Geology topics

Sheila F. Murphy

Publications and source records attributed to Sheila F. Murphy.

At least 37 records · Page 2Linked to original sources

USGS2022

Elevated nitrogen deposition to fire-prone forests adjacent to urban and agricultural areas, Colorado front range, USA

As humans increasingly dominate the nitrogen cycle, deposition of reactive nitrogen (Nr) will continue to have adverse consequences for ecosystems. In the Rocky Mountains, Nr deposition remains elevated and has become increasingly dominated by ammonium, despite efforts to reduce emissions. Currently, spatial models of Nr deposition do not fully account for urban and agricultural emissions, sources that contribute to the observed high rates of ammonium deposition in adjacent ecosystems. To address this gap in the Colorado Front Range, we measured Nr deposition along a transect from urban and agricultural plains to subalpine forests. We found elevated values of wet Nr deposition at the urban and foothill sites (4.7 and 4.4 kg N ha −1 yr −1 , respectively), and lower values at the montane and subalpine sites (2.5–2.8 kg N ha −1 yr −1 ). Ammonium dominated wet and bulk Nr deposition, accounting for approximately 69% of bulk Nr deposition. Seasonally, bulk Nr deposition was highest in the spring months, when air masses from the plains are transported west into the mountains. Previous work has demonstrated that high elevations of the Colorado Front Range are especially sensitive to Nr deposition due to thin soil and minimal vegetation. Our results indicate that despite lower precipitation, the fire-prone forested foothills receive even greater Nr deposition than higher elevations, due to proximity to urban and agricultural Nr sources. The interaction between elevated Nr deposition and wildfire in this region may pose a risk to water supplies and ecosystems, and is an important topic for future research.

Colorado↗

USGS2022

Extreme rainstorms drive exceptional organic carbon export from forested humid-tropical rivers in Puerto Rico

Extreme rainfall events in the humid-tropical Luquillo Mountains, Puerto Rico export the bulk of suspended sediment and particulate organic carbon. Using 25 years of river carbon and suspended sediment data, which targeted hurricanes and other large rainstorms, we estimated biogenic particulate organic carbon yields of 65 ± 16 tC km −2 yr −1 for the Icacos and 17.7 ± 5.1 tC km −2 yr −1 for the Mameyes rivers. These granitic and volcaniclastic catchments function as substantial atmospheric carbon-dioxide sinks, largely through export of river biogenic particulate organic carbon during extreme rainstorms. Compared to other regions, these high biogenic particulate organic carbon yields are accompanied by lower suspended sediment yields. Accordingly, particulate organic carbon export from these catchments is underpredicted by previous yield relationships, which are derived mainly from catchments with easily erodible sedimentary rocks. Therefore, rivers that drain petrogenic-carbon-poor bedrock require separate accounting to estimate their contributions to the geological carbon cycle.

Puerto Rico↗

USGS2021

Aquatic-terrestrial linkages control metabolism and carbon dynamics in a mid-sized, urban stream influenced by snowmelt

Freshwater streams can exchange nutrients and carbon with the surrounding terrestrial environment through various mechanisms including physical erosion, flooding, leaf drop, and snowmelt. These aquatic-terrestrial interactions are crucial in carbon mobilization, transformation, ecosystem productivity, and have important implications for the role of freshwater ecosystems in the global carbon budget. We utilized high-frequency oxygen, temperature, and carbon dioxide (CO 2 ) data to infer watershed connectivity in Boulder Creek, a mid-sized (1160 km 2 ) watershed located in Colorado, USA. Daily modeled gross primary production (GPP), ecosystem respiration (ER), net ecosystem production (NEP), and reaeration coefficients ( K 600 ) were paired with high-frequency, in-situ dissolved CO 2 data to characterize changes in metabolic regime and carbon flux on a stream influenced by seasonal snowmelt. GPP and ER were correlated ( ρ = −0.72, p ≪ 0.001) during the non-snowmelt period and NEP was frequently negative. Mean F CO2 during the non-snowmelt period was approximately 302 (±171) mmol C m −2 d −1 and was primarily supported by watershed CO 2 inputs. During snowmelt, GPP and ER were not significantly correlated ( ρ = −0.22, p = 0.05), and mean NEP was significantly more negative than during non-snowmelt. Watershed connectivity was higher during snowmelt, as evidenced by significantly higher F CO2 (843 ± 338 mmol C m −2 d −1 ) and greater allochthonous CO 2 inputs than during non-snowmelt periods, emphasizing the effects of seasonal differences in aquatic-terrestrial linkages in this stream. We suggest that our understanding of watershed carbon budgets is subject to temporal dynamics which control the degree of connectivity between terrestrial and aquatic ecosystems.

Colorado↗

USGS2021

Signatures of hydrologic function across the critical zone observatory network

Despite a multitude of small catchment studies, we lack a deep understanding of how variations in critical zone architecture lead to variations in hydrologic states and fluxes. This study characterizes hydrologic dynamics of 15 catchments of the U.S. Critical Zone Observatory (CZO) network where we hypothesized that our understanding of subsurface structure would illuminate patterns of hydrologic partitioning. The CZOs collect data sets that characterize the physical, chemical, and biological architecture of the subsurface, while also monitoring hydrologic fluxes such as streamflow, precipitation, and evapotranspiration. For the first time, we collate time series of hydrologic variables across the CZO network and begin the process of examining hydrologic signatures across sites. We find that catchments with low baseflow indices and high runoff sensitivity to storage receive most of their precipitation as rain and contain clay‐rich regolith profiles, prominent argillic horizons, and/or anthropogenic modifications. In contrast, sites with high baseflow indices and low runoff sensitivity to storage receive the majority of precipitation as snow and have more permeable regolith profiles. The seasonal variability of water balance components is a key control on the dynamic range of hydraulically connected water in the critical zone. These findings lead us to posit that water balance partitioning and streamflow hydraulics are linked through the coevolution of critical zone architecture but that much work remains to parse these controls out quantitatively.

Water Resources Research↗

USGS2021

U.S. Geological Survey wildland fire science strategic plan, 2021–26

The U.S. Geological Survey (USGS) Wildland Fire Science Strategic Plan defines critical, core fire science capabilities for understanding fire-related and fire-responsive earth system processes and patterns, and informing management decision making. Developed by USGS fire scientists and executive leadership, and informed by conversations with external stakeholders, the Strategic Plan is aligned with the needs of the fire science stakeholder community–fire, land, natural resource, and emergency managers from Federal, State, Tribal, and community organizations, as well as members of the scientific community. The Strategic Plan is composed of four integrated priorities, each with associated goals and specific strategies for accomplishing the goals: Priority 1: Produce state-of-the-art, actionable fire science; Priority 2: Engage stakeholders in science production and science delivery; Priority 3: Effectively communicate USGS fire science capacity, products, and information to a broad audience; and Priority 4: Enhance USGS organizational structure and advance support for fire science. The priorities of this Strategic Plan define the USGS’s commitment to producing and delivering cutting edge fire science, information, and decision-support tools in support of national, regional, and local priorities and stakeholder needs.

Circular↗

USGS2021

Summer runoff generation in foothill catchments of the Colorado Front Range

Climatic shifts, disturbances, and land-use change can alter hydrologic flowpaths, water quality, and water supply to downstream communities. Prior research investigating streamflow generation processes in mountainous areas has largely focused on high-elevation alpine and subalpine catchments; less is known about these processes in lower-elevation foothills and montane catchments. In these lower-elevation ecoregions, precipitation shifts seasonally from snow to rain, which can result in differing seasonal flowpaths. We analyzed stream water for electrical conductivity, SiO 2 , Ca, Mg, Na, Cl, SO 4 , K, and dissolved organic carbon on both a weekly and storm event basis from April to August 2018 in three small (<10 km 2 ) foothill catchments, and one larger (63.2 km 2 ) catchment extending from the foothills to the subalpine ecoregions, in the Colorado Front Range. Using two end-member hydrograph separations and concentration-runoff relationships, we inferred the dominant catchment-scale flowpaths of precipitation to the streams. We selected catchments with varying land use to investigate the relationship between these characteristics and hydrologic flowpaths. We observed that concentrations of lithogenic constituents generally increased and dissolved organic carbon decreased as seasonal runoff decreased in the three foothill catchments, reflecting a transition from shallow subsurface flowpaths to deeper subsurface flowpaths. Elevated SO 4 and Cl concentrations during low-flow periods in two of our catchments suggest that historical or current anthropogenic activities, such as mining, application of road salt, and/or near-stream septic systems, affect local stream and groundwater chemistry. In a foothill catchment with anthropogenic and geologic impervious surfaces, streamflow during storm responses was sourced from faster, surficial flowpaths compared to a less disturbed neighboring catchment, highlighting the influence of anthropogenic land-use on runoff generation. This study provides insight into the fundamental hydrology of foothill catchments and how they may function in the future with human development, precipitation shifts and disturbances.

Colorado↗

USGS2021

Wildfires: Identification of a new suite of aromatic polycarboxylic acids in ash and surface water

Ash and surface water samples collected after wildfires in four different geographical locations (California, Colorado, Kansas and Alberta) were analyzed. The ash samples were leached with deionized water, and leachates were concentrated by solid phase extraction and analyzed by liquid chromatography/time-of-flight mass spectrometry. In addition, three surface water samples and a lysimeter water sample were collected from watersheds recently affected by fire in California and Colorado, and analyzed in similar fashion. A suite of benzene polycarboxylic acids (BPCAs), with two and three carboxyl groups and their corresponding isomers were identified for the first time in both ash leachates and water samples. Also found was a pyridine carboxylic acid (PCA), 3,5-pyridine dicarboxylic acid. Furthermore, putative identifications were made for other carboxylated aromatic acids: quinolinic, naphthalenic, and benzofuranoic acid carboxylates. The wildfire ashes, a controlled wood ash, and post-fire surface water samples suggest that burned woody material, along with surface plant-material and heated o-horizon soil organic matter, contribute to both BPCAs and PCAs in runoff. This study is the first of its kind to identify this suite of aromatic acids in wildfire ash and surface water samples. These data make an important contribution to the nature of dissolved organic matter from wildfire and are useful to better understand the impact of wildfire on water quality and drinking water sources.

Science of the Total Environment↗

USGS2020

Changes in climate and land cover affect seasonal streamflow forecasts in the Rio Grande headwaters

Seasonal streamflow forecast bias, changes in climate, snowpack, and land cover, and the effects of these changes on relations between basin‐wide snowpack, SNOw TELemetry (SNOTEL) station snowpack, and seasonal streamflow were evaluated in the headwaters of the Rio Grande, Colorado. Results indicate that shifts in the seasonality of precipitation and changing climatology are consistent with periods of overprediction and underprediction in streamflow forecasts. Multiple linear regression of SNOTEL data, postcedent precipitation, and land‐cover changes explained 2%–18% more variability in streamflow prediction than using SNOTEL station data alone. Simulated basin‐wide snowpack from a physically based model had significant negative trends in snow water equivalent (−4.33 mm/yr) and snow‐covered area (−0.05%/yr) during the melt period April–June. Simulated streamflow from a precipitation‐runoff model increased an average 5% when the effects of bark beetle‐induced tree mortality were compared to a baseline simulation with static vegetation. The effects of a 2013 wildfire increased simulated seasonal streamflow an average 35% for 1–4 years postfire. The combined effects of climate and land‐cover changes on snowpack‐streamflow relations highlight the difficulty in seasonal streamflow forecasting, which has important implications for water‐resource management.

Colorado↗

USGS2020

Atmospheric dust deposition varies by season and elevation in the Colorado Front Range, USA

As atmospheric dust deposition continues to increase across the southwestern United States, it has the potential to alter ecosystem productivity and structure by delivering nutrients, base cations, and pollutants to remote mountain sites. Due to the sparse distribution of dust monitoring sites, open questions remain about the spatial and temporal variability of dust fluxes and composition across mountainous terrain. We present a 1 year (November 2017 to November 2018) record of seasonal dust fluxes and composition from an elevation transect across the Colorado Front Range extending from the urban plains to the remote alpine. At all nine sites, dust was enriched in the essential nutrient phosphorus and the metals copper, zinc, lead, and cadmium, elements that are enriched in dust deposited at sites across the Rocky Mountain West. We observed a seasonal pattern in dust composition, with the highest concentrations of zinc and cadmium during the summer, when back trajectory modeling suggested a greater contribution of dust from local urban and agricultural regions to the east of the collection sites. During the summer, there was also a trend of higher dust fluxes at lower elevations; dust fluxes ranged from 18.9 ± 0.1 g m −2 yr −1 on the plains to 5.9 ± 0.2 g m −2 yr −1 in the alpine. Our results suggest that urban and agricultural land east of the Colorado Front Range is an important source of nutrients and pollutants to all elevations of the mountain range.

Colorado↗

USGS2020

Wildfire-driven changes in hydrology mobilize arsenic and metals from legacy mine waste

Wildfires burning in watersheds that have been mined and since revegetated pose unique risks to downstream water supplies. A wildfire near Boulder, Colorado that burned a forested watershed recovering from mining disturbance that occurred 80-160 years ago allowed us to 1) assess arsenic and metal contamination in streams draining the burned area for a five-year period after the wildfire and 2) determine the fire-affected hydrologic drivers that convey arsenic and metals to surface water. Most metal concentrations were low in the circumneutral waters draining the burned area. Water and sediment collected from streams downstream of the burned area had elevated arsenic concentrations during and after post-fire storms. Mining-related deposits were the main source of arsenic to streams. An increased proportion of overland flow relative to infiltration after the fire mobilized arsenic- and metal- rich surface deposits and wildfire ash into streams within and downstream of the burned area. The deposition of this sediment into stream channels resulted in the remobilization of arsenic for the five-year post-fire study period. It is also possible that enhanced subsurface flow after the fire increased contact of water with arsenic-bearing minerals exposed in underground mine workings. Other studies have reported that wildfire ash can be an important source of arsenic and metals to surface waters, but wildfire ash was not an important source of arsenic in this study. Predicted increases in frequency, size, and intensity of wildfires in the western U.S., a region with widely dispersed historical mines, suggest that the intersection of legacy mining and post-wildfire hydrologic response poses an increasing risk for water supplies.

Colorado↗

USGS2020

Fates and fingerprints of sulfur and carbon following wildfire in economically important croplands of California, U.S.

Sulfur (S) is widely used in agriculture, yet little is known about its fates within upland watersheds, particularly in combination with disturbances like wildfire. Our study examined the effects of land use and wildfire on the biogeochemical “fingerprints,” or the quantity and chemical composition, of S and carbon (C). We conducted our research within the Napa River Watershed, California, U.S., where high S applications to vineyards are common, and ~ 20% of the watershed burned in October 2017, introducing a disturbance now common across the warmer, drier Western U.S. We used a laboratory rainfall experiment to compare unburned and low severity burned vineyard and grassland soils. We then sampled streams draining sub-catchments with differing land use and degrees of burn and burn severity to understand combined effects at broader spatial scales. Before the laboratory experiment, vineyard soils had 2–3.5 times more S than grassland soils, while burned soils—regardless of land use—had 1.5–2 times more C than unburned soils. During the laboratory experiment, vineyard soil leachates had 16–20 times more S than grassland leachates, whereas leachate C was more variable across land use and burn soil types. Unburned and burned vineyard soils leached S with δ 34 S values enriched 6–15‰ relative to grassland soils, likely due to microbial S processes within vineyard soils. Streams draining vineyards also had the fingerprint of agricultural S, with ~2–5 fold higher S concentrations and ~ 10‰ enriched δ 34 S-SO 4 2− values relative to streams draining non-agricultural areas. However, streams draining a higher fraction of burned non-agricultural areas also had enriched δ 34 S values relative to unburned non-agricultural areas, which we attribute to loss of 32 S during combustion. Our findings illustrate the interacting effects of wildfire and land use on watershed S and C cycling—a new consideration under a changing climate, with significant implications for ecosystem function and human health.

California↗

USGS2019

Inorganic nitrogen wet deposition gradients in the Denver-Boulder metropolitan area and Colorado Front Range – Preliminary implications for Rocky Mountain National Park and interpolated deposition maps

For the first time in the 40-year history of the National Atmospheric Deposition Program / National Trends Network (NADP/NTN), a unique urban-to-rural transect of wet deposition monitoring stations were operated as part of the NTN in 2017 to quantify reactive inorganic nitrogen wet deposition for adjacent urban and rural, montane regions. The transect of NADP stations (sites) was used to collect continuous precipitation depth and weekly wet-deposition samples in the Denver – Boulder, Colorado urban corridor. Gradients in reactive inorganic nitrogen (Nr) concentrations and wet deposition were identified along the transect, which included Rocky Mountain National Park. Back trajectory modeling and stable isotopes suggested contribution of agricultural ammonia (NH3) to urban Nr wet deposition in Denver, but apportionment of wet-deposited Nr to agricultural versus urban mobile sources was not possible for this study. The results demonstrate the importance of multiple monitoring sites across an urban area in defining fine-scale geographic patterns in atmospheric deposition and its sources. Data from new sites located within 50 km of the urban area demonstrate that the urban influence doesn't extend as far as the Inverse Distance Weighting would have suggested without such empirical monitoring data. It is important to determine the radius of influence of urban emissions and associated deposition on the interpolated deposition raster, which is constrained by a paucity of monitoring sites east of Denver.

Colorado↗

USGS2018

Fire, flood, and drought: Extreme climate events alter flow paths and stream chemistry

Extreme climate events—such as hurricanes, droughts, extreme precipitation, and wildfires—have the potential to alter watershed processes and stream response. Yet due to the destructive and hazardous nature and unpredictability of such events, capturing their hydrochemical signal is challenging. A 5‐year postwildfire study of stream chemistry in the Fourmile Creek watershed, Colorado Front Range, USA, focused on high‐frequency storm sampling. During the study, the watershed was impacted by three additional extreme climate events—drought and two periods of extreme rainfall totals. These events altered concentration‐discharge relationships in ways that elucidate how hydrologic flow paths and source material availability affect stream water chemistry. Reduced infiltration after wildfire led to overland flow during thunderstorms, which conveyed ash and soil into streams. This resulted in elevated stream concentrations of constituents elevated in ash—Ca, K, Mg, alkalinity, and dissolved organic carbon—along with sediment and nitrate. Subsurface flow paths were bypassed, leading to low concentrations of Na and SiO 2 , which are bedrock derived and not elevated in ash. During drought conditions, when stream discharge was <20% of average, concentrations of sediment, dissolved organic carbon, and Ca fell below average concentrations, but SiO 2 did not. Extreme rainfall totals saturated the subsurface and led to prolonged elevated stream discharge. Concentration‐discharge relationships for bedrock‐derived constituents, such as Ca and SiO 2 , were altered in that time period, while those for dissolved organic carbon were not. Previous disturbances, including historical mining, also affect stream chemistry, and water‐quality impairment can be exacerbated by extreme climate events.

Colorado↗

USGS2018

Before the storm: Antecedent conditions as regulators of hydrologic and biogeochemical response to extreme climate events

While the influence of antecedent conditions on watershed function is widely recognized under typical hydrologic regimes, gaps remain in the context of extreme climate events (ECEs). ECEs are those events that far exceed seasonal norms of intensity, duration, or impact upon the physical environment or ecosystem. In this synthesis, we discuss the role of source availability and hydrologic connectivity on antecedent conditions and propose a conceptual framework to characterize system response to ECEs at the watershed scale. We present four case studies in detail that span a range of types of antecedent conditions and type of ECE to highlight important controls and feedbacks. Because ECEs have the potential to export large amounts of water and materials, their occurrence in sequence can disproportionately amplify the response. In fact, multiple events may not be considered extreme in isolation, but when they occur in close sequence they may lead to extreme responses in terms of both supply and transport capacity. Therefore, to advance our understanding of these complexities, we need continued development of a mechanistic understanding of how antecedent conditions set the stage for ECE response across multiple regions and climates, particularly since monitoring of these rare events is costly and difficult to obtain. Through focused monitoring of critical ecosystems during rare events we will also be able to extend and validate modeling studies. Cross-regional comparisons are also needed to define characteristics of resilient systems. These monitoring, modeling, and synthesis efforts are more critical than ever in light of changing climate regimes, intensification of human modifications of the landscape, and the disproportionate impact of ECEs in highly populated regions.

Biogeochemistry↗

USGS2018

Anthropocene landscape change and the legacy of nineteenth- and twentieth-century mining in the Fourmile Catchment, Colorado Front Range

Human impacts on earth surface processes and materials are fundamental to understanding the proposed Anthropocene epoch. This study examines the magnitude, distribution, and long-term context of nineteenth- and twentieth-century mining in the Fourmile Creek catchment, Colorado, coupling airborne LiDAR topographic analysis with historical documents and field studies of river banks exposed by 2013 flooding. Mining impacts represent the dominant Anthropocene landscape change for this basin. Mining activity, particularly placer operations, controls floodplain stratigraphy and waste rock piles related to mining cover >5% of hillslopes in the catchment. Total rates of surface disturbance on slopes from mining activities (prospecting, mining, and road building) exceed pre-nineteenth-century rates by at least fifty times. Recent flooding and the overprint of human impacts obscure the record of Holocene floodplain evolution. Stratigraphic relations indicate that the Fourmile valley floor was as much as two meters higher in the past 2,000 years and that placer reworking, lateral erosion, or minor downcutting dominated from the late Holocene to present. Concentrations of As and Au in the fine fraction of hillslope soil, mining-related deposits, and fluvial deposits serve as a geochemical marker of mining activity in the catchment; reducing As and Au values in floodplain sediment will take hundreds of years to millennia. Overall, the Fourmile Creek catchment provides a valuable example of Anthropocene landscape change for mountainous regions of the Western United States, where hillslope and floodplain markers of human activity vary, high rates of geomorphic processes affect mixing and preservation of marker deposits, and long-term impact varies by landscape location.

Colorado↗

USGS2017

Reassessing rainfall in the Luquillo Mountains, Puerto Rico: Local and global ecohydrological implications

Mountains receive a greater proportion of precipitation than other environments, and thus make a disproportionate contribution to the world’s water supply. The Luquillo Mountains receive the highest rainfall on the island of Puerto Rico and serve as a critical source of water to surrounding communities. The area’s role as a long-term research site has generated numerous hydrological, ecological, and geological investigations that have been included in regional and global overviews that compare tropical forests to other ecosystems. Most of the forest- and watershed-wide estimates of precipitation (and evapotranspiration, as inferred by a water balance) have assumed that precipitation increases consistently with elevation. However, in this new analysis of all known current and historical rain gages in the region, we find that similar to other mountainous islands in the trade wind latitudes, leeward (western) watersheds in the Luquillo Mountains receive lower mean annual precipitation than windward (eastern) watersheds. Previous studies in the Luquillo Mountains have therefore overestimated precipitation in leeward watersheds by up to 40%. The Icacos watershed, however, despite being located at elevations 200–400 m below the tallest peaks and to the lee of the first major orographic barrier, receives some of the highest precipitation. Such lee-side enhancement has been observed in other island mountains of similar height and width, and may be caused by several mechanisms. Thus, the long-reported discrepancy of unrealistically low rates of evapotranspiration in the Icacos watershed is likely caused by previous underestimation of precipitation, perhaps by as much as 20%. Rainfall/runoff ratios in several previous studies suggested either runoff excess or runoff deficiency in Luquillo watersheds, but this analysis suggests that in fact they are similar to other tropical watersheds. Because the Luquillo Mountains often serve as a wet tropical archetype in global assessments of basic ecohydrological processes, these revised estimates are relevant to regional and global assessments of runoff efficiency, hydrologic effects of reforestation, geomorphic processes, and climate change.

Luquillo Mountains↗

USGS2017

Critical zone properties control the fate of nitrogen during experimental rainfall in montane forests of the Colorado Front Range

Several decades of research in alpine ecosystems have demonstrated links among the critical zone, hydrologic response, and the fate of elevated atmospheric nitrogen (N) deposition. Less research has occurred in mid-elevation forests, which may be important for retaining atmospheric N deposition. To explore the fate of N in the montane zone, we conducted plot-scale experimental rainfall events across a north–south transect within a catchment of the Boulder Creek Critical Zone Observatory. Rainfall events mimicked relatively common storms (20–50% annual exceedance probability) and were labeled with 15 N-nitrate ( NO 3 − "> NO − 3 NO3− ) and lithium bromide tracers. For 4 weeks, we measured soil–water and leachate concentrations of Br − , 15 NO 3 − , "> 15 NO − 3 , 15NO3−, and NO 3 − "> NO − 3 NO3− daily, followed by recoveries of 15 N species in bulk soils and microbial biomass. Tracers moved immediately into the subsurface of north-facing slope plots, exhibiting breakthrough at 10 and 30 cm over 22 days. Conversely, little transport of Br − or 15 NO 3 − "> 15 NO − 3 15NO3− occurred in south-facing slope plots; tracers remained in soil or were lost via pathways not measured. Hillslope position was a significant determinant of soil 15 N- NO 3 − "> NO − 3 NO3− recoveries, while soil depth and time were significant determinants of 15 N recovery in microbial biomass. Overall, 15 N recovery in microbial biomass and leachate was greater in upper north-facing slope plots than lower north-facing (toeslope) and both south-facing slope plots in August; by October, 15 N recovery in microbial N biomass within south-facing slope plots had increased substantially. Our results point to the importance of soil properties in controlling the fate of N in mid-elevation forests during the summer season.

Biogeochemistry↗

USGS2017

A method for quantifying cloud immersion in a tropical mountain forest using time-lapse photography

Quantifying the frequency, duration, and elevation range of fog or cloud immersion is essential to estimate cloud water deposition in water budgets and to understand the ecohydrology of cloud forests. The goal of this study was to develop a low-cost and high spatial-coverage method to detect occurrence of cloud immersion within a mountain cloud forest by using time-lapse photography. Trail cameras and temperature/relative humidity sensors were deployed at five sites covering the elevation range from the assumed lifting condensation level to the mountain peaks in the Luquillo Mountains of Puerto Rico. Cloud-sensitive image characteristics (contrast, the coefficient of variation and the entropy of pixel luminance, and image colorfulness) were used with a k -means clustering approach to accurately detect cloud-immersed conditions in a time series of images from March 2014 to May 2016. Images provided hydrologically meaningful cloud-immersion information while temperature-relative humidity data were used to refine the image analysis using dew point information and provided temperature gradients along the elevation transect. Validation of the image processing method with human-judgment based classification generally indicated greater than 90% accuracy. Cloud-immersion frequency averaged 80% at sites above 900 m during nighttime hours and 49% during daytime hours, and was consistent with diurnal patterns of cloud immersion measured in a previous study. Results for the 617 m site demonstrated that cloud immersion in the Luquillo Mountains rarely occurs at the previously-reported cloud base elevation of about 600 m (11% during nighttime hours and 5% during daytime hours). The framework presented in this paper will be used to monitor at a low cost and high spatial resolution the long-term variability of cloud-immersion patterns in the Luquillo Mountains, and can be applied to ecohydrology research at other cloud-forest sites or in coastal ecosystems with advective sea fog.

El Yunque National Forest, Puerto Rico↗