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Geology topics

T.D. Lorenson

Publications and source records attributed to T.D. Lorenson.

At least 37 records · Page 2Linked to original sources
USGS2009

Sensitivity of the carbon cycle in the Arctic to climate change

The recent warming in the Arctic is affecting a broad spectrum of physical, ecological, and human/cultural systems that may be irreversible on century time scales and have the potential to cause rapid changes in the earth system. The response of the carbon cycle of the Arctic to changes in climate is a major issue of global concern, yet there has not been a comprehensive review of the status of the contemporary carbon cycle of the Arctic and its response to climate change. This review is designed to clarify key uncertainties and vulnerabilities in the response of the carbon cycle of the Arctic to ongoing climatic change. While it is clear that there are substantial stocks of carbon in the Arctic, there are also significant uncertainties associated with the magnitude of organic matter stocks contained in permafrost and the storage of methane hydrates beneath both subterranean and submerged permafrost of the Arctic. In the context of the global carbon cycle, this review demonstrates that the Arctic plays an important role in the global dynamics of both CO 2 and CH 4 . Studies suggest that the Arctic has been a sink for atmospheric CO 2 of between 0 and 0.8 Pg C/yr in recent decades, which is between 0% and 25% of the global net land/ocean flux during the 1990s. The Arctic is a substantial source of CH 4 to the atmosphere (between 32 and 112 Tg CH 4 /yr), primarily because of the large area of wetlands throughout the region. Analyses to date indicate that the sensitivity of the carbon cycle of the Arctic during the remainder of the 21st century is highly uncertain. To improve the capability to assess the sensitivity of the carbon cycle of the Arctic to projected climate change, we recommend that (1) integrated regional studies be conducted to link observations of carbon dynamics to the processes that are likely to influence those dynamics, and (2) the understanding gained from these integrated studies be incorporated into both uncoupled and fully coupled carbon–climate modeling efforts.

Ecological Monographs↗
USGS2009

Natural offshore oil seepage and related tarball accumulation on the California coastline — Santa Barbara Channel and the southern Santa Maria Basin; source identification and inventory

Oil spillage from natural sources is very common in the waters of southern California. Active oil extraction and shipping is occurring concurrently within the region and it is of great interest to resource managers to be able to distinguish between natural seepage and anthropogenic oil spillage. The major goal of this study was to establish the geologic setting, sources, and ultimate dispersal of natural oil seeps in the offshore southern Santa Maria Basin and Santa Barbara Basins. Our surveys focused on likely areas of hydrocarbon seepage that are known to occur between Point Arguello and Ventura, California. Our approach was to 1) document the locations and geochemically fingerprint natural seep oils or tar; 2) geochemically fingerprint coastal tar residues and potential tar sources in this region, both onshore and offshore; 3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; 4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; and 5) interpret the petroleum system history for the natural seeps. To document the location of sub-sea oil seeps, we first looked into previous studies within and near our survey area. We measured the concentration of methane gas in the water column in areas of reported seepage and found numerous gas plumes and measured high concentrations of methane in the water column. The result of this work showed that the seeps were widely distributed between Point Conception east to the vicinity of Coal Oil Point, and that they by in large occur within the 3-mile limit of California State waters. Subsequent cruises used sidescan and high resolution seismic to map the seafloor, from just south of Point Arguello, east to near Gaviota, California. The results of the methane survey guided the exploration of the area west of Point Conception east to Gaviota using a combination of seismic instruments. The seafloor was mapped by sidescan sonar, and numerous lines of high -resolution seismic surveys were conducted over areas of interest. Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. These samples were used to construct a chemometric fingerprint (multivariate statistics) decision tree to classify 288 additional samples, including tarballs of unknown origin collected from Monterey and San Mateo County beaches after a storm in early 2007. A subset of 9 of 23 active offshore platform oils and one inactive platform oil representing a few oil reservoirs from the western Santa Barbara Channel were used in this analysis, and thus this model is not comprehensive and the findings are not conclusive. The platform oils included in this study are from west to east: Irene, Hildago, Harvest, Hermosa, Heritage, Harmony, Hondo, Holly, Platform A, and Hilda (now removed). The results identify three “tribes” of 13 C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl, and lower calcareous-siliceous members of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher-plant input. Tribe 2 contains four oil families with intermediate traits, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher-plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey Formation source rock favored generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (Tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (Tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception, where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. It is very desirable to be able to clearly distinguish the naturally occurring seep oils from the anthropogenically derived platform oils. Within the “training set” of oils and tars (388 samples), the biomarker parameters are sometimes sufficient to allow unique discrimination of individual platform oils. More often however, platform samples and seep samples with sources geographically close to each other are too similar to each other, with respect to the biomarker parameters, to definitively differentiate them on that basis alone. In some cases other parameters can be helpful. These other parameters are related to the degree of biogeochemical degradation or weathering that the oils or tars have experienced. These components include the typical oil distribution of n-alkane hydrocarbons and isoprenoids pristane and phytane. All of the platform oils in our sample set contain these components. On the other hand, the seep oils or tars have been exposed to significant biodegradation while in the near subsurface. The majority, but not all of seep oils or tars have been biodegraded up to or beyond the loss of n-alkanes and isoprenoids. Seep oils found in the vicinity of Coal Oil Point or Arroyo Burro are apparently the least weathered and are particularly likely to retain significant n-alkanes and isoprenoids. Therefore the combination of chemometric fingerprinting and the presence or absence of n-alkanes and isoprenoids help to differentiate anthropogenic production oils versus natural seeps oils and tars. The differentiation is not always definitive because of the close chemical similarity of some samples and the variability in the biodegradation progression. This is the case near Coal Oil Point, and near Platform A (Dos Cuadros Field) where seep oils and Platform Holly and Platform A oils are genetically very similar and cannot be definitively distinguished after a period of a few days of weathering. In contrast, oils from the Point Conception platforms can be distinguished on the basis of chemometric fingerprinting alone. In the middle of this spectrum are oils from Platforms Harmony, Heritage, and Hondo, where it is expected that oil weathering would take on the order of two weeks to a month to produce tarballs similar to those seen near Point Conception. In this case there is a much greater degree of weathering needed to proceed from produced oil to the biodegraded tar characteristic of tarball stranded on the beach. Tar deposition on beaches was monitored as part of cooperative with the County of Santa Barbara Energy Division and the U.S. Geological Survey during 2001-2003. We found tar deposition varies on a seasonal basis. In general, tarballs accumulate at a faster rate or remain longer on all beaches during the summer and fall months. The reasons for this are unclear based on our limited observations, however we speculate that factors such as prevailing winds and currents combined with more quiescent wave conditions favors the accumulation and preservation of tarballs on the beach during the summer and fall months. In contrast, winter storms, with much greater wave action remove beach sand and other materials, and stormy seas tend to break up oil that might weather into tarballs. Natural seepage is affected by the spring/neap tidal cycle; however, the link to tar deposition is unclear. Longer periods of monitoring are needed to address the variability in the data and provide a more robust statistical analysis.

California↗
USGS2008

Reply to comments by Mastalerz, V. on "Shallow gasoff the Rhône prodelta, Gulf of Lions" Marine Geology 234 (215-231)

We really appreciate the interest and comments regarding our manuscript. We hope we address all the lingering issues in this reply. This also gives us the opportunity of publishing an update on our dataset that will complete the original manuscript (see Table 1 ). We have followed the author pattern in our answers: 1-Gas sampling procedure, 2-Reported gas concentrations results, 3-General remarks, 4-Conclusions.

Marine Geology↗
USGS2008

Natural gas geochemistry of sediments drilled on the 2005 Gulf of Mexico JIP cruise

In April and May 2005, cores were acquired and sub-sampled for gases in lease blocks Atwater Valley 13 and 14 and Keathley Canyon 151 during deep subseafloor drilling conducted as part of the JIP study of gas hydrates in the northern Gulf of Mexico. Sample types included sediment headspace gas, free gas derived from sediment gas exsolution, and gas exsolution from controlled degassing of pressurized cores. The gases measured both onboard and in shore-based labs were nitrogen, oxygen, hydrogen sulfide, carbon dioxide, and the hydrocarbons methane through hexane. The presence of seafloor mounds, seismic anomalies, a shallow sulfate-methane interface, and similar gas compositions and isotopic compositions near the seafloor and at depth suggest an upward flux of methane at both sites. Sediment gases at the Atwater Valley sites, where seafloor mounds and adjacent sediments were cored, strongly suggest a microbial source of methane, with very little thermogenic gas input. Sediment gas from all cores contained from about 96 to 99.9% methane, with the balance composed primarily of carbon dioxide. Methane to ethane ratios were greater than 1000, and often over 10,000. Gases from cores at Keathley Canyon were similar to those at Atwater Valley, however, deeper cores from Keathley Canyon contained more ethane, propane, and butane suggesting mixing with minor concentrations thermogenic gas. The isotopic composition of methane, ethane, and carbon dioxide were measured, and ??13C values range from -84.3 to -71.5???, -65.2 to -46.8???, and -23.5 to -3.0???, respectively, all consistent with microbial gas sources, early diagenesis of organic matter and perhaps biodegradation of petroleum. The presence of deep microbial gas at these sites here and elsewhere highlights a potentially significant, predominantly microbial gas source in the northern Gulf of Mexico.

Marine and Petroleum Geology↗
USGS2008

Families of miocene monterey crude oil, seep, and tarball samples, coastal California

Biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs to better assess their origins and distributions in coastal California. These samples were used to construct a chemometric (multivariate statistical) decision tree to classify 288 additional samples. The results identify three tribes of 13C-rich oil samples inferred to originate from thermally mature equivalents of the clayey-siliceous, carbonaceous marl and lower calcareous-siliceous members of the Monterey Formation at Naples Beach near Santa Barbara. An attempt to correlate these families to rock extracts from these members in the nearby COST (continental offshore stratigraphic test) (OCS-Cal 78-164) well failed, at least in part because the rocks are thermally immature. Geochemical similarities among the oil tribes and their widespread distribution support the prograding margin model or the banktop-slope-basin model instead of the ridge-and-basin model for the deposition of the Monterey Formation. Tribe 1 contains four oil families having geochemical traits of clay-rich marine shale source rock deposited under suboxic conditions with substantial higher plant input. Tribe 2 contains four oil families with traits intermediate between tribes 1 and 3, except for abundant 28,30-bisnorhopane, indicating suboxic to anoxic marine marl source rock with hemipelagic input. Tribe 3 contains five oil families with traits of distal marine carbonate source rock deposited under anoxic conditions with pelagic but little or no higher plant input. Tribes 1 and 2 occur mainly south of Point Conception in paleogeographic settings where deep burial of the Monterey source rock favored petroleum generation from all three members or their equivalents. In this area, oil from the clayey-siliceous and carbonaceous marl members (tribes 1 and 2) may overwhelm that from the lower calcareous-siliceous member (tribe 3) because the latter is thinner and less oil-prone than the overlying members. Tribe 3 occurs mainly north of Point Conception where shallow burial caused preferential generation from the underlying lower calcareous-siliceous member or another unit with similar characteristics. In a test of the decision tree, 10 tarball samples collected from beaches in Monterey and San Mateo counties in early 2007 were found to originate from natural seeps representing different organofacies of Monterey Formation source rock instead from one anthropogenic pollution event. The seeps apparently became more active because of increased storm activity. Copyright ?? 2008. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle↗
USGS2008

Comments on potential geologic and seismic hazards affecting proposed liquefied natural gas site in Santa Monica Bay, California

In a letter to the U.S. Geological Survey (USGS) dated March 25, 2008, Representative Jane Harman (California 36th district) requested advice on geologic hazards that should be considered in the review of a proposed liquefied natural gas (LNG) facility off the California coast in Santa Monica Bay. In 2004, the USGS responded to a similar request from Representative Lois Capps, regarding two proposed LNG facilities offshore Ventura County, Calif., with a report summarizing potential geologic and seismic hazards (Ross and others, 2004). The proposed LNG Deepwater Port (DWP) facility includes single point moorings (SPMs) and 35 miles of underwater pipelines. The DWP submersible buoys, manifolds, and risers would be situated on the floor of the southern Santa Monica Basin, in 3,000 feet of water, about 23 miles offshore of the Palos Verdes Peninsula. Twin 24-inch diameter pipelines would extend northeastward from the buoys across the basin floor, up the basin slope and across the continental shelf, skirting north around the Santa Monica submarine canyon. Figure 1 provides locations of the project and geologic features. Acronyms are defined in table 1. This facility is being proposed in a region of known geologic hazards that arise from both the potential for strong earthquakes and geologic processes related to sediment transport and accumulation in the offshore environment. The probability of a damaging earthquake (considered here as magnitude 6.5 or greater) in the next 30 years within about 30 miles (50 km) of the proposed pipeline ranges from 16% at the pipeline's offshore end to 48% where it nears land (Petersen, 2008). Earthquakes of this magnitude are capable of producing strong shaking, surface fault offsets, liquefaction phenomena, landslides, underwater turbidity currents and debris flow avalanches, and tsunamis. As part of the DWP license application for the Woodside Natural Gas proposal in Santa Monica Bay (known as the OceanWay Secure Energy Project), Fugro West, Inc., had already prepared a document discussing geologic hazards in the area, titled 'Exhibit B Topic Report 6 - Geological Resources' (Fugro West, Inc., 2007); hereafter, this will be called the 'Geological Resources document'. The USGS agreed to evaluate the information in the Geological Resources document regarding (1) proximity of active faults to the proposed project, (2) potential magnitude of seismic events from nearby faults, (3) thoroughness of the assessment of earthquake hazards in general, (4) potential hazards from ground rupture and strong shaking, (5) potential hazards from tsunamis, and (6) other geologic hazards including landslides and debris flows. Because two new earthquake probability reports were scheduled to be released in mid-April, 2008, by the USGS and the California Geological Survey (CGS), the USGS suggested a 6-month review period to enable a thorough incorporation of this new information. Twenty-seven scientists from the USGS and the CGS reviewed various sections of the Geological Resources document. This report outlines our major conclusions. The appendix is a longer list of comments by these reviewers, grouped by section of the Geological Resources document. Before discussing our reviews, we first provide a brief overview of geologic hazards in the proposed site area. This report is a snapshot in time and any future work in the area will need to take into account ongoing research efforts. For example, USGS scientists collected seismic reflection data in the spring of 2008 to study the structure and seismic potential of several faults in the area. Their interpretations (Conrad and others, 2008a and 2008b) are too preliminary to be included in this report, but their final results, along with other researchers' studies in the project area, should be considered in any future work on the Deepwater Port project.

California↗
USGS2007

Origin of pockmarks and chimney structures on the flanks of the Storegga Slide, offshore Norway

Seafloor pockmarks and subsurface chimney structures are common on the Norwegian continental margin north of the Storegga Slide scar. Such features are generally inferred to be associated with fluid expulsion, and imply overpressures in the subsurface. Six long gravity and piston cores taken from the interior of three pockmarks were compared with four other cores taken from the same area but outside the pockmarks, in order to elucidate the origins and stratigraphy of these features and their possible association with the Storegga Slide event. Sulfate gradients in cores from within pockmarks are less steep than those in cores from outside the pockmarks, which indicates that the flux of methane to the seafloor is presently smaller within the pockmarks than in the adjacent undisturbed sediments. This suggests that these subsurface chimneys are not fluid flow conduits lined with gas hydrate. Methane-derived authigenic carbonates and Bathymodiolus shells obtained from a pockmark at >6.3 m below the seafloor indicate that methane was previously available to support a chemosynthetic community within the pockmark. AMS 14C measurements of planktonic Foraminifera overlying and interlayered with the shell-bearing sediment indicate that methane was present on the seafloor within the pockmark prior to 14 ka 14C years B.P., i.e., well before the last major Storegga Slide event (7.2 ka 14C years B.P., or 8.2 ka calendar years B.P.). These observations provide evidence that overpressured fluids existed within the continental margin sediments off Norway during the last major advance of Pleistocene glaciation.

Geo-Marine Letters↗
USGS2007

Origin of pingo-like features on the Beaufort Sea shelf and their possible relationship to decomposing methane gas hydrates

[1] The Arctic shelf is currently undergoing dramatic thermal changes caused by the continued warming associated with Holocene sea level rise. During this transgression, comparatively warm waters have flooded over cold permafrost areas of the Arctic Shelf. A thermal pulse of more than 10°C is still propagating down into the submerged sediment and may be decomposing gas hydrate as well as permafrost. A search for gas venting on the Arctic seafloor focused on pingo-like-features (PLFs) on the Beaufort Sea Shelf because they may be a direct consequence of gas hydrate decomposition at depth. Vibracores collected from eight PLFs had systematically elevated methane concentrations. ROV observations revealed streams of methane-rich gas bubbles coming from the crests of PLFs. We offer a scenario of how PLFs may be growing offshore as a result of gas pressure associated with gas hydrate decomposition.

Beaufort Sea↗
USGS2007

Authigenic carbonate formation at hydrocarbon seeps in continental margin sediments: A comparative study

Authigenic carbonates from five continental margin locations, the Eel River Basin, Monterey Bay, Santa Barbara Basin, the Sea of Okhotsk, and the North Sea, exhibit a wide range of mineralogical and stable isotopic compositions. These precipitates include aragonite, low- and high-Mg calcite, and dolomite. The carbon isotopic composition of carbonates varies widely, ranging from −60‰ to +26‰, indicating complex carbon sources that include 13 C-depleted microbial and thermogenic methane and residual, 13 C-enriched, bicarbonate. A similarly large variability of δ 18 O values (−5.5‰ to +8.9‰) demonstrates the geochemical complexity of these sites, with some samples pointing toward an 18 O-enriched oxygen source possibly related to advection of 18 O-enriched formation water or to the decomposition of gas hydrate. Samples depleted in 18 O are consistent with formation deeper in the sediment or mixing of pore fluids with meteoric water during carbonate precipitation. A wide range of isotopic and mineralogical variation in authigenic carbonate composition within individual study areas but common trends across multiple geographic areas suggest that these parameters alone are not indicative for certain tectonic or geochemical settings. Rather, the observed variations probably reflect local controls on the flux of carbon and other reduced ions, such as faults, fluid conduits, the presence or absence of gas hydrate in the sediment, and the temporal evolution of the local carbon reservoir. Areas with seafloor carbonates that indicate formation at greater depth below the sediment–water interface must have undergone uplift and erosion in the past or are still being uplifted. Consequently, the occurrence of carbonate slabs on the seafloor in areas of active hydrocarbon seepage is commonly an indicator of exhumation following carbonate precipitation in the shallow subsurface. Therefore, careful petrographic and geochemical analyses are critical components necessary for the correct interpretation of processes related to hydrocarbon seepage in continental margin environments and elsewhere.

Deep-Sea Research Part II: Topical Studies in Ocea↗
USGS2007

Initial report of the IMAGES VIII/PAGE 127 gas hydrate and paleoclimate cruise on the RV Marion Dufresne in the Gulf of Mexico, 2-18 July 2002

The northern Gulf of Mexico contains many documented gas hydrate deposits near the sea floor. Although gas hydrate often is present in shallow subbottom sediment, the extent of hydrate occurrence deeper than 10 meters below sea floor in basins away from vents and other surface expressions is unknown. We obtained giant piston cores, box cores, and gravity cores and performed heat-flow analyses to study these shallow gas hydrate deposits aboard the RV Marion Dufresne in July 2002. This report presents measurements and interpretations from that cruise. Our results confirm the presence of gas hydrate in vent-related sediments near the sea bed. The presence of gas hydrate near the vents is governed by the complex interaction of regional and local factors, including heat flow, fluid flow, faults, pore-water salinity, gas concentrations, and sediment properties. However, conditions appropriate for extensive gas hydrate formation were not found away from the vents.

Gulf Of Mexico↗
USGS2006

Methanogenic calcite, 13C-depleted bivalve shells, and gas hydrate from a mud volcano offshore southern California

Methane and hydrogen sulfide vent from a cold seep above a shallowly buried methane hydrate in a mud volcano located 24 km offshore southern California in?? 800 m of water. Bivalves, authigenic calcite, and methane hydrate were recovered in a 2.1 m piston core. Aragonite shells of two bivalve species are unusually depleted in 13C (to -91??? ??13C), the most 13C-depleted shells of marine macrofauna yet discovered. Carbon isotopes for both living and dead specimens indicate that they used, in part, carbon derived from anaerobically oxidized methane to construct their shells. The ??13C values are highly variable, but most are within the range -12??? to -91???. This variability may be diagnostic for identifying cold-seep-hydrate systems in the geologic record. Authigenic calcite is abundant in the cores down to ???1.5 m subbottom, the top of the methane hydrate. The calcite is depleted in 13C (??13C = -46??? to -58???), indicating that carbon produced by anaerobically oxidized methane is the main source of the calcite. Methane sources include a geologic hydrocarbon reservoir from Miocene source rocks, and biogenic and thermogenic degradation of organic matter in basin sediments. Oxygen isotopes indicate that most calcite formed out of isotopic equilibrium with ambient bottom water, under the influence of gas hydrate dissociation and strong methane flux. High metal content in the mud volcano sediment indicates leaching of basement rocks by fluid circulating along an underlying fault, which also allows for a high flux of fossil methane. ?? 2006 Geological Society of America.

Geology↗
USGS2004

Geochemical characterization of tarballs on beaches along the California coast. Part I - Shallow seepage impacting the Santa Barbara Channel Islands, Santa Cruz, Santa Rosa and San Miguel

Tarballs are common along the southern California coastline. This study investigates tarballs from beaches along this coastline, with a focus on Santa Cruz, Santa Rosa, and San Miquel Islands in the Santa Barbara Channel. The tarballs were fingerprinted using biomarker and stable carbon isotope parameters, and then grouped according to genetic similarities. The data show that the tarballs are of natural and not anthropogenic origin and that all originate from source rock within the Miocene Monterey Formation via shallow seeps offshore. Sterane biomarker parameters were found to vary widely in the sample set. Biodegradation, especially of the regular steranes, is the primary process impacting the biomarker distributions in a large group of samples. The most common tarball occurrences appear to come from offshore seepage near the west end of Santa Cruz Island. Another major group most likely was transported north from near Santa Monica Bay. Several individual occurrences of some of these tarball groups also were found on beaches as far north as Pt. Reyes and as far south as San Diego, indicating significant long-distance dispersal by ocean currents. This study begins a library of tarball fingerprints to be used as a database to help distinguish between natural and anthropogenic tar occurrences all along the California coast, and to compare shallow seepage with future samples of deeper production oils from the same area.

Organic Geochemistry↗
USGS2003

Temporal and spatial distributions of contaminants in sediments of Santa Monica Bay, California

Contaminant inputs from wastewater discharge, a major source of contamination to Santa Monica Bay (SMB), have declined drastically during the last three decades as a result of improved treatment processes and better source control. To assess the concomitant temporal changes in the SMB sediments, a study was initiated in June 1997, in which 25 box cores were collected using a stratified random sampling design. Five sediment strata corresponding to the time intervals of 1890-1920, 1932-1963, 1965-1979, 1979-1989, and 1989-1997 were identified using 210Pb dating techniques. Samples from each stratum were analyzed for metals, 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and its metabolites (DDTs), polychlorinated biphenyls (PCBs), and total organic carbon (TOC). Samples from the 1965-1979, 1979-1989, and 1989-1997 strata were also analyzed for polycyclic aromatic hydrocarbons (PAHs) and linear alkylbenzenes (LABs). Sediment metal concentrations increased from 1890-1979 and were similar during the time intervals of 1965-1979, 1979-1989, and 1989-1997, although the mass emissions of trace metals from sewage inputs declined substantially during the same time period. Trace organic contamination in SMB was generally highest in sediments corresponding to deposition during the years of 1965-1979 or 1979-1989 and showed a decline in concentration in the 1989-1997 stratum. Temporal trends of contamination were greatest in sediments collected from areas near the Hyperion Treatment Plant (HTP) outfall system and on the slope of Redondo Canyon. The highest contaminant concentrations were present in sediments near the HTP 7-mile outfall in the 1965-1979 stratum. Elevated trace metal and organic concentrations were still present in the 1989-1997 stratum of most stations, suggesting that sediment contaminants have moved vertically in the sediment column since sludge discharges from the 7-mile outfall (a dominant source of contamination to the bay) ceased in 1987. The widespread distributions of DDTs and PCBs in SMB and highly confined distribution of LABs around the HTP outfall system were indicative of a dispersal mechanism remobilizing historically deposited contaminants to areas relatively remote from the point of discharge. ?? 2003 Elsevier Science Ltd. All rights reserved.

Marine Environmental Research↗
USGS2003

Induction of lupus autoantibodies by adjuvants

Exposure to the hydrocarbon oil pristane induces lupus specific autoantibodies in non-autoimmune mice. We investigated whether the capacity to induce lupus-like autoimmunity is a unique property of pristane or is shared by other adjuvant oils. Seven groups of 3-month-old female BALB/cJ mice received a single intraperitoneal injection of pristane, squalene (used in the adjuvant MF59), incomplete Freund's adjuvant (IFA), three different medicinal mineral oils, or saline, respectively. Serum autoantibodies and peritoneal cytokine production were measured. In addition to pristane, the mineral oil Bayol F (IFA) and the endogenous hydrocarbon squalene both induced anti-nRNP/Sm and -Su autoantibodies (20% and 25% of mice, respectively). All of these hydrocarbons had prolonged effects on cytokine production by peritoneal APCs. However, high levels of IL-6, IL-12, and TNF?? production 2-3 months after intraperitoneal injection appeared to be associated with the ability to induce lupus autoantibodies. The ability to induce lupus autoantibodies is shared by several hydrocarbons and is not unique to pristane. It correlates with stimulation of the production of IL-12 and other cytokines, suggesting a relationship with a hydrocarbon's adjuvanticity. The potential to induce autoimmunity may complicate the use of oil adjuvants in human and veterinary vaccines. ?? 2003 Elsevier Ltd. All rights reserved.

Journal of Autoimmunity↗
USGS2003

Cruise summary for P-1-02-SC: acoustic imaging of natural oil and gas seeps and measurement of dissolved methane concentration in coastal waters near Pt. Conception, California

Water-column acoustic anomalies and methane concentrations were documented in coastal waters surrounding Pt. Conception, California, in March 2002. The purpose of this survey, supported by the Minerals Management Service, was to locate active oil and gas seeps in the area as a background for further studies to determine hydrocarbon flux, mainly oil, into the environment. Objectives in reaching this goal are to (1) document the locations and geochemically fingerprint natural seeps within the offshore southern Santa Maria Basin; (2) geochemically fingerprint coastal tar residues and potential sources, both onshore and offshore, in this region; (3) establish chemical correlations between offshore active seeps and coastal residues thus linking seep sources to oil residues; (4) measure the rate of natural seepage of individual seeps and attempt to assess regional natural oil and gas seepage rates; (5) attempt to predict transport pathways of oil from seep sources to the coastline and; (6) interpret the petroleum system history for the natural seeps. This survey, addressing objective 1, focused on the area from offshore Surf Beach to the north and Gaviota to the south in water depths ranging from 20 to 500m. In addition, nine stations were sampled outside this area to provide a regional context. Water-column methane concentrations were measured in water samples collected from the R/V Point Sur with Niskin bottles from various depths. A total of 724 water samples from 94 stations were collected.

California↗
USGS2002

Hydrocarbons in recent sediment of the Monterey Bay National Marine Sanctuary

A complex mixture of hydrocarbons is present in the recent sediment of the Monterey Bay National Marine Sanctuary. Eighteen samples from the continental shelf between San Francisco and Monterey contain aliphatic and aromatic hydrocarbons showing biological contributions from both marine and terrigenous sources, with the terrigenous indicators more pronounced near Monterey. Of particular interest, however, is a low-level background of petroleum-related compounds, including 28,30-bisnorhopane and 18??+??(H)-oleanane, which are characteristic of many crude oils from the Monterey Formation of California. Thus, the sediments are overprinted by a regional chemical signature which may be derived from eroded Monterey Formation rocks and from onshore and offshore seeps releasing petroleum from Monterey Formation source rocks. ?? 2002 Elsevier Science B.V. All rights reserved.

Marine Geology↗
USGS2002

Hydrocarbon geochemistry of cold seeps in the Monterey Bay National Marine Sanctuary

Samples from four geographically and tectonically discrete cold seeps named Clam Flat, Clamfield, Horseshoe Scarp South, and Tubeworm City, within the Monterey Bay National Marine Sanctuary were analyzed for their hydrocarbon content. The sediment contains gaseous hydrocarbons and CO2, as well as high molecular weight aliphatic and aromatic hydrocarbons with various combinations of thermogenic and biogenic contributions from petroleum, marine, and terrigenous sources. Of particular interest is the cold seep site at Clamfield which is characterized by the presence of thermogenic hydrocarbons including oil that can likely be correlated with oil-saturated strata at Majors Creek near Davenport, CA, USA. At Clam Flat, the evidence for thermogenic hydrocarbons is equivocal. At Horseshoe Scarp South and Tubeworm City, hydrocarbon gases, mainly methane, are likely microbial in origin. These varied sources of hydrocarbon gases highlight the diverse chemical systems that appear at cold seep communities. ?? 2002 Elsevier Science B.V. All rights reserved.

Marine Geology↗