Geology topics

T. Bullen

Publications and source records attributed to T. Bullen.

6 recordsLinked to original sources

USGS2018

Solute profiles in soils, weathering gradients and exchange equilibrium/disequilibrium

The spatial and temporal changes in hydrology and pore water elemental and 87/86 Sr compositions were used to determine contemporary weathering rates in a 65 to 226 ky old soil chronosequence formed from granitic sediments deposited on marine terraces along coastal California. Cl-corrected Na, K and Si increased with depth denoting inputs from the weathering of plagioclase and K-feldspar. Solute 87/86 Sr exhibited progressive mixing of sea water-dominated precipitation with inputs from less radiogenic plagioclase. Linear approximations to these weathering gradients were used to determine plagioclase weathering rates of between 0.38 and 8.9×10 −15 moles m −2 s −1 . The lack of corresponding weathering gradients for Ca and Sr indicated short-term equilibrium with the clay ion exchange pool which requires periodic resetting by natural perturbations to maintain continuity, in spite of soil composition changes reflecting the effects of long-term weathering.

Mineralogical Magazine↗

USGS2012

Geochemistry of yukon and copper river tributaries, Alaska

Alaska is already beginning to be affected by changes in global climate which make it a good location to study the feedback effects between climate, the water cycle and the carbon cycle. Using river dissolved elements and Sr isotopes we examine changes and/or differences in chemical weathering between watersheds in predominantly permafrost areas and glacial watersheds. Tributaries of the Tanana, Yukon, Nenana and Copper rivers were sampled during the early snow melt in late May and the late permafrost/glacial melt period in September of 2007. Waters are predominantly CaHCO 3 - /SO 4 which is typical of glaciated terrains. 87 Sr/ 86 Sr isotopes indicate three potential end-members, young basalts, radiogenic silicates and marine carbonates. The results are consistent with weathering observed in glaciated regions with trace calcites and salts dominating the dissolved load; however we have evidence for silicate weathering. Results also indicate that permafrost watersheds experience more progressive silicate weathering than glacial watersheds. ??2009 ASCE.

Conference Paper↗

USGS2007

Natural calcium isotonic composition of urine as a marker of bone mineral balance

Background: We investigated whether changes in the natural isotopic composition of calcium in human urine track changes in net bone mineral balance, as predicted by a model of calcium isotopic behavior in vertebrates. If so, isotopic analysis of natural urine or blood calcium could be used to monitor short-term changes in bone mineral balance that cannot be detected with other techniques. Methods: Calcium isotopic compositions are expressed as ??44Ca, or the difference in parts per thousand between the 44Ca/40Ca of a sample and the 44Ca/ 40Ca of a standard reference material. ??44Ca was measured in urine samples from 10 persons who participated in a study of the effectiveness of countermeasures to bone loss in spaceflight, in which 17 weeks of bed rest was used to induce bone loss. Study participants were assigned to 1 of 3 treatment groups: controls received no treatment, one treatment group received alendronate, and another group performed resistive exercise. Measurements were made on urine samples collected before, at 2 or 3 points during, and after bed rest. Results: Urine ??44Ca values during bed rest were lower in controls than in individuals treated with alendronate (P <0.05, ANOVA) or exercise (P <0.05), and lower than the control group baseline (P <0.05, Mest). Results were consistent with the model and with biochemical and bone mineral density data. Conclusion: Results confirm the predicted relationship between bone mineral balance and calcium isotopes, suggesting that calcium isotopic analysis of urine might be refined into a clinical and research tool. ?? 2007 American Association for Clinical Chemistry.

Clinical Chemistry↗

USGS2005

Use of tracers and isotopes to evaluate vulnerability of water in domestic wells to septic waste

In Nebraska, a large number (>200) of shallow sand‐point and cased wells completed in coarse alluvial sediments along rivers and lakes still are used to obtain drinking water for human consumption, even though construction of sand‐point wells for consumptive uses has been banned since 1987. The quality of water from shallow domestic wells potentially vulnerable to seepage from septic systems was evaluated by analyzing for the presence of tracers and multiple isotopes. Samples were collected from 26 sand‐point and perforated, cased domestic wells and were analyzed for bacteria, coliphages, nitrogen species, nitrogen and boron isotopes, dissolved organic carbon (DOC), prescription and nonprescription drugs, or organic waste water contaminants. At least 13 of the 26 domestic well samples showed some evidence of septic system effects based on the results of several tracers including DOC, coliphages, NH 4 + , NO 3 − , N 2 , δ 15 N[NO 3 − ] and boron isotopes, and antibiotics and other drugs. Sand‐point wells within 30 m of a septic system and <14 m deep in a shallow, thin aquifer had the most tracers detected and the highest values, indicating the greatest vulnerability to contamination from septic waste.

Ground Water Monitoring and Remediation↗

USGS1997

Geology and preliminary dating of the hominid-bearing sedimentary fill of the Sima de los Huesos Chamber, Cueva Mayor of the Sierra de Atapuerca, Burgos, Spain

Sediments of the Sima de los Huesos vary greatly over distances of a few meters. This is typical of interior cave facies, and caused by cycles of cut and fill. Mud breccias containing human bones, grading upwards to mud containing bear bones, fill an irregular surface cut into basal marls and sands. The lack of bedding and the chaotic abundance of fragile speleothem clasts in the fossiliferous muds suggests that the deposit was originally a subterranean pond facies, and that after emplacement of the human remains, underwent vigorous post-depositional rotation and collapse and brecciation, caused by underlying bedrock dissolution and undermining. The fossiliferous deposits are capped by flowstone and guano-bearing muds which lack large-mammal fossils. U-series and radiocarbon dating indicates the capping flowstones formed from about 68 ka to about 25 ka. U-series analyses of speleothem clasts among the human fossils indicate that all are at, or close to, isotopic equilibrium (>350 ka). The distribution of U-series dates for 25 bear bones (154±66 ka) and for 16 human bones (148±34 ka) is similar and rather broad. Because the human bones seem to be stratigraphically older than those of the bears, the results would indicate that most of the bones have been accumulating uranium irregularly with time. Electron spin resonance (ESR) analyses of six selected bear bones indicates dates of 189±28 ka, for which each is concordant with their corresponding U-series date (181±41 ka). Combined ESR and U-series dates for these samples yielded 200±4 ka. Such agreement is highly suggestive that uranium uptake in these bones was close to the early-uptake (EU) model, and the dates are essentially correct. Another three selected samples yielded combined ESR–U-series dates of 320±4 ka with a modeled intermediate-mode of uranium uptake. The dating results, therefore, seem to provide a firm minimum age of about 200 ka for the human entry; and suggestive evidence of entry before 320 ka.

Journal of Human Evolution↗

USGS1997

Chemical weathering of a soil chronosequence on granitoid alluvium: II. Mineralogic and isotopic constraints on the behavior of strontium

The use of strontium isotopes to evaluate mineral weathering and identify sources of base cations in catchment waters requires an understanding of the behavior of Sr in the soil environment as a function of time. Our approach is to model the temporal evolution of 87 Sr/ 86 Sr of the cation exchange pool in a soil chronosequence developed on alluvium derived from central Sierra Nevada granitoids during the past 3 Ma. With increasing soil age, 87 Sr/ 86 Sr of ammonium-acetate extractable Sr initially decreases from values typical of K-feldspar to those of plagioclase and hornblende and then remains constant, even though plagioclase and hornblende are absent from the soils after approximately 1 Ma of weathering. The temporal variation of 87 Sr/ 86 Sr of exchangeable Sr is modeled by progressively equilibrating Sr derived from mineral weathering and atmospheric deposition with Sr on exchange sites as waters infiltrate a soil column. Observed decreases in quartz-normalized modal abundances of plagioclase, hornblende, and K-feldspar with time, and the distinct 87 Sr/ 86 Sr values of these minerals can be used to calculate Sr flux from weathering reactions. Hydrobiotites in the soils have nearly constant modal abundances, chemistry, and 87 Sr/ 86 Sr over the chronosequence and provide negligible Sr input to weathering solutions. The model requires time and soil horizon-dependent changes in the amount of exchangeable Sr and the efficiency of Sr exchange, as well as a biologic cycling term. The model predicts that exchangeable Sr initially has 87 Sr/ 86 Sr identical to that of K-feldspar, and thus could be dominated by Sr leached from K-feldspar following deposition of the alluvium. The maximum value of 87 Sr/ 86 Sr observed in dilute stream waters associated with granitoids of the Yosemite region is likewise similar to that of the K-feldspars, suggesting that K-feldspar and not biotite may be the dominant source of radiogenic Sr in the streams. This study reveals that, when attempting to use Strontium isotopes to identify sources of base cations in catchment waters and biomass, both preferential leaching of Sr from minerals during incipient soil development and changing Sr exchange efficiency must be considered along with chemical contributions due to mineral dissolution.

Geochimica et Cosmochimica Acta↗