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Stewart A. Rounds

Publications and source records attributed to Stewart A. Rounds.

63 records · Page 4Linked to original sources

Chapter A6. Section 6.2. Dissolved oxygen

Accurate data for the concentration of dissolved oxygen in surface and ground waters are essential for documenting changes in environmental water resources that result from natural phenomena and human activities. Dissolved oxygen is necessary in aquatic systems for the survival and growth of many aquatic organisms and is used as an indicator of the health of surface-water bodies. This section of the National Field Manual (NFM) includes U.S. Geological Survey (USGS) guidance and protocols for four methods to determine dissolved-oxygen concentrations: the amperometric, luminescent-sensor, spectrophotometric, and iodometric (Winkler) methods. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations

Modeling hydrodynamics, temperature, and water quality in Henry Hagg Lake, Oregon, 2000-03

The two-dimensional model CE-QUAL-W2 was used to simulate hydrodynamics, temperature, and water quality in Henry Hagg Lake, Oregon, for the years 2000 through 2003. Input data included lake bathymetry, meteorologic conditions, tributary inflows, tributary temperature and water quality, and lake outflows. Calibrated constituents included lake hydrodynamics, water temperature, orthophosphate, total phosphorus, ammonia, algae, chlorophyll a, zooplankton, and dissolved oxygen. Other simulated constituents included nitrate, dissolved and particulate organic matter, dissolved solids, and suspended sediment. Two algal groups (blue-green algae, and all other algae) were included in the model to simulate the lake’s algal communities. Measured lake stage data were used to calibrate the lake's water balance; calibration of water temperature and water quality relied upon vertical profile data taken in the deepest part of the lake near the dam. The model initially was calibrated with data from 2000-01 and tested with data from 2002-03. Sensitivity tests were performed to examine the response of the model to specific parameters and coefficients, including the light-extinction coefficient, wind speed, tributary inflows of phosphorus, nitrogen and organic matter, sediment oxygen demand, algal growth rates, and zooplankton feeding preference factors.

Oregon

Water-quality data from 2002 to 2003 and analysis of data gaps for development of total maximum daily loads in the Lower Klamath River Basin, California

The U.S. Geological Survey (USGS) collected water-quality data during 2002 and 2003 in the Lower Klamath River Basin, in northern California, to support studies of river conditions as they pertain to the viability of Chinook and Coho salmon and endangered suckers. To address the data needs of the North Coast Regional Water Quality Control Board for the development of Total Maximum Daily Loads (TMDLs), water temperature, dissolved oxygen, specific conductance, and pH were continuously monitored at sites on the Klamath, Trinity, Shasta, and Lost Rivers. Water-quality samples were collected and analyzed for selected nutrients, organic carbon, chlorophyll-a, pheophytin-a, and trace elements. Sediment oxygen demand was measured on the Shasta River. Results of analysis of the data collected were used to identify locations in the Lower Klamath River Basin and periods of time during 2002 and 2003 when river conditions were more likely to be detrimental to salmonid or sucker health because of occasional high water temperatures, low dissolved oxygen, and conditions that supported abundant populations of algae and aquatic plants. The results were also used to assess gaps in data by furthering the development of the conceptual model of water flow and quality in the Lower Klamath River Basin using available data and the current understanding of processes that affect water quality and by assessing needs for the develoment of mathematical models of the system. The most notable gap in information for the study area is in sufficient knowledge about the occurrence and productivity of algal communities. Other gaps in data include vertical water-quality profiles for the reservoirs in the study area, and in an adequate understanding of the chemical oxygen demands and the sediment oxygen demands in the rivers and of the influence of riparian shading on the rivers. Several mathematical models are discussed in this report for use in characterizing the river systems in the study area; also discussed are the specific data needed for the models, and the spatial and temporal data available as boundary conditions. The models will be useful for the future development of TMDLs for temperature, nutrients, and dissolved oxygen and for assessing the role of natural and anthropogenic sources of heat, oxygen-producing and -consuming substances, and nutrients in the Klamath, Shasta, and Lost Rivers.

Scientific Investigations Report

Modeling water quality in the Tualatin River, Oregon, 1991-1997

The calibration of a model of flow, temperature, and water quality in the Tualatin River, Oregon, originally calibrated for the summers of 1991 through 1993, was extended to the summers of 1991 through 1997. The model is now calibrated for a total period of 42 months during the May through October periods of 7 hydrologically distinct years. Based on a modified version of the U.S. Army Corps of Engineers model CE-QUAL-W2, this model provides a good fit to the measured data for streamflow, water temperature, and water quality constituents such as chloride, ammonia, nitrate, total phosphorus, orthophosphate, phytoplankton, and dissolved oxygen. In particular, the model simulates ammonia concentrations and the effects of instream ammonia nitrification very well, which is critical to ongoing efforts to revise ammonia regulations for the Tualatin River. In addition, the model simulates the timing, duration, and relative size of algal blooms with sufficient accuracy to provide important insights for regulators and managers of this river.Efforts to limit the size of algal blooms through phosphorus control measures are apparent in the model simulations, which show this limitation on algal growth. Such measures are largely responsible for avoiding violations of the State of Oregon maximum pH standard of 8.5 in recent years, but they have not yet reduced algal biomass levels below the State of Oregon nuisance phytoplankton growth guideline of 15 ?g/L chlorophyll-a.Most of the dynamics of the instream dissolved oxygen concentrations are captured by the model. About half of the error in the simulated dissolved oxygen concentrations is directly attributable to error in the size of the simulated phytoplankton population. To achieve greater accuracy in simulating dissolved oxygen, therefore, it will be necessary to increase accuracy in the simulation of Tualatin River phytoplankton.Future efforts may include the introduction of multiple algal groups in the model. This model of the Tualatin River continues to be used as a quantitative tool to aid in the management of this important resource.

Oregon

Sources and transport of phosphorus and nitrogen during low-flow conditions in the Tualatin River, Oregon, 1991-93

In the 1980s significant nutrient-related water-quality problems that impacted beneficial uses were identified in the Tualatin River during the low-flow summer months, defined as .May 1 to October 31. Unsightly algal blooms resulted in fluctuations in oxygen concentrations and pH conditions; reduction of phosphorus concentrations was determined to the effective control mechanism for these conditions. Elevated ammonia concentrations also contributed to low oxygen concentrations. Because standards for beneficial uses were not being met, the Oregon Department of Environmental Quality established Total Maximum Daily Loads (TMDLs) for phosphorus and ammonia in the Tualatin Basin, as required by the Clean Water Act. To provide necessary context for the TMDL process, data were collected during the period 1991-93 to characterize the sources and transport of water, phosphorus, and major forms of nitrogen in the main-stem Tualatin River during the summer. A significant source of water to the river was not accounted for by surface-water inputs, and was consistent with direct discharge of ground water to the main-stem river channel. Ground water is also the primary source of water for the tributaries during the summer low-flow season. Because large natural supplies of highly mobile phosphorus exist in the upper 500 feet of valley-fill sediments throughout the Tualatin Basin, ground water in the basin is naturally enriched with phosphorus. While improvement in wastewater treatment efficiencies and land management practices have resulted in significant reductions in nutrient concentrations in the Tualatin River, phosphorus concentrations continue to exceed TMDL criterion concentrations. The presence of significant geologic sources of phosphorus in the basin will confound the achievement of current TMDL criteria for phosphorus in the Tualatin River and its tributaries. In contrast, natural sources of all forms of nitrogen to the Tualatin River are insignificant relative to the effluent from the wastewater treatment plants in the basin. Efficient wastewater treatment is, therefore, an effective means for controlling ammonia concentrations in the main-stem river.

Oregon

Modeling discharge, temperature, and water quality in the Tualatin River, Oregon

The discharge, water temperature, and water quality of the Tualatin River in northwestern Oregon was simulated with CE-QUAL-W2, a two-dimensional, laterally averaged model developed by the U.S. Army Corps of Engineers. The model was calibrated for May through October periods of 1991, 1992, and 1993. Nine hypothetical scenarios were tested with the model to provide insight for river managers and regulators.

Water Supply Paper

Occurrence of selected trace elements and organic compounds and their relation to land use in the Willamette River basin, Oregon, 1992-94

Between 1992 and 1994, the U.S.Geological Survey conducted a study of trace elements and organic compounds in the Willamette River Basin, Oregon, as part of the Willamette River Basin Water Quality Study. Low-level analyses were performed for trace elements, volatile organic compounds, organochlorine compounds, and pesticides. Overall, 94 water samples were collected from 40 sites, during predominantly high-flow conditions, representing urban, agricultural, mixed, and forested land uses. Although most observed concentrations were relatively low, some exceedances of water-quality criteria for acute and chronic toxicity and for the protection of human health were observed. Concentrations of chromium, copper, lead, and zinc in unfiltered water were well correlated with concentrations of suspended sediment. The highest trace-element concentrations generally were found at urban sites that receive a large portion of their runoff from industrial areas, particularly at high suspended- sediment concentrations. In contrast, concentrations of trace elements in some urban streams draining primarily residential areas appeared to approach a maximum as sediment concentrations increased. Whether this difference was due to a difference in the nature of the suspended sediments or to different concentrations in the aqueous phases from the two site types was not addressed. Eight organochlorine compounds were detected at 14 sites. Lindane, dieldrin, and DDT or its metabolites were each detected in about 30 percent of the samples, predominantly in samples collected from agricultural and urban areas. Polychlorinated biphenyl (PCB) compounds were detected in samples from two urban sites. For samples in which DDT and its metabolites were examined for partitioning, the largest proportion of the mass of DDT and its metabolites was associated with suspended sediment. In contrast, dieldrin and lindane were almost completely (greater than 99 percent) associated with the dissolved phase. Sixty-one of the 94 pesticides analyzed in filtered water were documented to have been used in the basin in 1987; 43 of these were detected at least once during 1992–94. An additional five were detected that were not documented in the 1987 estimates. Although a comparison between the frequency of detected pesticides and 1987 estimates of pesticide usage in the basin showed generally little correlation, some patterns of detections did appear to reflect land use in the basin. Of the 25 most frequently detected pesticides, 3 were found primarily at urban sites, 6 were found primarily at agricultural sites, and 7 were found at all types of sites except forested. The four most commonly detected pesticides in the basin, observed at all except forested site 2 types, were atrazine, metolachlor, simazine, and diuron. A greater variety of compounds was detected at sites in the northern portion of the basin than in the southern portion of the basin probably because the northern portion has more diverse agricultural practices and a larger urban component. Possible reasons for the lack of agreement between pesticide detections and pesticide usage estimates include (1) uncertainty in the usage estimates due to spatial and temporal variability or due to changes in agricultural practices since the 1987 estimates were compiled, (2) chemical or biological transformations in the compounds after application, (3) variable hydrologic conditions among sites at the time of sampling, or (4) the ability of laboratory analytical procedures to detect low concentrations of some analytes. Results from repeated samplings at two sites during sequential storms in the fall of 1994 indicated that concentrations and loads of several constituents, including suspended sediment, suspended organic carbon, DDT, metolachlor, and atrazine were highest during peak flows of the first or second significant storms of the fall. Samplings during subsequent storms indicated that instantaneous concentrations and loads were generally reduced; however, data were not sufficient to compare overall transport during sequential storms.

Oregon