdenum, nickel, and selenium were in water from the slag. Silica concentrations were highest in wells screened directly beneath the slag-aquifer interface, and magnesium concentrations were highest in intermediate and deep aquifer wells. Silica concentrations in shallow and intermediate aquifer wells ranged from 27 to 41 mg/L and were about 10 times greater than those in water from slag deposits. The highest concentrations for chromium, lead, and zinc were in ground water from immediately below the slag-aquifer interface. The solid-phase analyses indicated that calcite, dolomite, and quartz generally were present throughout the slag-aquifer system; barian celestite, cristobalite, manganese-bearing calcite, and minrecordite were present in fewer samples. Trace elements that are liberated from the slag may be incorporated as impurities during precipitation of major minerals, sorbed onto clays and other grainsize fractions not analyzed as part of this study, or present in low-abundance minerals that were not detected by the X-ray analysis. Mass-balance and speciation programs were used to identify geochemical processes that may be occurring as water infiltrates through the slag, flows into the aquifer, and discharges into Lake George. The geochemical models indicate that precipitation of calcite may be occurring where slag-affected water enters the aquifer. Models also indicate that dolomite precipitation and clay-mineral dissolution may be occurring at the slag-aquifer interface; however, dolomite precipitation is generally believed to require geologically long time periods. Silica may be dissolving where slag-affected ground water enters the aquifer and may be precipitating where slag-affected ground water discharges to the lakebed of Lake George. In addition to the site-specific study, a statistical analysis of regional water quality was done to compare ground water in wells affected and unaffected by slag. When com-pared to wells in background locations in the Calumet aquifer, wells screened in slag across northwestern Indiana and northeastern Illinois generally had relatively higher pH and specific-conductance values and relatively higher concentrations of alkalinity, dissolved solids, suspended solids, total organic carbon, calcium, potassium, sodium, chloride, aluminum, barium, and possibly magnesium, sulfate, chromium, cobalt, copper, cyanide, manganese, mercury, nickel, and vanadium. When compared to wells in slag and wells in background locations, ground water from immediately beneath or immediately downgradient from slag had relatively high concentrations of arsenic and silica. Water-quality characteristics in ground water at the Bairstow Landfill were similar to water-quality characteristics in slag-contact and slag-affected wells throughout northwestern Indiana.

Illinois, Indiana↗

USGS1997

Characterization of fill deposits in the Calumet region of northwestern Indiana and northeastern Illinois

In October 1993, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, began a study of the fill deposits in the Calumet region of northwestern Indiana and northeastern Illinois. Fill in this area is a mixture of steel-industry wastes, other industrial waste, municipal solid waste, dredging spoil, construction debris, ash, cinders, natural materials, and biological sludge. Fill deposits are concentrated along Lake Michigan; from the Lake Calumet area to the east of the Indiana Harbor Canal; along the Calumet, Little Calumet, and Grand Calumet Rivers; and along the Calumet Sag Channel. Industrial wastes and municipal solid wastes are used as fill near Lake Calumet. Steel-industry wastes, primarily slag, are used as fill along Lake Michigan, Wolf Lake, Lake George, parts of Lake Calumet, and parts of the Calumet and Little Calumet Rivers. Dredging spoil is located along the rivers, and in abandoned river channels, landfills, and tailing ponds. Cinders, ash, construction debris, and natural materials are scattered throughout the area. Currently (1996), fill covers about 60.2 square miles of the study area. A total volume of about 2.1 x 1010 cubic feet of fill was calculated to be present in the Calumet region. Most of this fill is steel-industry waste. Fill deposition in the study area has been essentially continuous from about 1870 to the present (1996). Fill deposited before 1964 was used as foundation for streets and railroad tracks, to create land for industrial expansion, and to dispose of waste material. Much of the fill deposited after 1964 was disposed of in landfills designed to minimize environmental effects. Industrial wastes, municipal solid wastes, steel-industry wastes, and, perhaps, dredging spoil can be associated with increased concentrations of volatile and semivolatile organic compounds, pesticides, cyanide, metals, or major ions in ground water in this area. Construction debris, ash, cinders, and natural fill may be associated with increased concentrations of major ions in ground water.

Illinois, Indiana↗

USGS1995

Water levels in the Calumet aquifer and their relation to surface-water levels in northern Lake County, Indiana, 1985-92

The U.S. Geological Survey made 2,328 water-level measurements at a total of 96 ground-water and surface-water sites in northern Lake County, Indiana, from August 1985 through September 1992. This report lists and summarizes the significance of the measurements. Northern Lake County is on the southern shore of Lake Michigan and includes the cities of East Chicago, Gary, Hammond, and Whiting. The study area is underlain by the unconfined Calumet aquifer and receives about 36 inches of precipitation per year. The U.S. Geological Survey investigated ground-water levels and flow in the Calumet aquifer and the effect of Lake Michigan levels on ground-water and surface-water levels throughout the study area. Summary statistics of the water-level data were computed for each site. Ground-water levels annually reach a maximum in June or July and a minimum in September or October. Measured groundwater fluctuations in the Calumet aquifer during the study period ranged from 0.40 to 5.01 feet, and the mean ground-water fluctuation was about 2.3 feet The largest surface-water fluctuations were affected by record setting Lake Michigan levels. Midmonth daily averages for the data-collection period show that Lake Michigan fluctuated 4.14 feet Water-level fluctuations on the Grand Calumet River were from 1.06 to 2.45 feet. Analysis of water-level data indicates that the 1988 drought did not substantially affect water levels in the Calumet aquifer, but the deficit in precipitation reversed vertical flow gradients in ground water at three paired deep and shallow wells. High water levels in Lake Michigan during 1985-87 created long-term backwater effects on the Grand Calumet River as far as 11.0 miles upstream from Lake Michigan. Analysis of water-level data from the data-collection network indicates that the water table normally slopes toward streams, ditches, sewers, the Indiana Harbor Canal, and Lake Michigan. The slope of the water table toward the Grand Calumet River is greatest in the winter and can decrease to being almost horizontal in the summer. Wells near streams respond quickly to nearby surface-water-level changes. Water-table maps indicate that sewers and dewatering systems are lowering ground-water levels in large areas. Ditches, the Grand Calumet River, and the Indiana Harbor Canal connect the Lake Michigan water level to large parts of the study area. The surface-water stage in the Indiana Harbor Canal, which functions as a ditch, can equal Lake Michigan's stage up to 3.75 miles inland from the lakeshore. Human activity, the stage of Lake Michigan, and the storage capacity of the Calumet aquifer combine to reduce vertical changes in the water table in the study area.

Indiana↗

USGS1994

Hydrogeologic atlas of aquifers in Indiana

Aquifers in 12 water-management basins of Indiana are identified in a series of 104 hydrogeologic sections and 12 maps that show the thickness and configuration of aquifers. The vertical distribution of water-bearing units and a generalized potentiometric profile are shown along 3,500 miles of section lines that were constructed from drillers' logs of more than 4,200 wells. The horizontal scale of the sections is 1:125,000. Maps of aquifers showing the areal distribution of each aquifer type were drawn at a scale of 1:500,000. Unconsolidated aquifers are the most widely used aquifers in Indiana and include surficial, buried, and discontinuous layers of sand and gravel. Most of the surficial sand and gravel is in large outwash plains in northern Indiana and along the major rivers. Buried sand and gravel aquifers are interbedded with till deposits in much of the northern two-thirds of Indiana. Discontinuous sand and gravel deposits are present as isolated lenses, primarily in glaciated areas. The bedrock aquifers generally have lower yields than most of the sand and gravel aquifers; however, bedrock aquifers are areally widespread and are an important source of water. Bedrock aquifer types consist of carbonates; sandstones; complexly interbedded sandstones, siltstones, shales, limestones, and coals; and an upper weathered zone in low permeability rock. Carbonate aquifers underlie about one-half of Indiana and are the most productive of the bedrock aquifers. The other principal bedrock aquifer type, sandstone, underlies large areas in the southwestern one-fifth of Indiana. No aquifer is known to be present in the southeastern corner of Indiana.

Water-Resources Investigations Report↗

USGS1983

Lineaments and fracture traces, Decatur County, Indiana

Lineanents and fracture traces have been mapped throughout Decatur County, Indiana. These lineaments and fracture traces may indicate that solution enlarged vertical fractures in the limestone and dolonite aquifers underlie most of the county. The use of lineament and fracture-trace maps in selecting bedrock-drilling sites results in a significant increase in the number of usable sites. Bedrock wells drilled on or near mapped lineaments and fracture traces have a higher average yield than veils drilled into interfracture areas. Parts of Decatur County and several adjacent counties are economically restricted by inadequate water supplies. The Greensburg Municipal Water Works, supplying 35 percent of the county's population, obtains 25 percent of its water from six wells in Greensburg. The remaining 75 percent is pumped from the Flat Rock River. This water is piped 8.25 miles and lifted 183 feet to the treatment station. Although the Flatrock River has adequate flow to supply Greensburg's water needs, a ground-water supply can probably be developed nearer the treatment plant. Pleistocene till covers most of the nearly horizontal bedrock. Although averaging about 50 feet thick, this unconsolidated unit does not seem to inhibit the mapping of lineaments and fracture traces. Bedrock is middle Paleozoic limestone, dolomite, and shale. Two sequences of limestone and dolomite, separated by a thin shale unit, constitute the principal aquifer. The extremely variable well yields from this aquifer indicate that the bedrock permeability is also variable. Well placement is important in a fractured bedrock terrane, as fractures are a principal source of water to the well. Here, the most productive bedrock wells are at the mapped intersection of two or more fracture traces or lineaments and at the lowest local altitude. Use of a fracture-trace map will not guarantee a sufficient supply of ground water but will reduce the chance of drilling an inadequate well.

Indiana↗