Geology topics

Stephen C. Peters

Publications and source records attributed to Stephen C. Peters.

3 recordsLinked to original sources

USGS2021

River terrace evidence of tectonic processes in the eastern North American plate interior, South Anna River, Virginia

We show that long-recognized seismicity in the central Virginia seismic zone of the eastern North American intraplate setting arises primarily from tectonic processes predicted by new, fully coupled plate tectonic geodynamic models. The study leverages much new geophysical and geologic data following the 2011 Mineral, Virginia, earthquake that ruptured a steeply dipping, northwest-verging reverse fault traversed by the South Anna River. The data are primarily assembled from a flight of six fluvial terrace geomorphic markers identified and correlated on texture, relative weathering, and numeric ages including one terrestrial cosmogenic nuclide (TCN) profile and 30 luminescence dates. Terrace thickness, stratigraphic age models, and incision rates downstream and upstream of the 2011 rupture are different. Long-term river incision rates of ∼25–30 m/My are superimposed on regional TCN-determined erosion rates of ∼8.5 m/My; however, there are at least 10 m of tectonically driven incision in the epicentral region at rates of ∼30–94 m/My. The inferred deformation resembles a hanging wall anticline above a blind reverse fault with a diffuse overlying carapace of minor brittle faults, an interpretation supported by seismology as well as bedrock and saprolite mapped across the epicentral region. These results are further supported by channel metrics that show nonuniform channel steepness ( k sn ) and a predicted steady-state channel elevation different from the actual channel elevation across the epicentral region. If all of the observed deformation is a consequence of the fault that ruptured in 2011, the recurrence interval of Mineral-sized events would be ∼5.5 ky.

Virginia↗

USGS2017

Enhanced Al and Zn removal from coal-mine drainage during rapid oxidation and precipitation of Fe oxides at near-neutral pH

Net-alkaline, anoxic coal-mine drainage containing ∼20 mg/L Fe II and ∼0.05 mg/L Al and Zn was subjected to parallel batch experiments: control, aeration (Aer 1 12.6 mL/s; Aer 2 16.8 mL/s; Aer 3 25.0 mL/s), and hydrogen peroxide (H 2 O 2 ) to test the hypothesis that aeration increases pH, Fe II oxidation, hydrous Fe III oxide (HFO) formation, and trace-metal removal through adsorption and coprecipitation with HFO. During 5.5-hr field experiments, pH increased from 6.4 to 6.7, 7.1, 7.6, and 8.1 for the control, Aer 1, Aer 2, and Aer 3, respectively, but decreased to 6.3 for the H 2 O 2 treatment. Aeration accelerated removal of dissolved CO 2 , Fe, Al, and Zn. In Aer 3, dissolved Al was completely removed within 1 h, but increased to ∼20% of the initial concentration after 2.5 h when pH exceeded 7.5. H 2 O 2 promoted rapid removal of all dissolved Fe and Al, and 13% of dissolved Zn. Kinetic modeling with PHREEQC simulated effects of aeration on pH, CO 2 , Fe, Zn, and Al. Aeration enhanced Zn adsorption by increasing pH and HFO formation while decreasing aqueous CO 2 available to form ZnCO 3 0 and Zn(CO 3 ) 2 2− at high pH. Al concentrations were inconsistent with solubility control by Al minerals or Al-containing HFO, but could be simulated by adsorption on HFO at pH < 7.5 and desorption at higher pH where Al(OH) 4 − was predominant. Thus, aeration or chemical oxidation with pH adjustment to ∼7.5 could be effective for treating high-Fe and moderate-Zn concentrations, whereas chemical oxidation without pH adjustment may be effective for treating high-Fe and moderate-Al concentrations.

Pennsylvania↗

USGS2015

Temporal geochemical variations in above- and below-drainage coal mine discharge

Water quality data collected in 2012 for 10 above- and 14 below-drainage coal mine discharges (CMDs), classified by mining or excavation method, in the anthracite region of Pennsylvania, USA, are compared with data for 1975, 1991, and 1999 to evaluate long-term (37 year) changes in pH, SO 4 2− , and Fe concentrations related to geochemistry, hydrology, and natural attenuation processes. We hypothesized that CMD quality will improve over time because of diminishing quantities of unweathered pyrite, decreased access of O 2 to the subsurface after mine closure, decreased rates of acid production, and relatively constant influx of alkalinity from groundwater. Discharges from shafts, slopes, and boreholes, which are vertical or steeply sloping excavations, are classified as below-drainage; these receive groundwater inputs with low dissolved O 2 , resulting in limited pyrite oxidation, dilution, and gradual improvement of CMD water quality. In contrast, discharges from drifts and tunnels, which are nearly horizontal excavations into hillsides, are classified as above-drainage; these would exhibit less improvement in water quality over time because the rock surfaces continue to be exposed to air, which facilitates sustained pyrite oxidation, acid production, and alkalinity consumption. Nonparametric Wilcoxon matched-pair signed rank tests between 1975 and 2012 samples indicate decreases in Fe and SO 4 2− concentrations were highly significant ( p < 0.05) and increases in pH were marginally significant ( p < 0.1) for below-drainage discharges. For above-drainage discharges, changes in Fe and SO 4 2− concentrations were not significant, and increases in pH were highly significant between 1975 and 2012. Although a greater proportion of above-drainage discharges were net acidic in 2012 compared to below-drainage discharges, the increase in pH between 1975 and 2012 was greater for above- (median pH increase from 4.4 to 6.0) compared to below- (median pH increase from 5.6 to 6.1) drainage discharges. For cases where O 2 is limited, transformation of aqueous Fe II species to Fe III may be kinetically limited. In contrast, where O 2 is abundant, aqueous Fe concentrations may be limited by Fe III mineral precipitation; thus, trends in Fe may not follow those for SO 4 2− . In either case, when the supply of alkalinity is sufficient to buffer decreased acidity, the pH could increase by a step trend from strongly acidic (3–3.5) to near neutral (6–6.5) values. Modeled equilibrium with respect to Fe III precipitates varies with pH and Fe and SO 4 2− reconcentrations: increasing pH promotes the formation of ferrihydrite, while decreasing concentrations of Fe limit the formation of ferrihydrite, and decreasing Fe and SO 4 2− concentrations limit the precipitation of schwertmannite and favor formation of Fe III hydroxyl complexes and uncomplexed Fe 2+ and Fe 3+ . The analysis of the long-term geochemical changes in CMDs in the anthracite field and the effect of the hydrologic setting on water quality presented in this paper can help prioritize CMD remediation and facilitate selection and design of the most appropriate treatment systems.

Pennsylvania↗