Geology topics

Steven Constable

Publications and source records attributed to Steven Constable.

6 recordsLinked to original sources

USGS2024

Mapping the resistivity structure of Walker Ridge 313 in the Gulf of Mexico using the marine CSEM method

A marine controlled source electromagnetic (CSEM) campaign was carried out in the Gulf of Mexico to further develop marine electromagnetic techniques in order to aid the detection and mapping of gas hydrate deposits. Marine CSEM methods are used to obtain an electrical resistivity structure of the subsurface which can indicate the type of substance filling the pore space, such as gas hydrates which are more resistive. Results from the Walker Ridge 313 study (WR 313) are presented in this paper and compared with the Gulf of Mexico Gas Hydrate Joint Industry Project II (JIP2) logging while drilling (LWD) results and available seismic data. The hydrate, known to exist within sheeted sand deposits, is mapped as a resistive region in the two dimensional (2D) CSEM inversion models. This is consistent with the JIP2 LWD resistivity results. CSEM inversions that use seismic horizons provide more realistic results compared to the unconstrained inversions by providing sharp boundaries and architectural control on the location of the resistive and conductive regions in the CSEM model. The seismic horizons include: 1) the base of the gas hydrate stability zone (BGHSZ), 2) the top of salt, and 3) the top and bottom of a fine grained marine mud interval with near vertical hydrate filled fractures, to constrain the CSEM inversion model. The top of salt provides improved location for brines, water saturated salt, and resistive salt. Inversions of the CSEM data map the occurrence of a ‘halo’ of conductive brines above salt. The use of the BGHSZ as a constraint on the inversion helps distinguish between free gas and gas hydrate as well as gas hydrate and water saturated sediments.

Louisiana↗

USGS2022

Monitoring offshore CO2 sequestration using marine CSEM methods; constraints inferred from field- and laboratory-based gas hydrate studies

Offshore geological sequestration of CO 2 offers a viable approach for reducing greenhouse gas emissions into the atmosphere. Strategies include injection of CO 2 into the deep-ocean or ocean-floor sediments, whereby depending on pressure–temperature conditions, CO 2 can be trapped physically, gravitationally, or converted to CO 2 hydrate. Energy-driven research continues to also advance CO 2 -for-CH 4 replacement strategies in the gas hydrate stability zone (GHSZ), producing methane for natural gas needs while sequestering CO 2 . In all cases, safe storage of CO 2 requires reliable monitoring of the targeted CO 2 injection sites and the integrity of the repository over time, including possible leakage. Electromagnetic technologies used for oil and gas exploration, sensitive to electrical conductivity, have long been considered an optimal monitoring method, as CO 2 , similar to hydrocarbons, typically exhibits lower conductivity than the surrounding medium. We apply 3D controlled-source electromagnetic (CSEM) forward modeling code to simulate an evolving CO 2 reservoir in deep-ocean sediments, demonstrating sufficient sensitivity and resolution of CSEM data to detect reservoir changes even before sophisticated inversion of data. Laboratory measurements place further constraints on evaluating certain systems within the GHSZ; notably, CO 2 hydrate is measurably weaker than methane hydrate, and >1 order of magnitude more conductive, properties that may affect site selection, stability, and modeling considerations.

Energies↗

USGS2022

Identification of fresh submarine groundwater off the coast of San Diego, USA, using electromagnetic methods

Climate change has a pronounced effect on water resources in many semiarid climates, causing populated areas such as San Diego County (USA), to become more vulnerable to water shortages in the coming decades. To prepare for decreased water supply, San Diego County is adopting policies to decrease water use and to develop additional local sources of water. One new local source of freshwater is produced by a desalination facility that purifies brackish groundwater from the coastal San Diego Formation. This formation has been studied extensively onshore, but little is known about the geology or groundwater quality offshore in the adjacent continental shelf. Because most groundwater systems are interconnected and complex, further analysis is needed to identify offshore geology, possible sequestration of freshwater in the shelf, and potential pathways for saltwater intrusion. This comprehensive understanding is important because seawater intrusion may limit use of the San Diego Formation and longevity of desalination facilities. Controlled-source electromagnetic methods are uniquely suited to detecting offshore groundwater as they are sensitive to changes in pore fluids such as the transition from fresh to brackish groundwater. This paper describes results from surface-towed electromagnetic surveys that mapped the pore-fluid salinity and possible fluid pathways in the continental shelf off the coast of San Diego. The results indicate a considerable volume of fresh-to-brackish groundwater sequestered in the shelf, both in continuous lenses and isolated pockets, that appear influenced by fault systems and shallow stratigraphy.

Baja California, California↗

USGS2020

Laboratory electrical conductivity of marine gas hydrate

Methane hydrate was synthesized from pure water ice and flash frozen seawater, with varying amounts of sand or silt added. Electrical conductivity was determined by impedance spectroscopy, using equivalent circuit modeling to separate the effects of electrodes and to gain insight into conduction mechanisms. Silt and sand increase the conductivity of pure hydrate, we infer by contaminant NaCl contributing to conduction in hydrate, to values in agreement with resistivities observed in well logs through hydrate The addition of silt and sand lowers the conductivity of hydrate synthesized from seawater by an amount consistent with Archie's Law. All samples were characterized using cryogenic scanning electron microscopy and energy dispersive spectroscopy, which show good connectivity of salt and brine phases. Electrical conductivity measurements of pure hydrate and hydrate mixed with silt during pressure‐induced dissociation supports previous conclusions that sediment increases dissociation rate.

Geophysical Research Letters↗

USGS2015

Electrical properties of methane hydrate + sediment mixtures

Knowledge of the electrical properties of multicomponent systems with gas hydrate, sediments, and pore water is needed to help relate electromagnetic (EM) measurements to specific gas hydrate concentration and distribution patterns in nature. Toward this goal, we built a pressure cell capable of measuring in situ electrical properties of multicomponent systems such that the effects of individual components and mixing relations can be assessed. We first established the temperature-dependent electrical conductivity ( σ ) of pure, single-phase methane hydrate to be ~5 orders of magnitude lower than seawater, a substantial contrast that can help differentiate hydrate deposits from significantly more conductive water-saturated sediments in EM field surveys. Here we report σ measurements of two-component systems in which methane hydrate is mixed with variable amounts of quartz sand or glass beads. Sand by itself has low σ but is found to increase the overall σ of mixtures with well-connected methane hydrate. Alternatively, the overall σ decreases when sand concentrations are high enough to cause gas hydrate to be poorly connected, indicating that hydrate grains provide the primary conduction path. Our measurements suggest that impurities from sand induce chemical interactions and/or doping effects that result in higher electrical conductivity with lower temperature dependence. These results can be used in the modeling of massive or two-phase gas-hydrate-bearing systems devoid of conductive pore water. Further experiments that include a free water phase are the necessary next steps toward developing complex models relevant to most natural systems.

Journal of Geophysical Research↗

USGS2011

Electrical properties of methane hydrate + sediment mixtures

As part of our DOE-funded proposal to characterize gas hydrate in the Gulf of Mexico using marine electromagnetic methods, a collaboration between SIO, LLNL, and USGS with the goal of measuring the electrical properties of lab-created methane (CH 4 ) hydrate and sediment mixtures was formed. We examined samples with known characteristics to better relate electrical properties measured in the field to specific gas hydrate concentration and distribution patterns. Here we discuss first-ever electrical conductivity (σ) measurements on unmixed CH 4 hydrate (Du Frane et al., 2011): 6 x 10-5 S/m at 5 °C, which is ~5 orders of magnitude lower than seawater. This difference allows electromagnetic (EM) techniques to distinguish highly resistive gas hydrate deposits from conductive water saturated sediments in EM field surveys. More recently, we performed measurements on CH 4 hydrate mixed with sediment and we also discuss those initial findings here. Our results on samples free of liquid water are important for predicting conductivity of sediments with pores highly saturated with gas hydrate, and are an essential starting point for comprehensive mixing models.

Fire in the Ice: NETL Methane Hydrate Newsletter↗