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Stephen A. Norton

Publications and source records attributed to Stephen A. Norton.

5 recordsLinked to original sources

A record of phosphorus dynamics in oligotrophic lake sediment

Historical phosphorus (P) dynamics were studied using sediment cores from three oligotrophic, acidic lakes in Maine, USA. Long-term oligotrophy of these lakes is consistent with high sediment aluminum (as Al(OH) 3 ) concentrations, as Al inhibits internal P loading, even under reducing conditions. The role of microbially-mediated reactions in controlling redox conditions was evaluated by estimating microbial biomass and relative abundance of specific functional groups. Sediments were fractionated using a sequential chemical extraction technique and all lakes met criteria for P retention based on threshold sediment concentrations of Al, Fe, and P fractions as determined by (Kopáček et al. ( 2005 ) Limnol Oceanogr 52: 1147–1155). Sediment NaOH-extractable molybdate-reactive P (rP) and non-reactive P (nrP) represent P associated with non-reducible phases, and organic matter-related P, respectively. Total P (TP) does not decrease with sediment depth, as is typical of eutrophic lake sediments; however, nrP/TP decreases and rP/TP increases for all three lakes, indicating nrP mineralization without any significant upward diffusion and release into the hypolimnion; i.e. diagenesis of P is conservative within the sediment. Two diagenetic models were developed based on nrP and rP concentrations as a function of sediment age. The first model assumes a first-order decay of nrP, the rate coefficient being a function of time, and represents irreversible nrP mineralization, where the produced PO 4 is permanently sequestered by the sediment. The second model assumes a first-order reversible transformation between nrP and rP, representing biotic mineralization of organic P followed by incorporation of inorganic P into microbial biomass. Both models reflect preservation of TP with no loss to overlying water. The rate coefficients give us insight into qualities of the sediment that have affected mineralization and sequestration of phosphorus throughout the 210 Pb-dateable history of each lake. Similar models could be constructed for other lakes to help reconstruct their trophic histories. Paleolimnological reconstruction of the sediment P record in oligotrophic lakes shows mineralization of nrP to rP, but unlike the case in eutrophic lake sediments, sediment TP is preserved in these sediments.

Maine

Distribution patterns of mercury in Lakes and Rivers of northeastern North America

We assembled 831 data points for total mercury (Hg t ) and 277 overlapping points for methyl mercury (CH 3 Hg + ) in surface waters from Massachussetts, USA to the Island of Newfoundland, Canada from State, Provincial, and Federal government databases. These geographically indexed values were used to determine: (a) if large-scale spatial distribution patterns existed and (b) whether there were significant relationships between the two main forms of aquatic Hg as well as with total organic carbon (TOC), a well know complexer of metals. We analyzed the catchments where samples were collected using a Geographical Information System (GIS) approach, calculating catchment sizes, mean slope, and mean wetness index. Our results show two main spatial distribution patterns. We detected loci of high Hg t values near urbanized regions of Boston MA and Portland ME. However, except for one unexplained exception, the highest Hg t and CH 3 Hg + concentrations were located in regions far from obvious point sources. These correlated to topographically flat (and thus wet) areas that we relate to wetland abundances. We show that aquatic Hg t and CH 3 Hg + concentrations are generally well correlated with TOC and with each other. Over the region, CH 3 Hg + concentrations are typically approximately 15% of Hg t . There is an exception in the Boston region where CH 3 Hg + is low compared to the high Hg t values. This is probably due to the proximity of point sources of inorganic Hg and a lack of wetlands. We also attempted to predict Hg concentrations in water with statistical models using catchment features as variables. We were only able to produce statistically significant predictive models in some parts of regions due to the lack of suitable digital information, and because data ranges in some regions were too narrow for meaningful regression analyses.

Maine, Massachusetts, New Brunswick, New Hampshire

Geology of the Windsor quadrangle, Massachusetts

The Windsor quadrangle lies on the boundary between the eugeosynclinal and miogeosynclinal rocks of the Appalachian geosyncline on the western flank of the metamorphic high in western New England. Precambrian rocks crop out in a north-trending belt in the central part of the quadrangle. They have been classified into 2 formations. The Stamford Granite Gneiss crops out in the eastern half of the Precambrian terrane. It is a microcline-quartz-biotite augen gneiss. Stratified Precambrian rocks (the Hinsdale Gneiss) crop out entirely the west of the Stamford Granite Gneiss. They are predominantly highly metamorphosed felsic gneisses and .quartzites with minor calc-silicate rock, amphibolite, and graphitic gneiss. Eugeosynclinal rocks (the Hoosac Formation and the Rowe Schist), .ranging in age from Lower Cambrian to Lower Ordovician, crop out in a north-trending belt east of the Precambrian terrane. They are composed predominantly of albite schist and muscovite-chlorite schist with minor garnet schist, quartz-muscovite-calcite schist, felsic granulite and gneiss, quartzite, greenschist, and carbonaceous phyllite and schist. West of the Precambrian rocks, the Hoosac Formation is overlain by a miogeosynclinal sequence (the Dalton Formation, Cheshire Quartzite, Kitchen Brook Dolomite, Clarendon Springs Dolomite, Shelburne Marble, and the Bascom Formation) ranging in age from Lower Cambrian to Lower Ordovician. These rocks are unconformably overlain by the Berkshire Schist of Middle Ordovician age that is composed of carbonaceous schist, phyllite, and quartzite. The relationships in the zone of transition between the miogeosynclinal and eugeosynclinal rocks are unknown because the rocks of this zone are no longer present. The contact between the eugeosynclinal Hoosac Formation and the Dalton Format ion is conformable and deposition. The dominant structure is a large recumbent, northwest-facing anticline (the Hoosac nappe) with a Precambrian co re. The miogeosynclinal rocks are inverted in the northwestern part of the quadrangle and upright in the southwestern part of the quadrangle. A later generation of open, post-metamorphic folds has folded the recumbent folds in the miogeosynclinal rocks. The eugeosynclinal rocks show 3 phases of folding. The earliest folds are isoclinal, have steep plunges, were synmetamorphic, and have a strong axial plane schistosity. Two post-metamorphic generations of folds are more open and have axial plane cleavage. The development of the Hoosac nappe and the isoclinal folds was accompanied by regional metamorphism of the garnet zone. The pressure exceeded the pressure for the triple point of the Al2SiO 5 polymorphs. The composition of the paragonite coexisting with muscovite suggests a period of retrograde metamorphism for the Paleozoic rocks as well as the Cambrian rocks that were originally of higher grade (sillimanite? ). Later events include high-angle faulting (Triassic?), erosion, and Pleistocene glaciation.

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