Stephe H. Kirby | Search USGS

USGS2018

Strategic and critical metals in produced geothermal fluids from Nevada and Utah

Herein we summarize the results of an investigation dealing with the concentrations and inventories of strategic, critical and valuable materials (SCVM) in produced fluids from geothermal and hydrocarbon reservoirs (50-250° C) in Nevada and Utah. Water samples were collected from thirty-four production wells across eight geothermal fields, the Uinta Basin oil/gas province in northeast Utah, and the Covenant oil field in southwestern Utah; additional water samples were collected from six hot springs in the Sevier Thermal Belt in southwestern Utah. Most SCVM concentrations in produced waters range from <0.1 to 100 µg/kg; the main exception is lithium, which has concentrations that range from <1000 to 25,000 ug/kg. Relatively high concentrations of gallium, germanium, scandium, selenium, and tellurium are measured too. Geothermal waters contain very low concentrations of REEs, below analytical detections limits (0.01 µg/kg), but the concentrations of lanthanum, cerium, and europium range from 0.05 to 5 µg/kg in Uinta basin waters. Among the geothermal fields, the Roosevelt Hot Spring reservoir appears to have the largest inventories of germanium and lithium, and Patua appears to have the largest inventories of gallium, scandium, selenium, and tellurium. By comparison, the Uinta basin has larger inventories of gallium. The concentrations of gallium, germanium, lithium, scandium, selenium, and tellurium in produced waters appear to be partly related to reservoir temperature and concentrations of total dissolved salts. The relatively high concentration and large inventory of lithium occurring at Roosevelt Hot Springs may be related to granitic-gneissic crystalline rocks, which host the reservoir. Analyses of calcite scales from Dixie Valley indicate enrichments in cobalt, gallium, gold, palladium, selenium and tellurium, and these metals appear to be depositing at deep levels in production wells due to boiling. Comparisons with SCVM mineral deposits suggest that brines in sedimentary basins, or derived from lacustrine evaporites, enable aqueous transport of gallium, germanium, and lithium.

Conference Paper↗

USGS2015

Great (≥Mw8.0) megathrust earthquakes and the subduction of excess sediment and bathymetrically smooth seafloor

Using older and in part flawed data, Ruff (1989) suggested that thick sediment entering the subduction zone (SZ) smooths and strengthens the trench-parallel distribution of interplate coupling. This circumstance was conjectured to favor rupture continuation and the generation of high-magnitude (≥Mw8.0) interplate thrust (IPT) earthquakes. Using larger and more accurate compilations of sediment thickness and instrumental (1899 to January 2013) and pre-instrumental era (1700–1898) IPTs (n = 176 and 12, respectively), we tested if a compelling relation existed between where IPT earthquakes ≥Mw7.5 occurred and where thick (≥1.0 km) versus thin (≤1.0 km) sedimentary sections entered the SZ. Based on the new compilations, a statistically supported statement (see Summary and Conclusions) can be made that high-magnitude earthquakes are most prone to nucleate at well-sedimented SZs. For example, despite the 7500 km shorter global length of thick-sediment trenches, they account for &sim;53% of instrumental era IPTs ≥Mw8.0, &sim;75% ≥Mw8.5, and 100% ≥Mw9.1. No megathrusts >Mw9.0 ruptured at thin-sediment trenches, whereas three occurred at thick-sediment trenches (1960 Chile Mw9.5, 1964 Alaska Mw9.2, and 2004 Sumatra Mw9.2). However, large Mw8.0–9.0 IPTs commonly (n = 23) nucleated at thin-sediment trenches. These earthquakes are associated with the subduction of low-relief ocean floor and where the debris of subduction erosion thickens the plate-separating subduction channel. The combination of low bathymetric relief and subduction erosion is inferred to also produce a smooth trench-parallel distribution of coupling posited to favor the characteristic lengthy rupturing of high-magnitude IPT earthquakes. In these areas subduction of a weak sedimentary sequence further enables rupture continuation.

Geosphere↗